Search Documents

By Yongbin Yang

Cathodic reduction of oxygen is a process involved in many fields. As is well known, the mechanism of oxygen reduction usually varies considerably with electrode substrates. In this paper, cathodic reduction of oxygen on gold electrode was studied by linear sweep voltammetry with regards to cyanide leaching of gold. As the results shows, the electron transfer number increases as potential shifted negatively and decreases as pH value increases. Besides, the increment of electron transfer number as a function of potential decreases when pH value increases. When pH increases to 13.0, the volt-ampere curve exhibits a relative flat section with currents approximate to the limit current density of a 2e process. By varying dissolved oxygen concentration, the electron transfer number was calculated for pH11.0 at different potentials, the results being 2.387e, 2.732e, 2.982e, and 3.227e at, -0.35V, -0.40V, -0.45V, and 0.50V, respectively. The calculated current densities are in good conformity with measured results.

Jan 1, 2010

By Lars Arne Granlund

Due to the coarse structure of mining explosives, one has to model a finite reaction zone,contrary to C-J calculations, describing their detonations, i.e they become dependent of diameter and confinement, An effort within the DYNO group has been to investigate if the DSD theory ( originally developed by Bdzil, Stewart / Los Alamos ) can be used to describe major groups of civil explosives.The groups of explosives tested are dynamite, anfo, aluminised emulsion, heavy anfo and straight emulsions.

Jan 1, 1995

By D. M. Evans, D. L. Buchanan

Paper presented at the IAGOD international symposium on mineralisation related to mafic and ultramafic rocks, held in Orleans, France, 1-3 September 1993. The Zinca area was chosen as a suitable location for an investigation of the weathering and secondary dispersion of platinum group metals from the Zone. It was concluded that platinum is immobile while within weathered rock, its mineral phases tending to alter from primary sulphides and tellurides to secondary Pt-Fe alloys. Palladium is variably mobile in weathered rock. In stream sediments Pt occurs mainly as small, dense, discrete particles, giving rise to a nugget effect, whereas Pd probably occurs as much finer particles or chemically adsorbed on to a suitable substrate. Pt shows a rapid decrease in sediments downstream from mineralisation, whereas Pd has a much slower downstream decay

Apr 1, 1994

By George J. Tamara

The urban environment presents special challenges for the design and construction of earth retention systems. Complications arising from difficult subsurface conditions are compounded by the presence of urban infrastructure and existing and prior construction. The proximity of adjacent structures as well as intense prior use can cause special concerns including the potential for archeological artifacts or contaminated ground or ground water. Utilities and structures may be particularly vulnerable to the effects of ground movement, dewatering and vibrations. Difficulty of access, congestion and limited work areas may severely restrict means and methods of construction. Dewatering may be limited or prohibited because of concerns for disposal of clean or contaminated water, depletion of aquifers, drawing of contaminants to the site or dewatering induced settlements.

