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By M. P. Tixier

Abstract In a review of the application of electrical logging in Canada, examples are .given of long and short distance correlations by means of the electrical logs. The use of MicroLogging for the determination of permeable and porous formations is explained. The question of log analysis for the quantitative determination of fluid saturation and porosity is .discussed. An example is provided to illustrate the significance of the resistivity gradient. The advantages of the new method of the Laterolog are shown, chiefly for the case of wells filled with high-salinity mud. Introduction Electrical logging techniques developed rapidly in Canada at the time an intensive drilling activity started for the exploitation of the Devonian series in Alberta, namely, at the beginning of 1947. The conventional service was soon thereafter supplemented with the latest technica1 improvements. Canada has been among the first regions to take advantage of MicroLogging*, which has proved a most powerful .tool for the investigation of permeable and porous formations; also, the more recent development known as the Laterolog has ?been introduced in Canada. The Laterolog provides a better determination of .the formations, particularly in the case of salty mud where the conventional logging is greatly handicapped. The various methods of electrical logging are now commonly known in oil industry and have been described in numerous publications ( 1) ( 2) (3).

Jan 1, 1951

By Hervé Toubon, Matthieu Davrinche, Jim Corman, Mamane Bello Boubacar Kinassa, Pierre Amadieu

Orano Mining maintains a significant level of Innovation and Development Research for its sites in Canada, Niger, Kazakhstan, Mongolia, and France. This effort is formalized within the six major thematic programs below, which include more than one hundred affiliated R&D projects:  Geological understanding, tools and methods for exploration  ISR technology (geology, modeling, mining development tools)  Mining technology (SABRE)  Ore treatment and processing (in particular via our Centre for Innovation for extractive metallurgy, CIME)  Environment (radiochemistry, modeling, tools and methods for remediation)  Digital Mine (sensors, transmission, database, and data modeling) This paper describes the main actions of these six programs, their stakes, and their progress. There is no single path leading to innovation but fostering an innovative context and a structured project approach are essential ingredients to successful development and industrial deployment. As a result, Orano Mining has, over the years, developed a disciplined methodology for R&D portfolio and project management. This methodology, presented here, targets a reduction in time to implementation while valuing both the expertise and the work in project mode.

Jan 1, 2020

By U. Erb, L. Monaco

"Electrodeposited nanomaterials are increasingly implemented in advanced industrial applications in the aerospace, automotive, defence, electronic and energy sectors due to their outstanding physical, chemical and mechanical properties, including increased strength and wear resistance, and superb magnetic properties. As with the development of any class of new materials, the corrosion behaviour of these electrodeposits requires considerable attention. This presentation reviews major developments in the understanding of the corrosion behaviour of nanocrystalline metals, alloys and metal-matrix composites over the last 20 years, with emphasis on how their intrinsically high density of intercrystalline defects does not compromise their corrosion resistance as initially expected.INTRODUCTIONOver the past 20 years there have been considerable advances in the understanding of the corrosion behaviour of nanocrystalline metals, alloys and metal-matrix composites. In this paper, the corrosion properties of nanocrystalline nickel, cobalt, zinc, and copper and some of their alloys are reviewed with emphasis on how a reduction in grain size affects their corrosion behaviour in different environments.It is possible to synthesize nanocrystalline material with microstructural refinement down to the range of 1 to 100 nm using a large number of processing methods. There are five basic synthesis methods that can be used to classify the different techniques: vapor-phase processing, liquid-phase processing, solid-phase processing, chemical synthesis, and electrochemical synthesis. Depending on the synthesis method, different microstructures (equiaxed, textured), shapes, and forms (films, particles, bulk material) may be produced. In addition, other factors may be introduced (eg. residual porosity or amorphous phases), aside from microstructural refinement, which can contribute to the observed properties (Erb, 2010). In order to interpret and categorize the resulting microstructures, a dimensional structure modulation scheme was introduced by Siegel (1996) in which zero-dimensional nanomaterials refer to individual particles, clusters, etc. One-dimensionality results from a layered (less than 100 nm thick) structure. Two-dimensional nanomaterials are thin, layered structures containing grains (less than 100 nm) within each layer. Finally, three-dimensional nanomaterials are bulk structures with an average grain size less than 100 nm."

