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By E. J. Marcotte

"BRIEF DESCRIPTION OF GRINDING CIRCUITCrushed ore at -5/ 16 in. is delivered by a conveyor system from the crushing plant to two 1250 ton fine ore bins. The ore is transferred from each bin by a 30 in. feeder conveyor belt, operated by a Link Belt P.I. V. (variable speed) drive, to a 24 in. conveyor that feeds the 8 x 10 Allis Chalmers rod mill.The rod mill discharges to a common mill discharge pump box. Three 6 x 6 SRL pumps are employed to pump the combined mill discharge pulp to a common distributor box which distributes the feed to two of the three Kreb D lSB cyclones in each of the two banks at a hydraulic pressure of 6 psi.The cyclone overflow at a specific gravity of 1. 25 (i.e. 32% solids) is transferred by gravity to two revolving chip screens for wood chip removal and from there to a pump box. Two 5 x 5 SRL pumps feed the pulp to the thickeners. The underflow from the cyclones is fed to two 8 x 8 Allis Chalmers ball mills which discharge to the common mill discharge pump box. Thus, a closed circuit is formed between the ball mills and their respective bank of cyclones. The circulating load as most recently calculated is 262%."

Jan 1, 1966

By K. E. Haque

"Radium is selectively leachable from uranium ores with various types of lixiviants. Among a number of lixiviants tried on Midwest Lake uranium ore, KCl provided the highest per cent of radium extraction (60%-65%). Leach results further confirmed that a certain portion of Ra is not amenable to KCl leaching. More than 99% of the dissolved radium could be removed by treating the KCl leach liquor with barite or with radium selective complex resin (XFS-43230 resin of Dow Chemical Inc.) or by precipitating as RaBaSO4. Uranium leachings from the Ra-preleached uranium ores indicate that radium leaching prior to uranium may be applied as an extension to the conventional or alternative (i.e. acid chloride) leaching process of uranium ores in order to yield environmentally acceptable tailings (in terms of radium in the solids).IntroductionAt present, radium is considered as an environmental issue, particularly for uranium ore mine mill operations, rather than a commercial commodity. Radium was once a highly priced commodity ($180/mg during the first great war) but now it hardly has any commercial value. Its principal applications were in the field of cancer treatment and in the manufacturing of lwninous dials for watches. Nowadays readily-available synthetic radioisotopes are finding applications in place of radium.Because of scarcity and high toxicity, further commercial applications have never been explored.Radium was first discovered and extracted from uranium ore by P. Curie, M. Curie and G. Bement in 1898. Radium is widely distributed in nature but in exceedingly minute quantities. It is one of the daughter products of uranium or thorium and its maximum concentration is 3.3 x 10-7 part/part of U(21). Because of its short half-life (approximately 1620 years) in a geological time scale, its occurrence in nature as a distinct mineral is most unlikely.The details of the original radium leaching process developed by the Curies and Bernont are in the literature. This process essentially involved the roasting of uranium ore with caustic. carbonate followed by sulphuric acid leaching. The precipitated RaSO4 and BaS04 were treated with boiling Na2CO3 to convert them into the corresponding carbonates which later were dissolved in HCI. RaCI2 and Ba02 were separated and concentrated from the chloride liquor by fractional crystallization. But, in the course of time several modifications were made or proposed to the original process. Regardless of the process employed 226Ra extraction from the uranium ore was seldom better than 90%, and further as much as 20% 2URa loss took place during the concentration and purification process."

Jan 1, 1987

By Masaharu Moteki

At present, the Unmanned Construction System (UCS) is adapted on initial operation against the disaster. For instance, it has been used in Unzen. When the scale of the disaster is big, or the danger to a person is big, the UCS is expected as a quick and safe construction technology. The Remote Controlled UCS is introduced into construction site to repair earth-fill embankment or to remove rock, as urgent measures after the disaster outbreak. For improvement of the operability, shortening of the skill time, reduction of the fatigue, examination of the most suitable system (placement of a monitor and the joy stick) of the remote system is a main theme in the Public Works Research Institute (PWRI). In the report of this year, when the operator controls construction machine directly or he controls it using remote system (he can check the situation of site only via monitor), the degree of achievement, construction efficiency and construction precision were inspected. The remote system which is based on the system used at Unzen was developed at PWRI.

