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In terms of throughput, product size and power draw, grindcurves provide a measure of the response of the mill performance to changes in mill operating parameters ? usually mill filling. Since presenting the principle in 2006, grindcurves have been applied to a wide variety of AG and SAG mills. Mill response has been carefully measured for variations in: mill fillings from 15% to 40%; throughput by a factor of two; power by 50%; feed blends; liner profile; and mill speed from 65% to 80%. The outcomes of this extensive program of work are presented as the measured grindcurves. How they have enhanced our understanding of mill operation and how they may be applied to practical daily mill control is discussed. It is proposed that this technique provides a viable and valuable mill control tool that may find extensive application in the industry.

Jan 1, 2012

By E. M. Stiles

Introduction The papers that follow deal with recently completed major improvements in practices at the Sullivan operations in Kimberley. The papers have been prepared by members of the Consolidated Engineering Staff and outline the construction programme which has been in progress for the past three years, entailing an expenditure of some millions of dollars. Four major operational changes have been brought about in the mine and concentrator. They are: (1) A change in backfill procedure for filling stopes below the 3900 level. (2) A 12,000-ton,per-day sink-float plant at the concentrator. (3) A new haulage system from the mine to the concentrator. (4) A completely new crushing plant and ore storage facilities located underground. A brief outline of the background and history leading up to this overall project will be given to show how each started as an independent betterment and how they were finally co-ordinated into one major programme. The first of these, namely, the necessity for backfilling stopes below the 3900 level, was the most pressing problem. All filling to date bad been done above the 3900 level, where mining was carried on in an irregular pattern of open stoping. Stopes below the 3900 level were first opened in 1940 and are being worked on a regular pattern of panel sub-level open diamond drill stopes. The two areas are separated by a sill pillar traversing the entire length of the vein at the 3900 level elevation.

Jan 1, 1950

By A. N. Shen

Fe3A1 intermetallics are potential inexpensive candidate for hot applications. In this project, torsion tests on hot-rolled and annealed Fe3A1 (Fe-15.5A1-5.8Cr-1.0Nb¬0.05C) were carried out over the ranges 750-950°C and 0.01~1s-1 . The experimental results showed that when peak stress op>90MPa (LogZ>16s-1 , Z: temperature-compensated strain rate), specimens cracked at randomly low strains. Optical microscopy exhibited original elongated grains and many grain boundary cracks associated with segregation. With op<40MPa (LogZ<16s-&apos;), specimens deformed with low random op but considerably high fracture strains; slowly propagating cracks may explain the reduced flow stress. Optical microscopy showed both elongated grains and equiaxed subgrains with some indications of geometric dynamic recrystallization (gDRX) and of static recrystallization (SRX). Compression tests gave higher stress with little effect of the preexisting cracks. The activation energy Quw of current material in satisfactory torsion and compression tests is about 10% higher than previously published. Fe3A1 has body-centered cubic structure in the experimental range, so it was compared with ferritic stainless steel 434C (Fe- 16.55Cr-0.96Mo-0.21Ni). Constitutive constants and restoration mechanism are compared between these materials. While Fe3A1 is hardly a light metal, it is considerably lighter than most steels. Furthermore, like the other body centered cubic metals (BCC) (a-Fe, ß-Ti, ß-Zr and ß-brass), it exhibits a high degree of dynamic recovery (DRV) like Al alloys, producing easier hot workability than that of austentic stainless steels.

Jan 1, 2007

By M. C. Harris

The past twenty to thirty years have seen unprecedented research activity aimed at understanding the performance of flotation froths. In 1990, Finch and Dobby coined the term froth recovery factor, Rr, to represent the efficiency of the froth in delivering particles from the pulp-froth interface to the concentrate. Originally defined for flotation columns, Rr has also been found useful in modeling mechanical flotation cells, and a number of techniques, based on quite different approaches, have been developed for measuring the froth recovery in industrial flotation cells. None of these techniques is universally successful. This paper reviews the concept of the froth recovery factor, and the basis of each of the techniques that have been proposed to measure Rr, and examines the reasons for this parameter being so difficult to pin down. Advances in Mineral Processing Science and Technology Proceedings of the 48th Annual Conference of Metallurgists of CIM Sudbury, Ontario, Canada Edited by

