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By J. Payton

Public Service Company of Oklahoma began burning sub-bituminous coal in December, 1979. Initially PSO had a single source coal supply from Jacobs Ranch Mine, and in 1982 added deliveries from Clovis Point mine. Both are Powder River Basin (Wyoming) coal mines. In 1986 PSO began burning Oklahoma coal to meet Oklahoma's 10% native use law. PSO experienced random s lagging during certain blends of these coals. PSO installed a boiler performance system to help control the slagging problems from the various coal blends, to improve boiler efficiency, and increase total coal consumption.

Jan 1, 1990

By James J. Gusek

The Atlantic City iron mine is located in Fremont County in central Wyoming, near the historic gold mining camps of Atlantic City and South Pass City. The mine lies on the southeast flank of the Wind River Mountains at an elevation of about 2,470 m (8,100 ft) above sea level (Fig. 1). An 81-h M2 (200-acre) tailings impoundment at the Atlantic City taconite operation has been a source of blowing dust. The site qualified for reclamation under Wyoming&apos;s Abandoned Mine Land (AML) reclamation program. The ultimate reclamation construction incorporated commercially available organic amendments and fertilizers into a 300-mm- (12-in.-) thick cap of a sterile clay loam cover material. The water level was lowered in an adjacent flooded mine pit that was feeding uncontrolled seeps into the tailings basin. A wide tailings pond spillway was built that allows flood control while minimizing seasonal water-level fluctuations in the pond. Rock berms and rock snow fences were built for wind-erosion control and soil-moisture preservation. Future work includes tree planting in the protective wind/ snow shadows of rock berms and rock snow fences and plugging a decant pipe. US Steel opened the Atlantic City iron mine in August 1962. It closed in 1983. Taconite iron ore was mined by surface methods. The ore was magnetically separated from the waste. The magnetic concentrate was mixed with bentonite, formed into pellets and roasted to produce a blast furnace feed stock for US Steel&apos;s blast furnaces in Geneva, UT. The pellets were hauled by rail to the Geneva Iron Works. The Atlantic City Mine produced three types of wastes. These included waste rock overburden from mining, a coarse-grained (sand to small-gravel sized), nonmagnetic reject rock termed "cobbs" and fine-grained tailings ranging from 600 to 75 µm (28 to <200 mesh). The waste rock has been used as an aggregate/rip rap source by a local contractor and the Wyoming Department of Transportation (WYDOT). WYDOT also

Jan 1, 1998

By C. M. Bristow

The mineral kaolinite is one of the commonest minerals in the uppermost 10 m of the continental crust; ranking in abundance alongside minerals like quartz, mica, feldspar and calcite. Only very exceptionally does it possess all the necessary properties needed to make it worth commercially exploiting. The terms &apos;Kaolin&apos; and &apos;Kaolinite&apos; are derived from a locality known as &apos;Kau-ling&apos;, in Jiangxi Province, Peoples Republic of China; where samples of a white clay used by the Chinese to make porcelain were first obtained by European missionaries and explorers in the eighteenth century.

Jan 1, 1986

By R. J. Pugh

In addition to directly analyzing the surfaces of minerals using high vacuum instrumentation methods, some important surface properties of mineral fillers can be determined indirectly by using reactive chemical probe molecules. This technique enables the strength and the number of the surface reactive sites to evaluation and this type of information is useful in predicting interfacial behaviour of minerals. One method of classifying these surface sites is by using Lewis acid/base theory and this type of approach could enable one to predict the adsorption of functional groups in dispersants, thickeners, pigments, etc. Also the adhesion of polymer matrices to the filler surface may be improved.

Jan 1, 1992

By Frank A. Jerabek

Problems of mine backfilling and fill material deposited underground, the characteristics and relationship between the deposited fill material and overlying ground, and the practical applications and limitations of hydraulic backfilling as ground support are discussed. A great variety of materials ranging from coal washery refuse to concentrator tailings is used as hydraulic fill. Some materials will solidify and cement; others will resemble quicksand, Hydraulic fill as ground support is more efficient in inclined mine openings than in horizontal mine openings, where it cannot be placed tightly to the back. This and other deficiencies of hydraulic backfilling led to the development of pneumatic stowing. Research work in hydraulic backfilling at the Pennsylvania State University is also discussed. This research work includes the investigation of segregation in the discharged fill slurry, the quantity of solids escaping in the drain liquid, the relationship of escaping solids to slurry concentration and discharge rate, and the compressibility of fine fill material.