Aug 1, 2013

By Ross Gallinger

In 1997 a group of Canadian mining companies met to review the Mine Environment Neutral Drainage (MEND) program and to consider future activities. They concluded (i) that Canadian industry and NRCan should fund a small secretariat in Ottawa to support technology transfer in Canada and (ii) that it was important for industry to continue the momentum of MEND on an international scale. The need for INAP (International Network for Acid Prevention) was strongly endorsed by company, university, consultant and government experts from Australia, Canada and the U.S. who were convened in Vancouver in February 1998. The initial focus was the development of a solid knowledge base covering the collective experience of INAP's members to promote the dissemination of successful practices, the identification of knowledge gaps and the formulation of effective research proposals. The sharing of information on past successes and failures alone was viewed as sufficient justification for the formation of INAP. INAP was officially launched in October 1998, and is now an effective, industry based initiative to globally coordinate research and development in the management of sulfide mine waste. Significant improvements in the management of sulfidic mine materials through knowledge sharing, research and development of technology by INAP will reduce liability associated with acid drainage. This paper will explore the international efforts and activities of INAP.

May 1, 2002

By John Kruse, Sethu Raman, Dave Tenney

The Cullaton Lake B-Zone gold mine was the first gold producer in the Kaminak Subprovince of the Canadian Shield . Located approximately 650 km north of Thompson. Manitoba, the mine produced 77,783 ounces of gold and 5,564 ounces of sil ver from 251 ,236 tons of ore during 1981-84 period. The depos it is a small , structurally controlled , stratabound orebody in an Archean iron formation. Most gold occurs in sulphide and silicate fac ies. Based on new ev idence, the depos it is interpreted to have fo rmed by remobilization of syngenetic low-grade gold mineralization in the iron fo rmation in a favoura ble fold structure. The concept and methods developed at the mine have been successfull y applied in the discovery of new deposits in the area. One of the concepts. which link Archean and Proterozoic mineralization. may have wider applications in the search fo r gold deposi ts elsewhere in Canada .

Jan 1, 1986

By William DeWit

When rivers are contaminated from industrial operations, as often occurs near repositories of spent mine tailings, decision-support tools can be critically important in evaluating the effectiveness of various engineering impact-management measures. Even where data describing river flows and quality are sparse, simple mixing-zone models can be constructed that can contribute greatly to understanding how impact-management measures can differentially affect existing river-chemistry regimes. There can be circumstances where accumulated surface waters near contaminated land can bear contaminant loadings that could be acceptable to river regimes if there were methods available to evaluate optional discharge rates and to predict post-mixing consequences on river chemistry. Nomographs can be constructed to evaluate discharge regimes that appear capable of releasing contaminated accumulated pond water without compromising water quality in a nearby river. River-mixing zone models also contribute to predicting rates of acceptable discharge and release to the receiving environment.

May 1, 2011

By B. A. Sparkes, J. H. Reeves

"The St. Lawrence Granite hosts vein-type fluorite mineralization that was mined until 1977. Recent drilling identified a significant fluorite-bearing structure hosted in adjacent meta-sedimentary country rocks. Several phases of vein fill and brecciation indicate there are three phases of fluorite mineralization, of which the later two phases are volumetrically significant. The earliest fluorite is purple and occurs along joint and fracture surfaces, in fault-breccia matrices, and as stockwork veins. The second phase comprises primarily red, yellow, blue-green, and white colours of fluorite. The latest phase is green with lesser clear fluorite. Identification of fluorite veins in the meta-sedimentary rocks opens up new areas for exploration.RÉSUMÉ Le granite St. Lawrence contient une minéralisation filonienne de fluorite, laquelle a été exploitée jusqu’en 1977. De récents forages ont permis d’identifier une structure importante contenant de la fluorite encaissée dans des roches métasédimentaires adjacentes. Les nombreuses phases de remplissage de filons et de formation de brèches indiquent qu’il y a eu trois phases de minéralisation de fluorite et les deux dernières sont importantes d’un point de vue volumétrique. La plus ancienne fluorite est mauve et se trouve le long de surfaces de joints et de fractures, dans les matrices de brèches de failles et en tant que stockwerks filoniens. La deuxième phase comprend surtout des fluorites de couleurs rouge, jaune, bleu-vert et blanc. La fluorite de la plus récente phase est verte avec des quantités moindres de fluorite claire. L’identification des filons de fluorite dans les roches métasédimentaires ouvre de nouveaux secteurs pour l’exploration."

