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By Seshadri Seetharaman, Nurni N. Viswanathan, Haijuan Wang

The present work aims at some process modifications in specified metallurgical processes, wherein CO2 can be used successfully as an oxidant for decarburization in steelmaking and applied in some non-ferrous metals production processes. During the decarburization of Cr-containing high alloyed steels, the present researchers investigated the possible use of CO2 instead of Ar-O2 mixture and could successfully decarburize the steel melt without significant loss of alloyed Cr to the slag phase. A mathematical model was developed based on the bubble formation accompanying the chemical reaction: C(molten steel)+ CO2(gas)= 2 CO(gas). The model predictions were tested by laboratory scale (1 kg) experiments carried out in an induction furnace and very good agreement between the model predictions and experimental results were observed. A national project has been sanctioned in China for the implementation of CO2 in decarburization of ferroalloys as well enable the addition of pig iron in the electric arc furnace process when the scrap supply is limited. New processes have been developed for the utilization of CO2 in the case of non-ferrous processes. A novel method of treatment of Al dross by leaching with water and capturing the evolved NH3(formed by the hydrolysis of AlN) has shown very promising results.

Jan 1, 2015

By I. Stefanou, J. Sulem

"In the last thirty years, the study of earthquake mechanisms has emphasized the major role of rock friction. Earthquakes appear to be the result of a frictional instability and occur by sudden slippage along a pre-existing fault or a plate interface. Multiphysics couplings play a major role in earthquake nucleation and seismic slip. The effect of shear heating and thermal pressurization may be of prime importance in the control of the stability of shear deformation inside the slipping zone. Other mechanisms in relation with thermal decomposition of minerals affect the pore pressure and the temperature evolution of the system, and can play a significant role in the extreme strain localization observed in field. The actual width of the localized zone is a key parameter for understanding fault weakening mechanisms. On the basis of field observations, laboratory experiments and recent advanced modeling, these phenomena are analyzed and discussed in order to bring some new insights in the understanding of earthquakes nucleation.INTRODUCTIONIn the last thirty years, the study of earthquake mechanisms has emphasized the major role of rock friction. Earthquakes appear to be the result of a frictional instability and occur by sudden slippage along a pre-existing fault or a plate interface (Scholz, 1998; Sykes, 1978). The conceptual model of spring slider system is commonly used to represent the interaction between an elastic crustal block and a fault zone. Stick-slip instability is possible if the softening rate of the shear resistance of the fault zone is high enough as compared to the stiffness of the crustal block. Therefore, weakening mechanisms that can explain how the frictional resistance of a fault decreases with slip and/or slip rate is of prime importance to understand how an earthquake nucleates. In recent years, several drilling programs in active faults (e.g. the Nojima fault in Japan, Boullier, 2011; the Aigion Fault in Greece, Cornet et al. 2004, the Chelungpu fault in Taiwan, Ma et al. 2006, and the San Andreas fault in the U.S.A. Ellsworth et al. 2000) as well as high velocity friction experiments (e.g. Tanikawa et al 2012a; Tanikawa et al. 2012b) have highlighted the physico-chemical processes involved in the nucleation of seismic slip (see for the example the review paper of Niemeijer et al. 2012)."

Jan 1, 2015

By D. Michaud, C. Bazin, S. Lévesque, L. Pérez-Barnuevo, H. Longuepée

In recent years, with the emergence of Geometallurgy, a great effort has been made to characterize ore resources as early and accurately as possible, to allow better design and a more efficient operation of mineral processing circuits. In this context, core logging plays an important role, since drill cores provide the first insight into the ore characteristics. However, to satisfy geometallurgical requirements, traditional core logging does not suffice. New tools and methodologies need to be developed for the automation of core logging and the acquisition of mineralogical data better related to mineral processing performances. In this paper, a methodology for the geometallurgical characterization of drill cores is proposed, based on the drill core textural patterns. Textural pattern is defined here as the macroscopic spatial arrangement of minerals. The Mont-Wright iron ore deposit (Quebec, Canada) is used as a case study. The first part of this work aimed at analyzing the potential link between the iron ores textural patterns observed in drill cores and their response to ore processing, namely comminution and concentration. Preliminary results show similar performances in terms of energy consumption and heavy liquid separation for samples showing the same textural pattern. In the second part, this work seeks to develop a methodology for the automated identification of drill core textural patterns by the application of digital image analysis and discriminant function analysis. The results obtained show that this methodology is able to discriminate between the textural patterns identified at Mont-Wright with a good rate of success. Therefore, this work lays the foundation for the development of a new drill core characterization tool, which would allow for the early prediction of the iron ore behaviour during mineral processing through the identification of drill core textural patterns.

