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By Michele L. Kimble

A fast-flow reactor mass spectrometer has been utilized to investigate the reactions of gas-phase gold cluster anions with CO and oxygen. Addition of CO to Aun - produces species of the form Au(CO)m -, where m = 2-5. However, CO does not bind to Au2 - or Au3 -. With oxygen addition in the cluster source, gold oxide species with both molecular and atomized oxygen are produced. The addition of carbon monoxide to these preoxidized gold cluster anions reveals that select species with 1, 2, and 3 gold atoms participate in the oxidation reaction to produce CO2. Bimolecular rate constants for the reactions between these species and CO are also discussed.

Oct 1, 2003

By Pierre Antoine Dhaiti, Gilbert Sergerie, Michel Dagbert, Jean-Maurice Brodeur

"Quality of iron ore is generally determined by several factors which can be correlated or independent. Among these f actors, we generally find per cent iron, silica, magnetite or hardness. Forecasting the short- and long-term fluctuations of these f actors in the future pit is an important feature of mine planning in these deposits. Computer simulation provides a realistic answer to these questions. It allows to generate values for the most important quality features of each shovel load with the proper correlations between them as well as between one load and the next being fully reproduced. Then different sampling schemes f or grade control or blending facilities can be examined on the simulated data. The mechanics of the simulation procedure and its potential applications are described in an example.IntroductionThe purpose of this paper is to illustrate the use of in-situ grade simulation in the planning o f the grade control in an iron ore min e. More precisely, given a production unit of given size, we need to know how many samples have to be collected in that unit so that we ca n recognize its grade with a reasonable precision. Conclusions that we would like to arrive at are of the type: with 4 blasthole samples we ca n get the iron grade of a 10,000 ton bloc k with less than a ± 2% Fe error 95% of the time.The approach t hat we take to solve this problem is simulation. We simulate the grade of samples and the grade of the block that contains these samples. We repeat the simulation for hundred s o f blocks. By comparing the sample grade with the block grade in each case, we determine the actual number o f blocks where the difference sample-bloc k is less than a given limit."

Jan 1, 1983

By B. Wasmund, B. Haneman, G. Sheehan

Success in implementing new technology for metallurgical processes is not a foregone conclusion: This paper includes a survey of 23 new technology-based metallurgical plant start-ups, in which the authors have identified 7 successes, 9 difficult start-ups, and 7 failures. Success is defined not only as meeting the schedule and budget to the end of mechanical completion; the key goal is a fast ramp up to the full design production level, with minimum plant and equipment modifications required after start-up. This paper sets out the key factors that underlie achievement of a quick production ramp up curve, as determined from the authors' project experiences and a quantitative analysis of over twenty metallurgical plant start-ups, both pyrometallurgical and hydrometallurgical. Thorough test-work and pilot plants, plus appropriate scale-up to the full commercial plant, are key determinants of success in implementing new technology in metallurgical processes. Another critical factor is the number of new elements and their interactions. Project phasing is also particularly important for new technology projects, with appropriate review after each phase to develop a risk mitigation plan for the subsequent phase. New technology projects need committed champions to advance the project in the face of sceptics, but also require dispassionate and unbiased experts to ask the hard questions. As a project evolves, it is important to periodically question the appropriateness of assumptions, as well as to re-assess the relevance and completeness of data from test-work I pilot plants I industrial analogues. Sufficient human and financial resources are required to complete the often arduous implementation phase. During the ramp-up period, the operation generates little positive cash flow; however, significant expertise and capital are required for the de-bottlenecking projects that are often necessary to reach the plant's design output level.