Jan 1, 2016

By M. Tsesarsky, M. Hazan, E. Gal

"Rock masses comprised of stiff inclusions in softer matrix are common in various geological environments. The heterogeneity and multi-scale nature of these materials make the evaluation of their mechanical properties a challenging task, which cannot be accomplished using conventional laboratory tests and composite mixture rules. We employ the homogenization method to estimate the mechanical properties of geological materials with inclusions. The homogenization method solves the equations of elasticity on the material (microscopic) scale for a unit cell subjected to unit strains under periodic boundary condition. The micro-scale elasticity equations are solved using the Finite Elements Method, and are in turn used to obtain the structure scale (macroscopic) material matrix.In this research, Finite Element models for unit cells with spherical and ellipsoidal inclusions were developed. Using the unit cells, a parametric study of the geometrical and statistical microscopic properties of the material composites was performed. The following parameters were studied: volumetric ratio, Young’s modulus ratio, size-distribution of inclusion and inclination angle of inclusions. The main purpose of the parametric study was to study the deviation from isotropy as a function of the aforementioned parameters.It was found that for volumetric ratio of 5%-40%, the deviation from isotropy increases, as the volumetric ratio of inclusions increases. For spherical inclusions, most of the cases studied exhibit quasiisotropic behaviour; whereas ellipsoidal inclusions exhibit considerable deviation from isotropy. The inclination of the ellipsoidal inclusions enlarges the deviation from isotropy (9% at random orientation and 26% at 0°)."

Jan 1, 2015

By L. H. Thorleifson

Demand for both gem and industrial diamonds is very strong. Synthetic production supplies industrial uses, but synthetic gems remain inferior and expensive, so the large gem market is supplied by mining. Several major mines have been depleted, and the market is receptive to new sources of high quality gems. Canada's Precambrian terrane, extending across the Canadian Shield and under the Phanerozoic cover of the Plains and Hudson Bay, has excellent potential for diamonds, but exploration conditions are difficult due to recent glaciation. Early world exploration relying on recognition of diamond in alluvial sediments was adequate to launch pre- 1900 production from India, Brazil, and Africa. Exploration success in Canada, as was the case in Russia and other more recently discovered sources, however, had to await large investments in effort supported by advanced science and technology. Canadian exploration in many ways is similar to that in other regions, relying on analysis of tectonics, indicator minerals, geophysical surveys, and multiple stages of drilling and sampling. Very different from other regions, however, is Canada's surficial environment, in which recent glaciation has caused fresh indicator minerals to be transported hundreds of km. Exploration accelerated in Canada after 1960, first in Ontario and the Arctic Islands, then in Saskatchewan in 1988, and most importantly after the Chuck Fipke - Stew Blusson discovery at Lac de Gras, Northwest Territories, in 1991 that led to the billion-dollar BHP - Dia Met Ekati Mine that opened in 1998. In 2003, production from Ekati will be supplemented by that from the similar and nearby Diavik Mine of Rio Tinto and Aber. These mines will bring Canadian output to over 10% of world supply, and will position Canada with Botswana and Russia as world leaders in production of high quality gem diamonds. There could be other mines as well, as sites across the Arctic and in the south from Alberta to Québec are being explored by an array of companies, including De Beers, other majors, and several juniors.

