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By W. Zheng

Pipelines can develop stress corrosion cracks in either intergranular or transgranular form. Since the mid-1980s, numerous colonies of transgranular cracks have been found across Canada and many other countries in the world. While the intergranular form of cracking has been well studied in the past 40 years, the mechanisms governing SCC in near-neutral pH environment, i.e., the transgranular form of the cracking, are yet to be understood in greater depth. Over the past ten years or so, a large number of research publications have been available on this subject and this paper summarize our latest progress in understanding the mechanistic aspect of the problem. Better understanding of the role of mill scale surface and the steel metallurgy in crack initiation has been indicated in the recent literature. However, the initiation of SCC in the lab research still relies on loading conditions that are far more aggressive than those encountered in the field. Most crack growth studies in the past are also performed under very aggressive mechanical conditions, which could have prevented the observation of environment effects. However, more recent research at lower K or Delta K ranges seems to suggest a strong role of the environment. Naturally, modeling of growth should reflect the effect of the environment, steel metallurgy, and the changing mechanical properties of the pipe steel with time. For a specific steel in a given environment, the crack growth rates tended to increase with the strain rate, indicated either by the nominal applied loading frequency or by the calculated crack tip opening rate. Future research needs to address the issue of concurrent growth of multiple interacting cracks. More attention should also be given to concurrent initiation of multiple cracks in a colony, as failure is usually caused by a coalesced crack not by an individual crack. The effect of soil environment should not be limited to the chemistry of soil solution; other factors such as cathodic processes, the variation of environment with time and physical conditions of coatings should also be considered as part of the study.

Jan 1, 2005

By D. B. Dreisinger, D. G. Dixon, G. Nazari

"The kinetics of chalcopyrite leaching in acidic ferric/ferrous sulfate media under atmospheric conditions in the presence of pyrite has been investigated. It has been found that pyrite samples from different sources affect the rate of chalcopyrite leaching differently. A strong correlation between the amount of silver associated with the pyrite and its effectiveness has been noted. In this study, improvement of the catalytic properties of pyrite such that all pyrite samples accelerate the rate of copper extraction regardless of their sources is demonstrated, and a detailed discussion of the mechanisms involved in the process of chalcopyrite leaching in the presence of silverenhanced pyrite is presented. INTRODUCTIONIt is well known that chalcopyrite resists leaching in sulfate media. It has been proved that pyrite facilitates the leaching of chalcopyrite (Berry et al., 1978; Dixon et al., 2008; Mehta and Murr, 1983; Muñoz et al., 2008; Nowak et al., 1984, Tshilombo, 2004). Considering the catalytic effects of pyrite on accelerating the kinetics of chalcopyrite leaching, Dixon and Tshilombo (2005) have developed a new process, known as Galvanox™, which has several advantages over other hydrometallurgical processes. Galvanox™ runs under atmospheric conditions, so it requires only low-cost leaching tanks. The sulfur yield at this temperature is high (>95%) which leads to low oxygen consumption and low sulfuric acid generation. The operating temperature is below the melting point of sulfur which eliminates the use of surfactants. This process also does not require fine grinding. Reaction 1 shows the overall leaching reaction in the Galvanox™ process.CuFeS2 + O2 + 2 H2SO4 = CuSO4 + FeSO4 + 2 S0 + 2 H2O (1)Complete copper recovery from the Galvanox™ process can be achieved at a considerably higher rate than other atmospheric ferric sulfate leaching processes (Dixon et al., 2008). Recycling pyrite and recovering copper from tailings with the Galvanox™ process have also been evaluated in continuous pilot leaching campaigns (Dixon et al., 2007)."