Jan 1, 2009

By D. Van Tonder, C. Edwards

ABSTRACT Solvent extraction is used in many acid leach uranium circuits to upgrade and purify the uranium-bearing solution prior to final product precipitation. A number of strip options are available to recover the uranium from the loaded organic. This paper compares seven of these options on the basis of typical capital and operating costs for the solvent extraction circuit and downstream uranium processing and also considers other related issues. The aim is to provide an objective comparative assessment of these options that could be used as a qualitative guide in process selection or improvement.

Jan 1, 2013

By Dennis Hoffmann

"Abstract - Banded iron formation rocks associated with massive sulfide lenses in the Broken Hill Pb-Zn-Cu-Ag deposit in the Namaqualand Metamorphic Complex, South Africa , were investigated with respect to the geochemistry of manganiferous silicate-rich bands. Two common varieties of these are: amphibole- and garnet-rich iron formation bands. The results reveal that the former are enriched in Fe, Mg, Cu, Co and S. The garnet-rich bands are enriched in Mn, Ca, P, Pb and Ba with significant detrital contamination of Ti, Al, Zr, Cr, Y, V, Ni and Nd.The silicate-rich bands have compositions, in terms of, Si/Al, Si/Fe, Fe/Mn, La/Ce and Co/Zn, comparable to submarine chemical sediments which precipitated from hydrothermal fluids. The garnet­ and amphibole-rich bands are interpreted as ""evolved"" and ""immature"" hydrothermal sediments, respectively. The latter resulted from rapid precipitation after exhalation, whereas the former had a longer residence within sea water. The silicate-rich bands both exhibit increasing Mn/(Mn+ Fe) fractions, which are consistent with a variation expected from proximal to distal depositional settings. The prevalence of garnet-rich bands over amphibole-rich bands is interpreted as the result of injection of hydrothermal fluids from a single vent situated along the northwest margin of the Broken Hill deposit."

Jan 1, 1994

By J. -C. Parisien-La Salle, D. Blais, G. P. Demopoulos

"In this work the dissolution, precipitation and adsorption behaviour of gold in acidic iron sulphate media containing small amounts of chloride ions is investigated via batch laboratory tests and OLI thermodynamic calculations over the temperature range 25-250°C. Chloride ions may be present in industrial pressure oxidation/pressure leaching (POX/PL) operations due to elevated water salinity levels or due to intentional addition as is the case of the CESL Copper Pressure Leaching Process. Thermodynamic calculations show that AuCl4 - may form depending on the free Cl-/Au ratio and temperature, its stability increasing with increasing Cl- concentration and decreasing with increasing temperature. On the other hand during POX/PL, we know that massive precipitation of iron in various hydrolysis products and compounds occurs. Hence of interest is the question how AuCl4 - that may form during leaching interacts with the iron precipitation products. Gold(III) chloride was found to co-precipitate with iron(III) (oxy) hydroxides and arsenates forming in the autoclave but not with natrojarosite. Upon further investigation it was discovered that activated carbon added in the autoclave (as done in CIL) acts as preferential sink for the mobilized gold, hence opening the potential for the development of a direct cyanide-free gold recovery process in acidic sulphate leach reactors.INTRODUCTIONThe recovery of gold from ores and concentrates has evolved over the years with processing routes becoming increasingly complex. Given the high value of gold, any reduction in losses during recovery operations constitutes an important economic benefit. One such loss that needs to be addressed is the potential solubilisation of gold during pressure oxidation (POX) of refractory sulphidic gold feedstocks. For example, Agnico Eagle Mines reported a loss in gold recovery due to the formation of a gold chloride complex (Garofalo, 2009). Gold is known to form complexes in solution, such as gold(III) chloride, if an excess of chloride ions are present. The fate of such soluble gold chloride during pressure oxidation and the subsequent neutralization of the acidic discharge slurry will determine if gold is lost or recovered in the downstream cyanidation operation. Thus it is of interest to know under what conditions gold chloride may stay soluble or co-precipitate along primary (formed in the autoclave) or secondary (formed during neutralization) precipitates. Furthermore, the mode of co-precipitated gold, such as adsorption on iron compounds, like goethite and hematite (Machesky et al., 1990; Nachayev, 1984); substitution in one of the precipitated phases; or finally chemical reduction to metallic state would have consequences in terms of gold recovery."