Jan 1, 2003

By Morgan L. Race, Matthew R. Glisson

"Most driven pile projects have plumbness limits from 0.25 in/ft (21 mm/m) to 0.5 in/ft (42 mm/m) to control bending stresses. For two projects, the project teams performed static load testing to evaluate performance of piles with sweep. One project, located in Grand Forks, North Dakota, used 9.625-inch (244-mm) diameter piles with a wall thickness of 0.395 inch (10 mm) and lengths ranging from about 130 to 160 feet (40 to 49 m). Measured pile sweep (lateral offset distance of the pile toe from the pile top) was between 12 and 17 inches (305 to 432 mm). Static load testing indicated that the piles could support the design load with axial deflection of less than 1 inch (25 mm) but only provided about 80 to 90 percent of the ultimate resistance at axial deflections of about 1.9 to 1.7 inches (49 to 43 mm), respectively. The other project, located in Shakopee, Minnesota, used 9.625-inch (244-mm) diameter pile but with a wall thickness of 0.352 inch (9 mm) and lengths around 50 to 90 feet (15 to 27 m). The measured sweep varied between about 20 and 63 inches (508 and 1,600 mm) for 9 of 214 piles driven at the site. Load testing indicated that these piles could provide the required design resistance with less than 0.3 inch (8 mm) of axial deflection and support the required ultimate resistance with about 0.5 to 0.6 inch (13 to 15 mm) to of axial deflection.INTRODUCTIONAnyone who has observed a significant number of piles has seen that, inevitably, the pile is not perfectly straight after driving. In spite of the best efforts of contractors, there are a whole host of reasons for piles to end up out-of-plumb or to have a curve, sometimes referred to as pile sweep. Most project specifications set limits for plumbness typically between 0.25 in/ft (21mm/m) and 0.5 in/ft (42mm/m) (USACE, 1991; PDCA, 2007; MnDOT, 2016; MoDOT, 2016). Closed-end pipe piles, including monotube or tapertube, are the only pile type that allow actual measurement of the final alignment of the pile.As Nadeem, et al. (2015) note, buckling failure of long, slender piles is the predominant mode of pile failure in soft soils. Pile sweep is just one source of buckling failure in long, slender piles. The nonlinear buckling analysis showed that increasing slenderness ratio and/or increasing degree of curvature decreases the loadcarrying capacity of a driven pile. Nadeem, et al. (2015) considered solid, steel pile with lengths from 24 to 66 feet (7.5 to 20 m), diameters from 9.75 to 26 inches (244 to 660 mm), initial bends from 2 to 6 inches (50 to 150 mm), and half- and quarter-sine shapes."

Jan 1, 2017

By G. S. Austin

The St. Cloud Mining Company extracts clinoptilolite about 6.5 km south of Winston, Sierra County, New Mexico. Production is about 18,000 mt/year. Natural zeolites are good adsorbents for positively charged solutes such as ammonium. St. Cloud’s production is used in animal hygiene, animal feed, environmental mitigation, air and water filtration, and other applications. By a simple chemical treatment with a surfactant, zeolites can also be modified to adsorb negatively charged solutes such as nitrate and arsentate, and neutral organics such as solvents and fuel components. These surfactant-modified zeolites are used in treating groundwater contamination, stormwater runoff, and solvent vapors from painting operations.

Jan 1, 2002

By D Craw

The Old Man Range, south of Alexandra, in central Otago consists of a package of highly folded greenschist facies schist of the Wanaka lithologic association. The range is crosscut by several east to ENE-striking high angle gold-bearing quartz veins, (eg Whites Reef and Grays Reef), which were extensively worked in the late 1800s. The range is bounded on its east side by the Old Man Fault, which separates these rocks from generally flat lying and planar Caples Terrane schist. To the west of the Old Man Fault, about halfway up the range, a large subparallel, 100 m wide fault zone strikes NNW and appears to cut off the historic veins. The fault zone consists of highly sheared and folded rocks and numerous high angle cataclasites and centimetre-scale clay gouge zones. Hydrothermal alteration is not apparent and the individual faults and shears are clay altered, possibly due to weathering, without visible quartz veins. Gold, limonite pseudomorphs after pyrite and rutile are concentrated in some of the narrow cataclasites and gouge zones. These mineralised structures are texturally similar to the gold-bearing reefs and may be structurally related. It is postulated that the NNW-striking shear zone and ENE-striking veins may be a conjugate array formed during a period of Cretaceous normal faulting.

