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By Christophe Thiébaut

Keywords: Pyrochemistry, Salts Treatment, Distillation The pyrochemical purification of metal generates spent salts. When this metal is an actinide such as plutonium, the slags cannot be discarded and are thus disposed in nuclear facility. In order to handle with these slags, the decision has been taken to reduce stored quantities. The development of a pyrochemical treatment is in progress in the CEA Valduc centre. The feed salt, typically composed of various Pu and Am species contained into monovalent or divalent chloride matrix, is first oxidized to convert the actinides into oxides. Then the chlorides are separated from the actinide oxides by vacuum distillation. Temperatures higher than 750°C for monochloride salts mixture NaCl/KCl and higher than 1100°C for divalent CaCl2 base salts, are required to produce an industrial flow of vaporization. Inactive qualification of the process for NaCl/KCl base salt has been carried out with lanthanide surrogates. Then, a pilot equipment, called distillator has been designed and built for production-scale distillation of NaCl/KCl and CaCl2 oxidized plutonium salts. Industrial flows of vaporization have been obtained with this pilot equipment : about 4 g/cm²/h for NaCl/KCl at 800?900°C and 1 Pa, and more than 1,5 g/cm²/h for CaCl2 base salts between 1000?1200°C at 0.1 Pa. The last step, now in progress, is the integration of the distillator into a glove box.

Jan 1, 2005

By Chen Jianping, Wu Li, Wei Banyun, Chen Canchang

Liquified petroleum gas mixed with oxygen has been used as a new type of mixed gas source for gas detonating system. The experimental studies have been done on the detonation feature of gas detonating transmission in a long and thin tube, the transmitting reliability for detonating network, the design on gas exploder and test devices. The results of the study show that (1 )Liquified petroleum mixed with oxygen can be used as a new type of regular gas source. (2)The transmission of detonating wave is reliable for new type of mixed gas in a 500-meter long plastic tube with 3mm inner diameter and the detonating velocity is up to 2500m/s. The detonating wave can surely initiate and transmit several branched gas detonating cap and explosive through the end of detonating network, the tubes inner diameter for the detonating quenching is 0. I’mm. (3)The gas exploder designed by authors can be used for gas propotional distribution,strong turbulence-mixing,initiating by reflex shock wave and safety control purposes. The developed double flowmeter can be used together or seperately in responsible for main testing in the system.

Jan 1, 1999

By Jim Wickens, Andy Cole, John Pekrul

"The roaster facility at Barrick Goldstrike Mine treats double-refractory sulfidic/carbonaceous gold ore. Prior to oxidation in the roasters, the ore is ground in two parallel dry grinding circuits utilizing 19’ Ø x 75’ double rotator mills. The design plant throughput was 12,000 dstpd. However, process improvements have significantly increased throughput rates by 25-50%. The current daily throughput record is 20,078 dstpd. Grinding circuit improvements contributing to this success include feed size reduction, ball size optimization, automatic ball charging optimization, and operating strategy changes. In addition to the changes already made, this paper discusses future optimization initiatives including on-stream particle size analysis and “real-time” ore hardness determination techniques.INTRODUCTIONBarrick Goldstrike Mines is located 29 miles Northeast of Carlin, Nevada, USA. Through 2001, the property has produced over 23 million ounces of gold making it one of the premier gold operations in the world.Prior to Barrick’s ownership, the property began producing gold from a small heap leach operation in 1975. The small-scale heap leach production continued through 1986, and in January 1987, Barrick acquired the property. Increased exploration activity by Barrick significantly increased gold reserves. In August 1988, a 4,500 dstpd mill facility was commissioned to treat high grade oxide ore. Also, heap leach operations had significantly expanded. In 1990, the mill was expanded to 6,000 dstpd, and the first autoclave was commissioned to treat refractory sulfide ore. By the end of 1996, the mill and pressure oxidation facility had expanded to 16,000 dstpd and heap leaching had ceased as oxide reserves were exhausted. In 2000, a roaster facility was commissioned to treat double-refractory sulfidic/carbonaceous ore."

