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By Ahmad Ghahreman, Denver Cowan, Yeonuk Choi

"Testwork was conducted in order to compare the effectiveness of carbon based catalysts while oxidizing a gold-bearing pyrite concentrate under atmospheric conditions. Without the use of a catalyst the oxidation of pyrite was incomplete after 96 hours, resulting in roughly 60% pyrite oxidation. Furthermore the resulting sulphate yield from unassisted pyrite oxidation ranged between 72 and 84%. It is evident that atmospheric oxidation of pyrite is not viable due to slow oxidation kinetics and high sulphuric acid production when using a ferric sulphate media without a catalyst. The effect of two different carbon based catalysts, one Lewatit® AF 5 a new microporous carbonaceous bead, and the second a granular coconut shell based activated carbon, were tested under the same oxidation conditions as the unassisted pyrite tests. After 96 hours, Lewatit® AF 5 assisted oxidation showed approximately 96% pyrite oxidation with a sulphate yield ranging between 26 and 35%, while the activated carbon assisted oxidation reached approximately 100% pyrite oxidation with a sulphate yield between 36 and 37%. Testwork indicated that not only does the addition of a carbon based catalyst greatly improve the oxidation kinetics and lead to almost complete oxidation, the sulphate yield is also drastically reduced, resulting in very high elemental sulphur yields.INTRODUCTION Pyrite is an important sulphide mineral due to its ability to contain invisible gold concentrations up to 132 g/t (Chryssoulis & Cabri, 1990). As a result, ores composed of only a small amount of pyrite still have the ability to contain high gold grades. This refractory gold cannot be accessed via conventional gold leaching processes, such as cyanidation, and additional oxidative pre-treatment is required to liberate the gold, making it more amenable to extraction (Marsden & House, 2006). Current oxidative pre-treatments do exist consisting of both pyrometallurgical and hydrometallurgical processes including high temperature and high pressure leaching within autoclaves, biological atmospheric leaching and roasting. Autoclaves are a proven process reaching desirable recoveries within approximately a 1–2 hour retention time, due to the increased temperatures and pressures, allowing for an increase in dissolved oxygen (Marsden & House, 2006). The typical reaction for pyrite oxidation within autoclaves is presented in Equations 1, 2 and 3."

Jan 1, 2017

By K. H. J. Clarke

SINCE the beginning of this century the non-ferrous mineral industry has contributed $17,809,-000,000 to the economic growth of Canada. To contemplate the vast amount of investment capital required and the resultant beneficial distribution of these billions of dollars for labour, transportation, supplies, taxes and dividends, challenges the imagination. It is the purpose of this paper, (a) to trace the development of the industry since its formative period to the present; (b) to discuss the current situation and problems; and ( c) to attempt to peer into the hazy future. Although there are 21 metals currently being produced in Canada which are classified as non-ferrous, or as alloying metals, copper, lead, zinc, nickel-the metals which will be discussed in this paper-constitute almost 60 per cent of their total value. ;The story

Jan 1, 1961

By P. Lostritto, G. E. Agar, G. Labonte, M. Cherevaty

"A locked cycle flotation test was done on a sample from the ovoid portion of the Voisey 's Bay copper-nickel sulphide ore. The chemical conditions for this test were generated by prior independent testing. In this test work the time in each of the five separation stages was optimized prior to executing the locked cycle test. A numerical simulation of the continuous circuit material balance was done prior to the locked cycle test. The test results were not fully satisfactory because the flotation of pyrrhotite in the bulk rougher and cleaner stages was not consistent. The preliminary indication was that the samples had oxidized to varying degrees during storage.INTRODUCTIONINCO has performed batch laboratory flotation testing on ore from Voisey's Bay which is a mixture of chalcopyrite, pentlandite and pyrrhotite. Earlier, Lakefield Research was contracted by Diamond Field Resources to test the ""flotability"" of the ore, which included a pilot plant trial. INCO's J. Roy Gordon Research Laboratory has repeated many of the batch tests that Lakefield did to verify their results. Based on their own work, INCO has modified the circuit proposed by Lakefield Research. The modified circuit is based on batch test work, but no locked cycle test (LCT) was done. It is believed that this circuit will produce a copper concentrate at 29-30% copper and a primary nickel concentrate at 15-20% with recoveries of 80% or above.For several years the University of Toronto has been working with INCO to provide ""hands on"" experience for undergraduate students as an Industrial Research Project (IRP). This year, the objective for IRP was to optimize the time for each of the five separation stages for the Voisey's Bay ore then to numerically and experimentally simulate the material balance for a continuous circuit."