Jan 1, 2012

By C. Morlot, C. Auvray, E. Fourreau, J. Talandier

"During the excavation of underground galleries in a rock mass, reorganisation of the stress field around the site results in damage to the surrounding material. In the framework of research undertaken at the ANDRA underground laboratory in France, galleries have been excavated in a Callovo-Oxfordian argillite formation. The damage has manifest as a number of fracture systems in the adjacent rock. Observations have shown that fractures generated during excavation and storage exploitation are able to self-seal during re-saturation of the site in the post-closure stage. Although indirect evidence for argillite self-sealing has previously been reported, from experiments performed both in situ and on samples, no direct observations of self-sealing have yet been made.For the present study, we performed a range of self-sealing experiments using a newly-developed triaxial compression cell placed within a nano-CT scanner with a 10 µm resolution. The body of the compression cell is X-ray transparent, allowing sample healing to be monitored directly. The samples contained an artificial fracture that had been generated in the laboratory, into which a fluid was injected. The fractures were orientated either perpendicular or parallel to the plane of anisotropy of the material. Our initial results demonstrate that when fluid is injected perpendicular to the plane of anisotropy, the flow-rate has no apparent influence on the kinetics of fracture closure. Permeability varies significantly, from 2.10-14 to 2.10-18 m2 over 116 hours. Post-test observations of the fracture lips show swelling that appears to be orientated perpendicular to the fracture plane and therefore parallel to the plane of anisotropy. Initial results for an injection parallel to the plane of anisotropy suggest that, in this case, the rate of flow affects the kinetics of fracture closure. For a flow-rate of 0.25 ml/min, closure begins after around one minute. In contrast, for a rate of 0.05 ml/min, it is necessary to wait several minutes before partial sealing of the zone is observed. The reduction in permeability is again significant, from 2.10-15 to 4.10-18 m2 over 96 hours. After completion of the test, swelling was observed in elongated zones that lie parallel to the fracture plane and therefore to the plane of anisotropy."

Jan 1, 2015

By J. D. Zhu

A numerical model for predicting microporosity formation in aluminum castings has been developed, which describes the redistribution of hydrogen between solid and liquid phases, the transport of hydrogen in liquid by diffusion and Darcy flow in the mushy zone, One of the key features of the model is that it uses a two-stage approach for porosity prediction, In the first stage, the volume fraction of porosity is calculated based on the reduced pressure, whereas, in the second stage, at fractions solid greater than the liquid encapsulation point, the fraction porosity is calculated based on the volume of liquid trapped within the continuous solid network, which is estimated using a correlation based on the Niyama parameter, The porosity model uses thermal data calculated using the commercial finite element package ABAQUSTM. The model has been applied to examine the evolution of porosity in a series of experimental samples cast using unmodified A356 in which the initial hydrogen content was varied from 0,048 to 0.137 [cc/100g], A comparison between the model predictions and the experimental measurements indicates good agreement in terms of the variation in porosity with distance from the chill and the variation resulting from initial hydrogen content.

Jan 1, 2005

By J. A. Reid

THE views and observations expressed herein on this old but constantly recurring question are our own, no effort having been made to align them with standard texts. Therefore, while they may find general acceptance amongst fellow engineers, they must stand as personal opinions and as such are open to debate and discussion. In order properly to consider the subject, it should first be 'set in proper perspective. Why are Prospects Examined? Prospects are examined to determine whether they may contain economic concentrations of metals or minerals, the legitimate mining business being run, pretty largely, to make money. Next to food and clothing, modern civilization is based on metals, with which are included in this discussion minerals, oils, and fuels. A constant and increasing demand for the common metals requires the location of replacements for depleted orebodies, while the use and appreciation of new metals brings increasing demand for them. Aluminium is a good example of a metal which has, within recent years, made great progress. Today, we are becoming increasingly aware of magnesium, chromium, tungsten, thallium, and other lesser known, metals.