Jan 1, 2003

By K. K. Murray, D. G. Gelderland

"The pressure oxidation autoclave at the Goldcorp’s Red Lake Gold Mines (RLGM) was commissioned in 1991. Since commissioning, the circuit has been well maintained and its capacity increased to mechanical and gaseous oxygen limitations. With advances in available technology, opportunities to produce more sulphide concentrate and a changing business environment, an optimization project has been initiated at RLGM. A multi-phase approach has been developed to optimize both the operations and economics of the circuit. This paper describes the history and future of the autoclave circuit at RLGM.AcknowledmentsWe would like to thank the operations and maintenance staff at Red Lake Gold Mines for their support and openness of mind to enact changes to enhance the operation. We would also like to acknowledge the members of the integrated team from Red Lake maintence, metallurgy, operations and corporate technical services that did the hard work to push past the status quo in order to advance productivity.OpportunityThe Red Lake Gold Mines (RLGM) pressure oxidation (POx) circuit has been in operation for over 25 years processing the high sulphide content gold bearing minerals. Increased sulphide concentrate production from improved flotation recovery and increasing gold sulphide association at depth has led to the POx circuit becoming a throughput bottleneck. The opportunity exists to process increased tonnages of sulphide concentrates and increase gold production. In order to realize this value, it will be necessary to increase the throughput capacity of the POx circuit.BackgroundThe POx autoclave at the RLGM, commissioned in 1991, was Canada’s first gold autoclave. It was installed to replace the two-stage fluid bed roaster that was built when the Campbell mine and mill were constructed in the late Forties. The circuit was originally designed to process 12.5 t/d sulphide sulphur in about 50 t/d of Campbell flotation concentrate. Following the merger of the Campbell and Red Lake Mines in 2006, the POx circuit started processing flotation concentrate from both Campbell and Red Lake Mills. In recent years, the circuit has been processing about 18 t/d sulphide sulphur in 75-85 t/d flotation concentrate."

Jan 1, 2017

By R. L. Brown

The Buchans mining district is located roughly at the center of the island of Newfoundland and contains some 18 separate mineral deposits. The first of these deposits was discovered in 1905, the latest discovery having been made in 1979. To the present (1983), some 16 Mt (17.7 million st) grading 1.33% Cu, 7.5% Pb, 14.5% Zn, 115 g/ t (3.7 oz per ton) Ag, and 1.4 g/t (0.04 oz per ton) Au have been mined. Mining operations are now largely terminated, but a few hundred thousand tons of economically marginal reserves may be mined in a salvage operation. The Geological Association of Canada Special Paper No. 22, "The Buchans Orebodies, 50 years of Mining and Exploration," contains papers which describe the history, geology, and the application of evolving geological concepts in exploration. Papers by Neary, Swanson, and Thurlow and Swanson in that volume are topical to the present discussion. Successful exploration techniques at Buchans included physical prospecting, utilization of the state-of-the-art geophysical techniques, saturation diamond drilling which was made possible by the high gross value of the existing ore, and, since 1955, diamond drilling directed by fairly well understood geological parameters. The record of discovery started in 1905 when the Buchans River deposit was found by Matty Mitchell, a prospector employed by the Anglo- Newfoundland Development Co., a British company which owned mineral rights over a very large area in the Red Indian Lake-Exploits River drainage system.

Jan 1, 1991

By M. Maldonado, J. A. Finch

"A flotation bank consists of a serial arrangement of cells. How to optimally operate a bank remains a challenge. This article reviews three strategies for optimizing bank performance: air profiling, mass-pull (froth velocity) profiling and Peak Air Recovery (PAR) profiling. These are all ways of manipulating the recovery profile down a bank, which may be the property being exploited. Mathematical analysis has shown that a flat cell-by-cell recovery profile maximizes the separation of two floatable minerals for a given target bank recovery when the relative floatability is constant down the bank. Available bank survey data is analyzed in respect to recovery profiling. Possible variations on recovery profile to minimize entrainment are discussed.INTRODUCTION Flotation is used to separate valuable minerals from each other and from gangue. To reach a target metallurgical performance, usually assessed in terms of concentrate grade and recovery, feed is passed through stages such as roughing, cleaning and scavenging. All these stages comprise serial arrangements of flotation cells known as banks, lines or rows. Although a bank is the simplest interconnection of cells in a circuit, i.e. the tails of one cell is the feed to the next cell down the bank, how to operate each flotation cell in a way that the whole bank performance is optimized remains a challenge. Significant efforts have been made towards understanding the effect of operating variables on the flotation performance of an isolated cell (Lynch et al., 1981; Finch and Dobby, 1990; Gorain et al., 1998). However in the case of banks the variables that can be manipulated increase with the number of cells in the bank and the problem of how to manipulate them to achieve optimum performance is difficult even disregarding variation in ore characteristics (Lynch et al., 1981, p. 16). In general, the more manipulated variables available the better for optimization purposes, however without clear guidance how to effectively use them it becomes an “embarrassment of riches”."