May 1, 2003

By M. Amsden

"Since the computer program is far from complete this must be only a brief progress report on the computerization of flotation metallurgy at the Ecstall concentrator at Timmins.Ecstall is currently treating about 10,000 tons per day of two different ore types. One is a low sulphide copper-zinc ore, the other is a high sulphide lead-zinc-silver ore. The concentrator is divided into three individual grinding and flotation circuits. In effect there are three mills under one roof. Normally there are two circuits on copper-zinc ore and oneone lead-zinc-silver ore. At this point in time one of the copper-zinc circuits is under computerized metallurgy control.The first step in this control is the use of an ARL on-stream x-ray analyzer, coupled with a Honeywell 21 computer which types out assays and recoveries for each individual circuit. Our approach to a computer program was to keep it simple. The program was written to coincide as closely as possible to what an operator would do in the performance of his duties based on the in-formation he was getting from the x-ray analyser read-out. Initially, computer control was put on just the copper circuit of the ""A"" Division, controlling the collector addition at three points in the circuit; primary, secondary, and scavengers. The control was based on recoveries and the grade of the copper concentrate. Targets like 95% recovery and 24% copper concentrate grades that it was felt the circuit could achieve were set to start with. It quickly became apparent that this alone was not enough because if on a certain ore the best recovery that could be made was only 94.9% the computer kept calling for more reagents until the circuit was completely out of control. On another ore it might have been quite possible to get 96% recovery but when the set point of 95% was reached the computer stopped trying for any more. To overcome this problem a very simple optimum seeking program was devised by one of the Ecstall staff and it has worked very satisfactorily since being put into use in July 1970.In the copper float only the two collectors R-208 and the xanthate R-317 are under computer control. The addition of frother and depressant is left to the operator. The flotation cells have automatic level controls which can be adjusted by the operator. pH is controlled automatically through a lime loop-sensor arrangement."

Jan 1, 1971

By A. I. Gorshkov, Y. A. Bogdanov, O. Y. Bogdanova

Abstract - Detailed crystal-chemical study of iron and manganese oxides and some other minerals from low-temperature hydrothermal deposits in a newly discovered inactive mound in the TAG hydrothermal field were used to determine the precipitation sequence of mineral phases during lowtemperature processes and their post-sedimentary transformations. Particles of primary sedimentary X-ray amorphous proto-ferrihydrite with high silica content were replaced in situ by nontronite, ferrihydrite, or goethite during alteration. Ferrihydrite is the only proto-hematite phase. The transformation of the iron minerals, related to change in the physicochemical environment, is an important characteristic of low-temperature hydrothermal processes. The occurrence of hydrogenetic Fe vernadite and Mn feroxyhyte in the uppermost part of low-temperature deposits and bottom sediments near the base of the mound is evidence for cessation of low-temperature hydrothermal processes. Among the investigated mineral phases, goethite, nontronite, and hematite are stable in reduced sediments only.

Jan 1, 1999

By P. R. Brito-Parada, G. Bhutani

"The physical processes occurring in flotation columns are very complex as they take place at different scales over a range of sizes and multiple phases. Column design and optimum operating parameters are usually obtained from empirical studies and although progress has been made on its numerical modelling, most column models rely on simplifications that do not fully capture the hydrodynamics. In particular, Computational Fluid Dynamics (CFD) models of the pulp phase in flotation usually assume the bubble population to be monodispersed. While this assumption may be reasonable in some situations, the polydispersed nature of the gas phase can have a significant impact on the predicted flotation rates.Techniques to model size distribution do exist in the literature and have been rigorously analysed in the past two decades for bubble columns, which are very similar to flotation columns from a hydrodynamics point of view. In fact, available CFD models of flotation columns are an extension of bubble column models, sometimes including additional equations for solids treated as passive scalars. This work focuses on the development of an efficient CFD model for flotation columns. The bubble size distribution in the column has been modelled using the Population Balance Equation (PBE), which is solved using the Direct Quadrature Method of Moments (DQMOM). Coupled with the PBE, the multiphase flow equations in the column have been modelled using the standard Eulerian–Eulerian approach. The solution of this coupled system has been made tractable in this work with the implementation of a highly parallelised adaptive-mesh finite element method. This powerful framework has been implemented in the open source CFD code Fluidity and it allows the carrying out of detailed simulations of flotation columns in 2D and 3D, with important implications for industrial column evaluation and design."