Jan 1, 1945

By M. Jackson, R. McDonald, T. Osken, D. Robinson

"The addition of sulphidic materials in the leaching of nickel laterites has several potential benefits that include improvements in the rheological behaviour of the blends, reductions in the sulphuric acid and steam requirements, sweetening of the nickel grade of the combined feed material, and the option of using a range of sulphidic materials. The current study examines the oxidative processing of 30% w/w blends of nickel concentrate and nickel laterite ore at 250oC. In particular, the viability of using low oxygen overpressures was examined for significant amounts of nickel flotation concentrate, up to 12% w/w. Further to this the impact of process water quality, in particular the presence of chloride, upon the kinetics of extraction and the mineralogy of the residue were also investigated. This paper will present the results of preliminary work in this area.INTRODUCTIONThe use of sulphidic ore as a source of sulphuric acid during oxidative hydrometallurgical processing is not a novel idea and can be traced back over forty years (Seidel & Fitzhugh, 1968). A series of patents pertaining to application of this approach for laterite ores can be subsequently found (O’Neill, 1973; Opratko et al., 1974; Rodriguez, 2008a, 2008b; O’Callaghan, 2010; Liu et al., 2011) and a few of articles containing published data (Ferron & Fleming, 2004; Quinn et al., 2009). The use of pyrrhotite tailings as a source of sulphuric acid has also been employed for the leaching of converter slags (Perederiy et al., 2011).It is known that hydrometallurgical operations such as the HPAL plant at Murrin Murrin have added small amounts of sulphides as either transitional (mixed sulphide/oxide) ore or non-smeltable concentrate. This can improve the rheology (Rodriguez, 2009) and provide heat credits. However these plants are generally limited in their ability to add such materials due to their reducing nature and given under highly acidic conditions that the breakdown potential of the titanium used for the autoclave lining is significantly reduced. A suitable oxidant must therefore be present to ensure the potential remains sufficiently high."

Jan 1, 2012

By A. Lopez-Valdivieso

Particle size enlargement processes play an important role in solid/liquid separation, and in beneficiation unit operations. In the latter, not only the size of the formed aggregates but also their surface properties are very important. Oil agglomeration has a special place among such processes: it is a selective process in which hydrophobic particles are agglomerated into hydrophobic agglomerates which can be recovered by flotation. This explains the broad applications of oil-assisted beneficiation processes not only in the beneficiation of fine coal, but also in agglomerate flotation of many different types of ores, and in coal/gold agglomeration.

Jan 1, 2004

By C. A. Pickles

Microwaves are being applied industrially in a number of fields and possess a number of potential advantages that could be applied in extractive metallurgy. Microwave heating has a number of unique characteristics, which distinguish it from the conventional heating methods. In microwave heating, the absorption of energy occurs at the molecular or atomic level and therefore the heat is generated within the material itself. In conventional heating, the exterior temperature is usually higher than the interior, but with microwave heating, the temperature gradient is inverted and thus the interior temperature can be much higher than that of the surface. The energy densities in microwave systems can be relatively high and this in combination with the low thermal conductivities of oxide ores, can lead to very high internal heating rates. In this research, the application of microwave energy for the reduction of a nickeliferous silicate laterite ore has been investigated. The real and imaginary permittivities are the two fundamental properties which determine the microwave absorption characteristics of a material and these were measured for the ore, both with and without carbon additions using the cavity perturbation technique. The microwave heating and reduction experiments were performed in a 0 to 2 kW CTC microwave system. The effects of power input, processing time, sample mass and charcoal additions on the microwave absorption were investigated. Then reduction experiments were performed and the nickel grade of the magnetic concentrate and the nickel recovery in the concentrate were determined.