Jan 1, 1998

By S. Qian

Galvanic corrosion is a potentially major concern associated with the application of stainless steel reinforcement which is in direct (electrical) contact with carbon steel reinforcement in concrete structures. Judicious use of stainless steel rebar in both new construction and rehabilitation of older structures is a viable, cost-effective option for extending service life and reducing maintenance costs. Questions, however, had arisen about the possibility of increased corrosion due to galvanic effects. This paper investigates the galvanic-coupling behaviours of three different types of stainless steel and carbon steel. Tests were performed both in electrochemical cells and with specimens in concrete inside an environmental chamber. The results show that oxygen reduction on stainless steel is the rate-determining factor for galvanic coupling of these two metals. It is much lower than that of passive carbon steel. As a result, the galvanic coupling of stainless steel with carbon steel will not increase the risk of corrosion of carbon steel reinforcement.

Jan 1, 2005

By A. Alfantazi

Recently, titanium and its alloys have been the materials of choice for the liner and internal components of autoclaves used to extract Ni and Co from laterite ores. There have been many corrosion incidents ranging from localized attacks due to scale formation or welding, to damage caused by pockets of concentrated acid. Most of the literature focuses on methods to avoid the corrosion altogether. Little has been published to increase awareness of the chemistry at these conditions. For this paper, a literature review of the thermodynamics of titanium was undertaken to decipher the slew of information available. E-pH diagrams were constructed from select data and compared with the results of electrochemical experiments. Since nickel laterite leaching takes place in sulphuric acid, and in many cases chloride concentrations are very high, the Ti-H2O, Ti-Cl--H2O and Ti-SO4---H2O systems were considered.

Jan 1, 2004

By J. D. T. Steyl

Anglo American Corporation and the University of British Columbia have developed a medium-temperature oxygen pressure leaching process for the extraction of copper from chalcopyrite concentrates in an acid-sulphate system (AAC/UBC process). Leaching is performed at 150°C and surfactants are added to disperse molten elemental sulphur from the unreacted sulphide surface to prevent liquid sulphur occlusion. Copper extractions of over 95% and elemental sulphur yields of around 60% were observed over a 2-hour average residence time in a continuous pilot autoclave. Sporadic blockages occurring under continuous conditions were found to be caused by the accumulation of molten elemental sulphur mixed with unreacted sulphide mineral. A batch programme of experimentation was undertaken to establish the reason for this phenomenon. Batch experiments were conducted at low pulp densities on concentrate samples with narrow size distributions and at similar solution compositions to those experienced in the pilot autoclave. The overall rate of chalcopyrite oxidation was shown, under approximately constant solution composition, to be a strong function of the total available mineral surface area. Initial copper extraction rates followed the shrinking particle kinetic model under intrinsic surface control. Deviation from shrinking particle kinetics was however observed after a certain oxidation time. Secondary electron images identified small (typically less than 20 µm) sulphur conglomerates at the point of deviation, which 'collected' unreacted chalcopyrite mineral particles and lowered the total mineral surface area available for oxidation. These sulphur clusters are thought to be the precursor for blockages experienced in the continuous pilot autoclave. These results emphasised the importance of fine grinding (P80 5-20 µm) and suggest that shorter residence times may minimise the formation of sulphur conglomerates in a continuous autoclave operating at medium temperature.