Jan 1, 2012

By Martin Herrenknecht

After the successful breakthrough at the end of 2006 of both TBMs into the multifunctional site Faido (MFS), in the middle of 2007 the two tunnel boring machines resumed the 12 km long section between Faido and Sedrun. In the roughly a 10 month interval both approximately 465 m long tunnel boring machines were partly dismantled, pushed through the 2.5 km long MFS, rebuilt for the new larger diameter of 9.5 m and reassembled to be ready for operation. In the rebuilding phase, improvements were made to the equipment, especially as a result of experience gained from the previous 14 km long drive in the section Bodio and taking into account the latest information regarding the upcoming 14 km section Faido. Both TBM drives are currently in the rock formations of the Lucomagno gneiss, which stretch over a section of 3.5 km from the MFS Faido to the predicted Piora Syncline. This section is divided into two fold axes of the Chièra Synform, where the Lucomagno gneiss pass from a sub-horizontal into vertical bedding. The drives, with current rock overburdens exceeding 1,500 m and, as known from the excavation phase of the MFS, in part highly disturbed rock formations, are characterized by the locally intense rock squeezing conditions with large convergences in the vicinity of the driving TBM as well as backwards due to the interaction of the two drives. High expenditure for the support measures, reduced driving performances together with extensive extra work associated with deadlines and increased costs are the result. In the paper the previous experience with the TBM drives in the section Faido and the challenges still awaiting us are presented and discussed.

By A. McKenzie

During the late 1990s Anglo American PLC was evaluating the Gamsberg zinc deposit in the Northern Cape Province. As the primary South African metallurgical technology provider, Mintek became involved in the evaluation of a pyrometallurgical process for the recovery of zinc from the Gamsberg deposit. eloping DC arc furnace technology for the metallurgical industry. This includes the patented Enviroplas® process for the treatment of zinc bearing waste materials. As a consequence Mintek has developed extensive expertise in the pyrometallurgical processing of zinc bearing materials. However, Mintek?s technologies stopped with the production of Prime Western Grade (PWG) zinc. Early on in the evaluation of the Gamsberg project, it became evident that the refining of PWG zinc would play an important part in the economic viability of the project. At the time the only pyrometallurgical technology available for the refining of PWG zinc to Special High Grade (SHG) zinc was the New Jersey process. This process represents 50-year-old technology and has not undergone significant refinement since the technology was developed. In order to provide a complete pyrometallurgical flow sheet for possible implementation at Gamsberg, Mintek assessed the New Jersey process with a view to either improving the technology or developing a new technology appropriate to the 21 century. In 1998 Mintek convened a consortium consisting of Mintek, the University of Cape Town, Eskom Enterprises, Bateman Metals and Anglo American PLC. The consortium successfully applied to the Innovation Fund for funding to develop a new process for the pyrometallurgical refining of PWG zinc to SHG zinc. The main aims of the project were to develop a new technology for pyrometallurgical zinc refining that conformed to the following: ?Decrease the production cost of SHG zinc metal to stimulate the development of the Gamsberg deposit. ?Be compatible with the current Enviroplas® process, preferably as an add-on to that process. ?Should use electrical energy to benefit from local price tariffs. The project commenced at the beginning of 2000 and consisted of three phases: ?an initial technology search and assessment of the fundamental aspects of zinc distillation. ?the design of a pilot plant for zinc refining. ?the manufacture, commissioning and operation of the pilot plant. A new technology based on a DC arc boiler feeding a packed distillation column was developed and during 2003 the project culminated in the successful operation of a 200 kg/h pilot plant. Ultimately, all of the aims of the project were met and the main outcome is that an advanced process for the pyrometallurgical refining of zinc (the Zincref process) has been developed. The main innovation of the technology was the switch from an energy transfer limited process to a mass transfer limited process (for which a patent has been registered).