Jan 1, 2016

By Gilles Tremblay

The legacy of orphaned/abandoned mines, with their associated environmental liability, human health concerns and the financial costs of clean up is a serious issue facing Canada. In 1999 and 2000, a number of stakeholders put forth requests to Mines Ministers to establish a joint industry-government working group, assisted by other stakeholders to review the issue of abandoned mines. The Ministers supported this initiative and asked that a multi-stakeholder workshop be organized to identify key issues and priorities. The Workshop on Abandoned Mines, held June 2001 in Winnipeg, developed consensus, guiding principles and recommendations that were presented at the Mines Ministers? Conference, September 2001. Ministers agreed on the importance of a large-scale program for the rehabilitation of orphaned/abandoned mines sites. A multi-stakeholder Orphaned/Abandoned (O/A) Mines Advisory Committee was formed and a plan was developed to study various issues relating to the implementation of remediation programs across Canada. Three task groups were formed to address the following key areas: Information Gathering; Community Involvement; and Barriers to Collaboration. The presentation will include a summary of the results of the three projects and the future work plan for the program.

Nov 1, 2002

By E. J. Debicki

"At the 1992 PDAC Convention, Norman Keevil announced the formation of the Exploration Technology Division (ETD) of the Mining Industry Technology Council of Canada (MITEC). It was evident that base metal reserves in Canada were declining and that the cost of discovering a deposit in Canada was increasing. Coordinated research to develop new exploration technologies was required to discover the next generation of ore-bodies. The ETD was formed in response.The mission of the ETD is to contribute to the survival, profit, and growth of the Canadian mining industry by improving the efficiency and effectiveness of mineral exploration through development of innovative technology by man-aging and coordinating applied cooperative research. In addition, it is the intent of the ETD to become the principal agency by which cooperative research funds are transferred to researchers from the mining industry. The division is industry driven, industry funded and industry managed.The ETD’s Three-Year Plan has focussed80% of its research funds toward two objectives, improving the efficiency of exploration for VMS deposits and establishing the parameters necessary to discover the next Hemlo deposit. The remaining 20% is allocated to other projects, with the current emphasis on geophysics.In 1995, corporate members total twenty-three major mining companies accounting for90% of the exploration expenditures in Canada. The ETD is currently managing ten cooperative research projects totalling $4.6million. Other projects, estimated at $1.6 mil-lion, are currently under development."

Jan 1, 1996

By Robert MacPhail, Louis Racine, Bret G. Cousins

"Sodium Isopropyl Xanthate is employed in a wide variety of sulphide flotation procedures due to the specificity over other xanthates and the cost savings over other sulphide collectors such as thionocarbamates, xanthogen formates and dithiophosphates. An investigation carried out by Tennants Research Technology Applications (TRTA), has produced a chemically enhanced SIPX that has shown all the advantages of normal SIPX along with improved recoveries.Currently, FLEX 31 is manufactured at the Prospec Chemicals xanthate plant in Fort Saskatchewan, Alberta, Canada. Prospec, founded in 1983, produces approximately 4500 tonnes of xanthates per year and is presently undergoing expansion to produce approximately 6000 tonnes. The proprietary process for FLEX 31 is a new addition to plant operations that include the production of xanthates, thionocarbamates and xanthogen formates.This paper will cover the testwork on the zinc flotation circuit at the Louvicourt Mine in Val d'Or, Quebec. This testwork indicated that FLEX 31 could replace SIPX due to the ability of the FLEX to improve zinc flotation kinetics without adversely affecting final concentrate grade. FLEX has presently replaced SIPX in the zinc circuit at Louvicourt.BackgroundThe Louvicourt deposit is hosted by greenschist facies Archean volcanic rocks located in the southeast portion of the Abitibi Greenstone Belt. In the Val d'Or area, the volcanic rocks form an east-west striking, steeply dipping and south-facing sequence composed of thick mafic and ultramafic flows of the Lower Malartic Group.The joint venture has three partners-Aur Louvicourt Inc. (30%), Novicourt Inc. (45%) and Teck Corp (25%). Aur Resources holds 30% interest through Aur Louvicourt, a wholly owned subsidiary and is the operator of the project. Novicourt Inc. is 60.9% held by Noranda.Approximately 75% to 85% of Louvicourt's revenue comes from the sale of copper; 10% from gold (in the copper concentrate); 7% from zinc and 3% from silver (also in the copper concentrate) The copper at Louvicourt is fairly ""fast floating"". About 60% of the copper in the ore can be concentrated in the first flotation cells with feed grades of approximately 4% copper.The initial testwork and pilot trials had indicated that it would be difficult to achieve zinc grades over 52% and recoveries would have to be kept at a level amenable to salable concentrate grades. The actual mill results, with a fine regrind, achieved zinc grades of 55% to 56% at about 75% recovery."