Jan 1, 2016

By W. Curlook, V. G. Papangelakis, M. Baghalha

A pressure acid leaching process has been developed for the extraction of metal values, nickel, copper, cobalt and zinc, from base metal smelter slags. The basic concept contemplates cooling the smelter slags through solidification sufficiently slowly to induce a good measure of crystallization; and subsequently, after fine grinding, to pressure leach such slags at around 250°C while applying oxygen overpressure, utilizing smelter byproduct sulphuric acid. High levels of extraction of the slags' metal values are thereby achieved. It has been shown that if the same slags are quenched thereby producing an amorphous structure, the resulting metal extractions are very low. The process is applicable to smelting furnace throwaway/discard/dump slags, as well as to in-process converter slags. By extracting the bulk of the residual base metal values in the throwaway/discard/dump slags, the resulting leached residues are rendered virtually benign vis-à-vis the external environment.

Jan 1, 2004

By S. Foged

Umicore and MWH jointly demonstrated that mechanical dewatering of goethite and neutralised tailings significantly increased the life of a 30 ha tailings pond and improved the operation of the pond. Umicore operates one of its zinc production plants in Balen, Belgium. As part of its production process, an excess of neutralised and goethite¬containing tailings is generated. These have historically been stored inside large lined ponds. As the storage area of the current goethite pond was nearing its capacity, Umicore studied the potential for an extension to the existing embankment. However, this extension would face intense regulatory scrutiny, because the environmental and safety impacts were considered important. Together with Umicore, MWH suggested and investigated an alternative treatment approach consisting of mechanical dewatering prior to storage. A feasibility study was prepared where wet storage was compared to dry storage. Differences in safety risks, environmental impacts and economic costs were outlined. The study demonstrated that the life of the tailings pond could be increased from 6 to 22 years, seriously reducing the environmental impacts and safety risks at no significantly higher cost than would have been incurred with the continued operation of the existing pond. The results of the study are presented in this paper.

Jan 1, 2006

By Brian L. Beninger

This paper discusses the application of the computer to coal preparation process predictions. In broad terms, the computer is used to perform two main functions. Firstly, the given float-sink analysis is interpolated and extrapolated to cover the entire actual range of raw coal specific gravity. Assumptions based on historical data must be made at times. Secondly, the partition curve, which, from historical data, defines the efficiency of a specific coal washing process, is applied to the washability data in order to determine the expected clean coal yield and quality. The vast amount of numerical work which is required to make a prediction of this type exhibits the need for computer methods in this area.

Jan 1, 1979

By V. L. Gravitis

Radioisotope X -ray techniques of analysis for nickel have been tested in laboratory and plant trials. In the laboratory tests. a comparison was made of radioisotope and conventional analyses for nickel in solid s samples taken from streams of a nickel concentrator. Coefficients of variation of 1.7% for feed and concentrate samples , and equal to 10% for final tailing samples, were obtained. Continuous determination of nickel in final tailing slurries was demonstrated in a trial lasting 20 days at a nickel concentrator (Western Mining Corporation), nickel being determined with a standard error of 0.036% Ni in the slurry solids within the range of 0.24 to 0.68% Ni. This error, obtained by comparison of on-stream probe analyses with assays of samples taken from the stream, includes errors in sampling and assay by conventional techniques.

Jan 1, 1977

By E. C. W. Perryman

Materials research and development has played an important role in the commercial success of the CANDU- PHW nuclear reactor and in the production of heavy water. Both capital investment and energy conservation demand very high component reliability in such systems. The interactions among reliability, plant performance and economics will be discussed in relation to materials research and development. Likely materials requirements for the nuclear industry over the next twenty five years will also be discussed.

Jan 1, 1977

By Somasundaran P., M. Vasudevan, Z. Dai, D. R. Nagaraj, T. Bhambani, P. Patra

Historically, efficient beneficiation of ultramafic ores has been challenging, partly due to a lack of clear scientific understanding of the effects of Mg silicates, particularly fibrous serpentines, on selective Ni recovery. Recent research at Columbia-Cytec as a part of a Vale JDP project has led to new insights into the mechanistic aspects of the adverse effects of Mg silicates. Our research has provided strong evidence to support the hypothesis that the adverse effects of Mg silicates are mediated through their large influence on pulp rheological properties, far more than any other pathway. The severity of the effect of Mg silicates is predominantly dependent on the aspect ratios of Mg silicates. For example, the pulp viscosity increases dramatically with increase in the fibrous nature of the gangue mineral leading to poor Ni separation. Various ways by which the suspension rheology affects flotation sub-processes, with implications for remedy are discussed. The insights and results have served to develop (or construct) a phenomenological model to adequately explain all of the ore flotation data, particularly the Mg silicate transport to the froth phase and the concentrate.