Jan 1, 2005

By Yongfeng Jia, Shaofeng Wang, Danni Zhang

Ferrihydrite is ubiquitous in soils, groundwater and aquatic sediments and is usually classified as "2-line" or "6-line" according to the number of diffuse XRD peaks. It has high surface area and reactivity; therefore, it may serve as a sink for sequestering trace metals, metalloids and organic matters via adsorption and co-precipitation. Although considerable attention was paid to the transformation process of this thermodynamically metastable solid, there are still some controversies on the mechanisms of the formation of goethite or hematite from the ferrihydrite precursor. This work systematically investigated the transformation of 2-line ferrihydrite produced by using different neutralization regent (CaO vs. NaOH) into crystalline products at different pHs (4, 7 and 8), three temperatures (25, 40, 75 °C) and in different media (sulfate vs. nitrate). X-ray diffraction (XRD), Raman, Fourier transform infrared spectroscopy (FTIR) and chemical extraction were employed to characterize the transformed solids as well as the redistribution of Fe between the amorphous and more crystalline phases. The results showed that the transformation product in nitrate media was hematite (major) and goethite (minor), which was independent of pH, temperature or neutralization reagent. In sulfate media, goethite was the dominant solid under slightly acidic conditions (pH 4) with 6-line ferrihydrite as the intermediate product, whereas neutral to slightly alkaline conditions still favor the formation of hematite. Chemical extraction results indicated that there was only ~3 % of amorphous phase detectable after aging at 25 °C for 280 days at slight acidic pH. In contrast,~70 % of the iron remained as an amorphous phase under neutral to slightly alkaline conditions. The results suggested that the pH as well as the reaction media (sulfate ion) plays an important role in the 2-line ferrihydrite transformation process.

Jan 1, 2016

By R. Amata

"The Gakara Rare Earth deposit in Burundi (East Africa) is unique for its high grade (e.g., 54.3% TREO on average) and low uranium and thorium levels. The majority of the light rare earth (RE) elements in material from Gakara are contained within the familiar RE minerals bastnaesite and monazite. Extensive metallurgical test work was conducted by SGS Minerals Services on mineral samples collected from the Gakara deposit. Various whole ore hydrometallurgical processing routes were examined in a scoping level test program. Preliminary beneficiation testing was also conducted, though it was determined that only marginal upgrading would be achieved with significant RE losses. Thus a hydrometallurgical process on whole ore was developed to minimize the overall process complexity and achieve maximum RE recovery. Results from the test work will be presented, along with the selected base case flowsheet involving agitated atmospheric sulphation of the RE minerals, RE double sulphate precipitation, caustic conversion, redissolution, and carbonate precipitation. Following the base case flowsheet, a purified cerium free mixed RE carbonate with low levels of radioactive elements was produced.INTRODUCTIONRainbow Rare Earths Limited (Rainbow) is a mining company engaged in the exploration and development of the Gakara rare earth deposit in Burundi; Figure 1 shows the project location. The project is located in the Bujumbura Province and 45 km from the Burundi capital of Bujumbura. Notable for its exceedingly high in-situ grade – 54.3% on average total rare earth oxide (TREO), low uranium and thorium levels and familiar rare earth minerals, bastnaesite and monazite – Gakara is the world’s richest rare earth deposit. The project, a previously operating mine from 1948–1978, has a significant mineral inventory base, a long life of mine, well understood mineralogy, and robust economics. Rainbow is focused on bringing Gakara into production in the near term, ramping up to produce 5,000 t/y of a 54%+ TREO concentrate."

Jan 1, 2016

By J. C. Gathje

Newmont acquired the Phoenix Project through the acquisition of Battle Mountain Gold in 2000. Shortly after the acquisition, Newmont Metallurgical Services (NMS) and Nevada Operations began development work on a process to Pressure Oxidize (PDX) precious metal rich copper concentrates from Phoenix using the Lone Tree PDX facilities at Valmy, Nevada. The high precious metals content of the Phoenix concentrate - Au up to -300 g/t and especially Ag, up to -1700 g/t - led Newmont to the development of a High Temperature PDX process that achieves high cyanide leach recovery of Au and Ag, from the PDX solids, without the requirement for a messy and expensive "lime boil" or sulphate destruction process. Base metals content in Phoenix concentrates range from: 15-25 % for Cu, 1-10 % for Zn and 0-2 % for Pb. Excellent solution extraction of Cu and Zn is achieved while Pb is precipitated in the PDX residue. In addition to achieving high Au and Ag recovery this process produces very clean PDX discharge liquors that require minimum effort to remove contaminant metals and PDX solids that have superior settling and filtration characteristics. All of these factors contribute to lower capital and operating costs for the overall process. This paper describes the laboratory and PDX pilot plant developments for this process.