Jan 1, 2004

By J. A. Finch

Individual mineral cyclone performance curves were determined for the four major minerals at two lead-zinc concentrators. Sizing was by screen and cyclosizer down to approximately 10 um, with lead , zinc and iron as saying of each size fraction. The performance curves were similar in shape and located according to the mineral specific gravity, Pm. The curves displayed a discontinuity at the fine end and a magnitude of short-circuiting of fines to the underflow which increased with Pm. Mass fraction of water to the underflow was only a guide to this short-circuiting. Sharpness of separation seemed in dependent of Pm. An inflection in the over-all performance curve was shown to be a consequence of the individual component mineral performance. A general relationship was observed showing that the flow regime of classification changed from laminar/ intermediate to turbulent with increasing cyclone feed size. Individual mineral size reduction for the four major minerals at one of the concentrators was also determined. Size reduction of the silica was greater than that of the galena, in contradiction to their accepted relative grind-ability. The observation did correlate with silica being much coarser than the galena in the feed to the ball mill. It is suggested that the silica acted as a buffer to the galena.

Jan 1, 1977

By J. J. Brummer

The possibility of diamonds occurring in Canada was first raised by W. H. Hobbs in 1899, who concluded: "that the apex of the fan of diamond distribution probably lies somewhere in the strip of the territory bordering James Bay on the east." This was based on the occurrence of diamonds in surficial sediments at various locations south of the Great Lakes. There are two recorded discoveries of drift diamonds in Ontario: (a) the Peterborough Diamond, 33 carats in size, poorly documented and found sometime before 1920;and (b) the Jarvi Diamond, 0.255 carat, found during 1971 in Sheraton Township near Timmins . Both discoveries were in surficial sediments and their source(s) have not been located. During 1960, Selco Exploration Company Ltd. started a heavy-mineral sample program of river gravels in the James Bay Lowlands of Ontario. This was continued by Canadian Rock Company Ltd. (1962-1963) and the Ontario Division of Mines (1973). The surveys discovered the presence of kimberlite minerals in gravel samples from streams draining the Moose River Basin. A total of 53 pyrope grains, four magnesian ilmenites and one grain of chrome diopside were identified from 32 sample locations. A study of the distribution of these minerals suggested the kimberlite source rocks to be located along the north margin or within the Kapuskasing gravity "high" in the area immediately south of James Bay. The Jarvi Diamond, found on an esker east of Timmins, could well have originated from this area. During 1965, an esker was sampled by the Geological Survey of Canada, and the results attracted attention to the area south of Lake Abitibi. At 9 out of 34 sites sampled along the Munro esker, Lee recorded the presence of pyrope garnets and very minor chrome diopside.

Jan 1, 1978

By H. Bouzahzah

Sulfidic tailings, subjected to atmospheric water and oxygen action, can generate acid mine drainage (AMD); which is the most important environmental problem facing the mining industry. AMD generating potential can be assessed by the static tests which consist of a screening method where the neutralization potential (NP) and the acid-generating potential (AP) of a given rock sample are determined. The AP and NP are determined separately in the different static test existing procedures which can be divided into two distinct classes: chemical and the mineralogical methods. For some chemical method, the AP is calculated on the basis of total sulfide sulfur content in the sample which may overestimate its AP if significant quantities of non-sulfide sulfur species are present (e.g. organic S in coals, some sulfate as gypsum, barite, etc.). However, the mineralogical method evaluates the AP by the sum of the individual sulfides participation on acid generation based on their concentration within the sample and can be more accurate than the chemical method. For AP calculation, the Paktunc (1999a) mineralogical static test takes into consideration all sulfide minerals occurring in the sample. However, it does not take into account the rates of acidity production of these sulfides submitted to weathering conditions. So, the present study focusses on the modification of Paktunc AP calculation by considering the acidity production rates of these minerals. To reach this objective, five base-metal sulfides (pyrite as reference, chalcopyrite, sphalerite, arsenopyrite, galena), diluted within quartz (25?75 wt.%) simulating mill tailings were subjected to a kinetic test to evaluate their AP. The results show that all the studied sulfides minerals generate acidity at different rates, so the Paktunc?s equation for AP calculation has been adapted accordingly.