Jan 1, 2011

By R. G. L. McCready, Marco Zentilli

"Brogan coal containing mean averages of 6,93% w/w total sulphur (1.1% sulphate sulphur, 1.6% organic sulphur and 4.24% pyritic sulphur) and 16.34% mineral ash was used as the test coal in these studies.Shake-culture leaching studies on seven size fractions of the coal, ranging in size from 0.045 mm to 1.7 mm, showed that the rate of pyrite leaching was inversely proportional to the particle size. As the use of continuous stirred tank reactors would be uneconomical for the reclamation of waste coal, column leaching studies were initiated on coal sieved to >6.35 mm to < 12.7 mm, The leachate was monitored for all metal ions and the release of iron was used to monitor the rate of pyrite oxidation . Measurable amounts of Zn, Co, Ni, Mn, and V, all of which can replace iron in the pyrite crystal structure, were released during the initial stages of leaching. Further, high concentrations of AI, Ca and Sr and trace amounts of Sn, As. Se, B, Ca, Cr, Si, and Ti were detected in the column effluents.These studies suggest that bacterial leaching will remove the pyrite and qualitative amounts of environmentally undesirable trace metals from the coal if such a process is developed for waste coal reclamation.IntroductionIn 1947, Colmer and Hinkle showed that acid mine drainage was the result of an oxidative attack of the iron-mineral sulphides by Thiobacillus ferrooxidans to produce sulphuric acid . Ashmead (1955) proposed the use of these organisms to desulphurize coal , but the subsequent research effort was concentrated on the metabolism and physiology of these extreme acidophiles.A limited number of studies have been reported on the bacterial leaching of pyrite from coal (Silverman et al., 1963; Dugan, 1977). However, the bacterial oxidation of pyrite is a self-limiting first-order reaction, probably due to the precipitation of Fe(OH)J and elemental sulphur , which progressively inhibits intimate contact between the bacterial cells and the sulphide-mineral surface. Consequently, the best pyrite oxidation experiments with coal reported to date required five days to remove 97070 of the pyrite (Dugan &Apel , 1978) using mixed cultures of T. ferrooxidans and T. thiooxidans."

Jan 1, 1985

By A. D. Burns, K. M. Nikolaisen

Electrolytic reduction followed by the addition of sulfuric acid and the application of heat can be used to selectively crystallize uranous sulfate from solution. This approach, when coupled with downstream thermal decomposition, forms the basis of a process for primary uranium recovery and purification where much of the sulfuric acid value can be recovered and recycled. In this process, a purified uranium (VI) leach solution is first electrolytically reduced to uranium (IV) in a membrane electrolysis cell. Sulfuric acid is then added to the solution which, in conjunction with the input of heat, causes the crystallization of uranous sulfate tetrahydrate. The precipitate is then dried and thermally decomposed to U3O8, which releases a mixture of high-purity SO2, SO3, oxygen, and water vapour. This gas can be recovered as sulfuric acid in an existing acid plant, processed through a new wet sulfuric acid process, or absorbed directly into the upstream electrolyte as a substitute for fresh acid in the crystallization step. This process has been shown to be practical, efficient, and cost-effective on the laboratory scale, and could be practiced on the industrial scale using commercially available equipment. This paper focuses on the thermal decomposition process and options for acid recovery.

Jan 1, 2020

By Dart Wantland

"AbstractThe scope of geophysics in civil engineering and the nature of exploration geophysics are briefly discussed. Engineering problems amenable to geophysical attack are illustrated by specific examples. The various methods available, accuracy of results, and costs are treated. The possibilities of new uses of geophysical techniques are pointed out.IntroductionTHE SCOPE of geophysics in engineering is different than in oil or mining exploration. In civil engineering, geophysics solves specific problems; as for example, what is the depth to bed-rock along the axis of a proposed dam? The area to be surveyed is of limited extent, and the subsurface information .sought is relatively near the surface. The engineering geophysicist is not called upon to investigate geological basins or extensive mineralized areas or to probe for data to thousands of feet in depth. The geophysical tools employed in the three fields are, however, quite similar; the differences are mainly in the objectives.The Natural Geophysical ExplorationThe terms geophysics and geophysical exploration have been used heretofore and will .be employed in what follows. The question is, therefore, What is geophysical exploration?Geophysical exploration is a line of field work where measurements are made at the ground surface with special instruments to get geological subsurface information. Briefly stated, geophysics is a form of exploration that supplements geological work. It is a blend of physics and geology since physical measurements are made •at the surface of the ground that can be interpreted in terms of subsurface conditions."