Jan 1, 2004

By Christopher Mark

Pillar recovery continues to be one of the more hazardous activities in underground coal mining. Safety requires that the roof above the intersection remain stable until after the pillar has been extracted. Artificial supports (timbers and Mobile Roof Supports) arc essential to roof stability, but so is the final remnant stump or pushout. Traditional mining practices usually called for the complete extraction of the final stump, but the recent trend (both in the U.S. and internationally) seems to be towards mining plans that leave a remnant stump. For this study, a sample of roof control plans from the Mine Health and Safety Administration (MSHA) Coal Districts were analyzed to determine current pillar recovery practices. Both full- and partial- extraction plans were included. Special attention was paid to whether plans require that a final stump be left, and whether requirements regarding the dimensions of the remnant stump are included. Foreign experience with final stumps is also summarized. It seems that the risk of major pillar falls can often be reduced by leaving final stumps that are large enough to protect the intersection, but small enough that they do not inhibit the caving of the gob. Because final stumps are often irregular in shape, a new approach for estimating their strength is described. Analyses were conducted to assess the effect of seam height and depth of cover on the potential variation in the size of remnant stumps.

Jan 1, 2001

By W. M. Dressel

This Bureau of Mines report describes a shaft closure demonstration project in which 11 inverted pyramid-shaped plugs were used to plug abandoned open mine shafts in Galena, KS, The inverted pyramid-shaped forms, fabricated from steelplate, were designed so that the inverted base would be larger, by 4 ft on a side, than the approximate size of the shaft opening at the surface residuum-solid rock interface. After the surface openings of the shafts were trimmed with a backhoe, the steel forms, complete with reinforcing, were lowered into the openings and filled with concrete; the remaining portions of the openings above the plugs were backfilled to slightly above the surrounding surface level with waste rock and soil. Location and elevation monuments were installed for long-tern evaluation of the success of the project.

Jan 1, 1985

By M Donghi, G Ramage, A Barnes

As the mining landscape continues to transform, the challenge of accessing deeper orebodies quickly and safely is becoming a frequent topic of conversation amongst those in the mining industry. The rapid development of underground mine entries to gain earlier access to deeper orebodies is an ever-present challenge to mine owners and contractors. Overcoming this and providing economical solutions to unlock the value in these deeper deposits is a challenge that should be confronted.In 2013, Redpath Australia Pty Ltd (Redpath) commenced construction of what would be the first of two drifts excavated through the use of a tunnel boring machine (TBM) in Queensland’s Bowen Basin.The excavation and development of the two drifts (declines) was completed as part of a contract for underground mining services between Redpath and Anglo American at the Grosvenor Coal Mine Project in Central Queensland, located approximately 5 km north of the town of Moranbah. Having recently completed the drift development, this paper will extend on the early writings of Donnelly, Ramage and Donghi (2014) and provide detail on the operational achievements, advance rates, threats, opportunities and learnings during the excavation of the two declines: the conveyor (CV) drift and the transport (M&M) drift.CITATION:Ramage, G, Donghi, M and Barnes, A, 2016. Experiences gained through tunnel boring machine decline development, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 695–712 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

The Nena high sulphidation-type copper-gold deposit is composed of andesitic pyroclastic units with minor interstratified lava flows. Epiclastic sandstone and conglomerate, and siliciclastic rocks consisting of mudstone, shale, lithic and bioclastic sandstone and conglomerate are locally present. Pre-mineral diorite intruded and domed the volcano-siliciclastic sequence. Economic copper-gold is hosted by vuggy quartz altered lapilli tuff and tuff breccia. The early hydrothermal alteration stage involved deposition of epithermal banded quartz and chalcedonic silica in localised environments. This alteration stage was locally superimposed by a hydrothermal breccia event. Following the breccia event, magmatically-derived volatiles were channelled through a NW striking dilational fault zone and generated the high sulphidation alteration. The high sulphidation alteration is zoned from a vuggy quartz core with local massive replacement silica through a broad pyritic quartz-alunite halo and finally to a thin illite-smectite zone. This is surrounded by regional chlorite-epidote-smectite alteration. A gangue mineral phase consisting of quartz, alunite and baryte overprinted the zoned high sulphidation alteration and preceded the main copper-gold-arsenic mineralisation. Early sulphide deposition is characterised by marcasite, arsenical pyrite and melnicovenite. Main-stage copper-gold mineralisation involved sequential deposition of hypogene bladed covellite+chalcocite, enargite-luzonite and luzonite+stibioluzonite respectively. The copper sulphides are zoned from bladed covellite-chalcocite in the north (cross-sections 5000 - 5600 N) through enargite-luzonite (cross-sections 4700 - 5000 N) and to luzonite????stibioluzonite in the south (cross-sections 4400 - 4700 N). A late phase of minor acicular covellite and enargite+luzonite overprinted the zoned copper sulphides and associated gold mineralisation. Gold mineralisation commenced at the transition from enargite to luzonite, and continued through the deposition of luzonite-stibioluzonite in both stages. Most gold was deposited during the main-stage mineralisation. Yellow native sulphur was deposited in the remaining vugs and defines the waning stage of the hydrothermal system. Post-mineral dioritic intrusives and feldspar porphyries intruded the volcano-siliciclastic sequence. Finally, supergene chemical processes with associated erosion and uplift generated a 40 - 50 m thick oxide-hosted gold cap. The oxide gold cap is underlain by a 35 - 45 m thick blanket of supergene chalcocite+covellite mineralisation which overlies and occurs throughout the main hypogene copper-gold zone. Supergene gold is related to the distribution of primary gold-bearing sulphides. Therefore, remobilisation and redeposition of gold are considered to be insignificant and very localised.