Jan 1, 2012

By J. Font

The RAF or copper fire refining process at the Caletones smelter of CodelcoChile consists of several pyrorefining stages that successively lowers the levels of S, Fe, Pb, As, Sb, Te, Se and to some extent 0 in the copper melt, allowing the production of high quality fire-refined copper of 99.93 % purity (RAF copper). This chemical feature of the RAF copper is only achieved by quite long processing times, and a considerable consumption of fluxes and fuels in the RAF vessels. The main goal of this study was to improve the RAF process performance by thermodynamic considerations and industrial scale tests, i.e., an in situ approach for the process as featured by intensive sampling, characterization and subsequent modifications. Thus, both theoretical and industrial data were derived, and based on kinetic and thermodynamic evaluations, a higher operational standard was achieved for the RAF process. These new operational practices allowed enhancing the overall economic of the RAF process, by reducing the time and operational costs, and consequently increasing the availability of the vessels.

Jan 1, 2007

By H. Assadi, S. Reutzel, D. M. Herlach

Intermetallics exhibit unique solidification behaviour due to their chemical longrange order. This includes, for instance, generally slow solidification kinetics, and in some cases, an anomalous partitioning behaviour. In the present work the electromagnetic levitation technique - complemented by theoretical modelling - is used to explore various aspects of this behaviour, as observed in solidification of B2 phase in undercooled melts of the Ni-Al system. Moreover, a phase-field model is developed and used to illustrate the effect of chemical order on the solidification kinetics of a B2 phase in a model system. The phase-field model provides an additional basis for the simulation of solidification microstructures in intermetallic forming systems. Both experimental studies and theoretical work signify the role of chemical order in solidification of intermetallics.

Jan 1, 2006

By M. Potesser

In the past, different furnace types have been developed for use within the copper industry, with two common anode furnace designs typically used in copper smelting plants worldwide: the tiltable reverberatory furnace (KPO) generally used for the secondary copper industry and the cylindrical or drum type anode furnace (TRO) for handling a liquid blister charge generated in primary copper production. The disadvantage of the KPO is its design related to the longer refining period, because of the low bath depth, however it provides good conditions in the melting period due to its large bath surface. On the other hand, small amounts of scrap charged into the TRO increase the melting and dissolution period, but it provides good conditions for the refining period. The newly-developed elliptical furnace concept (TRE) offers the advantages of each of these furnace types. The special design allows melting of the scrap more efficiently than in the KPO and refining the liquid copper more efficiently than the TRO. This paper shows a metallurgical comparison of the three furnace types in regard to the melting period by heat technological considerations (optimized arch design) and of the refining period done by CFD with concentration on current, recirculation and dwell time of the gas in the melt. The paper outlines the possibilities for a reduction of the tap-to-tap time and energy consumption as well as for an increase of the production capacity, which can be achieved by applying the TRE instead of the conventional furnace designs.

Jan 1, 2007

By A. M. Salomon de Friedberg

With respect to impurities, HBM&amp;S&apos; copper smelter, located in Flin Flon, Manitoba, is in an unusual position. In addition to the usual concerns, the fact that copper and zinc production at Flin Flon is closely integrated results in the unique situation where feed to the copper smelter typically contains 7% to 8% zinc. This paper discusses the ramifications to copper smelter operations resulting from the marriage of HBM&amp;S&apos; metallurgical plants. Distributions of impurities (specifically Zn, Pb, Ni, As, Bi, Sb, and Cd) are presented and operating practices designed to reduce the impact of impurities on anode copper quality are detailed.

