Search Documents

By K. van Netten, T. P. Ernst

"Froth flotation has been used successfully for about a century in the beneficiation of both coal and mineral particles. With the on-going trend towards lower feed grades, however, there is a need to transform this technology in ways that can deliver ultrafast separations, with strong selectivity, and recovery, covering a broader size range. It should be recognised that the hydrophobic effect, with its highly selective and long-range interactions, will most likely underpin any new technology. We identified the separation of the concentrate from the tailings as the rate determining step of conventional flotation technology. This limitation was then addressed by developing a novel flotation technology, insuring the formation of a concentrate that could be separated more rapidly from the tailings. We introduced a novel binder medium, a highly concentrated water in oil emulsion, to act as the focal point for hydrophobic adhesion, effectively replacing the air bubbles used in conventional flotation. The hydrophobic particles adhere to and become embedded within the binder, forming saturated agglomerates that float upwards. Moreover, by forming these large and resilient agglomerates, the product can be quickly dewatered over a screen and separated almost immediately from the tailings. Remarkably, this new binder permits residence times in the order of a few seconds under batch conditions. This paper examines the performance of the technology as a function of the oil wt% added to the slurry. The paper also examines the performance of the technology as a function of the particle size, showing a decline as the particle size exceeds 0.50 mm.INTRODUCTIONFroth flotation involves the collision and adhesion of hydrophobic particles to rising air bubbles, the carrying of those particles from the bubbly-pulp zone into a froth zone, and subsequent drainage and migration of the pulp to achieve the final concentrate (Wills, 2006). Within a Jameson Cell the feed slurry and air bubbles are brought into intense contact within the active area of the downcomer, achieving rapid kinetics of hydrophobic particle adhesion to the air bubbles (Harbort et al., 1994). However, once the bubble laden product and tailings emerge from the downcomer there is the need for separation of the concentrate from the tailings, an inherently slower process. In other devices such as mechanical cells the initial kinetics of particle adhesion are far slower, relying on the turbulent eddies throughout the cell, while in a column the kinetics rely upon an even slower process of bubble interception with suspended and settling particles (Gorain, 2007). However, in all cases the driving force for segregating the bubbles from the tailings, and the drainage of the froth are inherently the same. We do note, however, recent advances by Galvin and co-workers in achieving so-called Fast Flotation, utilizing a system of inclined channels to dramatically increase the segregation rate of bubbles from the tailings, permitting much higher gas and feed fluxes to be applied, achieving up to a ten-fold throughput advantage (Dickinson et al., 2014). Any further improvement within the existing flotation paradigm would require the introduction of centrifugal forces, but this would also require the formation of much finer bubbles than is typically used given the tendency of relatively large bubbles to reach a limiting slip velocity due to deformations and increased drag. Across all flotation devices we argue the rate determining step remains the segregation of the bubbles from the tailings."

Jan 1, 2016

By K. Niboucha, M. Zergoug, S. Brick-Chaouch, H. Houali

"Corrosion is an electrochemical process that causes degradation and deterioration of various steel works (pipelines, drains, cisterns) whether they are buried, immersed, or not. Worldwide, we estimate that corrosion destroys a quarter of the annual production of steel at a rate of 5 tons per second. Several techniques are used to protect against corrosion. Among these processes, Cathodic protection, which is regarded as the best technique to assure the protection of steel, works against this phenomenon. This is achieved either by a system of reactive anodes, or by the technique of impressed current protection or other techniques. Before any installation of cathodic protection, a preliminary study and pre-evaluation of certain parameters must be made. In the present work, we will present an example of dimensioning of an installation of cathodic protection by imposed current of a pipeline using solar energy, where we discuss the following items:•,Evolutions of the potential as well as current along the pipeline and their respective expressions deduced from the laws known as telegraphists;•,Range of protection (potential of protection along the pipeline);•,Influence of the isolation resistance of the coating on the range of protection;•,Effect of the aging of the coating and its influence on the current of protection."