Jan 1, 1999

By Secretary of the Interior

"INTRODUCTION The Bureau of Mines Synthetic Liquid Fuels Program again forged ahead during 1952, and important technical advances led the way to improved methods of converting coal and oil shale into liquid fuels. Marking the eighth year of activities under this program, the pact 32 months brought a new domestic industry nearer realization.The increasing demand for gasoline and oil and the rising cost of finding new petroleum, coupled with America's growing dependence on imports and the unsettled international situation, have continued to emphasize the importance of the Bureau's Synthetic Liquid Fuels Program. Oil, the indispensable material of wartime, likewise has critical importance in peacetime, touching as it does the life of every individual. Supplementing petroleum with synthetic liquid fuels will not only conserve this Nation's petroleum reserves but also will bring into greater use its tremendous reserves of coal, as well as the vast deposits of oil shale for which no other practical use has yet been found.The Bureau of Mines Synthetic Liquid Fuels Program is one of the most important and far-reaching of the Government's research projects. Through development of commercial synthetic liquid fuels, the United States can obtain oil products from its great inland reserves of coal and oil shale to supplement petroleum in any quantity that may be necessary, consistent with economic and other requirements, such as national defense. The use of raw materials from such deposits would be of highest importance in wartime, when shipping lanes are menaced by the enemy. The Synthetic Liquid Fuels Program of the Bureau of Mines and research efforts of industry have advanced. American technology to the point where it is now possible to begin the design and construction of prototype plants. Certainly, significant improvements will be made as the program continues, but this prospect in no way alters the fact that the start of prototype plants should be encouraged. These plants, as the first step in the development of a synthetic fuels industry, would serve a threefold purpose:"

Jan 1, 1953

By Serge Ouellet

Identification and quantification of cementitious phases in cemented paste backfill (CPB) is difficult due to the fineness of tailings and the low binder content used in the mixture. Techniques such as X-ray diffraction and thermogravimetry were ineffective (mainly due to tailing mineral interference) to identify and quantify hydration products in most works reported in the literature. On the other hand, scanning electron microscopy (SEM) was used in many cases but mainly for qualitative purposes. This paper presents the development of a new approach based on a computer program (SEM-XMAP) that combines X-ray dot mapping images acquired by SEM and generates a coloured image representing the mineralogy and the microstructure of a given CPB specimen. The technique is applied to one CPB sample mixed with blast furnace slag (BFS) and acidic sulphated mixing water sampled in a mine dewatering system. The technique allowed identifying calcic matrix, unhydrated and partially hydrated BFS particles, and sulphated phases.