Jan 1, 2011

By A. B. Irwin

"Discussion at MeetingDR. D. DERRY (Ventures Limited) referring to the diagram (Figure 15) which shows a transverse structure section across the Central Slocan area, asked what the assumed structure at depth was, remarking that dips are steeper and more uniform at depth and that the contortions with gently-dipping axial planes are at higher elevations. He wondered whether the section represented ,part of a very large fold with steeply-dipping axial plane.MR. J. D. LITTLE (Canadian Exploration, Limited) replied that E. B. Mayo (Kelowna Exploration Company) and others had considered that the entire section illustrated faces to the southwest and represents part of the lower limb of a great overturned •syncline which is concave toward the southwest.DR. R. DEWIT (Geological Survey) remarked that the photograph of a ripple mark (Figure 7) showed internal lamination conformable to the ripple mark and wondered if the structure was not due to slumping during consolidation, since the normal mode of formation of ripple mark would seem to preclude the possibility of such internal stratification.MR. LITTLE remarked that in his opinion such structures should not be depended upon alone with-out other confirmatory evidence of the direction of tops of beds."

Jan 1, 1952

By F. Charette

Instrumentation has been developed that can monitor the strain applied to a D-Bolt up to 7.5% elongation. The technology far exceeds the limit for foil resistance strain gauges. In the laboratory the instrumentation has provided insight into the fundamental behaviour of the D-Bolt following yield. Currently the instrumentation is undergoing field trials at a number of Canadian Mines. Discussion on field results is provided with regards to significance, reliability and temperature effects.

Aug 1, 2013

By L. J. Cabri

A gold sample assaying 11.4 g Ault was selected for this study. Approximately 99% of the gold in this sample occurs as discrete gold minerals; the balance occurring as invisible gold in pyrite (determined by SIMS analysis). The sample was coarsely ground and sieved, yielding -38, 17, 22 and 22 wt.% in the -400+160 um, -160+80 um, -80+40 µm and -40 µm size fractions. Assays of the size fractions gave a gold distribution of -32, 20, 21, and 27% respectively. Processing with the hydroseparator (model HS-02) gave two tailings products and one concentrate from each size fraction. Assays of the concentrate from each size fraction gave gold recoveries of -7, 7, 24, 19%, respectively. Polished sections were prepared from each hydroseparation product and studied by image analysis to automatically search for gold minerals. Calculations were done using the surface area of the grains of gold minerals found on the polished sections.

Jan 1, 2005

By K. Ramji

"The development curve in the extractive sector has become longer, steeper, and riskier due to increased social, legal, and political risks from various stakeholders. Indigenous peoples are a unique stakeholder because their growing legal rights to lands and resources can often determine a project’s outcome. A project will only be successful if it is able to obtain the legal permits, withstand any judicial reviews, and gain and maintain the social license to operate. Stakeholder identification, management, and engagement are key risk-mitigation tools required to successfully convert risks into opportunities.RÉSUMÉ La courbe de développement du secteur de l’extraction s’est allongée, elle est devenue plus abrupte et plus hasardeuse en raison de l’accroissement des risques sociaux, légaux et politiques venant des divers intervenants. Les peuples autochtones sont des intervenants uniques puisque leurs droits légaux croissants sur les terres et les ressources déterminent souvent ce qu’il adviendra d’un projet. Un projet ne pourra réussir que s’il est capable d’obtenir les permis légaux, passer à travers les analyses judiciaires, puis obtenir et maintenir le permis social d’exploitation. L’identification des intervenants, la direction et l’engagement constituent les outils clés de l’atténuation des risques nécessaires pour bien convertir les risques en possibilités."