Jan 1, 2005

By Zygmunt Wegrzyk

Poland is rich in hard and brown coal reserves, which have become the most important, and steadily developing, primary source of energy. With 192.6 mill. t of hard coal production and 40 mill. t of exports in 1978, Poland is fourth and second in the world respectively. The paper discusses the various mining methods adopted in the country's history of mining. Particular emphasis is placed on longwails, their mechanization and equipment assembled in the form of fully mechanized face complexes suited for varied geological conditions. Measures to improve the recovery ratio of coal resources are dealt with. investment efforts undertaken in the coal industry are outlined. An account is given of the ever improving techno-economic results of coal mining. The country also exports a wide range of mining equipment and transfers its well-founded technical know-how to others. There are strong cooperative links with many foreign partners.

Jan 1, 1979

By G. Belzil, F. Robichaud, M. Fullam

ABSTRACT The Goldex mining and milling complex is operated by Agnico-Eagle and is located in the Abitibi greenstone region of northwestern Quebec, Canada. Commercial production started in 2008. Average gold recovery is 93.5% with approximately 68% of gold recovery coming from the gravity circuit. During the first three years of production, three gravity audits were carried out to optimize performance of the gravity circuit. This paper presents results of the audits and the development of a model linking gravity and overall gold recovery, and outlines improvements made to increase gravity performance and reduce operating costs.

Jan 1, 2013

By J. H. Starkey

Large differences between macro and micro grindability relationships have been discovered for mill design measurements using the patented SAGDesign(TM) test. Crushing, Rod and Ball Mill Wi tests, and breakage parameter measurements have previously been used to design SAG mills but have not revealed the true magnitude of these differences. A SAGDesign(TM) test measures the SAG/Bond Wi Ratio (defined below) for every sample tested and gives a good design result because the F80 of the SAG stage test feed is 19 mm and because the test includes a Bond Ball Mill Work Index on SAG ground ore. Good flotation operation demands properly sized grinding mills and steady feed to the flotation circuit.

Jan 1, 2009

By P. Nayak

"Comminution is an energy intensive and expensive process consuming approximately 40-50% of the total processing costs in a mining operation. This process poses an even greater challenge with gold ores due to their low elemental concentration and small particle size. Over 99.9% of the ore fed to the mill is waste which must be removed during the ore processing stage. Preconcentrating the Run of Mine (ROM) ore before feeding the mill will result in significant cost savings. In partnership with Sacré-Davey Engineering, Agnico Eagle Mines Limited identified this opportunity and is currently evaluating the implementation of sorting technology to preconcentrate the ore or upgrade the waste material at its operations. This paper will discuss the steps adopted by Agnico Eagle in the evaluation and installation of sorting technology at its operations. Since the Company has a large portfolio of operations, the first step in the project was to shortlist the operations that had the highest probability for successful application of the technology. Following this, the top three operations were selected for bench scale evaluation. The projects which showed the most economic potential were then considered for detailed evaluation and pilot plant installations. This paper provides an insight into the methodology followed by Agnico Eagle and Sacré-Davey in the evaluation of the technology.INTRODUCTION The benefits of ore sorting technology are being increasingly understood by the mining industry today. The application of ore sorting in gold mining is attractive due to the nature of the mineral distribution. The presence of high value minerals distributed in an extremely small mass of the ROM ore creates a tremendous opportunity for preconcentration with ore sorting. Since Agnico Eagle currently has a portfolio of eight operating mines and numerous development projects and exploration properties, the challenge was to identify the deposits which had the most favourable mineralogy and grade distribution for successful ore sorting. The success of ore sorting is mostly based on the minerals present in the deposit and the grade distribution. The minerals signify the amenability of the deposit for ore sorting and the kind of sensing technology to be used. On the other hand, the grade distribution demonstrates the amount of material that can be rejected without losing value. In order to understand a deposit’s characteristics, it is important to examine the sample’s behaviour with various sensors and then assay it to know its actual value. It is a common practice in the mining industry to document assay value of drill cores and/or material feeding in and out of the mill. However, those VALUES (are insufficient to understand the grade variability on a granular basis. To capture the ore variability in very high resolution and significantly improve the selectivity of the material feeding the mill, it is vital to assay the samples on a rock-by-rock basis, as this is the level of resolution which will be examined by the ore sorter during sorting. A careful and elaborate procedure was followed in evaluating the technology at Agnico Eagle’s operations which is discussed in this paper."

