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By L. M. Demers, R. E. Edelson, M. P. Rose, D. T. Superdock

The pulmonary alveolar macrophage is a major defensive cell which counteracts the invasive properties of bacteria and particles when these substances invade the pulmonary environment. Pulmonary exposure to coal dust particles is believed to activate these macrophages to release a host of d1emical mediators which can neutralize or contribute to the harmful effects of these dust particles. Our efforts have been concerned with assessing a specific family of mediator substances produced by the alveolar macrophage from arachidonic acid when these cells are in contact with activating substances such as coal dust. Metabolites of arachidonic acid produce a vast array of effects which can impact significantly on pulmonary function both with normal pulmonary events and with pathologic processes of the lung. Our studies demonstrate that isolated alveolar macrophages obtained from rats or guinea pigs cultured in vitro release appreciable amounts of the cyclooxygenase products prostaglandin E2 and thromboxane A2 and release significant amounts of the lipoxygenase products .5-HETE and LTB4. In the presence of l x 104 -1x10·7 g/ml of a coal dust suspension, alveolar macrophages from the rats and guinea pigs alters their pattern of arachidonic acid metabolite release. In the rat, exposure of alveolar macrophages in vitro to the higher concentrations of coal dust causes a significant reduction in PGE2, TXB2 and LTB4 in a 4 hour time course study. In contrast, macrophages from the guinea pig in response to coal dust had little change in TXB2 release, only a slight inhibition in PGE2 production and an initial stimulation in LTB.t release over the 4 hour time course. Cells from guinea pigs released considerably more TXB2 than the rat under these conditions while rat cells formed considerably more LTB4 than guinea pig alveolar macrophages. These findings support the following conclusions.

Mar 1, 1989

By A. E. Back

[Several processes for recovering manganese from low-grade ores have been proposed3/4/5/ in which an aqueous slurry of the ore is leached with gas containing nitrogen, oxygen, and sulfur dioxide as obtained from burning sulfur or roasting sulfide ores. The manganese dioxide is dissolved, and most of the sulfur dioxide is oxidized to sulfate, but an appreciable quantity of dithionate is usually formed, together with acid from oxidation of the sulfur dioxide. The over-all reactions may be represented as follows: (1) Mn02 + S02 = Mn++ + S04--. (2) Mn02 + 2S02 = Mn++ +S206--. (3) H20 + So2 + 1/2 02 = 2H+ 5S4--. (4) H20 + 2S02 + 1/2 02 = 2H+ + S206---.]

Jan 1, 1952

By L. W. Scott

This report presents an overview of explosionproof (X-P) enclosure research being conducted by the Bureau of Mines, This report emphasizes the increasing importance of research related to the safety con- siderations of X-P enclosures used in underground coal mines. Selected topics are included that summarize results of research in the areas of electrical clearances, reliability of enclosures with windows, safety factors in X-P enclosures, potting materials, performance tests for X-P enclosures, protection against high-voltage explosions, and innovative X-P devices.

Jan 1, 1985

By Will H. Coghill, F. D. DeVaney

"Many of the iron ore deposits on the western end of the Mesabi Range Minnesota consist of the so-called ''wash ores."" Because of their high silica content these ores must be washed or concentrated to make them merchantable. Washing plants have been in operation for 20 years, during this period large quantities of tailings have accumulated in tailings ponds. These tailings contain the aggregate millions of tons of iron oxides which, if recovered, would greatly to the available tonnages and to the revenues of the mining companies. It the purpose of this paper to outline give results of concentration tests on tailings.In order that the reader may understand more clearly the type of material under consideration, a short description of the characteristics of the wash ores of the Western Mesabi Range and a brief resume a washing methods that have been are now being employed will be given. Appleby and Newton4 In their description of the district and of the ores say:The Western Mesabi district embraces the territory west of the town of Nashwauk in Itasca County. The territory to the east of this dividing line is known as the Central and Eastern Mesabi district. This subdivision is rot wholly arbitrary. While the ore bodies in the two districts resemble each other in. shape, size, and general structure, there is a marked and very important difference in the character of the respective ores. For purposes of comparison, the western deposits have been called washable ore bodies, and the central and eastern, standard ore bodies. The latter ores are the result of natural concentration processes which have teen carried far enough to produce a large proportion of high-grade ore Wet can be marketed direct; the Western Mesabi ores present a lesser degree of natural concentration and are as a rule of too low grade to admit of marketing without preliminary treatment. In many cases the grade can be improved by washing, hence the material is called washable ore. Exceptions to thin general rule may be noted in both districts. Many of the Western Mesabi ore bodies contain quite a proportion of merchantable ore. There are also portions of central and eastern Mesabi ore deposits which are of low grade and which can be improved by washing."