Jan 1, 2016

By Robert A. Gault, T. Scott Ercit, Mehmet F. Taner

"Abstract -Vanadium mineralization occurs in oxide-rich horizons within the layered gabbro zones of the upper parts of the Bell River Complex, Matagami, Québec and the Lac Doré Complex, Chibougamau, Québec. The vanadium-rich horizons are well defined on the ground and in aeromagnetic surveys by their high magnetic susceptibility; consequently, magnetic susceptibility can be an indicator of vanadium mineralization. The main oxide minerals are ilmenite and titanian magnetite, containing 20% to 70% of volume and the ratio of titanian magnetite to ilmenite is relatively constant, ranging from about 1:1 to 2:1. Their sizes are less than 5 µm to greater than 1 mm to 2 mm, occurring as coarse- to medium-grained subhedral crystals intergrown with cumulate silicate minerals (plagioclase, pyroxene, etc.). Electron microprobe analyses indicate that the ilmenite grains are mineralogically and compositionally homogeneous and have low V contents (average 0.18% equivalent V2O5). In contrast, the titanian magnetite grains are inhomogeneous, consisting of trellisworks of ilmenite lamellae in Ti-poor, V-rich magnetite [less than 2 wt% TiO2, and 1.41% equiv. V2O5 (1.16% V2O3) for 20 analyses]. Thus, the magnetite is the principal ore mineral of vanadium; it hosts vanadium in the form of V3+, not V5+, as is commonly and erroneously reported. We have also devised a flowchart for the beneficiation of vanadium-titanium ores. Sommaire - La minéralisation de vanadium se trouve dans des horizons riches en minéraux oxydés de la partie supérieure des zones de gabbros lités des Complexes de la Rivière Bell, Matagami, Québec et du Lac Doré, Chibougamau, Québec. Des horizons riches en vanadium ont été bien définis sur le terrain et dans les levés aéromagnétiques par leur susceptibilité magnétique élevée; conséquemment, la susceptibilité magnétique est l’indicateur directe du contenu en vanadium. Les principaux minéraux oxydés sont l’ilménite et la magnétite titanifère, contenant 20% à 70% du volume et le rapport de magnétite titanifère à ilménite est relativement constant, allant d’environ 1:1 à 2:1. Leur dimension varie de 5 µm à plus grande que 1 mm à 2 mm, apparaissant sous forme de cristaux subidiomorphes, de grains grossiers à médiums, intercroissant avec la gangue silicatée (plagioclase, pyroxène, etc.) de la texture de cumulat. Les analyses à la microsonde électronique montrent que les grains d’ilménite sont minéralogiquement et chimiquement homogènes avec un faible contenu en V (moyenne 0.18% équiv. V2O5 ). Contrairement, les grains de magnétite titanifère sont hétérogènes, contenant des lamelles d’ilménite en "trellisworks"; ces grains sont pauvres en Ti et riches en V pour la portion magnétite de la magnétite titanifère [surtout contenant moins de 2 wt. % TiO2, et en moyenne 1.41% équiv. (1.16% V2O3) pour 20 analyses]. Ainsi, la magnétite est le principal minerai de vanadium; elle renferme du vanadium sous forme de V3+ et non de V5+, tel qu’il a été communément et à tort rapporté. Nous avons aussi défini un "flowchart" pour la bénéficiation des minerais de vanadium-titanium."

Jan 1, 1998

By A. F. Abd El-Rehim

The behavior of both transient and steady state creep of Al-4.5 wt% Cu and Al-4.5 wt% Cu-0.1 wt% In alloys was investigated using a constant stress where torsional oscillations of different frequencies and shear strain amplitudes were operated at various working temperatures. An augment in both transient and steady state creep rates was observed by increasing both frequency and shear strain amplitude of the applied oscillations. The mean values of the activation energy of both alloys for both creep stages were found to be equal to that quoted for dislocation intersection mechanism.

Jan 1, 2006

By H. W. Leon, F. J. Ellis

"This paper covers the new six-strand curved-mould billet casting machine at the Contrecoeur Works of SidbecDosco. It commenced production of 3 Yz-in. square billets at the beginning of January 1972. Together with two 100- ton ultra-high-power electric furnaces in a new meltshop, it is the principal source of billets for the existing rod and bar mill also located at Contrecoeur. The paper develops the reasoning for casting-to-size 3Y2 -in. billets and for choosing a six-strand machine. It indicates the significance of Sidbec-Dosco Montreal Works' extensive experience in operating a four-strand curvedmould billet machine since 1965 and the ways in which this experience influenced the design and operation of the new caster. Machine features are described in detail, as are the reasons for some of the features. The installation, checkout and crew training are briefly discussed as well as the tundish teeming trials. The first cast on January 5, 1972, is covered and a log is shown of the first casts to an empty ladle. There are operating statistics covering the first 100 casts, which produced 8000 tons of good billets in ten weeks of operation. Machine performance and billet quality were good and the few minor problems encountered are described."