Jan 1, 2019

By T. Guan, G. Fu, X. Zhou, L. Deng

"One kind of tailings from gravity separation of polymetallic mine contains 0.5–0.8% SnO2. The proportion of –0.037 mm size fraction of the tailings is 37.12%, and the distribution rate of SnO2 is 60.32% in it. For this tailings, two processing technology was carried out. One was felt-shaking table gravity separation in which the concentrate with a grade of 30% SnO2 at a recovery of 10% was obtained. Another was flotation-gravity separation in which the concentrate with a grade of 51.20% SnO2 at a recovery of 51.69% was obtained, but the dosage of collectors was as much as 990g/t. Therefore, the experimental research on the influence of grain size composition on the cassiterite recovery were conducted. The results show that: (1) the flotation recovery of the cassiterite distributed in +0.043 mm size fraction is only 10%, flotation recovery is not suitable for it; (2) a portion of cassiterite distributed in –0.01+0.005 mm size fraction could be recovered by flotation, but the tin flotation performance will be worsened rapidly and the dosage of collectors will be increased due to the increase of the content of –0.010 mm size fraction; (3) flotation processing is not suitable for –0.005 mm size fraction of the tailings. According to the results, a new technology has been carried out, that is discarding tailings by gravity separation-hydrocyclone desliming-flotation-gravity separation processing flow. The processing index is close to that of the flotation-gravity separation processing flow, and the collector dosage is decreased to 360 g/t by this processing technology. And, it has been achieved that the cassiterite slime is recovered economically and reasonably.INTRODUCTIONAs the density of cassiterite is higher than that of gangue, gravity separation is considered to be a low cost, pollution free, and effective process for cassiterite recovery (Wills, 2009). However, cassiterite is a kind of fragile mineral, over crushing is easy to take place and a large amount of slime is inevitably produced in the crushing and grinding of cassiterite. For the cassiterite slime exists in –0.043 mm size fraction, the efficiency of gravity separation decreases sharply. The production practice shows that, for the fine cassiterite, the recovery of tin exists in –0.043 mm +0.010 mm size fraction is about 13% through shaking table gravity separation, and the tin exists in –0.010 mm size fraction is almost impossible to be recovered by gravity separation. If flotation is adopted to recover fine cassiterite, the problems of high reagent dosage, high cost, environmental pollution, and poor economic benefit would take place. Therefore, the recovery of cassiterite slime is a worldwide problem. A key way to increase the utilization of tin resource and increase the economic benefit of tin mines is developing suitable beneficiation process for fine cassiterite."

Jan 1, 2016

By S. Glen

Cyanide management practices on modern gold plants are becoming more onerous, due to environmental pressures, particularly for signatories to the International Cyanide Management Code. Operations are therefore seeking to reduce levels of weak-acid dissociable (WAD) cyanide reporting to spigot discharge as well as to any eventual discharges from the tailings storage facility (TSF). Current gold industry standard processes primarily include the oxidation of cyanide by means of sodium meta-bisulfite (SMBS, or SO2) with air, Caro&apos;s acid (H2SO5) or hydrogen peroxide (H2O2). These processes require the transport and usage of expensive oxidizing reagents, along with the safety and environmental issues associated with these corrosive and toxic chemicals. Maelgwyn Mineral Services (MMS) has developed the MMS CN-DTM process, which utilizes the Aachen ReactorTM, a high-energy mass-transfer superoxygenation system, in conjunction with an activated carbon-based catalyst and no additional reagents, to increase the rate of cyanide oxidation to cyanate, the thermodynamically more stable form. Testwork conducted at the Maelgwyn Australia testwork facility in Perth Australia is described, at both pilot scale and continuous bench-scale, on a sample of tailings effluent obtained from an Australian gold plant. WAD cyanide is demonstrated to be lowered using the MMS CN-DTM process from an influent of 130 mg/L to the required levels for discharge to TSF (<50 mg/L). The continuous test results showed stable operation over three residence time turnovers. The pilot-scale results demonstrated the efficiency of the process at the reasonably large scales required for engineering cost estimation.