Jan 1, 1965

By R. DasGupta

The dissolution behavior of gold in ammoniacal solutions at 75°C has been investigated. The variables investigated include concentration of lixiviants, pH of the solution and various oxidants. The anodic dissolution of gold was studied in the absence of oxidants using the potentiodynamic polarization technique. The cathodic reaction of oxidants was studied on a platinum electrode. Tafel polarization tests were also performed to determine the dissolution rate. The overall dissolution of gold in ammoniacal solutions was examined using a mixed potential theory. A comparative study on the role of cupric am mine, oxygen, hydrogen peroxide, sodium hypochlorite as oxidants for the dissolution of gold in ammoniacal solutions has been carried out.

Jan 1, 1996

By Shenghui Chu, Zhibiao Guo, Dongshan Yang, Yuanxin Zhao, Xiaohui Kuai, Jingwei Gao

The technology of automatically formed roadway without pillars (AFRP) via roof cutting and pressure releasing (RCPR) is a reformatory method for gob-side entry retaining, which automatically creates a roadway by utilizing the fragmenting and expanding properties of rock strata and the mining pressure, to realize a novel technique for coal mining without coal pillars. The Anju Coal Mine is the first kilometer-deep mine where this technology is applied. To conduct a geomechanical model experiment, this research uses the 5307 working face in this mine as its backdrop. The experimental results show that this technology can efficiently decrease the pressure of the AFRP surrounding rock. The roof maximum stress of the AFRP is 21% lower than that of the belt roadway, while the side abutment pressure of the former is 13.4% lower than that of the latter. The comparison of model experiment data and field monitoring data shows that the roof and floor approaching deformations on the roof-cutting side and solid coal side of AFRP differ by 8.8% and 9.6%, respectively. The model experiment results and field monitoring data show good agreement, and the deformation of the AFRP surrounding rock can be successfully managed by this technique. The study’s findings can serve as a guide for using this technology in kilometer-deep coal mines.

Jul 31, 2023

By QUANWEN PU, Yonggang Wei, Bo Li

The spent catalyst is one of solid waste resources, which contains precious metals with considerable recovery value. However, due to the different compositions of catalyst, the recovery process is difficult. Most of the catalysts are supported by alumina which has good alkali-soluble properties, while platinum is insoluble in alkali. Platinum is enriched by pressurized alkaline solution which is a kind of hydrometallurgical process. The novelty of this study is the separation of alumina and platinum from the spent catalyst and the enrichment of platinum in the solid phase. In this study, a leaching process using NaOH as leaching agent under high temperature and pressure was employed. The effects of alkali concentration, leaching temperature, leaching time, and liquid–solid ratio on leaching efficiency were investigated. The optimum process conditions were determined as follows: alkali concentration of 240 g/L, temperature of 200℃, pressure of 1.20 MPa, time of 1 h, liquid–solid ratio of 5:1. It was concluded that the leaching rate of alumina can reach 99.69%. The content of platinum increased from 0.1749 to 21.12%, the loss of platinum was 3.39%, and the enrichment ratio of platinum increased by 120.82 times. The leaching kinetics of alumina was studied based on the shrinkage core model. The activation energy of alumina leaching is 19.53 kJ/mol, and the leaching process is controlled by chemical reaction. Pressurized alkali solution can not only efficiently leachate alumina from the spent catalyst and enrich platinum, but also reduce the reaction time and increase reaction rate.

Feb 11, 2022

By James H. Boettcher

In the second quarter of 1979, ASL Inc. inquired whether Crocker National Bank ("CNB") would provide $4 million in term loan financing to help ASL acquire the outstanding shares of the S&S Coal Company in West Virginia. ASL had, prior to approaching CNB, sought financing with the assistance of a financial advisor from a number of commercial banks without success. A summary of the initial terms requested by ASL is shown in Table I compared with the actual terms the transaction closed with. It is not difficult to note that the two sets of terms differ significantly. This is often the case when financing requests based on the expectations and vision of a mine developer are juxtaposed with more pragmatic requirements of a commercial bank. The "art" and fun of structuring financing plans for mining ventures (highly leveraged acquisitions or grass roots) comes in working with mine developers to arrive at a final financial structure that meets their objectives and constraints as well as those of the bank or other financial institution providing much of the financing. This article briefly describes the process we went through with ASL beginning with the terms they requested initially and ending with the ones on which the transaction was finally closed.