Jan 1, 1973

By G. Minhas, M. Pule, Y. Laffitte, M. c. McGurn, T. Tzanetakis, Peacey. J., R. Susilo

Titanium (Ti) metal production from titanium tetrachloride (TiCl4) using magnesium (Mg) as a reducing agent is the well-known Kroll process. A chloride route is used to avoid oxidation of the titanium sponge. The sponge is consolidated into ingots and can then be made into powder by melting and atomizing or by hydriding/dehydriding. Attempts at direct powder production have met with difficulties, including low Ti yield and the formation of very fine particles (particles between 25-100 µm are desired). This paper discusses two methods to produce Ti powder in a molten salt medium using magnesium powder as a starting material instead of a pool of molten magnesium. The first method is a direct reduction of gaseous TiCl4 injected in the melt with the magnesium powder in suspension in the molten salt. The second method is a two stage TiCl4 reduction reaction where recycled Ti was used to form titanium dichloride (TiCl2) in the first stage followed by addition of magnesium powder into molten salt in the second stage. A correlation between Ti yield and processing variables such as TiCl4 to Mg ratio, Mg particle size, TiCl2 concentration in the melt, and reaction temperature was studied. The Ti powder formed was also analyzed for particle size distribution. Despite challenges and difficulties encountered, this paper shows some promising results which could provide guidance to others working on direct Ti powder production.

Jan 1, 2015

By S. C. Robinson

"IntroductionALTHOUGH most uranium deposits of the Canadian Shield lie along its western and southern margins, those of the Lake Athabasca region extend easterly along the north shore of the lake and beyond to Charlebois lake. The western end of this belt of deposits, in the vicinity of Goldfields, is 80 miles from the Palaeozoic contact, and its eastern end, at Charlebois lake, is 240 miles from the nearest Palaeozoic rocks.Deposits in this belt may be grouped in four districts, which are, from west to east:(1) The Goldfields district, an area approximately 20 miles square, centred on Beaverlodge lake and extending eastward from St. Joseph's point to Moose channel.(2) A small area in the vicinity of Sucker bay, which is about l0 miles east of Fond du Lac.(3) An area including Middle lake to the northwest shore of Black lake at the Nisto mine.(4) A fairly large area extending northward from the eastern end of Black lake, through Charlebois lake to Spreckley lake.HistoryThe region has stimulated interest in mining circles since the reconnaissance survey of J. B. Tyrrell of the Geological Survey of Canada in l893, who reported concentrations of iron along the north shore of lake Athabasca. The deposits were staked and re-staked up to the early 'twenties' but are too lean to form ore."

Jan 1, 1952

By David L. Anderson

"The government o f Canada has, since 1981, been under intense political pressure to modify its foreign direct investment (FOI) regulatory regime(1). To date the government's response has been limited to administrative and ""cosmetic"" changes: substantive issues have been largely ignored(2). However, as long as the economy continues to flounder , the Foreign Investment Review Agency (FIRA), as it is presently formulated , will continue to be an easy target for government critics . This phenomenon, in conjunction with the virtual certainty of a federal general election within two years, suggests that changes to the FIR Act will be seriously entertained by the present government.Recent events indicate that if change s are made, they will likely entail the adoption of a special-sector approach within the existing framework of a general screening system(3). Since this approach is currently employed in Australia(4), it would seem to be appropriate, from a public policy perspective to study that country's experience in developing and operating such a scheme. In doing so, I shall focus on the mineral sector; the rationale for doing so is as follows. First, this sector served as the focal point of the Australian FOI regulatory debater(5), Second , with the exception of the oil and gas industries, the non-petroleum mineral sector is one of the few areas of the Canadian economy wherein the Trudeau government has adopted an explicit domestic ownership target(6). Third, the non-petroleum mineral sector is, undoubtedly, a prime candidate to be denoted a s a special-sector if such a framework were to be utilized by the Canadian government!"".Although international comparisons are fraught with danger , a Canadian/Australian comparison is particularly appropriate(8). Both countries have reasonably similar economic, political and social structures . Furthermore, as noted above , Australia is the only other western country which employs a general screening mechanism for FOI. In addition, it utilizes a special area approach ; within this scheme, an explicit target of a minimum of 50% Australian ownership of all new resource projects has been formulated and clearly promulgated to all of the relevant interest groups. This policy, broadly defined, has been in place for more than six years and during this time the Australian mineral sector has, by world standards, prospered(9). Hence, the Australian experience in designating the mineral sector as a key area within a general screening system, should be of interest to Canadian policy-makers."