Aug 1, 2013

We describe a new method of characterising the effect of dissolved materials on the rate of coalescence of bubbles in aqueous media. Single bubbles were allowed to rise to meet the surface of an aqueous solution, and the time of persistence between arrival and bursting of bubble was measured as a function of solute concentration. A laser beam was placed just above the surface of the liquid, with a detector in the light path, so that any disturbance at the surface could be seen as a break in the beam. The arrival of a bubble at the surface could be detected from the behaviour of the trace on an oscilloscope, and when the bubble broke, another significant change in the signal could easily be seen. The time between disruptions was reported as the persistence time. The effect of a homologous series of n-alcohols (C1 to C8) on the persistence time was measured, in aqueous solution. It was found that with increasing concentration of a particular solute, the persistence time increased up to a point, and then declined. However the magnitude of the persistence time was found to increase with increasing numbers of carbon atoms in the molecule. Bubbles of 1, 2 and 3 mm diameter were used. Persistence time increased with increasing bubble diameter, the maximum values observed being of order 100 secs. For a given solute, the persistence (drainage) time increased with increasing bubble diameter. The concentration Cmax at which the maximum persistence time was observed, was found to be independent of the bubble size. It decreased uniformly as the carbon number increased, and was well correlated by the function y1/2 (dy /dc) -2 I dc)-2 . There was no apparent correlation with the surface excess at maximum persistence time.

Jan 1, 2006

By The Staff

Introduction It is the purpose of this paper to discuss a number of the metallurgical improvements in the technology of copper-nickel ore treatment which have been introduced during recent years in the plants of ?the International Nickel Company of Canada, Limited. In common with other ore treatment processes, the procedure for extracting nickel and copper is changing almost continuous! y. These changes are necessitated by reason of changes in ore grades and characteristics, rising material and labour charges, and the constant drive to maximize metal recovery and to minimize production costs. It is not possible to present a comprehensive list of all the changes made, and only a selected number of the improvements in the milling, smelting, and refining operations are covered. It should be clearly understood that some phases of the procedures described have been pioneered by others in kindred fields and due acknowledgment is given to their foresight and efforts. Articles have been published over the years describing the operations of the International Nickel Company plants and the reader is referred to the Engineering and Mining Journal, Vol. 130, No. 9, November 10th, 1930, and to the Canadian Mining Journal, Vol. 58, No. 11, November, 1937, and Vol. 67, No. 5, May, 1946. Other references are the Transactions of this Institute, 1932, 1938, and 1946; Metals Technology, American Institute of Mining and Metallurgical Engineers, February, 1938, and Canadian Chemistry and Process Industries, April, 1940.

Jan 1, 1948

By L. Bichler

Utilizing thermal analysis techniques, pioneering research into the solidification mechanism of a popular magnesium alloy AZ91E cast by the Lost Foam Casting (LFC) process was carried out, Foam characteristics, section thickness and application of vacuum were seen to have profound effect on the cooling rate, thermal gradients and casting temperature profiles.

Jan 1, 2005

By D. Chakravarty, D. Dutta, B. Samanta, S. Patteti

"This paper presents the mixed spectral behaviour of iron ores from deposits in Gua, India. Spectral signatures of powder samples and their two-component mixtures were generated by spectro - radiometry. Spectra were divided into continuum and absorption components. A modified Gaussian model was used to extract subtle features from the absorption components of the spectra. A linear unmixing model (LUM) applied to estimate minerals from the spectra of mixed powder samples indicated that this model achieved an R2 value of 0.88. The LUM was then applied to estimate the abundance of ores from a hyperspectral satellite image of the deposit area.RÉSUMÉ Le présent article montre le comportement spectral mixte de minerais de fer de gisements à Gua, en Inde. Les signatures spectrales d’échantillons de poudres et leurs mélanges à deux composantes ont été générés par spectroradiométrie. Les spectres ont été divisés en composantes de continuum et d’absorption. Un modèle gaussien modifié a été utilisé pour extraire des caractéristiques subtiles des composantes d’absorption des spectres. Un modèle de démélange linéaire, appliqué pour estimer les minéraux dans le spectre des échantillons de poudres mixtes, indique que ce modèle a atteint une valeur R2 de 0,88. Le modèle de démélange linéaire a ensuite été appliqué pour estimer la quantité de minerai à partir d’une image satellite hyperspectrale du secteur du gisement."