Jan 1, 1981

By Éder Domingos Oliveira, Carlos Antonio Morais, Ruberlan Gomes Silva

The objective of this study is to assess the impact of different reagents, such as limestone, lime, magnesium oxide, and sodium hydroxide, in experiments carried out in the single purification step and in two consecutive purification steps by raising the pH of a rare earth sulfuric liquor with the aim to remove or reduce the impurity concentrations in the rare earth sulfuric liquor. The choice for the best purification condition was made based on the minimum loss of rare earth elements (REEs), reagent consumption, and residue generation. The exploratory experiments show that it takes place in the two consecutive purification steps, the first one consists in dosing the limestone pulp until it reaches a pH of 3.5 followed by an addition of a lime pulp reaching a pH of 5.0. Under this condition, the results were a total removal of Fe3+, PO4 3− , and Th4+ ions and a reduction of 99%, 87%, and 37% w/w in the Al3+, UO2 2+, and SO4 2− concentrations, respectively, in the purified rare earth liquor. Furthermore, the lowest REE losses (8.3% w/w) and reagent consumption (4.3 kg/m3 ) and also a low residue generation (7.5 kg/m3 ) were observed in this condition. Despite reaching similar results regarding impurity removal, the experiments done with the addition of limestone, lime, magnesium oxide pulps, and sodium hydroxide solution in the single purification step, where the pH was raised to 5.0, presented higher REE losses (64.9%, 42.5%, 44.8%, and 60.9% w/w, respectively) and a higher residue generation (43.2, 25.1, 11.1, and 13.6 kg/m3 , respectively). This occurred due to the co-precipitation of salts containing rare earth elements in their composition. The experiments conducted with limestone, lime, and MgO resulted in a higher consumption of reagents, while the same result was observed when NaOH was used (4.3 kg/m3 ). In the experiments carried out with the addition of magnesium oxide and sodium hydroxide, the respective purified rare earth liquors presented a high concentration of magnesium, sulfate, or sodium, which could impact the quality of the marketable rare earth salts, whereas the salts obtained under the best condition observed in this study seem to be amenable for use as raw material in an attempt to obtain rare earth products with an acceptable chemical quality.

By Xiaobo Zhang, Panshi Xie, Xiaobo Wu, Ding Lang, Jiandong Yu, Yongping Wu, Kun Feng

In a fully mechanized top coal caving mining process, the mechanical properties of the top coal deteriorate constantly, and the stability of the support is determined by the boundary position of the top coal entering the limit equilibrium state. Top coal flaking occurs more easily along the advancing direction owing to an increase in the distance of the boundary from the wall. Moreover, the strength of the coal seam is an important factor that determines the boundary position. The equation of the top coal limit equilibrium zone boundary, used in fully mechanized top coal caving mining, was determined based on the limit equilibrium theory, continuum damage mechanics, and the Hoek–Brown rock empirical strength criterion. Using the RFPA3D and UDEC numerical analysis methods, the effect of top coal strength on the mechanical behavior during the mining process was determined; and the space–time relationship between the top coal deformation failure, damage evolution, and boundary of the limit equilibrium zone was established. The results revealed that when the coal mass entered the limit equilibrium zone, accelerated crack development, accelerated damage, and axial unloading occurred. Moreover, an increase in the coal seam strength caused the boundary of the top coal limit equilibrium zone to be closer to the wall. By comparing the numerical results with the theoretical results, the overall trend was found to be consistent, allowing the verification of the rationality and reliability of the determination equation of the boundary position of the limit equilibrium zone.

Sep 21, 2021

By Robert R. Beebe

At first glance, mineral processing on an industrial scale might seem entirely in the realm of macro-engineering, with large machines operating on minerals and rocks to achieve size reduction, classification, chemical treatment, separation and dewatering. These operations must be conducted on a large scale to be of practical interest. But the machines and processes may not be designed and operated to take fullest advantage of micro-engineering factors. At the same time, idealized designs based solely on micro-engineering research may require adjustments to gain the desired results in the larger scale, operational context. Using micro-engineering research in this way allows the design and implementation of more efficient versions of the machines and processes currently used, while aiding the revolutionary developments unlikely to come from macro-engineered, trial-and-error solutions. Thus, from an industrial viewpoint, micro- and macro-engineering are complementary functions.