Jan 1, 1984

By D. M. Muir

The mineralogy of residues formed during the pressure acid leaching of arid region nickel laterite ore varies according to the salinity of the process water, alkali cation additives and the overall acid loading. In fresh water, hematite is the main iron-bearing leach residue component, together with amorphous silica and hydronium or sodium alunite/jarosite [(H3O,Na)(Fe,Al)3(SO4)2(OH)6]. As the process water salinity increases, or as NH4+ or K salts are added, alunite/jarosite is the kinetically favoured iron-bearing phase accompanied by an increase in acid consumption. The alunite/jarosite appears as two XRD distinct phases with different Fe:Al molar ratios. In weakly saline water, iron-rich alunite/jarosite slowly transforms to hematite and an aluminium-rich alunite/jarosite together with the release of acid. The addition of potassium salts forms a more stable alunite/jarosite whilst the addition of ammonium salts leads to greater transformation of alunite/jarosite at 250°C. Weakly saline process water gives enhanced nickel recoveries, whilst strongly saline process water gives lower nickel recoveries but higher soluble iron because of chloro-complexation. SEM and microprobe analysis shows very little nickel is associated with the alunite/jarosite and hematite phases. Nickel losses to the residues are attributed to adsorption on amorphous silica and to a lesser extent on alunite/jarosite.

Jan 1, 2006

By John Drew Ridge

"Over the years, ore geologists have made innumerable observations as to the relationships of certain kinds of ore deposits to particular types of rocks and to the types of primary and secondary structures that these rocks contain. On the basis of these, the places in which to look for new are deposits are more clearly defined than they would be in an exploration program based largely or solely on concepts of ore genesis. This paper discusses the affinity of certain rock types and structures for such ore deposits as: (1) tin-tungsten associated with granitoid rocks; (2) lead-zinc of simple mineralogy in carbonate rocks; (3) massive base-metal sulphides in sedimentary or volcanic rocks; (4) massive base-metal sulphides and oxides at, or near, contacts with igneous rocks; (5) gold or gold-uranium in, or adjacent to, conglomerates; (6) shale- or sandstone-hosted copper; and (7) porphyry coppers. Additional varieties could be considered, but it appears that these examples are sufficient to demonstrate the validity of the suggestion that the use of observational characteristics is far more useful in mineral exploration than that of theories of ore genesis.As by-products of the theory of plate tectonics, many concepts have been put forward to explain how ore deposits of different kinds have been formed. Most, if not all, of these theories seem to be as valid as present-day information permits. However, do these ideas add to the ability of the ore geologist to find ore deposits? I doubt it, and offer reasons as to why I think so.To produce maximum results in any exploration program, the one that makes the greatest use of information produced about the geologic environment of the area being investigated is the one that will provide the greatest return in deposits found for the sponsors of the program. Such exploration is best designated as total exploration, and it certainly is the most effective way of uncovering such new deposits as may exist in the area being studied in particular and of adding to the sum total of nonfuel minerals deposits available to the industrial world in general."