Jan 1, 2011

By A. J. MacEachen

"LIKE ALL OTHER NOVA SCOTIANS, I have been thrilled during the past few years with the growing evidence that substantial reserves of oil and gas are being discovered off the Atlantic coast of Canada. There are those in this province who believe that large-scale commercial production is just around the corner, and that when it starts Nova Scotia will begin to float on a sea of royalties. These overly optimistic people, of whom I am not one, are convinced that with the first barrel of oil shipped to market, Nova Scotia can forget its financial problems while its people take on the luxurious lifestyle of the shieks of Kuwait or Saudi Arabia. You and I know, however, that even though offshore oil and gas may turn out to be the greatest gift nature has ever bestowed on Eastern Canada, it may take some considerable time before the reserves can be accurately assessed, before the industry can become fully operational, and before the benefits of production can be translated into royalties and tax revenue, improved public services, new industrial facilities and more jobs. While it is premature for the ordinary Nova Scotian to take on the habit of buying expensive cigars and lighting them with ten-dollar bills, it is not too early for him to insist that governments and industry plan intensively and well for the beneficial exploitation of undersea resources."

Jan 1, 1973

By M. Bigdeli Karimi

In this study, the effect of strain level and holding time in semisolid temperature range via SIMA process on AS21 Mg alloy was investigated. Some cylindrical samples of this alloy with 1cm in height and 2.5cm in diameter (H/D=0.4) were compressed to 10%, 20%, 30% and 40% at 300-C. Then, the samples were reheated in semisolid temperature range at 614°C for various times. The results of optical microscopy and image analysis showed that with increasing of strain and holding time, dendritic structure changed to equi-axed structure, gradually. Also, the best conditions to obtain good globular structure were achieved. Furthermore, it was seen that after compression and reheating, Mg2Si intermetallics with Chinese script morphology converted to dispersed-fine particles which were distributed into the ci-Mg grains.

Jan 1, 2007

By L. V. Bell

THE object in prospecting is to find ore. With the exception of certain discoveries of more or less accidental nature, intelligent prospecting as conducted today is, whether consciously or not, based upon a process of elimination. In the following discuss on it is proposed to evaluate those factors that enter into the eliminating of certain tracts of ground and, conyersely, the concentrating of attention upon others. The danger of generalizations as to the barrenness of cer.ain areas, without having due regard for all such factors, is emphasized. The fact that our conception as to what areas or rock formations are to be regarded as favourable or unfavourable is, in some measure at least, changing with new discoveries under diverse and unexpected circumstances, adds more point to the discussion. The criticism might be raised that the subject is treated largely from the standpoint of geology, but that may be met by stating that it is, and must continue to remain, precisely from this standpoint that the prospecror directs his activities. Briefly, the geologist may render the greatest service to the prospector in the early steps of selecting (a) the general territory in which to prospect; (b) the area to be intensively prospected; and, finally, (c) those parts of the claim or claims to be prospected in detail. Although certain phases of the discussion will be, in some measure, of general application, we shall here concern ourselves essentially with prospecting in the pre-Cambrian shield. Furthermore, the subject is so large that it has been decided to limit it to a consideration of that portion of the pre-Cambrian rocks in which is situated the mining district of western Quebec, of which the writer can speak with more personal knowledge. This limitation need not, however, seriously detract from whatever merit the discussion may possess, since the deposits concerned cover a fairly wide range of metallic ores, including gold, copper with associated zinc, and, lastly, molybdenum.

Jan 1, 1936

The effect of long term exposure of full size bolts to corrosive environments is presented. A special test rig was used to test four bolts under different loading conditions. Four, X-grade identical profile bolts, each of 21.7 mm core diameters (23.7 mm full diameter) were subjected to prolonged corrosion testing using acid sulphate water. The pH value of the circulated water varied between 3.4 and 4.3. The corrosion exposure test period lasted three and half years. Two bolts were axially loaded to 10 and 20 tonnes force respectively, the third bolt was subjected to a 360 Nm torsion load and the fourth bolt was left unstressed to act as a reference bolt. After the test period ended, the bolts were stripped of their corroded coatings and weighted for weight loss. The diameter of each bolt was subsequently measured, and the loaded bolt samples were first tested non-destructively for tensile cracks and then tested for tensile failure. No cracks were found on post corrosion bolts tested non-destructively. The failure strength reduction on all four post-corroded bolts was significant, varying between 21% and 39%. The onset of corrosion was not confined to the targeted mid-section length of the bolt, however, the severest corrosion occurred at the anchored ends of the bolts.