Jan 1, 2012

By T. Fliß

The protection of natural resources is of essential importance in times of rapidly increasing populations and resulting shortage of agricultural land. Soil and groundwater resources play a central role for the production of food or feed of any kind. The intensive agricultural and environmentally friendly use of these resources must ensure sufficient income and sustainability of life for future generations. Mining projects often represent a particularly deep intervention into ecosystems due to their size as well as the most expensive treatment processes. Conventional mines comprising of shafts and developed mining fields require the stockpiling of waste rock and in particular to potash mining, the discharge of brines from raw salt processing. In contrast, mining operations based on the solution mining method can be operated without major environmental impacts and lower security risks. While the solution mining for the production of rock salt finds application since more than 500 years, exist a procedure to produce potash using solution mining only since the 1980's. For solution mining drill holes are used to exploit the potash, launched from the surface into the deposit. The exploitation of the raw material occurs by the dissolution of the potash injecting solvents and creating so-called brine caverns. Currently, a number of mining projects in Carnallite deposits by the solution mining method are in progress around the world. Often these projects are located in sensitive ecosystems. K-UTEC project and support actual a solution mining operation of a Carnallite deposit for a Chinese customer in South-East Asia. This work comprises a comprehensive geological and geomechanical modeling as well as stability analyses. Furthermore the cavern design and brine field layout as well as the planning of the brine processing and the plant design. The present paper introduces this project as a case study. The application of a special solution mining procedure and processing design ensures an emission-free mining operation (Zero Disposal Plant). The emission-free operation is achieved by utilizing the full extent of the caverns to dispose the liquid solutions from processing. The presentation of principal salt processing and technical equipment will be rounded by information about the geology of the deposit. Since the deposit includes a number of sensitive minerals, such as Tachyhydrite and Bischofite the presentation comprise a lot of interesting items with special view at the brine field operation. K-UTEC designed and delivered a special blanket measuring system and a well cement according the request of the customer. K-UTEC, a research and engineering company with more than 60 years of experience in the sector of potash and rock salt mining, developed the world's first solution mining operation for Carnallite in Germany more than 30 years ago. In recent times K-UTEC served in different solution mining projects worldwide, with special view at the environmental impact, as well as the optimal utilization of the deposits.

Aug 1, 2013

By Jian Li, Robbie McDonald, David Robinson

"The pressure oxidation of sulfide minerals at temperatures above 200°C enables the extraction of base metals, improves the extractability of gold from refractory ores, enables solubilisation of PGEs and can be used to hydrothermally upgrade base metal-containing feeds. Fundamental studies reveal that the solution chemistry (and mineralogy of the solids) during pressure oxidation can be manipulated with outcomes that include (1) increased leaching rates, (2) lower oxygen requirements and (3) the formation of chemically more stable residues. This paper presents examples describing how these outcomes might be achieved based upon fundamental investigations.INTRODUCTION The application of pressure oxidation to the processing of gold ores and concentrates dates back several decades and continues to be the process of choice at operations such as Pueblo Viejo (pyritic gold) which host the largest autoclave of its kind in the world (Barrick Gold Corporation, 2016). Commercial application to the processing of base metals and PGMs resides with long established processes such as the Sherritt process, ore specific applications such as by Noril’sk, at Sepon etc. or has not proceeded to date beyond pilot scale testing (e.g. Phelps Dodge, CESL, Activox, Platsol). Recently there has been significant interest in hydrothermal upgrading options for concentrates including the NONOX and Toowong processes (Rohner et al., 2016; Weidenbach et al., 2016). The latter options suggest directions where sound knowledge of the underlying fundamentals enables novel outcomes and efficiencies to be obtained. It comes as no surprise that investigations similar to those underpinning these developing processes can be traced back several decades. It is not the subject of this paper to provide a historical perspective of the relevant autoclave chemistries but rather, to present some potential opportunities suggested by studies in our laboratories. Topics to be discussed in this paper include (1) control of metal extraction rates, (2) control of iron-residue composition and (3) control of sulfur oxidation and hence acid generation and oxygen requirements. The work described will focus upon the pressure oxidation of a nickel concentrate."