Jan 1, 1983

By C. R. van Staal, L. R. Fyffe, J. A. Winchester

"The geochemical characteristics of Early Paleozoic volcanic rocks are used to establish the following tectono-volcanic regimes in the northeastern mainland Appalachians: foreland continental rift volcanics; fore-arc ophiolites; island-arc volcanics; back-arc ophiolites; and back-arc ensialic volcanics. A Late Precambrian calc-alkaline magmatic arc bounds the Early Paleozoic volcanics to the southeast.The Precambrian calc-alkaline volcanics of the Caledonian Highlands, primitive Cambro-Ordovician oceanic-arc volcanics of the Eastern Townships, and within-plate Ordovician volcanics of the Miramichi Highlands can be related to a progressive change in mode of subduction from compressional Andean-type in the Late Proterozoic to extensional Western Pacific-type in the Early Paleozoic. The development of marginal oceanic basins in the Paleozoic created a more favourable environment for volcanogenic sulphide deposition, particularly in back-arc areas.The influence of tectonic setting is reflected in the distribution, size and metal ratios of the massive sulphide deposits associated with the volcanic rocks; deposits within intra-oceanic arcs in the Eastern Townships of Quebec average two million tonnes grading 2.2% Cu, 4.0% Zn, and 0.6% Pb, whereas those within a back-arc, ensialic rift near Bathurst, New Brunswick, average nine million tonnes grading 0.6% Cu, 5.4% Zn, and 2.2% Pb."

Jan 1, 1990

By Karl J. C. Harries

13.1. RIGHT TO RECEIVE ROYALTY CONTRACTUAL ONLY1

Jan 1, 2003

This paper generalizes open stopes into elliptical cross sections and applies the results of calculations based on the mathematical theory of elasticity to indicate stress distribution on the boundaries of such stopes. These show both compressive and tensile stresses and provide an ex-planation for the development of excessive dilution in shrinkage toping. Introduction T HE stress pattern around shrinkage stopes is identical with that around other stopes under the same physical conditions. However, a shrinkage stope ends as an unsupported open stope, and the method i limited to the stress range within which the rock is generally self-supporting. If it is acceptable to generalize the outline of a shrinkage stope into an elliptical cross section, then the graphs of Geldart & Udd (1) (see also Panek (2) and Denkhaus (3)) provide a good base for approximating the stress distribution as mining progresses. However, with failure conditions in the walls, the axis ratio, as cut

Jan 1, 1964

By Rakesh Kumar, Rajabrahma K., A. K. Verma, V. Mukesh

"In this study, laboratory investigation as well as numerical investigation is carried out to ascertain the transition from one mode to another for Semi-circular bend setup. Laboratory investigation is carried by varying the span length (s/2R); crack length (a/R); notch angle (a); and notch thickness (t). The specimen consists of cement, sand and water mixture in a ratio of 1:1:0.5 by weight and are prepared as per the ISRM standards (2014). Tests are conducted by a servo controlled universal testing machine at a strain rate of 0.2 mm/ min. The results are collected in terms of failure load, crack mouth opening displacement (CMOD) and images of crack initiation and propagation.Image analysis of laboratory tested samples shows that crack initiates at the notch tip when the notch inclination angle is 0°. As the notch angle increases (i.e. 30° and 60°) the fracture begins to initiate behind the notch tip. The direction of crack propagation in front and back side of the sample is same for notch inclination angle is 0° whereas it differs more and more as crack inclination increases. The transition represents the change in mode of failure from mode I (0°), mode II (30°) and mixed mode I/II fracture (60°).Finite element method used to find the transition based on MTS failure criterion. The inclination of notch is varied like 40, 42, 44, 45, and 50 deg and FEM analysis shows that the transition from mode-I to Mode-II take place at 49 deg. The same procedure can be extended to find the transition from mode-II to mode-III."

Jan 1, 2015

By C. -S. Xie, J. -H. Kong

The microstructure and mechanical properties of X80 hot-rolled thick steel strips with a thickness of 17.5mm produced in Wuhan Iron & Steel Company (WISCO) are introduced in the paper. The steel strips as fabricated through proper thermomechanical processing (TMP)/ on-line accelerated cooling (OLAC) processing have shown high strength and toughness, low brittle transition temperature, good weldability, and high Shear Area (SA) percentage in Drop Weight Tear Test (DWTT). The microstructure of the steel strips is characterized with mainly acicular ferrite, and fine dispersed Martensitc-Austenite (M-A) phases. It is determined that the mechanical properties are improved due to the presence of the fine M-A phases and precipitates, which could be formed by reducing the finish rolling and coiling temperatures.

Jan 1, 2005