Aug 1, 2013

By S. W. Marcuson, P. J. Mackey

The 1973 Oil Embargo and succeeding disruptions in supply had a profound effect on energy costs and consumption patterns in the developed world. This was especially true in the USA where post World War II growth, fueled by low-cost imported oil, left the country dependent on uninterrupted oil shipments from the volatile Middle East. In this atmosphere, Professor H.H. Kellogg of Columbia University, convinced of the necessity of good environmental stewardship by the writings of the era’s leading environmentalists, developed a methodology for evaluating energy and process efficiency of metallurgical processes and wrote a series of papers describing and applying the techniques. One of these, "Energy Use in Sulfide Smelting of Copper" is recognized as a seminal work which both described the state of energy usage in copper smelting in the mid-1970’s and portended future developments. The background to these papers is examined and the current and past Cu-Ni matte smelting practices in Canada are examined in the context of the results. Data from early 20th century publications describing reverberatory and blast furnace operation is employed to show that energy consumption for much of the century was several multiples higher than that calculated for best reverberatory operation in the 1970’s.

Jan 1, 2015

By W. G. Scott

IT IS APPROPRIATE that your Institute should have chosen, for its 1956 Annual General Meeting, the Capital City of a province which is making such rapid advances in mining. The railway industry is proud to be playing an active role in this development, expenditures on equipment and railway construction in the Province of Quebec alone in recent years being in ?excess of a quarter of a billion dollars. In looking up some background material for this address I ran across a definition of a mine by Mark Twain, the great American humorist, which I thought might amuse you. He said that a mine was "a hole in the ground owned by a liar". I am sure that if he were alive to witness the enormous value attached to Canada&apos;s mineral resources today he would quickly change his definition. Canada&apos;s postwar record of mining development has been staggering in its variety and enormity. Historically, only the ?construction of our transcontinental rail ways outranks the largest of three of these development projects - the aluminum undertaking at Kitimat; the Quebec-Labrador iron ore deposits ; and the petroleum and natural gas developments in Wes tern Canada.

Jan 1, 1956

By S. Huang, K. Xia

"During crushing, rock particle is subjected to complicated loading and the particle shape influences the fragmentation outcome. Thus, a highly controlled laboratory test is desired to establish the relation between the loading and the fragmentation parameters for better understanding the rock crushing mechanism. In this work, a split Hopkinson pressure bar system in combination with high speed cameras is utilized to carry out a dynamic ball compression test, in which the spherical rock sample is adopted to avoid the shape effect. Using the elasticity theory, the history of the axial symmetric tensile stress perpendicular to the diametrical direction along the loading axis is determined, from which the loading rate and the dynamic indirect tensile strength are calculated. With the aid of the moment-trap technique, the total energy absorbed by samples is accurately determined from the one-dimensional wave analysis. Furthermore by considering the kinetic energy of the sample fragments using the high speed camera snapshots, the surface energy is determined for each sample. The relations between the loading rate and the fragmentation parameters, i.e., the number of fragments and the surface energy are established. The application of this method to a granitic rock shows that it is flexible and can be applied to the crushing study of generic brittle solids. INTRODUCTIONCrushers are widely used to break rocks to extract specific minerals in the mining industry, and to obtain rock fragments with desired size distribution in construction industry. During crushing, the breakage of particles can be in either the single-layer mode or the multi-layer mode. In the single-layer mode, the particle breakage can be assumed to be isolated, in which the interaction between particles can be ignored. It is thus suggested by many researchers that highly controlled single particle test should be performed to establish the relation between the input mechanical energy and size reduction for better understanding the crushing mechanism (Yashima et al., 1987; Tavares, 2007; Pitchumani et al., 2004)."