Jan 1, 2004

By W. J. Birch, R. Farnfield, S. Hosein, C. Johnson

Modern smart phones include accelerometers based on MEMS (Micro Electro Mechanical System) technology giving the possibility to measure both acceleration and orientation. The widespread use of such phones has driven technological development to such a degree that it is now possible to obtain a triaxial accelerometer unit, that also include signal conditioning and analogue to digital conversion, in a package smaller than 1 cm2 (1/2 sq.in) for a relatively low cost.

Feb 6, 2023

By M. Hopf, E. Rossouw

Keywords: Pyrometallurgy, furnace, copper coolers, freeze lining, monitoring, Saveway The use of water-cooled copper components as sidewall elements of submerged arc furnaces and other pyrometallurgical applications has become increasingly common. The high cooling efficiency of copper has made it possible to increase the service life of furnace refractories when compared to conventional refractory linings. However even the self-healing effect of ?freezing? worn areas of the lining does not necessarily protect the copper coolers against wear or corrosion completely. In order to avoid furnace explosions, various methods have been used to monitor the wear of coolers. Unfortunately, these have not been able to consistently identify localized wear. Thos Begbie (South African) and SAVEWAY (German) jointly developed technology to embed a line sensor into the copper cooler during the casting process. This system allows an exhaustive monitoring of the copper cooler. A SAVELINE sensor is placed inside the copper-cooling panel between the water-cooling passage and the hot face of the panel. The sensor follows the meandering shape of the cooling water channels. In the first instance, the sensor provides analogue information as the thickness of the copper reduces. Secondly, this wear signal will be confirmed by a signal of interruption if the sensor is washed away. Because of the structure of the sensor, a self-diagnosis is possible and indications can be confirmed (double proofed). Subsequent to the manufacture of some test pieces, coolers for a large submerged arc furnace were manufactured. The sensorized coolers have been installed at the intermittent surface (slag line) where the largest amount of corrosion has been encountered. The system has been operating since December 2005 in what is considered one of the largest submerged arc furnaces in South Africa.

Jan 1, 2006

By D M. Frantois-Bongarton

"A few situations are first reviewed where practical shortcuts lead to acceptable solutions where none seemed to be possible. These include: The solving of many complex sampling optimisation problems with the simple approach of the worst case policy (WCP). A simple approach to single-stage sampling problems will be mentioned at continuation. In the plants, minimising the impact of border effects in incorrect samplers, so that the resulting samples are approximately correct and acceptable in practice because the bias risk attached to them is controlled. Examples are given, as well as practical tools and a general methodology.Finally, some sources of undue conservatism are reviewed with general recommendations aiming at eliminating them.CITATION:Frantois-Bongarton, D M, 2012. Practical considerations and shortcuts in sampling, in Proceedings Sampling 2012, pp 171-174 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 21, 2012

By Alain Blanchier, Gilles Gomez

Neighborhood pressure on quarries has become urgent to deal with quarry managers and operators must apply the most recent technologies and communicate it for long shelf life time exploitation, the quarry in which the work is located in urban or suburban environments needs to take into account blasting rules as well as site environment. The main problems to be addressed are:

Jan 1, 2009

By D. Govender

In recent years, economies of scale have continued to drive copper projects to larger throughputs to offset depleting lower grade resources. A decade ago there were only a small number of projects that stretched beyond 100,000 Mtpd throughput rates. Nowadays and moving forward virtually all the major copper projects are sized beyond this, with throughput rates up to 250,000 Mtpd now under evaluation for a number of key projects in Chile and Peru. This paper explores the development from the 160 m3 flotation cells, through to the 257 m3 cells and nowadays to the 660 m3 machines. The contributions of specific copper concentrators to this growth phase are reviewed herein. The historical basis of flotation machine scale-up is also briefly discussed. Metallurgical results as well as layout, maintenance and operational aspects are highlighted.