Jan 1, 2015

By J. K. Weglo, M. U. Savich

"The measurement and evaluation of the noise emanating from an ST4A scooptram in an underground stope under a simulated work cycle, and under three conditions of after-treatment systems is covered.These include scooptram without muffler or filler (bare engine), an in-line small filter, compared to a larger-filter, and the larger filter with an in-line muffler in series with fume diluter, which were tested under three engine operating conditions-IDLE, wide open throttle (W. 0. T.), and working condition. This is load, short haul and dump operation.The results showed an attenuation of the scooptram at work of 8 to 15 dBA, 16 cm from the exhaust pipe of the machine, to 4.8 dBA at the operator's ear. Recommendations are made to increase the attenuation at the operator 's ear by additional improvement in design of the fume diluter.IntroductionIn current mining operations, the diesel engine provides a safe, efficient and highly mobile source of power. In the major underground mine s in Canada the most common types of diesel equipment are load-haul-dump (LHD) machines and ore trucks. In general, there is a tendency to use high horsepower, diesel LHD machines in mines to achieve maximum productivity. The increased use of diesel-powered equipment in underground mines has shown no cause pressure levels were measured at the exhaust and outlet pipe. Also, while measuring the octave band and A-weighted sound pressure levels, the operator's position was also measured."

Jan 1, 1986

By P. F. Berry

X-ray fluorescence analytical techniques are fairly well established in the mining and metallurgical industries. In recent years, instruments utilizing radioactive isotopes have been developed which, owing to their more compact size, greater reliability and independence of substantial power supplies, are often preferred to X-ray tube installations. Analyses can now readily be carried out in the field, on the factory floor and in otherwise difficult locations. This paper describes many examples of radioisotope X-ray fluorescence for the analysis of metallic minerals, finished metals and alloys and also for the continuous measurement of metallic coatings, such as tin and zinc, on steel. Radiation scatter techniques are also described for certain analyses and for thickness and density measurements.

Jan 1, 1967

By Arnaud Faucher, Amar Sabih, Sudarshan Martins, Tristan Martin, Sami Makni, Peter Radziszewski, Poorya Hosseini, Francois-Raymond Boyer

The measurement of acoustic signals produced by a tumbling mill has been previously used to determine the operating state of the mill and correlate the variations of the sound intensity with the operating conditions of the mill. Separately, the discrete element model (DEM), a software simulation of the mill, was developed to provide insight into the operation of the mill. Presently, there has not been much work reconciling the DEM simulation of the mill with the acoustic signal. Working from basic principles of linear, time-invariant systems, agreement between an acoustic DEM simulation and the measured signal is sought. First, the impulse response function of the mill is measured. The DEM provides the forces applied to the mill shell as a function of time. A convolution of these simulated shell forces and the transfer function gives the simulated acoustic signal. This signal is compared to the measured acoustic signal, both in the time domain and the frequency domain. Finally, a discussion of the results is given.

Jan 1, 2012

By C. Yoo

"Geosynthetics engineering has made phenomenal advances during the last decade in areas of manufacturing as well as practical applications. As a result, geosynthetics are now being recognized as essential construction materials that can be used to facilitate construction, ensure better performance of the structures and reduce the long-term maintenance in routine civil engineering works. The creative use of geosynthetics in geo-engineering practice is expected to continuously expand as innovative materials and products are becoming available. In this paper, a wide variety of geosynthetic products available to geoengineers to solve a wide range of problems are briefly presented along with their functions and possible applications. Fundamentals of geotextile filter design principles are then introduced for use in the tunnel drainage system. Practical applications of geosynthetics relevant for tunnel engineering are also highlighted with emphasis on the issues associated with the geotextile filter application for use in the tunnel drainage system.INTRODUCTIONGeosynthetics have emerged as essential engineering materials in a wide range of civil engineering applications, e.g., transportation, geotechnical, geoenvironmental, hydraulics, and private development since the first geosynthetic conference in Paris, 1977 (Koerner 2012). Due to their costeffectiveness, ease of installation, and well established mechanical and hydraulic properties, geosynthetics are now playing important roles in the field of geo-engineering.As indicated in the 9th Bucahanan Lecture paper by Holtz (2001), major developments in civil engineering have only been possible with the parallel developments in the technology of construction materials. For example, larger scale structures became possible with the help of developments in concrete, reinforced concrete, and prestressed reinforced concrete technology which replaced wood and building stone as construction materials. The best example of a parallel development in geo-engineering between the material and the geotechnical application may perhaps be the soil reinforcement technology which has a direct analogy with reinforced concrete as a polymeric reinforcement material provides added level of tensile resistance and stability to soils that have little to no tensile strength, thus giving additional margin of safety."