Jan 1, 2015

By P. O. Sandvik, George Erdosh

"AbstractThe Cargill phosphate deposit, located 32 kilometers southwest of Kapuskasing, Ontario, was discovered by the Resource Development Group of International Minerals & Chemical Corporation in 1975 and has been evaluated through an extensive program of 190 drill holes, numerous chemical analyses, metallurgical tests, and engineering and economic studies.The Cargill alkalic complex, comprising principally car-bonatite and pyroxenite-amphibolite rocks, was intruded in to the rift system of the Kapuskasing High during late Precambrian time about 1,800 million year s ago, near the intersection of northeast- and northwest- trending faults. The Cargill complex is one of at least ten known alkalic complexes in or close to the Kapuskasing magnetic-gravity-high system and is expressed by an elongated, northeast- oriented, three-part magnetic anomaly 7.2 kilometers long by 2.8 kilometers wide . Weathering and leaching under assumed temperate to cool, moist climatic conditions , and controlled by faulting, shearing and/or initial petrographic variations within the carbonatite , developed a small, locally confined karst system in the car bonatite rocks and resulted in a thick enriched leached carbonatite zone, capped by troughs and sinks, filled with a residuum of apatite, goethite, clay and other minerals stable in the near -surface, oxidizing environment. Overburden is 5 to 165 meters thick."

Jan 1, 1977

By Somasundaran P., M. Vasudevan, Z. Dai, D. R. Nagaraj, T. Bhambani, P. Patra

Historically, efficient beneficiation of ultramafic ores has been challenging, partly due to a lack of clear scientific understanding of the effects of Mg silicates, particularly fibrous serpentines, on selective Ni recovery. Recent research at Columbia-Cytec as a part of a Vale JDP project has led to new insights into the mechanistic aspects of the adverse effects of Mg silicates. Our research has provided strong evidence to support the hypothesis that the adverse effects of Mg silicates are mediated through their large influence on pulp rheological properties, far more than any other pathway. The severity of the effect of Mg silicates is predominantly dependent on the aspect ratios of Mg silicates. For example, the pulp viscosity increases dramatically with increase in the fibrous nature of the gangue mineral leading to poor Ni separation. Various ways by which the suspension rheology affects flotation sub-processes, with implications for remedy are discussed. The insights and results have served to develop (or construct) a phenomenological model to adequately explain all of the ore flotation data, particularly the Mg silicate transport to the froth phase and the concentrate.

Jan 1, 2011

By Fazel G. Jahromi, Ahmad Ghahreman

"Atmospheric leaching of arsenical sulfide concentrates, and especially enargite leaching, is one of the major challenges within the current hydrometallurgy research area. One of the recent processes developed for sulfide ore treatment is atmospheric leaching in the presence of AF 5, a novel carbon based catalyst, in chloride media. The quantification of different ion concentrations during enargite and chalcopyrite leaching in the presence of AF 5 were measured and the copper recovery rates of 97% and 96% were achieved. The objective of this study is to shed light on the leaching mechanism of the sulfide minerals. Based on the speciation of iron and copper by different titration methods, the AF 5 catalyst first reduced ferric and cupric ions and then oxidized ferrous, cuprous and arsenite ions. The oxidation behavior of the catalyst enhanced the leaching results. The AF 5 catalyst also caused in situ precipitation of scorodite in leaching experiment. The speciation of ions in the chloride media were simulated by Phreeqc software and the dominant species in the leaching solution were determined.INTRODUCTION The hydrometallurgy of copper has been used for several decades and is still under development for more complex copper sulfide minerals due to their refractory nature. Most of the world copper reserves are in the form of chalcopyrite; and enargite is known as a major contaminant. Pyrometallurgical processing of enargite is problematic due to arsenic release and tight environmental regulations (Peacey, Gupta, and Ford n.d.). On the other hand, lower recoveries in the hydrometallurgical processes make most of these processes impractical. Several leaching processes have been developed for the leaching of copper sulfide minerals. Some of the common treatment methods for copper sulfide minerals are pressure oxidation leaching (POX), CESL, Activox, Albion process, atmospheric ferric sulfate leaching, Dynatec, Galvanox, and Hydro copper process (Barr, Defreyne, and Mayhew 2005; Conner and Anderson 2013; D.G. Dixon, Mayne, and Baxter 2008; Hyvärinen and Hämäläinen 2005; Palmer and Johnson 2005; Rohner, Bartsch, and Ngoviky 2012). Generally it is not viable to dissolve copper sulfide minerals at ambient pressure in mild acidic media and dissolution of these refractory minerals requires harsh conditions in the presence of oxidant materials (Biswas and Davenport 2002). Ferric ions have been used as an oxidant in different media in copper sulfide leaching processes. U. S. Bureau of Mines’ Reno Metallurgy Research Center in 1969 (Haver and Wong 1971) investigated ferric chloride leaching of chalcopyrite. Dutrizac and Macdonald (1972) studied ferric sulfate leaching of enargite. Based on this study, 50% of the copper was recovered at 80-85 ºC after 7 days of leaching. Cupric ions can also be used as an oxidant. Parker, Paul, and Power (1981) stated that cupric/cuprous couples are more effective than ferric/ferrous couples in chloride media because they are rapid and reversible. The Hydro Copper process leaches copper sulfide minerals in chloride solution catalyzed by cupric ions. In this process, copper dissolves as cuprous ions in presence of cupric ions (about 10 g/L) (Hyvärinen and Hämäläinen 2005)."