Jun 1, 1993

By A. Berry, N. R. Banerjee, C. S. Finnigan, M. Fayek, N. J. Bridge

Lac Cinquante is a mineralogically simple, vein-hosted uranium deposit in Archean basement rocks (Angikuni greenstone belt) that originally were unconformably overlain by Proterozoic sedimentary and volcanic rocks of the Baker Lake Group (BLG). Basement rocks are mainly pillowed and massive tholeiitic lavas (N-MORB) with interbedded tuff; overlying sedimentary rocks comprise a basal talus/fault breccia that grades upward into fluvial sedimentary rocks and subaerial, trachytic volcanic rocks; granite and porphyry dikes (Hudson and/or Nueltin granitoids) intrude the basement rocks. A typical section through the Main Zone comprises 1) laminated ‘tuff’, 2) altered (carbonate-hematite-chlorite) schistose ‘tuff’, 3) a pitchblende-bearing, breccia-vein, 4) altered ‘tuff’, and 5) laminated ‘tuff’. The vein comprises brecciated chlorite, hematite, and pitchblende with carbonate cementing the breccia. Graphitic ‘tuff’ with sulfide-stringer veinlets locally overlies or underlies the vein. Pitchblende also occurs in the altered rocks and in gash veins that cut basement rocks. U-Pb ages on pitchblende fall into two groups: one at 1828 } 29 Ma reflects primary uranium mineralization, and a second at 1437 } 31 Ma represents resetting. Pb-Pb chemical ages show other resetting events at 1260-1321Ma, 895 Ma, 741-813 Ma, and 660-706 Ma. One possible genetic model for the Lac Cinquante deposit involves leaching of uranium from granitoids and the BLG by basinal brines that migrated to depositional sites where graphitic rocks acted as a reductant. A second model requires that uranium was sole-sourced from the BLG and that granitoid rocks provided heat to drive the hydrothermal system, which leached and ultimately precipitated uranium. The deposit has characteristics similar to vein-type uranium deposits in the Beaverlodge District of Saskatchewan

Jan 1, 2013

By F. C. Lendrum

Introduction The property of Normetal Mining Corporation is in Desmeloizes township, Quebec, twelve miles north of Dupuy on the main line of the Canadian National railway from Quebec city co Cochrane, Ontario. The ore bodies occur within a band of highly sheared and sericitized agglomerate which strikes N.60°W. and clips 82° north. Along a zone 1,000 feet or more in length and of variable width, the agglomerate has been replaced by copper, zinc, and iron sulphides, with copper usually predominant on the hanging-wall side and pyrite replaced in part by sphalerite on the footwall. A northsouth diabase dyke cuts through the ore zone near its east end. The Normetal mill produces a copper concentrate and a zinc concentrate which are shipped, respectively, to Noranda, Que., and Newcastle, Penn., U.S.A., for further treatment. The present paper deals with the milling of ore from what is known as No. 3 orebody. This is a lenticular body of high-zinc ore lying co the east of the diabase dyke, along the line of strike of the main ore zone, which extends westward from the dyke. On its northern side, No. 3 orebody is in contact along most of its length with a narrow band of copper ore which is highly oxidized.

Jan 1, 1948

By D. Sammut, F. Houllis, J-L. Huens, J. Moyes

The Intec Gold Process has been developed as a halide-based alternative for the recovery of gold from refractory sulphide deposits. The halide medium allows sulphide oxidation and gold extraction to be performed concurrently at moderate temperature and atmospheric pressure sourcing oxygen from direct air injection. The dissolved gold is loaded onto activated carbon and stripped in a conventional Zadra circuit. High gold extractions have been achieved from a range of refractory gold concentrates at laboratory scale, which has led to a continuous locked-cycle pilot plant program. The pilot plant operated at >99% availability, with a maximum of 96.5% gold extraction from a concentrate containing 58.6 g/t gold. >99% of the dissolved gold was loaded onto carbon at up to 1% w/w, with no loss of carbon activity detected over five loading/washing/elution cycles. This paper describes the process and presents both laboratory and pilot plant results as well as economic data from two costing studies.