Nov 1, 1930

By R. V. Higgins

This paper describes a method and a computer program for calculating shape factors and areas of channels that turn more than 90° and conduct fluids into the backs of wells. The program represents an improvement over a previous Bureau of Mines investigation by using a 4-point Lagrange interpolation equation instead of a 3-point and by summing areas of trapezoids with either x altitudes or y altitudes. Some of the techniques reported in this paper can also be used to compute the areas between contours and the lengths of lines that turn more than 90°.

Jan 1, 1968

By W. A. Young

Vermiculite deposits on the. Platt ranch, 12 miles southeast of Encampment Carbon County, Wyo., were investigated by the Bureau of Mines early in 1949. Major activity was centered on property held under lease by the Mikolite Mining & Development Co. (figs. 1 and 2). Vermiculite occurs in masses and lenses of varying size and as disseminations in altered hornblende diorite. Alteration of the host rock probably resulted from the proximity of dikes and irregular masses of pegmatite. Investigation of the Mikolite property consisted of surface trenching, diamond drilling, and sampling. Four trenches totaling 5,401 linear feet were excavated with a bulldozer and Diesel power shovel. Three diamond-drill holes totaling 600 feet were drilled from the surface to determine the character of mineralization at depth. Eighty-one bulk samples were obtained from the trenches, and 130 sludge samples were collected from the drill holes. Samples were analyzed, and ore-dressing tests were made in the Bureau of Mines laboratories at Salt Lake City.

Jan 1, 1952

By G. S. Knoke

This report presents the results of a demonstration of the technical, economic, and environmental feasibility of hydraulic borehole mining of shallow oil sands. Borehole mining offers a method for extracting the oil sands with minimal disturbance to environmental quality because (1) no overburden is removed, (2) no waste rock piles are required, (3) the tailings can be backfilled into the borehole cavity, (4) the ground water quality should be undisturbed, (5) a closed-loop water system can be employed so that no surface streams are polluted, and (6) surface subsidence can be minimized by backfilling the mined cavities. This project consisted of two concurrent tasks: mining operations and environmental monitoring. To generate the environmental impact, nearly 1000 tons of oil sands were mined from two boreholes. Water quality and ground subsidence were monitored. No significant changes occurred in the chemical composition of the process water, indicating that the borehole mining process does not dissolve the mined material. The average subsidence in the immediate vicinity of the boreholes was about 1/2 inch, although some points were noted to be slightly elevated. In general, the amount of subsidence increased with time and decreased with distance from the bore-hole. A mining cost analysis was used to project an estimated cost for production mining of about $38 per barrel of oil.

Jan 1, 1980

By E. J. Gleim

In the mining of coal the trend is toward more and more mechanization. This increased use of machinery to replace hand labor is assuming many new forms and presents a constantly changing aspect. Safety engineers must be alert if the many electrical problems resulting from these new installations are to be handled safely. Some of these problems present possible electrical hazards that may be overlooked by the safety engineer unless they are called to his attention by one who has made a special study of the conditions. The foregoing is especially true of conveyor systems of mining. The terms "conveyor systems" and "conveyor mining" as used in this paper refer to those systems in which various types of conveyors are employed to transport coal away from the working place. In some mines this means complete elimination of track, cars, and locomotives. In others it means that conveyors take the coal from the working place to a convenient loading point, from which transportation is completed by cars and locomotives.

Jan 1, 1941

By M. M. Wong

Salt mixtures consisting of KC1, BaC12, and HfCl4 with RbCl or CsCl were investigated as electrolytes for refining hafnium. The presence of RbCI or CsCl in the electrolyte appeared to suppress the volatility of. Best electrorefining was obtained with an electrolyte containing 50.7 percent KCl, 27.l percent BaCl2, 15.7 percent CsCl, and 6.5 percent HfCl4. In this electrolyte, hafnium metal with an average oxygen content of 470 ppm was produced from an anode feed containing l,600 ppm oxygen. All metallic impurities were lowered, except titanium, manganese, and tin.