Jan 1, 2004

By John Plecash

This paper comprises a general outline of all of the developments, including the history, geology, mining, milling, power and transportation installations, at the gold mining operation of La Luz Mines Limited and the copper mining operation of its wholly-owned subsidiary, Rosita Mines Limited, both located in north-central Nicaragua. The low-grade, gold-bearing ore-bodies of La Luz Mines, contained in highly fractured and folded Lower Cretaceous sedimentary rocks, were from 1909 to 1928, mined and treated by primitive methods by the La Luz and Los Angeles Mining Company. The abandoned property was acquired by La Luz Mines Limited in 1936, and was equipped with modern machinery and put into production in 1939. Between 1939 and 1948, the daily rate of production was in-creased from 300 tons per day to 2,-000 ton per day. The ore reserves available for open-pit mining were depleted in 1954. Since then, the entire production has come from under-ground operations.

Jan 1, 1963

By J-F. Turgeon, Y. Pépin, G. Hudon

The high temperature hydrochloric acid leaching of titanium slag in the QIT upgraded slag process (UGS) creates a harsh environment for materials of construction. Because of their excellent chemical and heat resistance, furan mortars are a key component in the lining system of the UGS pressure leach reactors. Similar products coming from different manufacturers have however shown unequal performances in service. In some cases, cracking of the brick lining has occurred during curing of the mortar. This study was initiated to investigate the impact of the curing conditions on the properties of carbon filled furan mortars. Laboratory tests were conducted to assess the effects of temperature and exposure to water and HCl solutions on mortar shrinkage and mechanical properties (tensile, compressive and bond strength). Three commercial furan mortars that have been used in the UGS leach reactors were thus characterized. Mortar properties were found to vary significantly among the products tested. Moreover, the curing conditions were shown to have a significant impact on mortar shrinkage and mechanical strength. The experimental findings provide explanations for the unequal performances of the mortars in service and for the problems of brick lining cracking that occurred in the UGS leach reactors. This study demonstrates that excessive mortar shrinkage compromises the integrity of a brick lining system.

Jan 1, 2004

By C. A. Young, H-H. Huang, L. G. Twidwell

Equilibrium calculational software programs can be effectively utilized to model important parameters in aqueous and aqueous/solid systems, e.g., activity or concentration, solubility, temperature, solution pH, solution potential, and ligand complexation. In this regard, the calculational program ST ABCAL will be demonstrated. Illustrative examples for the creation of diagrams such as potential-pH, and activity or concentration-pH will be presented to demonstrate the fundamentals in real hydrometallurgical systems. Speciation, titration and mixing will be used to simulate or predict operational processes. Berkeley Pit water from a flooded abandoned copper open-pit mine will be used to illustrate the modeling process. According to analytical results the water contains about 20 important constituents. In addition to measured potential and dissolved oxygen, there are two distinctive oxidation/reduction couples. Concentration and other experimental parameters are seldom matched to each other and 12 different conditions have been identified. Water for each condition must be speciated in order to find the best-fit model. The STABCAL program will be used for the modeling calculations and the implication of the water chemistry to defining treatment opportunities will be discussed.

Jan 1, 2005

By D. B. Dreisinger, M. R. Tavakoli

"Vanadium has been produced from a variety of sources. This metal is known to make aqueous solutions of complex speciation as a function of vanadium concentration and pH. Considering the method of leaching, the impurities in the pregnant leach solution, and the planned vanadium product, different extractants and flowsheets can be applied for solution purification. This paper reviews the purification of vanadium leaching solution using organophosphorus, solvating, and amine extractants. This review focuses on vanadium separation from iron, molybdenum, and uranium, which are often present in vanadium resources such as primary ores, fly ashes, and spent catalysts.RÉSUMÉ Le vanadium est produit à partir de diverses sources. Ce métal est connu pour permettre des solutions aqueuses de spéciations complexes en fonction de la concentration du vanadium et du pH. En tenant compte de la méthode de lixiviation, des impuretés dans la solution mère de lixiviation et du produit de vanadium planifié, divers agents d’extraction et schémas de traitement peuvent être mis en oeuvre pour purifier la solution. Le présent article étudie la purification de la solution de lixiviation du vanadium au moyen d’extractants organophosphorés, solvants et aminés. L’étude cible la séparation du vanadium du fer, du molybdène et de l’uranium, lesquels sont souvent présents dans les ressources de vanadium telles que les minerais primaires, les cendres volantes et les catalyseurs usés."