Jan 1, 1996

By Noel Billette, Jean-Luc Chouinard

"An analysis of the number of industrial injuries shows that the mining sector is particularly affected, since mining is one of the most dangerous industrial activities in Canada. This has led to numerous inquiries, and supports the need for an in-depth study aiming at the identification of factors responsible for these accidents. One possible factor often pointed at is the small crews incentives and this paper presents a scientific approach applied to check a potential link between bonus and accidents at two mining companies located in northwestern Quebec.The data required to do so were the accidents, the salaries and the number of hours worked at each mining site by the hourly paid personnel for the period from June 1979 to January 1982. The analysis of the results derived from the initial information shows different behaviours of the frequency rate vs the bonus rate at these mines. The number of days lost per accident is independent of the bonus rate at both mine sites, as shown by Khisquare tests on contingency tables.IntroductionA wide variety of opinions has been pinpointed by a survey of the literature related to individual or small crew incentives and industrial accidents in sectors of activity where it applies. In addition, various formulae of mining contracts take place in the industry on one part, and statistics from this sector indicate a high accident frequency rate on the other part. These fact s have lead to this scientific investigation which does isolate the direct impact of the bonus on workers' accidents. This study was undertaken with the full support of the Quebec Metal Mining Association.The conclusions of this preliminary phase of the researchproject are presented for two mining complexes in northwestern Quebec. The procedure is somewhat similar to the approach of the Belmoral Commission, with the underlying assumption that bonus has a direct impact on accidents."

Jan 1, 1986

By R. K. Jonas

Many leading copper and other mineral processors have rapidly adopted advanced controls in last 5-10 years. Almost 600 multivariable predictive controls have been installed in mineral processing, and almost 50% of those are in copper concentrator plants. In most cases, mineral processors rely on 3rd party support to implement these advanced technologies. One challenge facing advanced control user is the selection providers and services for these technologies. The trend has been towards the use of multivariable predictive control and use of technology provider’s services. This paper will discuss status of advanced control, and the merging trends in the mining industry. A review will be presented of how advanced control is being applied in the mining industry over the last decade, and how user challenges are being overcome. Next the emerging uses of multivariable predictive control (such as multi/inter-unit optimization), focusing on the latest trends in concentrator plants. Finally, a review will be made of emerging technology advances in the that can be advantageous to mineral processors. INTRODUCTION Review of advanced control in mineral processing Advanced controls are serving an increasing role to improve processing plant operations and profitability. As advanced control is being installed into more mining processing plants such as copper concentrators, many of these plants are concerned about the selection technologies and vendors to support the installation and maintenance of these controls. In a study by Jonas and Craw (2011), they found that most new users have not had prior experience with advanced controls. It is the author’s experience of almost 30 years in advanced controls that most mineral processers considering advanced controls can benefit from better understanding of the technologies and their support requirements.