Jan 1, 1966

By J. B. Gayle

During the past several decades, there has been a steady increase in the number and size of experimental ovens used for carbonization research. Although many were originally intended principally for studies of coal expansion, current practice usually includes determinations of the properties of the experimental cokes. With respect to size and shatter characteristics, the cokes from the larger experimental ovens closely approximate those from duplicate charges carbonized in commercial ovens; however, they are consistently lighter and frequently less resistant to degradation by abrasive forces. To minimize these differences, some operators dry the experimental charges before carbonization. The resulting higher dry coal charge densities do, in fact, yield cokes with gravities closely approximating those produced commercially from the same coal or blend but without drying. The drying of the experimental charges may be criticized on the grounds that it represents a departure from commercial practice and may result in oxidation of the samples; for these reasons, the practice has not been universally adopted.

Jan 1, 1961

By K. L. Paciorek

The aim of the present study was to determine the thermal oxidative behavior of materials used in coal mines, with emphasis on the type and relative concentration of the products, in particular the toxic species formed. To supplement this work and to gain understanding as to the type of products possibly formed and also to assess the limitations and advantages of the various analytical methods used a literature survey of the past investigations performed on the compositions of direct interest to the subject program was conducted. The compositions thus covered were cellulose, polyvinyl chloride, neoprene, urethanes, polyamides, polyesters, polyethylene, epoxy, phenoxy, urea-formaldehyde and melamine formaldehyde resins. The results of this review are compiled in the Appendix. The experimental work consisted of thermal oxidative degradation of 36 materials and 4 composites using a stagnation burner apparatus developed in these laboratories which affords a dynamic system approximating somewhat the conditions encountered in underground coal mines. This technique as employed during this program gave only the relative product concentration at specific periods of the decomposition process, The advantage of this approach is that in this manner screening of materials can be accomplished in conjunction with some assessment of the decomposition rate as influenced by temperature and material composition. Limited static tests were performed using a sealed tube method. The materials studied were grouped according to their compositions. The following were the main groups: (a) polyvinyl chloride-containing materials, (b) neoprene compositions, (c) rigid foams (urethanes, isocyanates), (d) miscellaneous materials (including jute, fiberglass, polyethylene and some articles of unknown composition), (e) coal and fluids (phosphate esters, organic esters, oil-water emulsions), and finally (J) composites. The latter comprised a mixture of a phosphate ester fluid with (a) coal, (b) a representative polyvinyl chloride sample, and (c) a neoprene type composition.

Jan 1, 1972

By David E. Siskind

A Bureau of Mines survey of noise from quarry production blasting was conducted at seven crushed-stone quarries, providing information on close-in noise generation, comparative instrumentation, and evaluation of the sound levels as related to blasting parameters and existing State and local noise standards. The results from this preliminary survey will be useful in the design of a complete investigation of the problem of noise from blasting. There exists an immediate need for technical guidelines for noise pollution control agencies presently working on the regulation of impulsive noise sources. This survey and results from previous work by other researchers are used to derive interim recommendations on weighting scales, generated sound levels, and instrumentation. These recommendations are based on the limited data presently available and may be modified with subsequent investigation of noise generation, propagation, structural damage, and human tolerance.

Jan 1, 1974

By Lawrence G. Houk

Lithium is the lightest of all metals, but as it deteriorates rapidly in air it has no structural applications. Alloys of lithium that will float upon water can be made with other light metals, but these ultralight alloys are not useful in aircraft production or elsewhere at present. Alone or alloyed with alkaline earth meals, lithium acts as reining agent on molten metals, and as a minor constituent with other metals it imparts characteristic properties to the allay. Lithium compounds have somewhat wider application in commerce than either the metal or the alloys. They are used in the glass, ceramic, chemical, and air-conditioning industries and less extensively in the optical, pharmaceutical, electrical, and textile industries. The United States is the leading producer anti consumer of lithium ores and compounds and apparently has the largest known ore reserves. The value of lithium ores and primary chemical byproducts produced is relatively small, yet the lithium chemical industry yields products worth hundreds of thousands of dollars each year, owing partly to the high degree of purity demanded by the trade for most finished products and to the low combining weight of lithium. Fortunately, the low-grade ores can now be concentrated economically, and this fact, together with our extensive reserves, assures adequate supplies to meet any reasonable increase in demand. Lithium is listed as essential by both the American and British war agencies, and its military importance may be greatly enhanced.