Jan 1, 2016

By Roger T. Laine

"The Carswell structure, located in the western part of the Athabasca Basin, northern Saskatchewan, has been extensively explored since 1967. This exploration has been successful and lead to the discovery, in 1970, of the D sandstone-hosted unconformity related deposit. By the end of 1984, five additional basement-hosted unconformity related deposits had been delineated: the OP and N discovered in 1970, the Claude in 1971, the Dominique-Peter in 1981, and the Dominique-Janine in 1984. The D deposit has been mined out; the Claude open-pit has already produced more than 500 tonnes of uranium, the development of the Dominique-Peter underground mine (first phase) has been completed, and production from the latter started in 1985.All six deposits are located in the southern part of the Aphebian metamorphic core, 18 km in diameter, which has intruded at least 1250 metres of Helikian Athabasca Group sediments during a cryptoexplosion event at 480 Ma, unrelated to the emplacement of uranium mineralization. The metamorphic rocks, affected by the Hudsonian Orogeny, are divided in two lithostratrigraphic units: the Peter River gneiss, aluminous gneiss series, and the Earl River complex, mixed quartzofeldspathic and mafic gneiss series. A well developed regolith profile is recognizable in the south along the contact with the sandstone and inside the metamorphic core sometimes associated with conformable sandstone beds.Basement and sandstone-hosted uranium deposits show many similarities:-linkage to unconformity;-mineralogy and geochronology with a first phase mineralization characterized by a polymetallic sulphide-uraninite-brannerite assemblage dated at 1150 to 1050 Ma, a second phase characterized by a simple sulphide-uraninite assemblage dated at 890 to 820 Ma, and a third phase characterized by a pitchblende-hematite dated at 380 Ma; and,-linkage to early Hudsonian structures with remobilization of these structures during intense hydrothermal alteration resulting in Mg chlorite-illite halos."

Jan 1, 1986

By James A. Robertson

"In the Blind River area Proterozoic clastic and sedimentary rocks and minor volcanic rocks (The Huronian Supergroup) uncomformably overlie and trangress northwards over dominantly granitic Archean terrane (2500 + Ma) and are intruded by Nipissing Diabase (2ll5 Ma). Later deformation and metamorphic events are recognized. The developing depositional basin was controlled by the incipient Great Lakes Tectonic Zone marginal to the Algoman Craton.The Matinenda Formation (basal Huronian) comprises northwards-derived fluvial arkose, quartzite, and pyritic, uraniferous oligomictic conglomerate which contained in 1981 some two-thirds of Canada's uranium resources. Production to December 1981 from Elliot Lake totalled 98.3 thousand tonnes U for an average recovered grade of 0.1% U with an additional 671 tonnes U recovered by leaching at Agnew Lake. The remaining resources are at lower grades. Some thorium and yttrium have been produced. Minor amounts of gold reflect the paucity in the source area. Gold is better-developed in the Huronian north of Sudbury reflecting the local source area.The conglomerate beds lie in southeasterly-striking zones controlled by basement topography down sedimentation from uraniferous Archean granite. Uraninite textures, the distribution of monazite, and local enrichment by reworking indicate a syngenetic, probably placer, origin of the mineralization. ""Brannerite"" has formed by solution of uranium from the margins of the uraninite grains and redeposition on the original titaniferous minerals. Penecontemporaneous volcanics may have been a source for sulphur in some of the pyrite and of trace amounts of Co, Ni and Au. Some pyrite may be detrital, some may be authigenic and some introduced.Drab coloured rocks, uranium and sulphide mineralization, the presence of hydrocarbon (thucholite) and a post-Archean regolith formed under reducing conditions have been cited as evidence of an early Precambrian reducing environment extended to the atmosphere. Sedimentary features indicating fast-flowing water and possibly a cold climate imply that the uraninite would be exposed to whatever oxygen was present in the atmosphere under conditions which would inhibit complete solution. In the upper Huronian, red beds and in the Lorrain Formation a monazite - iron oxide assemblage and copper mineralization indicate more oxidizing conditions. . Similar uranium deposits occur at Agnew Lake and in the basal Huronian north of Sudbury there are minor uranium and gold values.Provenance, lack of complete oxidation, transportation and depositional processes, redistribution during diagenesis and possibly low grade metamorphism, and the lack of post-depositional destructive processes are the dominant factors in the formation and preservation of the ores. The modified placer theory of genesis is well entrenched and an exploration model for such deposits throughout the world is well-documented.Research continues on mineralogy and textures of the ores, detailed sedimentology of the ores and their host rocks, with particular emphasis on: provenance area, the influence of early Precambrian mineralization patterns on the mineralization present in the Huronian both in space and in time, fluvial sedimentation and diagenesis. Expansion and reopening of the mines of the Elliot Lake camp should facilitate further studies."