Jan 1, 2017

By E. P. Wiechrnann, C. M. Castro, G. A. Vidal, F. A. Muñoz

Different authors and publications indicate that Optibar Segmented Intercell Bars cause a remarkable distortion in the distribution of the current in a cell group. However, these results were based in inaccurate computer based models and do not represent the technology. During the last trimester of 2010, a 92 cells circuit from Barrick Zaldívar EW plant was implemented with Optibar Segmented Intercell Bars. The technology was incorporated progressively without disrupting the plant production. Depending on operational conditions, this led to a 2 to 4% current efficiency increase and 3 to 5% specific energy consumption reduction. By October 2011, 40,000 tons of copper will be produced with the technology.

Jan 1, 2011

By C. Joulian, A. G. Guézennec, A. Chmielarz, Y. Ménard, M. Hanke, P. d’Hugues

"The copper concentrate used in this study is produced by flotation of a black shale organic rich ore. This resource is a carbonate-rich, polymineral concentrate. In the last 5-6 years, ore characteristics changed and the concentrate grades degraded. This study evaluated bioleaching of the concentrate in stirred tank reactors as an alternative to the pyrometallurgical technology that is currently applied, and which may no longer be feasible in future given the concentrate chemistry.The first part of the study focused on testing non-traditional operating conditions during continuous bioleaching experiments: high solids concentration (> 20% solids), reduced agitation and aeration rates. For the same residence time, bioleaching performance at high solids loading (25%) was the same as that reached during previous bioleaching experiments at 15% solids. No mixing or microbial issues were encountered. The bacterial consortium used in the experiments demonstrated a high copper tolerance.The second part of the study was devoted to technology development for metal recovery from copper bearing solutions obtained during bioleaching experiments. Due to the high copper concentration of the leachate, solvent extraction prior to electrowinning was not necessary. After iron removal, high quality copper cathodes (morphology and composition) were obtained from the PLS by electrowinning."

Jan 1, 2014

By Brent C. Jellicoe, Phil Robertshaw, J. Murphy, Peter Williamson

Kimberlites and associated diamonds have been the focus of extensive exploration in central Saskatchewan since 1988. During 1989, Uranerz Exploration and Mining Limited identified 71 shallow magnetic anomalies in the Fort a la Corne area from detailed aeromagnetic surveys. By the end of 1991, 18 of these targets had been proven, by drilling, to be kimberlite bodies encased within Cretaceous sedimentary strata. From 1991 to 1997, the number of drill-confirmed kimberlite bodies increased to 69. Our current view, drawing on an integration of geophysical and geological information, is that the kimberlites are composed of individual bodies and multi-vent clusters of coalesced bodies, all apparently constructed of stacked, temporally distinct layers of pyroclastic crater-facies kimberlite. Diamond recoveries and geochemical results from associated heavy minerals at Fort a la Corne remain highly variable, although continued minibulk sampling is expected to improve the estimation of diamond grades for the most prospective bodies.