Jan 1, 1942

By R. V. Ramani

In this report, the application of the Open Pit Materials Handling Simulator (OPMHS) to a mine located in Illinois using bucket wheel excavator (BWE) and a stripping shovel in tandem for overburden removal is described. The specific objective of the study is to demonstrate the application of the simulator to analyze mine planning and scheduling problems and to generate and analyze alternatives for increased production. On the basis of the simulations it was concluded that the maximum productive capacity of the system in raw coal was around 3000 tons per shift. At this production level, the equipment combination and availability also satisfy the match requirements for the stripping shovel and the BWE, and the overburden and coal removal systems. Several alternatives requiring new equipment are proposed and analyzed for increasing production. However, no economic analyses of these proposals were done.

Jan 1, 1977

By Robert W. Geehan

The Bureau of Mines developed, by core drilling, the property of Nevada Scheelite, Inc., from October 5, 1943, to February 24, 1944. Claims of the corporation are near Rawhide in the northern portion of Mineral County, Nev. The purpose of the work was to determine possible reserves in the lateral and vertical extensions of a tactite zone which was being mined for scheelite. Production from this zone to January 1, 1944, was said to be 64,500 tons, with a recovery of 50,618 units of tungsten trioxide. The development work was done by the Bureau of Mines in cooperation with the U. S. Geological Survey and comprised a study of the geology, mapping the areas, and exploring the deposit by diamond drilling, trenching and sampling. Eleven holes were drilled for a total footage of 2,365 feet of holes.

Jan 1, 1950

By James J. Dowd

The investigation to evaluate the reserves of coking coal is being made by the Bureau of Mines in three parts: (1) To estimate known measured and indicated recoverable reserves of all coking coal; (2) to upgrade marginal coals through effective preparation; and (3) to study the carbonizing properties of coal and coal blends not now widely used for metallurgical coke making. This is the tenth of a series of reports giving the results of studies by counties under part (1) of the investigation. (See appendix.) This report covers Knott County, Ky., which comprises parts of the Salyersville, Prestonsburg, Troublesome, Hindman, Pikeville, Cornettsville, and Whitesburg quadrangles. (See fig. 1.) A base map for each bed in each quadrangle was made to the scale 1 inch equals 1,200 feet. Maps of mines, locations of drill holes, bed and total coal thicknesses, and the outcrop of the bed were plotted on the maps. With all available data plotted, isopach lines were drawn to limit areas of known unmined reserves in beds up to 14 inches thick, 14 to 28 inches thick, 28 to 42 inches thick, and over 42 inches thick. These areas of coal reserves also were divided into "measured" and "indicated" categories. All areas in each thickness range and category, mined-out areas, areas excluded from the estimate but which may contain reserves based only on geologic inference, and areas outside of the outcrop were measured by planimeter on the base maps. Estimates of total reserves 14 inches and more thick and maps for individual beds were prepared from these data.

Jan 1, 1952

By Donald W. Ross

Petroleum oils of widely different grades have long been clarified or decolorized by contact with fuller's earths. More recently, so-called activated clays have also been used for this purpose. Still more recently ouch clays have been used in the form of nodules termed "catalytic pellets." Clays of varied appearance and from different localities possess the desired bleaching qualities, but evaluation of such clays, so useful to the oil industry, has not been simple. Previous methods of identification and evaluation have largely followed procedures of production methods and were not primarily based upon the fundamental properties of the clays. Thus) a false assumption has grown up that) bleaching clays probably have no common properties on which a-method of comparison can be based. Fuller's earths and activated clays have a large absorptive capacity for the color constituents of petroleum and its products decolorizing is accomplished by bringing the oil into intimate contact with the clay and later separating the decolorized oil from the clay with its load of absorbed coloring matter. Former practice in absorbing "color" was to use the clay as granules or In' powdered form. More recent practice is to use clay pellets that are more abrasion-resistant than the granules. The oil is either filtered through a bed of clay, percolation method, or agitated on contact with the clay, contact method. Viscous oils are decolorized at an elevated temperature, so that their viscosity is lowered to the point at which thorough contact with the clay is insured. Nonhumidifying, nonoxidizing gas, such as dry steam or dry nitrogen, is used to seal such hot oil masses from the atmosphere.