Jan 1, 1986

By A. Alfantazi, L. Choudhary

Gold leaching in thiosulfate solution has attracted widespread research interest through the last two decades primarily due to its perceived environmental benefits in comparison to the conventional gold cyanidation technique. However, the data on the corrosion and/or corrosion-induced failures of plant infrastructure materials in the solutions relevant to thiosulfate gold leaching are very limited. Accordingly, this study aims to characterize the electrochemical corrosion behavior of stainless steel 316L in the thiosulfate gold leaching solutions. Electrochemical corrosion response was investigated using potentiodynamic polarization and electrochemical impedance spectroscopy. The morphology of corroded specimens was analyzed using scanning electron microscopy.

Jan 1, 2014

By J. Visman

"The Compound Water Cyclone is a concentrator for the wet processing, in bulk, of finely divided materials such as slack coal, fine ores and mineral sands. It was originally developed by the Fuels and Mining Practice Division of the Mines Branch, Department of Mmes and Technical Surveys, Ottawa, for the cleaning of friable slack coals and slurries.Since its introduction in the coal industry in 1962, its application to other materials has also been studied, with special emphasis on simplicity of operation and low over-all cost per ton of finished product .In this paper, a description is given of commercial two-stage units presently available for the processing of granular materials, including wastes a1:1d other low-grade products. A pneumatic control system is used for operating the cyclone under back pressure .and for automatic cut-point adjustment. An account is given of results obtained on coal mineral sands and ores in the Wes tern Regional Laboratory of the Department of Mines and Technical Surveys. Results of several industrial applications are discussed."

Jan 1, 1966

This paper describes basic parameters, such as surface forces and film elasticity, affecting the stability of foams (two-phase froths). We used the thin film pressure balance (TFPB) technique to measure the surface forces in foam films stabilized with various frothers such as pentanol, octanol, methyl isobutyl carbinol (MIBC), and polypropylene glycol (PPG). The results were compared with the foam stabilities measured experimentally and the film elasticities calculated using a new model developed by Wang and Yoon (2006). It was found that at low electrolyte (NaCI) concentrations foam stability is controlled by both film elasticity and surface forces (or disjoining pressure), the relative contributions from each changing with frother type and concentration. Further, the kinetics of film thinning was studied at a high electrolyte concentration. The results obtained in the present work showed that the major role of a frother is to decrease the hydrophobic force rather than to increase the film elasticity. This conclusion is drawn from the observation that at the typical frother (MIBC) concentrations employed in flotation, frother additions cause sharp decreases in hydrophobic force while causing relatively little changes in film elasticity.

Jan 1, 2006