Jan 1, 2001

By L H. Warren

The types of equipment available for generating a plasma have been reviewed. The efficiency and potential of the plasma generating equipment used in performing extractive metallurgical reactions have been determined. A general classification of the reactions that might be per-formed in a plasma has been proposed. Experimental work done on extractive metallurgical plasma reactions, heat transfer between the plasma and solids, and the quench of the products of plasma reaction has been summarized. From the preliminary results it appears that the high-intensity are or the transpiration-cooled anode plasma torch offer the most promising areas for further research. C ONSIDERABLE world-wide research effort is currently being devoted to the development of processing technologies which employ the new high-temperature generating devices that have appeared over the past few years. The plasma flames produced by these devices offer the potential for subjecting materials to any single gas or mixture of gases at temperatures up to 20,000°K. With these conditions available, many reactions in extractive metallurgy,

Jan 1, 1965

By K. Adham, C. Lee

The demand for nickel is continuing to exceed inventories, and producers are working vigorously to increase capacity. Many nickel processes utilize the fluidized bed technology for its fast heat and mass transfer, excellent temperature control and low maintenance. The following four nickel applications of the fluidized bed technology have been commercialized: I) Sulfide ore roasting; II) Nickel sulfide (matte) roasting; III) Nickel oxide reduction; IV) Nickel chloride pyrohydrolysis. This paper examines the issues surrounding the application of fluidization technology to the above processes, from the stand point of the engineer modeling the process and designing the key equipment, based on the historical success stories and the fundamental principles of flow sheet synthesis. Using the available data in open literature, typical flow diagrams (with convenient bases of 1 t/h feed or product) are developed to illustrate the relative flow rates and to highlight the key features of each application. In addition, some historical background information is provided for each process with supplemental notes with regards to our company's involvements.

Jan 1, 2005

By G. Ladouceur

"Northgate Patino Mines produces a copper concentrate assaying 22% Cu. Moisture content of the product averages 12.5% H20 when dewatering with conventional vacuum disk filters. Recent smelter contracts reflect higher energy costs and increased moisutre penalty charges. This situation forced Northgate to investigate possible alternatives such as rotary dryers and pressure filtration. After laboratory testing, it was found that pressure filtration could economically meet the smelter's requirements. Pilot plant testing was then undertaken and confirmed the laboratory test results. Based on these findings, a model I.S.F. 1500 x 28/22 I.R. Lasta filter press was purchased.This paper describes the Copper Rand dewatering flowsheet the operation of the press and the economics of the process.IntroductionNorthgate Patino Inc. operates 2 und erground copper mines and a 3300 ton per day concentrator located in Chibougamau, Quebec, some 425 miles north of Montreal and 300 miles northeast of Noranda, Quebec.Copper concentrate is produced at a rate of 250 tons per day and trucked to a C.N. siding 10 miles from the mill site and then railed to the Noranda Smelter.Until early 1981, moisture content of the concentrate at 12.5070 was acceptable since smelter penalty charges were relatively low ($0.10 per ton per unit over 10070 moisutre). In January 1981, a new contract was signed in which the penalty was raised to $1.10 per ton per unit over 8070 . This and the increasing truck and rail costs justified the change-over from vacuum to pressure filtration . The Lasta I.S .F. 1500 x 28/22 was then purchased and installed, and operation of the plant started in December 1981."

Jan 1, 1987

By M. Wu, G. Plascencia, A. E. M. Warner, A. Vahed, T. A. Utigard

Nickel oxide granules formed by pyrohydrolysis of a chloride solution, were reduced in hydrogen. Below 400 °C, an incubation period was observed, followed by very slow reduction. In the temperature range from 400 to 600 °C, the rate of reduction increased with increasing temperature and increasing hydrogen pressure. Microscopic analysis showed that in this temperature range the reaction followed the shrinking core model. Above 600 °C, the reduction rate decreased noticeably before suddenly becoming very fast at and above 950 °C. Microscopy showed inner bands of metallization inside the outer metallic rim, indicating partial blockage of the interface between the reacted and un-reacted NiO core. At these temperatures, particle agglomeration and sintering were also found to take place. Surface segregation of sulphur may account for the slow down in reduction rate above 600 °C. From an industrial point of view, reduction should be carried out from 550 to 600 °C with as high a concentration of hydrogen as possible. If sintering and agglomeration are not of any concerns, reduction can be carried extremely fast at about 1000 °C.