Jan 1, 1948

By Richard L. Fowler

Study and development of sensing techniques and sensors were performed to aid shuttle car drivers in detecting obstacles and in guiding the car along the face haulage route. Microwave, acoustic, and optical sensing techniques were considered as part of the feasibility study for obstacle detection. Various guidance techniques, including wire-following and rib-ranging were investigated. Active optical sensing was selected for obstacle detection to obtain the beam coverage and sharp angular cutoff characteristics required within the packaging limitations defined by the shuttle car configuration. Rib-ranging guidance was selected to achieve a completely self-contained shuttle car system which responds to the existing mine geometry without need for wires, stripes, or other path defining devices. Extensive hybrid computer simulation runs were performed to evaluate various guidance techniques during the feasibility study. Subsequent simulation runs were performed to establish parameter values for the rib-ranging guidance system. The obstacle detection and guidance system was designed, fabricated and installed on a standard shuttle car. The system satisfied all applicable permissibility requirements of Schedule 2G. An experimental permit was issued to Bendix for operation in an underground coal mine. System evaluation tests were performed first above ground at the Bendix Research Laboratories. The simulation model was validated by these runs. Final testing was performed underground in an operating mine with an experienced shuttle car driver. All sensors successfully demonstrated the predicted performance capability during underground face haulage tests. Dust did not impair system performance and lens cleaning was not required during working shifts. Further development is required to achieve the desired obstacle detection performance. Closed loop steering control with manual override is recommended for the lateral guidance system. The guidance system should be an invaluable aid to low-coal shuttle car drivers where continuous mining machines are utilized.

Jan 1, 1973

By Walter R. Storms

"INTRODUCTION Geological examination of the Iron Mountain beryllium deposits was begun by a field part 3/ of the Federal Geological Survey in May 1942. Later in that month the occurrence was examined by the author and C. H. Johnson, of the Bureau of Mines, and a preliminary exploratory program was outlined. Trenching and sampling began about June 15 and were completed in July 1942. A large tonnage of beryllium-bearing material was indicate by this preliminary survey, so that additional funds wore allotted for further trenching and sampling, underground exploratory work, and diamond drilling. This later program was initiated in July 1942 and was completed in May 1943. 4/ACKNOWLEDGEMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilisation of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R.G, Knickerbocker, chief, analyzes samples and performs beneficiation tests."

Mar 1, 1947

By J. J. Demeter

As part of its work on converting coal to fluid fuels, the Federal Bureau of Mines has been studying the synthesis of liquid fuels from carbon monoxide and hydrogen by Fischer-Tropsch synthesis. A fluidized bed of nitrided, fused-iron catalyst has been operated successfully to produce high yields of oxygenated compounds. Trouble-free operation continued for over 800 hours, and the test was terminated voluntarily. About 85 percent of the fresh feed was converted when the unit was operated at a space velocity of 500 hr.-1, a 12:1 recycle-to-fresh-feed-gas ratio, a 300-p. s. i. g. pressure, and a temperature of 252° C. When operating at a fresh-feed-gas space velocity of 1,000 hr.-l and a 9:1 ratio of recycle to fresh gas, conversion of fresh feed was 68 percent, and the product yield was 235.9 grams per cubic meter of synthesis gas converted. The oxygenate and C5 and heavier hydrocarbon yield was 110.6 grams per cubic meter of gas converted, 83 percent of this was oxygenates. The atom ratio of N:Fe of the catalyst, initially 0.455, decreased to 0.288 by the end of the 800-hour experiment. Nevertheless, the yield of oxygenated compounds per cubic meter of H2 + CO converted at the end of the run was approximately the same as that obtained 500 hours earlier with identical operating conditions. X-ray analysis of the discharged catalyst indicated that only ?-iron carbonitride was present. Sieve analysis of the discharged catalyst indicated that only 2 percent of fines was produced during the reduction, nitriding, and synthesis.

Jan 1, 1959