Jan 1, 2015

By M. Hames, K. Larmour-Ship, B. Grinbaum, E. Buchalter, R. Hackl, B. Wassink

Sodium cyanide continues to be the lixiviant of choice for gold dissolution. Many gold ore-bodies contain a significant amount of cyanide-soluble copper which increases the cost of processing due to high cyanide consumption and high cyanide destruction and disposal costs. Several cyanide destruction processes are in use today, however, there are just a few cyanide recovery plants operating. A solvent extraction process to recover cyanide has been developed which utilizes the organophosphorous extractants Cyanex 923, di-butyl-butyl-phosphonate (DBBP) or tri-n-butyl phosphate (TBP) in Bateman Pulsed Columns. Copper cyanide species are first converted to hydrogen cyanide (HCN) by acidification, with or without sulfide addition. HCN is extracted by the organic and stripped using a suitable base (eg. NaOH) resulting in a high strength cyanide solution (eg. NaCN) for recycle to the gold recovery process. Continuous pilot plant testwork on HCN extraction using a 40 mm diameter Bateman Pulsed Column demonstrated a cyanide recovery of greater than 99% with final levels of cyanide in solution of less than 10 ppm. These results illustrate the potential of this technology to recycle cyanide and to detoxify final effluent streams.

Jan 1, 2005

By A. O. Orumwense

Mill circumferential speed, the number of passes of pulp through the grinding chamber, media type, size and filling ratio were investigated in an attempt to determine how to effectively grind copper concentrates in a stirred mill. The stirred mill product fineness was enhanced to some extent by decreasing media size, high media filling, and an increased number of passes of the pulp through the grinding chamber. Shape also plays a major role in grinding media effectiveness, with spherically shaped media producing a finer size. The fineness of the product increases with increasing power consumption but the method of energy transfer is very important in energy utilization. The effect of the mill parameters on copper flotation was evaluated. Copper recovery was influenced by grinding media size, mill speed and the number of pulp passes through the grinding chamber.

Jan 1, 2006

By V. G. Papangelakis, G. A. Moldoveanu

"One of the major commercially viable secondary sources of rare earths elements (REE) are the ion-adsorption ores, containing 0.05-0.3 wt% rare earth oxides physically adsorbed on the surface of clay minerals formed during weathering of lanthanide-rich rocks. Although ion-adsorption deposits are substantially lower grade than other types of rare earth sources, this is offset by the easier mining and processing costs and the low content of radioactive elements. The conventional extraction route involves ion exchange leaching with monovalent cation solutions (usually ammonium sulphate) under ambient conditions; during the process, the lanthanides are desorbed and transferred into solution, being replaced by the exchange cation. While ammonium ions are known to perform best, there is increased environmental motivation to investigate alternative lixiviants in order to minimize ammonium sulphate impact via reducing its use without considerable loss in rare earth recovery.The objective of the present research was to screen various cations salts (alkaline and alkalineearth metals present as sulphates, chlorides and acetates, respectively) in order to comparatively evaluate lanthanide desorption levels and provide a theoretical base of the observed behaviour. The overall aim is to gain a better understanding of how both cation and anion may affect the overall REE recovery from ores in order to provide alternative processing routes. The distinct exchange capabilities of cations were explained in terms of differences in cation hydration enthalpy within the same group, i.e. Cs+ > NH4 + > K+ > Na+ > Li+ and Ba2+ > Ca2+ > Mg2+. For the same cation, it was determined that REE extraction efficiency follows the order sulphate > acetate > chloride, based on dissimilarities in constants of formation values. Various process implications scenarios will be described based on using mixed cations and anion matrices."

Jan 1, 2016