Jan 1, 1992

An important problem in mine operations is the classification of material as waste, low-grade stockpile, and ore. This classification must often be made with blasthole data that are widely spaced and that have sampling errors. Geo-statistical simulation techniques combined with basic economic principles allows a procedure for classification that maximizes expected profit. Geostatistical simulation methods (Gaussian, indicator, or annealing-based) allow the integration of hard and soft data in the creation of alternative, equally-probable, realizations of the mineral grade(s). At each location, for each realization, we calculate the "profit" if the block were to be classified as ore or waste The optimal classification is the one that maximizes expected profit (a Maximum Profit Se-lection (MPS) procedure). We discuss the theoretical justification of the method and implementation details. The use of blasthole data from different types of mineral deposits, that is, different levels of continuity, is considered. We also show the efficacy of the procedure with different levels of sampling error. The increased revenue due to the MPS procedure and improved sampling is shown. We show the geostatistical simulation procedure and the uncertainty in block grades that result from incomplete and imperfect sampling. The optimal classification is presented. Optimal block classifications are transferred to realizable dig-limits by hand-drawing polygonal boundaries. We compare the results of the proposed method to classification based on kriging. Limitations and areas of future work are identified.

Jan 1, 1999

By William A. Riggs

Salt, a non-metallic mineral whose use dates back to earliest history of mankind, and whose uses cover the widest range for any mineral raw material, is generally of widespread occurrence in commercially recoverable quantities in the oceans, in certain sedimentary rocks, in certain lakes, and in certain underground waters. Passing over geological detail, it may be said that, generally, all of the salt in the world has, at least once in geological history, been in solution in the oceans. The total salt content of today&apos;s oceans, said to equal 4.5 million cubic miles of rock salt, dwarfs the tremendous volume of salt in the sedimentary rocks. In 1958, United States production of salt was about 22 million net tons and world production about 82 million. About 3 percent of United States production is table salt, with chemical, municipal, industrial and agricultural uses taking the remainder. Mississippi River. Figure 1 has been expanded sufficiently to show also those salt occurrences and producing points which might economically ship salt into these states. Although widespread in occurrence, salt deposits and possible production areas generally show very sharp local boundaries. Salt-for non-table use is susceptible to ?place value?, a common problem in low valued raw materials, where transportation costs often exceed the value of the material f.o.b. the production point. Generally only large capacity mechanized salt producing operations can compete in United States markets, as contrasted to the many small local salt evaporators in less industrialized Mexico.

Jan 1, 1962

By Cyrus W. Field

The Pacific Northwest as defined in this review comprises an exceedingly large and geologically complex terrain that occupies the &apos;Western Cordillera mobile tectonic belt. This metallogenic province is approximately 2100 miles long and 350 to 500 miles wide. It extends north-northwest from northern California and Nevada, through western Idaho and Montana, Oregon, Washington, British Columbia, and southwestern Yukon Territory, to southern Alaska, and west from the western flank of the Northern Rocky Mountains to the continental margin (Fig. 1). Many detailed and thorough exploration programs that have been conducted by mining and petroleum companies for over a decade have demonstrated that porphyry-type deposits are both numerous and wide-spread throughout this province. Although the Granby Mining Company extracted about 34 million tons of copper sulfide ore from Copper Mountain during the period 1900-1957, intentional large-scale production of porphyry-type ores was first initiated in 1962. It began at Bethlehem Copper Corporation&apos;s East Jersey orebody in the Highland Valley District of south-central British Columbia, approximately eight years after Mr. H. H. Huestis rediscovered that broad zone of copper-molybdenum metallization and recognized its potential significance.