Jan 1, 2005

By S. J. Cook

Copper, a world commodity, and the first metal used by man, played a great part in the beginnings of modern civilization, which rests so dependently on the utilization of metals. Then, long after the close of the so-called &apos;bronze age,&apos; when iron and steel had attained great prominence as the world&apos;s most important metals, the practical application of electricity to industry and commerce, for the improvement of every phase of man&apos;s multitudinous activities, gave a new impetus to the production of copper. Improved metallurgical practice made it possible to work low-grade properties at a profit. Research disclosed many new uses for copper. The metal, now produced from the mines of the world in the proportion of about one pound to every 50 tons of pig iron, has attained an importance which rivals that of iron and steel in the commerce and daily life of every nation. New fields of copper-bearing ore have been discovered in Canada in recent years. Established mines in the United States and Chile are producing on a great scale. Africa looms up as one of the great question marks in the future of copper. Whereas, a few years ago, the end of the world?s resources was predicted as being in sight, the evidence now available seems to show that the copper production of the world is likely not only to continue, but to increase for a long time yet to come. Canada&apos;s future in copper is a great subject; in the present paper only a few of the most outstanding factors affecting Canada&apos;s destiny in this large field may be noted, but if consideration of the points raised herein serves to focus attention on the magnificent possibilities of Canada as a producer of copper, the preparation of the paper will be more than justified.

Jan 1, 1928

By O. Engler, J. Friis, S. J. Andersen, C. D. Marioara, Y. Aruga

"This work investigates the early stages of precipitation in Al-Mg-Si alloys using a combination of high angle annular dark field scanning transmission electron microscopy (HAADF-STEM), selected area electron diffraction (SAED) and density functional theory (DFT) calculations. Quenching from a high temperature (solution) treatment leaves an alloy in a high-energy unstable state, with solute and vacancies in supersaturation. Thus, already at room temperature (RT) a large driving force exists for solute atoms to cluster and order on the Al matrix positions. DFT calculations indicate that strain alleviation is important at this stage. We observe larger regions of Mg-dominated L10 ordering together with a Si-dominated ordering of smaller clusters in a particular geometry connected to the Si-network found in all the precipitates. In addition, building blocks of the main hardening phase ?'', stabilized by vacancies, are observed at higher, typical pre-aging temperatures.INTRODUCTION Al-Mg-Si (6xxx) alloys are widely used in industry due to a combination of favorable properties such as strength, ductility, corrosion resistance and lightweight. They undergo a complex production route, usually consisting of the following thermo-mechanical steps: casting, homogenization, extrusion or rolling, solution heat treatment (SHT) and artificial aging (AA). The SHT takes place at temperatures above the solvus line in the phase diagram, usually between 500°C and 570°C, followed by a rapid cooling to RT. This ensures that high amounts of solute atoms, uniformly distributed on the cubic face-centered (FCC) Al lattice, together with a large amount of vacancies, are quenched-in. The material is therefore in a super-saturated and unstable state. During the subsequent AA, at temperatures usually between 150°C and 220°C, the solute atoms diffuse and cluster, forming metastable precipitates with needle/ lath/ rod morphologies having the main growth direction along <100>Al. With a maximum alloy solute level (Mg + Si) of only 2%, these precipitates increase material strength up to three times that of pure Al, and are essential for the final material properties. To understand and make better use of this phenomenon, it is imperative to research the nature of the precipitates (such as their atomic structure), measure their key parameters (number density, size, volume fraction) and connect it to material properties (Marioara, Andersen, Zandbergen & Holmestad, 2005; Marioara et al., 2014). The following precipitation sequence is given for the Al-Mg-Si system:"

Jan 1, 2018

By K. B. Young

Possibly the most complex fatigue problem associated with the development of the axial-flow &apos;gas turbine is discussed in its broader aspects from the metallurgical viewpoint. Reference is made to nodal patterns, interference diagrams, etc. The use of such data in analysis of a turbine :blade failure is illustrated. Special attention is given to the influence of some metallurgical variables affecting fatigue strength and, in particular, heat treatment is shown to have a pronounced effect on .the relative fatigue and creep strength properties of a nickel-chromium-cobalt base alloy suitable for turbine blade applications.