Jan 1, 1953

By J. Kouam

Al-Si-Cu and Al-Si-Mg alloys are widely used in several applications. Although they can be produced near-net-shapes, products made of these alloys very often require some machining. The purpose of this study is to evaluate the machinability of A319 and A356 under TO and T6 conditions. The machinability was assessed using during dry drilling machining process and the machinability indexes used are the chip form, the chip breakability and the cutting forces. It is found that 319 and 356 exhibit different machinability behaviors, especially in the T6-condition in terms of forces requirements, chip breakability and chip segmentation. It is also found that both the microstructure of the workpiece materials and the machining conditions significantly affect the chip formation mechanism, and therefore, the machining parameters could be selected to promote a chip form that is easily manageable in production.

Jan 1, 2011

The fracture behavior of second phase particles and the role of matrix material on the wear resistances of the three Al-Si alloys containing 8, 17, and 19% Si were investigated using single pass scratch testing technique by applying normal loads between 0,15 and 5,00 N, in ambient air, Optical microscopy and SEM with EDS were used to analyze microstructures and morphologies of scratch tracks of the Al-Si alloys, The results showed that needle-like Si particles fractured under a load of 0.50 N, while block-like Si particles fractured at loads above 3,00 N, The Al-17% Si alloy with large number of needle-like particles (area fraction 16,4%) exhibited the highest coefficient of friction (0,8) and the widest scratch track, The Al-19%Si alloy containing high Si percentage and larger number of block-like particles (area fraction 16%) exhibited the lowest coefficient of friction (0,37) and the narrowest scratch track width. Presence of block-like particles was effective in reducing the amount of material transfer from Al-Si alloy surfaces to the counterface.

Jan 1, 2005

By K. A. Clark

"The repacked mineral aggregates of good grade oil sands have permeabilities ranging between 15 darcys to 350 millidarcys. The variation is due to the silt contents of the aggregates. Few good grade oil sands contain as much as 30 per cent •silt, most of them contain less than 20 per cent, and a large proportion have less than 10 per cent.The permeabilities of repacked good grade oil sands (oil included) depend on the degree of liquid saturation. When saturation with oil plus water reaches between 80-90 per cent, permeability is reduced to zero. As total saturation decreases below 80 per cent, permeability increases ranidly. Permeabilities of between one and two darcys were observed for total saturations between 60-70 per cent.The mean value for 18 measurements of the permeabilities of ""undisturbed"" core samples of good grade oil sands was 50 millidarcys. This value is •probably too high. The mean value for 20 measurements on core samples of interbedded oil sand and shale was 100 millidarcys. The mean value for 11 measurements on shale was 10 millidarcys."

Jan 1, 1960

By Martin Lebeuf

The phenomena occurring in the cathode and at the cathode surface of aluminum electrolysis cells are very important in regards to cathode voltage drop and cathode wear. In the current study, laboratory-scale aluminum electrolysis cell cathodes were analyzed by X-ray microtomography. This technique allows an excellent visualization of the distribution of different substances, if their respective X-ray attenuation coefficients are different enough. In the current case, the important difference in the mean atomic number between cryolitic bath and graphitic carbon results in good contrasts. The volumetric bath penetration profile, porosity and impurities distribution in the cathode were thus obtained. Furthermore, metallic impurities and bath heterogeneities were observed at the cathode surface. Observations were also made with Scanning Electron Microscopy - Energy Dispersive Spectroscopy (SEM-EDS).