Jan 1, 2017

By Takao Oishi, Go Ohara, Toru Kitazaki, Masahiro Tanaka

"The High Pressure Acid Leach (HPAL) plant for nickel-cobalt mixed sulphide production at Coral Bay Nickel Corporation (CBNC) in the Philippines has been in operation since 2005 with a capacity of 10,000 t/year of nickel. Subsequent to the commissioning of the second plant in 2008, the production capacity increased to 22,000 t/year of nickel (Llerin et al., 2011). CBNC’s annual nickel production reached more than 24,000 tons of nickel in 2014. The concepts to achieve this capacity are the high availability and the reciprocally flexible operation of both plants. The availability depends on some factors, such as the control of impurities in the process and the equipment condition, to mention a few. In the HPAL process, it is not only the autoclave operating conditions that affect nickel extraction but also the impurities in the ore greatly influence it. The major element in the ore is iron and most of this iron is precipitated as Fe2O3, while the rest remains as Fe2+ or Fe3+ sulphate in solution. These ions in solution reduce the availability, so it is important to control the formation of iron ions by controlling the impurities in feed ore as well as the HPAL conditions. This paper presents the general HPAL process and the behaviour of impurities, focusing on iron behaviour in the HPAL process.INTRODUCTIONCoral Bay Nickel Corporation ProfileCoral Bay Nickel Corporation (CBNC) was founded on April 2002, as a joint venture of four companies; namely, Mitsui Corporation (18%), Sojitz Corporation (18%), Nickel Asia Corporation (10%) and Sumitomo Metal Mining Corporation (SMM) with a controlling stake of 54%. Aside from its capital share, Nickel Asia Corporation also supplies the ore and limestone for the High Pressure Acid Leach (HPAL) plant located in Rio Tuba, Philippines, as shown in Figure 1 (Tsuchida, 2008). The objective of the CBNC project is to produce 22,000 t/year (original design) of nickel and 1,500 t/year of cobalt, as sulphide, by the treatment of nickel laterite ore which is a low grade nickel oxide ore in the Philippines (Mines and Geosciences Bureau, 2014). The sulphide product has been exported as a raw material to the SMM Nickel Refinery in Japan for 30 years. The product of this plant, a mixed (Ni/Co) sulphide, is shipped to the SMM’s Nickel Refinery in Niihama, Japan. SMM Corporation provides the technology and management personnel to the plant. SMM Corporation also supplies the sulphuric acid, which is the main reagent for the HPAL process."

Jan 1, 2016

By J. Lipp

The lion share of lithium produced globally originates from South American salars. The standard operation for lithium production utilizes an array of evaporation ponds. This process consume vast areas and is either very slow when relying on solar evaporation - roughly 18 months of residence time; or with very high energy consumption since over 90% of initial water volume needs to be evaporated. A new technology, based on solvent extraction was developed. Results indicate a distribution coefficient up to 30, and selectivity greater than 1,000 towards Na extraction. The loaded solvent is stripped using a strong mineral acid, and the product solution is the lithium derivative of that stripping acid. Utilization of this new LiSXTM technology results in reducing the area needed for a commercial plant as well as reduces the residence time. In addition applying different stripping acids can diversify the product line of such facility.

Jan 1, 2014