Jan 1, 2019

By B. S. W. Buffam

"The property of Moneta Porcupine Mines, Limited, consists of a group of eight claims in Tisdale township, Ontario. It includes part of the townsite of the town of Timmins, and adjoins the west boundaries of the Hollin_ger Consolidated and Mace properties. The Moneta property was first staked in 1909, about a year after the first discovery of gold in the Porcupine camp. In 1910 the Moneta Company was incorporated and some preliminary exploratory work performed by Nova Scotia Mines of Cobalt. In 1912 English interests advanced $90,000 for diamond drilling and underground work. One drill hole gave high assays, but apparently the records were poorly kept or the cores were interchanged. As a consequence, when underground exploration was undertaken in 1923 it was directed south rather than west and no ore was found . In 1924 about 5,000 feet of diamond drilling was done in the southern part of the property, but without intersecting ore.In 1931 W. E. Segsworth assumed the direction of the property. Diamond drilling commenced on August 18, 1936. The first hole intersected 9.9 feet of ore averaging 1.23 oz. gold a ton. Underground work was started early in 1937. A mill was erected in the autumn and the first gold brick was poured January 29, 1938.The Moneta mill began operation on January 2, 1938, and the following table gives a summary of the production to June 30, 1943, when the mill was closed."

Jan 1, 1954

By Masashige Makifuchi, Hiroki Kumakura, Kota Nagai, Takahiro Kikuchi

"A large amount of platinum group metals (PGM) are used in automobile catalyst. It is important to recover the metals from wasted catalyst. Nomura and Kageyama (2013) suggested recovery process that PGM oxides were absorbed to perovskite-type oxide based on LaScO3. In their process, the PGM in wasted catalyst as absorbed to the perovskite-type oxide as PGM oxide. It has potential to each element in the process if the perovskite-type oxide is selected properly. In this study, the PGM oxide absorption properties of various perovskite-type oxides are investigated to develop a new recovery and separation process. The various perovskite-type oxide were synthesized with metallic platinum, palladium, rhodium at high temperature in air atmosphere. And the PGM contents in the perovskite-type oxide after the experiment are determined by chemical analysis. Some of them have the properties to absorb specific PGM oxide selectively. In addition, in order to increase the amount of absorption of PGM oxide and composition of the perovskite-type oxide experimental temperature was investigated. Then it is also found that doping another specific element to the perovskite-type oxide is effective to increase the amount of absorption of PGM oxide. Then a new recovery process of PGM from wasted automobile catalyst, in which PGM can be separate to each element, was designed.INTRODUCTIONA large amount of Platinum (Pt), Palladium (Pd), and Rhodium (Rh) are used in automobile catalysis (Figure 1) (Platinum, 2013). Natural supplies for these metals are limited and PGM mining can detrimental environmental impact. Therefore, the recycling of PGMs from wasted automobile catalysis is very important. The Rose process (Figure 2) was developed as a process to recover PGM from wasted automobile catalysis. In this process, the automobile catalysis is first crushed mechanically, and then extracting agent, copper (Cu), and flux are melted at high temperature. The mixture separates into a metal phase, (Cu alloy containing PGM) and slag. The PGM is enriched by oxidizing. Cu to Cu oxide. The PGM are then recovered and separated to each element in a wet process. However, it is hard to dissolve the PGM with acid because they are chemically stable and strong oxidation agent such as aqua regia is used. Moreover, to separate the PGM to each individual element, a solvent extraction process is required."

Jan 1, 2016

By K. P. Plucknett, Z. Memarrashidi

WC-Co ‘hard metals’ are widely used in a variety of industrial applications due to their resistance to abrasive wear, in addition to their high hardness and toughness. However, in contrast to their mechanical properties, the corrosion response of these materials is relatively poor. In the current work the corrosion mechanisms of two WC-Co cermets are analysed, with 10 and 30 vol. % of the Co metal binder, in a 3.5 wt.% NaCl aqueous solution. The assessment of corrosion involved a variety of electrochemical measurements, including open circuit potential, potentiodynamic polarisation and cyclic polarisation, together with systematic analysis of the post-corrosion solution chemistries using inductively coupled plasma optical emission spectroscopy. The corrosion potential and current density were determined, following Tafel extrapolation, allowing the calculation of the corrosion rates. It is demonstrated that continuous dissolution of the cobalt phase occurs during corrosion, which is a result of poor cermet passivation behaviour, and this response increases with the amount of binder in the cermet.

Jan 1, 2015