Jan 1, 1958

By V. ?. Chanturiya, I. Zh. Bunin, M. V. Ryazantseva

"Surface changes in naturally occurring metal sulfides (pyrite, arsenopyrite, sphalerite, chalcopyrite, galena, and molybdenite) due to treatments from high-power electromagnetic pulses (HPEMP) at varying times were studied using X-ray photoelectron spectroscopy. Analysis of the obtained results revealed common patterns and differences in surface transformations. The transformations were found to include two main stages. The first stage was observed at low treatment intensities (up to n ~103 pulses). At this stage, formation and accumulation in the surface layer of the nonstoichiometric sulfide phase, oxides and hydroxides, as well as elemental (polysulfide) sulfur and/or metastable sulfur species (thiosulfate, sulfite) was observed. The second stage (N = 3·103 pulses) is characterized by thermal removal of sulfur species and renewal of the mineral surface (sulfidization).It was found that the chemical changes of the sulfur on the surface layer of pyrite, arsenopyrite, chalcopyrite included accumulation/formation of S0 (Sn 2-) at the first stage of the transformation, followed by its removal. An increase in the surface concentration of elemental sulfur for pyrite and chalcopyrite was 10–12% while arsenopyrite was approximately 5%. A more complicated chemical change was observed for sphalerite and galena, that included formation/accumulation of metastable sulfur species (thiosulfate, sulfate) at the initial stage (up to 103 pulses) and during longer treatment times, the sulphur is reduced back to its initial state (sulfide or disulfide). The increased concentration of S0 sulfur, compared to the original sample, was only 3% in galena and sphalerite.The application of HPEMP treatment to improve flotation selectivity is supported by singlemineral flotation tests. Changes in flotability as a result of HPEMP treatment are principally explained by surface phase changes that resulted in higher adsorption activity."

Jan 1, 2016

By K. Ohto, B. B. Acihikari, H. Kawakita, M. Gurung, S. Alam

Two kinds of adsorbents were prepared from persimmon tannin extract to investigate their adsorption behavior of metal ions from hydrochloric acid solution; one was prepared by treating with concentrated sulfuric acid while another was prepared by immobilizing functional groups of quaternary amine. The former adsorbed only gold(III) and its maximum adsorption capacities was evaluated as high as 1510 g/kg while the latter adsorbed not only gold(III) but also palladium(II) and platinum(IV), the maximum adsorption capacities of which were evaluated as 820, 89 and 101 g/kg, respectively. For both adsorbents, practical adsorption of base metals was not observed.

Jan 1, 2011

By C. Rodgers, E. (Ted) Warren

"LocationThe Key Lake operation of Cameco Corporation is located at latitude 57°N in northern Saskatchewan, within the southem boundary of the Athabasca formation. The nearest city is LaRonge, located 240 km to the south. Access to the mine is by all-weather road and by private airstrip.Description of OperationThe mill was designed to produce twelve million pounds of uranium oxide (U3O8) a year from a feed grade of 2.4% U3O8. Current production is fourteen million pounds from 2.0% feed.Following grinding, the uranium is leached using sulphuric acid and oxygen in autoclaves. An eight thickener counter current decantation (CCD) circuit is used to separate the uranium-bearing solution from the solid waste residue. The uranium in solution is further purified in a solvent extraction circuit. The purified uranium is then precipitated using ammonia, calcined at 840°C, and packaged in drums for shipping to refineries. There is a crystallization circuit to recover excess ammonium sulphate produced in the process, and a waste treatment circuit.HistoryUranerz Exploration and Mining discovered the Gaertner and Deilmann orebodies in 1975 and 1976, respectively. Between 1975 and 1977, Uranerz conducted laboratory studies and delineated a process for the Key Lake ore known as the ""Bonn process."" In 1977, Sherritt Gordon Mines Ltd. was retained to conduct further studies in cooperation with U ranerz. The technical feasibility of the Bonn process was generally confirmed. Howeve1~ alternative processing methods also appeared feasible, and over the period 1978-1979, a detailed research and development program was conducted to finalize the processes to be used and to provide data for design of the plant."

Jan 1, 2000