Feb 27, 2013

"As mine head grades decline and orebodies become more complex, traditional mineral processing techniques and flowsheets to achieve saleable concentrate become more difficult to design and construct. Mines with lower quality concentrates or concentrates with penalty elements are particular under threat. The economics of these operations are far more susceptible to metal price, concentrate treatment terms and the availability of other, cleaner concentrates. Additional value may be realised for these orebodies through improved recovery by producing a low grade middling concentrate for further processing, in conjunction with a saleable concentrate.The most cost effective way to reduce impurity levels is to do so as early as possible in the mining value chain. Technologies such as fine grinding and fine particle flotation are well established as effective methods for impurity rejection in mineral processing. What is normally overlooked is how a hydrometallurgical process could also be integrated in the overall flowsheet to achieve higher overall recovery at the mill. In the base metals environment, this is mainly because hydrometallurgical processes are associated with production of metal or use of expensive and toxic precipitating agents once the minerals of interest are solubilised. These processes can be very expensive, particularly with rising power costs and poor economies of scale in capital costs associated with low production rates from middling streams.Glencore Technology (GT) has recent experience in the treatment of middling and low grade concentrate streams as well as tailings streams to compliment a concentrator flowsheet in a refractory gold and base metals setting. The value proposition is the isolation of a low grade middlings concentrate from the primary circuit or the tailings stream for upgrading to an intermediate product with an equal or higher grade than the primary concentrate to allow blending for sale. This allows plants to operate on a more favourable part grade-recovery curve while avoiding the expense of metal production. For existing operations this is particularly attractive since it can be added on with no process interruptions.Two case studies are examined showing flowsheets and costings to arrive at the value proposition of the GT low grade treatment flowsheet."

Jan 1, 2017

By Oliver Bowles

"Underground operation.In its broader sense the term ""mining"" is applied to all processes whereby raw materials are taken from the earth to be used as sources of mineral products. In a more restricted sense ""mining"" is applied to underground operations as contrasted with open pit work designated as quarrying. The tern is used in the restricted tense in this paper; for it relates to the exploitation of limestone deposits by modern methods of underground operation rather than by open pit methods.Present tendency toward miningIt may seem to some readers that a paper on mining limestone will find little general interest among lime plant operators, for only a limited number of them have yet resorted to this means of procuring raw materials. It is noteworthy, however, that a growing tendency exists toward underground operation, for one by one quarry owners are faced with increasing difficulties in open pit operation. It seems desirable, therefore, for operators to keep closely in touch with this gradual change in process, to inquire into the underlying causes, to compare costs, and to study the effects of the change in method on subsequent steps in calcining the stone to produce lime."

Mar 1, 1924

By Dominic Orf, Gregory Poole

On December 12, 2018 at 4:14 AM EST, an earthquake registering a 4.4 magnitude on the Richter Scale occurred in central Tennessee. According to a survey posted on the USGS website, this earthquake was felt throughout the southeast and even as far away as Arnold Nebraska. That’s over 900 miles (1,448 kilometers) from the epicenter. We recorded the vibrations from this earthquake on 44 different seismographs that were set up with remote access to continuously monitor vibrations from blasting activities. Having this data gave us an opportunity to compare the vibrations caused by earthquakes and blasting. A simple observation of the amplitudes, frequencies, and durations is enough to notice that vibrations from earthquakes are very different than vibrations caused by blasting in mining and construction. We were also able to observe the dissipation of the vibrations from the earthquake and see if the low frequencies, that are typical of earthquakes, dissipate at a consistent rate. Regression calculations were performed in order to see if there was a good data fit and if a specific vibration prediction could be made based on the magnitude of an earthquake. “How does quarry/mining/construction blasting compare to the Richter Scale?” This is a very common question that we get from homeowners when discussing vibrations due to blasting activities. This paper is intended to provide some simple answers for such a complicated question. Both the Richter and Mercalli scales are compared to the particle velocities as they were recorded from this earthquake.

By Jeffrey D. Winterton

Keywords: Copper, ion exchange, sulfonic acid, bis-picolylamine, ion exchange modeling, ion exchange kinetics As part of an investigation into the feasibility of using ion exchange resins to recover copper from aqueous waste streams generated during the manufacturing of semiconductor devices, the uptake of copper onto two ion exchange resins was investigated. The resins studied were DOWEX G-26, a standard gel type sulfonic acid resin, and DOWEX M4195, a macroporous chelating resin with a bis-picolylamine functional group. The equilibrium and kinetic behavior of the uptake of copper were investigated over a range of copper concentrations with constant sulfate concentration and different levels of acidity. The homogeneous structure of the G-26 resin yields equilibrium relationships that fit the Langmuir equation, and equilibration times of less than 30 minutes. The uptake behavior of M4195 is complicated by the need to absorb co-ions to maintain electroneutrality, resulting in uptake profiles that change character with increasing copper concentrations, and extended equilibration times.