Jan 1, 1973

By H. Huang, Y. Takasaki, R. N. Gow

"The presence of enargite (Cu3AsS4) is problematic in gold processing not only because it is environmentally hazardous due to its arsenic content but also because it is refractory, causing both cyanide and oxygen consumption to increase. Selective leaching and treatment of the arsenic would prove advantageous prior to applying conventional gold leaching methods. The reactivity of enargite samples from Butte in Montana and Quiruvilca in Peru were spectroelectrochemically studied under alkaline conditions – pH range of 8-13 – using Raman spectroscopy and cyclic voltammetry. Raman spectra of the surface were collected during and after potentially cycled voltammograms in order to determine and compare surface species against theoretical EH-pH diagrams constructed from mass-balanced thermodynamic calculations using STABCAL software. Under slightly oxidizing conditions, covellite (CuS) peaks were found in a short matter of time, above ~100mV vs. SHE for pH 9-13, suggesting arsenic leaching specifically occurred. At longer conditioning times, elemental sulfur was observed and tended to passivate the surface. The presence of elemental sulfur suggests that copper was eventually leached from the surface. By operating above pH 12, under slightly reducing conditions near -300mV vs. SHE, arsenic can be selectively leached as thioarsenate (AsS4 3-) or thiosulfate (AsO4 3-) without sulfur formation.IntroductionEnvironmental limitations on the pyrometallurgical processing of ores and concentrates bearing arsenic and other hazardous elements often outweigh those in hydrometallurgical processing, particularly when minerals like enargite (Cu3AsS4) are present. The hydrometallurgical processing of enargite-bearing materials can be broken down into two categories: the co-dissolution of arsenic and copper under acidic conditions, and the selective leaching of arsenic under alkaline conditions. The selective leaching of arsenic would preferably leave behind copperrich sulfide phases, typically chalcocite (Cu2S) and covellite (CuS), which then become more amenable to conventional copper (and gold) processing. Furthermore, selective leaching often employs sulfide (S2-), bisulfide (HS-) or polysulfides (Sx 2-) to first extract the arsenic as AsS4 3- and AsS3 3- (Delfini et al., 2003; Anderson and Twidwell, 2008; Tongamp et al., 2010a,b). However, hypochlorite leaching (Viñals et al., 2003; Curreli et al., 2005; Mihajlovic et al., 2007), ammoniacal leaching (Gajam and Raghavan, 1983), and finegrinding to mechanically activate the enargite surface (Balaz and Achimovicova, 2006) have been investigated to increase the normally slow reaction kinetics. Because gold ores are becoming more refractory due to increasing arsenic contents as a result of enargite, these methods are being examined more closely by the gold-mining industry."

Jan 1, 2015

By Alden B. Carpenter

Oil-field brines have been collected and analyzed from Jurassic and Cretaceous rocks in the Mississippi Salt Dome Basin, from Jurassic and Lower Cretaceous rocks, southwestern Arkansas, and from Ordovician and Silurian rocks, southern Michigan. All of these brines are genetically related to evaporites and appear to be brines expelled from halite-bearing rocks, presumably during compaction. The brines in rocks closest to the halite-bearing rocks are uniformly low in lead and zinc suggesting that the metals in metal-rich brines are not acquired within evaporite sequences. The metals in metal- rich brines in Mississippi and in Russia appear to be derived from red beds and may have been originally associated with ferric iron oxyhydroxides. Reduction of these compounds by migrating hydrocarbons appears to release lead and zinc to the associated brines accompanied by the fomation of authigenic ankerite.

Jan 1, 1979

By H. M. Thorne

Industrial shale-oil operations in North America and Europe predated the Drake discovery, but, since then, most have succumbed to competition from petroleum. However, the existence of enormous oil-shale resources in the Green River formation of Colorado, Utah and Wyoming [estimated at over a trillion bbl of shale oil in place] and the advancement of United States oil- shale technology by research and development programs of government and industry during the past 15 years point to a natural partnership of petroleum and oil shale to meet the accelerating energy demands of the future. The utilization of oil shale is not a question of limited petroleum supplies, but one of economics. Two factors are expected to improve the economic outlook for industrial shale oil production -- a rise in petroleum replacement cost and further advances in oil-shale technology.

Jan 1, 1963

By I. H. Warren

The high temperature lubricant molybdenite, MoS2, is usually produced by a complex sequence of processes involving mineral dressing of molybdenite concentrates followed by leaching with hydrofluoric acid to remove abrasive impurities such as silica (1). Many attempts have been made, mostly by techniques involving, direct fusion of molybdenum compounds with sulphur, to produce synthetic molybdenite. However, apart from some experiments of geochemical interest (2) in which aqueous solutions of sodium sulphomolybdate, Nat MoS4, were decomposed under pressure at temperatures between 300°C and 700°C, no attempts to produce the mineral by hydrometallurgical procedures have been reported. Since molybdenite is nominally a compound of tetravalent molybdenum with sulphur, and the most common state of molybdenum is +6, production of molybdenite is likely to involve reduction and sulphidization. The present study, therefore, describes the reduction, with hydrogen and carbon monoxide, of molybdenum in the hexavalent state in alkaline aqueous solutions containing sulphide ion. In these

Jan 1, 1972

By H. Dreissen

Upgrading of low-concentration ores is of growing importance today. The Heavy Medium Cyclone Process, thanks to strong centrifugal forces, effectively separates particles varying only slightly in specific gravity but widely in size. The paper discusses the separation efficiency, the method of assessing that efficiency, and the influence of such factors as medium solids. The operating results of nine heavy medium cyclone plants handling following minerals are reported: barite, wolfram, iron, magnesite, diamond, lead-zinc, fluorspar, rocksalt potash. Highlighted are an improved recovery system for heavy medium and some other developments, such as techniques for separation down to 0.1mm and the application in the field of recycling.

Jan 1, 1980