Jan 1, 2011

By Henri-Loui Jacob, Suzie Nantel

"Depuis la fin des annees 1800, la province de Grenville represente pour Ie Quebec une source importante et diversifiée de minéraux industriels. Le Ministère de l&apos;Énergie et des Ressources du Québec, dans Ie cadre de I&apos;entente auxiliaire Canada-Québec, et les compagnies minieres y ant multiplié, surtout depuis 1983, leurs travaux d &apos;exploration, de cartographie, et d&apos;évaluation pour les minéraux industriels. Ces travaux ant conduit ala découverte et ala mise en valeur de gisements de granite architectural, de graphite, de dolomite et ant aussi permis de repertorier des gîtes et des indices prometteurs de wollastonite, de silice, de calcite. de dolomite, de silicates d&apos;alumine et de terres rares. Les gisements récemment découverts sont actuellement exploités au sur Ie point de l&apos;être et les gîtes et les indices les plus prometteurs ant été jalonnés.ABSTRACTSince the late 18oos, the Grenville Province in Québec has been an important and diversified source of industrial minerals. The Ministere de l&apos;Énergie et des Ressources du Québec, under the Canada-Quebec Mineral Development Agreement, and the private sector have put an emphasis on exploration, mapping and evaluation programs in the Grenville Province for minerals, particularly since 1983. These programs have led to the discovery and the development of deposits such as architectural granite, graphite and dolomite, and have also led to inventories of occurrences and prospects of wollastonite, silica, calcite, dolomite, alumina silicates and rare earths. The deposits discovered lately are presently being quarried or will be in the near future. The most promising occurrences and prospects have been claimed."

Jan 1, 1990

By S. C. Ellis

THE bituminous sand of northern Alberta has already an extensive literature, and most of the reports dealing with the subject are still available (see Selected Bibliography at end of paper). A phenomenon so striking and, as regards its extent, so unique, as the deposit in the vicinity of McMurray settlement could not fail to attract the notice of the early explorers, and we find references to it as far back as the latter part of the eighteenth century. However, scarcely a thought had been bestowed upon the possible economic value of minerals in the the remote northern parts of Canada before the second decade of the present century, and practically no detailed mapping had been done north of the town of Athabaska. The late Wm. Ogilvie made a track survey of Athabaska river in 1884, and surveys of certain lines-including the 23rd base line-had been completed by 1911. Between this base line and lake Athabaska, nothing had been attempted. Actually, no definite information at all was available regarding the character and extent of the bituminous sand when, in the earl y summer of 1913, a reconnaissance party set out from Athabaska for McMurray. At that period, the journey was made in summer by scow or canoe. No telegraph line had been laid, and a casual mail service by canoe or dog team once in three months formed the only means of communication with the outside world. The investigation has begun by the Mines Branch was continued during several subsequent years. The sand deposits were studied and sampled, the bi rumen was extracted from the sand and studied chemically and physically, and the economic significance of the deposit was given exhaustive study.

Jan 1, 1937

By A. Brown

THIS P APER has been pre-pared as a progress report on Mines Branch investigations into problems of ground stress in certain co al mines of Western Canada. As such, it should be considered as a companion report to the one ( 1) presented to the Mining Society of Nova Scotia in 1956 and which dealt with similar investigations in the coal mines of Eastern Canada. For the past 50 years, dynamic incidents in the form of &apos;bumps&apos; and &apos;outbursts&apos; have been occurring in the coal mines of the Inner Foot-hills belt of tl1e Canadian Cordillera. As these phenomena generally become more frequent with in-creased thickness of overburden, a limiting depth of mining of 2,500 feet has been set (2) for estimating recoverable reserves of coal. If such a view were accepted, from a long-term viewpoint very large resources of coking-grade ?coal -in a part of the continent deficient in such coals -would not be available to the nation. The terrain in which these in-6dents take place may be described in geological terms as being dominated by pronounced structure in strata ?consisting of a large proportion of highly indurated rocks. The Geological Survey of Canada has co-operated by carrying out structural studies (3) at the mines, supplemented lithological by stratigraphic observations.

Jan 1, 1958

By R. Carter, C. S. Samis

"SummaryThe results of this investigation indicate that the gold in the cyanide tailing of refractory gold cyanides is occluded in fused •particles formed during roasting. This conclusion was reached following microscopic examination of calcines produced at various furnace temperatures with different atmospheres, and a •comparison with calcines produced by decomposing samples of completely sulphated concentrate under conditions such that the maximum particle temperature varied between 6•50°C. and 1,100°C. This comparison showed that the particle temperature during a normal roast may be several hundred degrees higher than the furnace atmosphere, or that the fusion is associated with a low melting (950°C.) eutectic mixture of FeO and FeS.Because of the unavoidable particle fusion during a furnace roast, and because low particle temperatures are essential for gold extraction by cyanidation, aqueous medium oxidation under high oxygen pressures was studied. Gold recovery from calcines produced by this means was over 98 •per cent •compared with a maximum of 80 per cent from furnace calcines.IntroductionMANY arsenical gold ores are called 'refractory' because much ' of the gold cannot be satisfactorily extracted by cyaniding the raw ore or concentrate. Even when such ores are roasted to oxidize .the iron and arsenic and 'release' the gold, often 10 to 25 per cent of the gold present is lost in the cyanide residues."

Jan 1, 1952