Jan 1, 2005

By W. G. Miller, J. D. Scott, D. C. Sego

ABSTRACT An overall study was conducted to evaluate the properties and processes influencing the rate and magnitude of consolidation for oil sands fine tailings produced using different extraction processes. As part of the overall study, a comprehensive description of physical and chemical characteristics of fine tailings generated by caustic and non-caustic processes was carried out. Ultimately, the influence of these fundamental properties on the compressibility, hydraulic conductivity and shear strength properties of the fine tailings was assessed. The characteristics of the fine tailings are presented in terms of index properties, mineralogy, specific surface area, water chemistry, liquid limits, particle size distribution and structure. A difference in water chemistry was concluded to be the cause of substantial differences in particle size distributions and degree of dispersion of the comparable caustic and non-caustic fine tailings. The degree of dispersion was consistent with predictions for dispersed clays established by the sodium adsorption ratio (SAR) values for these materials. A linear variation of increasing dispersion with increasing SAR up to a SAR value of about 40 has been suggested, above which fine tailings are completely dispersed. The observed dispersed or flocculated structures (viewed using a scanning electron microscope) supported the predictions based on SAR values.

Jan 1, 2010

By R. Wirth, B. Orberger, C. Wagner, A. Tudryn, B. Baptiste, S. Miska, Université Paris-Sud

Banded iron formations (BIFs) comprise complex textures and mineralogy, which result from fluid-rock interactions related to high and low temperature alteration. The initial iron oxy hydroxide mineralogy and associated phases such as carbonates, quartz, apatite and phyllosilicates were transformed leading to an upgrading of these BIFs into the world’s largest source of iron ore. In low-grade BIFs, a large part of the iron is related to micro- and nano- metric iron-bearing inclusions within micrometric quartz and/or carbonates (mainly dolomite). We studied laminated jaspilitic BIF samples from a drill core containing 26.71 wt.% total iron, 0.2 wt.% SiO2, 0.32 wt.% MnO, 15.46 wt.% MgO, 22.32 wt.% CaO, 0.09 wt.% P2O5, < 0.05 wt.% Al2O3, 0.15 wt.% H2O and 34.08 wt.% CO2 (Aguas Claras Mine, Quadrilatero Ferrifero, Brazil). Bright rose coloured dolomite and quartz bands alternate with massive specular hematite bands. Raman spectroscopy, X-ray diffraction and FIB-TEM analyses reveal that the micro- and nanometric inclusions in dolomite are mainly hematite and minor goethite, partly occurring as clusters in voids. Curie Balance analyses were carried out at different heating steps and temperatures on whole rock samples and a synthetic mix of decarbonated sample and pure dolomite. X-ray diffraction on the products of the heating experiments shows that that hematite is stable and new phases: magnesioferrite (MgFe2O4), lime (CaO), periclase (MgO), portlandite (Ca(OH)2) and srebrodoskite (Ca2Fe2O5) were formed between 680°C and 920°C. These finding gives hints to optimizing the beneficiation process, as the presence of hydroxyl ions bearing goethite micro- and nanoinclusions lowers the sintering temperature. Prior separation of coarse hematite and barren dolomite and quartz, followed by lower temperature sintering of the inclusionbearing dolomite/quartz leads to transformations into phases with higher magnetic susceptibilities (such as hematite and magnesioferrite). The entire Fe and Fe/Mg oxide feed (the priorly separated fraction added to the sintered fraction) can then pass through wet-high intensity magnetic separation after crushing.

Jan 1, 2016

By R. J. Enright

Eight mines in canada and three in Australia were visited between September 1987 and Februacy 1988. All mines had encountered problems with sulphide dust explosions and had introduced defence mechanisms to prevent or limit the extent of these explosions. Techniques included dispersion of limestone by various methods, use of water foggers, placing of water and inert stenuning in blast holes, and removal of settled dust to prevent secondary explosions. The techniques were evaluated and it was concluded that certain practices should be modified or discontinued as they were of little value in preventing dust explosions.