May 1, 2007

By A. J. Geldenhuys

This paper will focus on two topics, namely (1) an innovative process for the neutralization and partial sulphate removal of acid streams produced during coal mining and processing and (2)optimization of this integrated neutralization process by adding small amounts of synthetic organic polymers. The integrated lime and limestone process has been developed to neutralize acid mine water and to remove sulphate (to less than1 200 mg/l), magnesium and metals. Limestone and lime treatment is the most cost-effective technology for neutralization and partial sulphate removal of acidic/sulphate-rich water to sulphate levels of less than 1 500 mg/l due to precipitation of magnesium and removal of the associated sulphate fraction (through gypsum crystallization). Neutralized mine water of this quality may be suitable for irrigation. The process consists of the following stages: 1. Limestone (CaCO3) neutralization to raise the pH to 7 and CO2-production. 2. Lime (Ca(OH)2) treatment to pH 12 for Mg(OH)2precipi-tation and gypsum (CaSO4.2H2O) crystallization. 3. pH adjustment with CO2recovered from stage 1 and CaCO3 precipitation. Retention times of 1 hour, 4 hours and 1/2an hour were required by stages 1, 2, and 3 respectively. The sulphate level was reduced to 1 094 mg/l, which is less than the original aim of 1 200mg/l. Chemical costs associated with neutralization, using limestone instead of lime, are reduced by 69% in the integrated limestone/lime process. The overflow water from the clarifier of each of the above stages generally contains a wide variety of colloidal impurities that may cause the water to appear turbid or may impart colour. This results in very slow sludge settling rates that cause overflow water with a high degree of turbidity and colour. There are a number of successive or simultaneous stages involved in the agglomeration of particles. To get optimum neutralisation of the acid water and partial sulphate removal to below the saturation level of gypsum (i.e. 1 500mg/l), maximum sludge recovery is needed. The higher the concentration of seed crystals, the larger the surface area. Therefore, effective removal of suspended and colloidal matter from the overflow of each stage is required and can be achieved by coagulation and flocculation. The polymers PAC6 and 3095 were effectively used as coagulant and flocculant respectively. The addition of these polymers resulted in a clear overflow in each of the above stages with a very low turbidity.

Jan 1, 2003

The Northparkes E26 Mine is AustraliaÆs first block cave mine. This paper presents an outline of the design and construction philosophies that drove the project development and details the excavation, ground support and construction methods used. Features of the block caving method at Northparkes include:high production rates from multiple drawpoints;hard blocky ore fractured along gypsum veins; andloading/unloading of openings due to mining induced stresses.The drawpoints are subjected to high abrasion from the flow of ore, as well as impact from both secondary blasting and from the production LHDs. In order to withstand these harsh conditions and to ensure a low maintenance environment, a conservative approach to ground support was taken. The experiences gained during construction are discussed and whether the design expectations have been achieved. By installing a high level of ground support during excavation of the openings subject to mining stresses, a low maintenance environment has been constructed. Operating costs are therefore minimised and Northparkes E26 Mine continues to produce at the lowest cost per tonne of all Australian underground mines.

Jan 1, 1999

By W. D. Mcmillan

Important reserves of nickel ore occur in the Levies district in Oriente, Cuba. The area is mountainous and mostly covered by heavy vegetation. The ore bodies comprise surface tracts of nickeliferous laterite underlain with decomposed serpentine of ore grade. The Cuban Nickel Co., a wholly owned United States Government corporation, owns a plant for leaching the nickel from its ores at Nicaro, Oriente, Cuba, Between December 1943 and March 31, 1954, 5,902,225 short tons of ore was treated, with a recovery of 116,206,519 pounds of nickel (52,711 metric tons). In 1953, 1,330, 224 short tons of ore was mined and 27;"3,129 pounds of nickel produced. The Cuban Nickel Co. also owns a townsite, with the necessary facilities, mining equipment, and 11 miles of railroad. Ore for the plant has been produced from the Ocujal-San Juan claims on lends owned by the Nicaro Nickel Co., a sub¬sidiary of Freeport Sulphur Co. The Government enterprise is man-aged by the Nickel Processing Corp. The Cuban Nickel Co. has denounced mineral concessions and has purchased other claims from private owners.