Jan 1, 2005

By Jilai Xue

Fe-Ni alloys can be used as raw material in making stainless steel. Laterite nickel ore is one of mineral resources for producing nickel alloys. In this work, the laterite ore after dehydration at 800 °C and the anthracite as reducing agent were mixed for pre-reduction at 900 °C, and then reduced to form Fe-Ni alloys at 1550-1620 °C through carbon-thermal reduction process. A high Ni-content alloy component in the metallurgical mixture can be formed through pre-reduction. Better separation of the resulting metals from the slag is found with lower Ni-content alloys produced or higher temperatures during reduction. An effective processing of Fe-Ni alloys needs further understanding of the process fundamentals and optimizing of the process parameters.

Jan 1, 2010

By Matthias Pulsfort, Markus Herten, Rolf Breitenbücher, Claudia Fierenkothen

"Secant bored pile walls are frequently used as retaining walls in watertight excavations to cut off ground water aquifers and are subsequently exposed to ground water pressure loading in addition to earth pressure loads. To avoid extra loading from ground water pressure in soils with limited permeability, it can be useful to arrange drainage windows within secant bored pile walls by means of single primary piles filled with porous concrete without reinforcement cages, which usually have to be placed within casings in submerged conditions. This concrete may serve as a horizontal arch between the reinforced secondary piles, but it must however enable vertical draining between load carrying construction beams and the bottom of the excavated pit. In the present submission, the results of several material tests with different mix designs of porous concrete with certain admixtures are presented together with first and important experiences with a wellsuited placement technique for porous concrete casings in small- and large-scale laboratory tests. It can be shown that the usual placement technique of employing a tremie pipe is not suited for this type of unsaturated concrete. Instead, pouring with a particular kind of cone and an open conductor pipe has proven successful.Additionally, special testing methods are currently developed for judging the suitability of the desired concrete mix design in preparation for an upcoming real-scale experimental pile installation in Germany.1. INTRODUCTIONRetaining walls are often built as secant bored pile walls in order to cut off aquifers saturated with groundwater against deep building pits. In soil types with relatively low permeability, however, seepage flow may be permitted, because the quantity of groundwater to be pumped is limited, and the range of influence due to dewatering is not reaching far. Thus, the hydrostatic water pressure on the retaining wall can be considerably reduced, leading to a more economic design (see Fig. 1).In unsaturated soils, the dewatering effect can be achieved by means of porous pervious concrete with a uniform grainsize distribution of aggregates typically placed in a borehole under dry conditions. With regard to the use of porous concrete to be placed at the ground surface in road pavement applications, experience is sufficiently available as shown, for instance, by Neithalath et el. (2010). However placing the porous concrete in a bored pile using a tremie pipe under submerged conditions is a challenge and a completely new approach, because there is a considerable risk of segregation of the fresh concrete, separating the cement lime paste from the aggregates when in contact with water and leaving only neat gravel on the one hand as well as a tight cemented area at the bottom of the pile on the other hand. If this concrete placement is successful, additional dewatering by means of extra wells behind the retaining wall can be avoided. Of course the seepage flow in the adjacent soil needs to be regarded seriously."

Jan 1, 2017

By M. Bilal Khan

Thermal stress relief by means of a typical heat treatment cycle (660oC for one hr) is compared with the one achieved through vibratory stress relief at resonant and multiple resonant frequencies for the D-406 HSLA material. Our analysis of the data is based on the microhardness profiles measured for the entire length of scales, namely, base metal, heat affected zone (HAZ) and the weld bead itself. The profiles obtained using the two techniques mimic each other, for an equivalent 70% stress relief level. The data are further qualified by impact testing wherein the zone of interest is projected in the retention groove to provide impact by the pendulum striker in the Charpy mode. Higher equivalent energy absorption in the treated specimens confirms the efficacy of the vibratory method. The present work rectifies earlier anomaly where heat treatment has been reported at 310oC for the same material.

Jan 1, 2009