May 11, 1988

Surfaces forces have been measured between gold sphere and gold-coated glass plate in xanthate solutions using an atomic force microscope (AFM). The measurements conducted in potassium amyl xanthate (PAX) and potassium ethyl xanthate (KEX) solutions showed long-range hydrophobic forces, with the force curves showing no evidence for nanonubbles on the surface. The strongest hydrophobic force was measured at contact angle of 94° with a decay length of 23 nm. The hydrophobic force became weaker at higher concentrations and after a long immersion time, which may be attributed to the xanthate species adsorbed on top of the first mono layer. The hydrophobic force became stronger when the residual xanthate solution is displaced by pure water, indicating that hydrophobic force becomes the strongest in pure water.

Jan 1, 2009

By N. R. Andrade-Gonzalez

In this paper, the effect of magnesium and strontium additions on the heat treatment behaviour of cast A319,2 alloy was investigated, Permanent mold samples were heat treated at 495 °C for 4 and 24 h, then quenched in hot water and aged at 180 °C and 220 °C for different temperatures, It is found that multiple aging peaks are present in the age-hardening curves of Al-Si-Cu alloys, mainly when Mg and Mg-Sr are added, The results of electron probe microanalysis (EPMA) observations reveal that the age-hardening behaviour is related to the precipitation sequence of alloys, For the Al-Si-Cu alloy, the first aging peak is the result of the high-density GP zones, while the subsequent peaks arise from metastable phases, Obvious intervals during the transition from GP zones to metastable phases may be the main reason of the formation of multiple aging peaks, It is seen that addition of Mg (-0,40 wt %) leads to the precipitation of coarse Al5Mg8SioCu2 particles. When modifying the high Mg alloys, Cu-intermetallics segregate in areas away from the growing Al-Si eutectic regions, Modification with strontium retards the precipitation of the silicon out of the matrix.

Jan 1, 2005

The control of AG mills fed by ores with harder and softer components can be challenging due to the sensitivity of the mill to the ratio of hard to soft components. The mills at LKAB?s iron ore operations are generally well controlled, but there are periods when the throughput falls off dramatically, due to a loss of mill filling. As the ore is upgraded in the sorting plant through magnetic separation prior to milling, this presents an opportunity to manipulate the feed blend in advance. In order to assess this opportunity, a fullscale mill charge was dumped and assayed by size to quantify the build-up of competent waste in the mills. This was supplemented by pilot and locked-cycle laboratory tests at a wide range of feed blends in order to facilitate the development of an appropriate multi-component AG mill model. This paper reports the experimental campaign requirements and methodologies, as well as the major outcomes from analysis and modelling exercises using the industrial, pilot and laboratory multi-component data.

Jan 1, 2012

By W. K. Buah, R. K. Amankwah

Waste-activated carbon generated by gold ore processing plants that employ carbon adsorption technologies may contain very high gold values and represent a potential source of extra revenue. In this research, two methods that augment combustion of waste-activated carbon are evaluated. These are mechano-chemical activation and charcoal-enhanced ashing. It was found that mechano-chemical activation caused structural transformation of the waste carbon, which resulted in a reduction in the temperature for complete oxidation from above 700oC to 450oC. Complete oxidation was also achieved at the same furnace temperature, for a combined sample of waste-activated carbon and 50% by weight of wood charcoal. In both cases, gold was extracted from the ash by conventional cyanidation, with recoveries greater than 98% from a head grade of 3.2 kg/t.

Jan 1, 2007

By M. J. Gagnon

The agglomeration of particulate materials is used in many mineral processes to enhance the settling of the fine particles, Depending upon many physical and chemical parameters, the aggregates demonstrate specific density-size distributions, In this study, a fractal model of the agglomeration process is introduced, Based on reliable experimental data and on physical calculation, the model presented helps to envisage the initial formation of the micro-flocs, and to interpret the subsequent interactions between the aggregates in terms of either coagulation or flocculation, Data from different sources, materials and different agglomeration processes are analysed and compared in the light of the proposed model.

Jan 1, 2005