Jan 1, 1955

By Messenger A. J, Miles J. G

A thermal neutron irradiation technique using a mCf neutron source has been developed and applied to thp.simultaneous determination of iron and aluminium (expressed as AI2O3) in iron ore fines (-6 mm particle size) on a moving rubber conveyor belt.While the determination of iron with this technique is based on the use of a NaI(TI) detector to monitor the characteristic prompt gamma rays (7.64 MeV) emitted by thermal neutron capture reactions in the iron, the etermination of AI2O3 is based on the use of a second Nal(Tl) detector to monitor the characteristic gamma rays (1.78 MeV) emitted after thermal neutron activation of the aluminium. The second detector is located downstream from the first. Although the speed of the conveyor belt has no direct effect on the iron measurements, it must not exceed about 3 m/min if good accuracy is required for the AI2O3 measurements. Consequently an auxiliary conveyor belt is required in order to avoid interference with normal ore processing.Dynamic trials of the technique, using 1500 kg samples of ore on a 460 mm-wide rubber conveyor belt moving at 1.7 m/min, have demonstrated that the method can achieve accuracies of 0.7% Fe and 0.1% AI2O3. At the present stage of development, it is recommended that lump ore be crushed to a particle size of 6 mm before analysis.In addition to iron and AI2O3 determinations, measurements of total moisture content and bulk density are possible. The determination of Si02 is also feasible, but a separate fast neutron source (e.g., Am-Be) and a separate gamma ray detector are required.

Jan 1, 1980

By R. E. Chaney

This report summarizes the research on the Strategic and Critical Materials Program tasks conducted at the Idaho National Engineering Laboratory (INEL) between Mdy 1983 and April 1984. The work is divided into two areas: 1. Production Technologies - Tasks directed at developing advanced extraction technologies ? Biologically-Assisted Minerals Processing ? Metal/Gas Reactions and Thermal Plasmas ? Dehydration of Aluminum Chloride Hexahydrate. 2. Conservation/Substitution Technologies - Tasks directed toward establishing the technical processing base which will permit the use of advanced materials ? Joining of Rapidly Solidified Alloys (RSA) ? Joining of Silicon Nitride-Based Ceramics ? Nondestructive Evaluation of Ceramic and RSA Joints and Materials.

Jan 1, 1984

By M. A. Schellhardt

The Bureau of Mines has made periodic back-pressure tests on numerous gas wells in the Texas Panhandle field during the past several years to study the delivery capacities of the wells under different pressure and operating conditions and to determine the relationships between pressures and rates of delivery from gas wells.4/ However, information regarding the intake capacities of gas-well systems is meager, end in projects involving the flow of gas into porous-rock reservoirs it has been necessary to determine intake capacities of gas wells by trial. Accordingly the fundamental intake characteristics of natural-gas yells have been studied to develop a method for determining intake capacities under different wellhead pressures from data descriptive of the "output" or producing characteristic of the wells.

Jan 1, 1936

By Svetlana Nikitina

While many question "sustainability" as an intellectual field on the grounds that it is too broad and "undisciplined," we are able to achieve a good balance between breadth of coverage and depth of inquiry in our team-taught seminar "The Grand Challenges: Sustainable Development for the 21st Century" offered to first year students at Worcester Polytechnic Institute. We strike this balance between breadth and depth by a) problematizing key sustainability issues in class discussions; b) by explicitly exploring the lenses of different disciplines (the historical context, the scientific facts, the engineering interventions and the philosophical foundations of unsustainable behaviors); and c) by offering our students opportunities to pursue a targeted project on specific sustainability issues (vertical gardening, metals recycling on college campus) through which they gain depth of understanding as well as practical exposure to all components of the problem, which puts them on the path of seeking effective solutions.

Jan 1, 2010