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By K. Esmaieli

This paper addresses issues associated with ore pass degradation caused by material impact. A series of numerical experiments, using the particle flow code, were undertaken to investigate the influence of various finger raise configuration. This has allowed the identification of favorable configurations. The results of this analysis, when coupled with field observations, can contribute to the design of ore pass systems that can prolong the useful operating life of ore pass systems.

May 1, 2009

By Timo Heikkinen

We have read, with great interest, Mr. Crocker's article on "Recent Trends in Autogenous Grinding," published in the October issue of The Canadian Mining and Metallurgical Bulletin. Referring to our paper, "Two-Stage Autogenous Grinding Investigations at Outokumpu," we can now report that last August we changed to this method at the Keretti concentrator. Prior to the conversion, the Keretti plant (see flow-sheet, Figure 1) had two primary rod mills, 6 ft. in diameter and 12ft. in length, in open circuit, followed by four secondary 9-by 12-ft. pebble grate mills in closed circuit with rake classifiers. Last summer, wl1en the Since August, grinding has been successfully carried out autogenously in two stages, with two mills being employed in the primary stage and four in the secondary. The size of the pebbles in the secondary mills is about the same as earlier -l V: i to 3 inches (Figures 4 and 5). Also, we generally prefer two-stage grinding to single-stage grinding because, in the former,

Jan 1, 1964

By X. Cao, J. J. Jonas, Wanjara. P., J. Gholipour, E. Dalgaard

The linear friction welding (LFW) behaviour of near-ß titanium alloy Ti-5Al-5V-5Mo-3Cr (Ti- 5553) was investigated. Microhardness measurements were performed in order to evaluate the mechanical properties of the welded material. The linear friction welded (LFWed) Ti-5553 was examined with optical microscopy and scanning electron microscopy (SEM) to evaluate the microstructure’s response to the thermomechanical conditions. Characterization of the welds included analysis of the microstructural features of the weld region and thermomechanically affected zone (TMAZ) in relation to the parent material.

Jan 1, 2010

By Yang Shuxin, Guo Qiliang, He Ping, Lu Lizhi, Yao Rui

"We combined stepwise regression and constrained regression statistical method to obtain the best boundary conditions for the calculation of in-situ stress field in Wushaoling tunnel using finite element method. Our numerical results reveal that: the main geologic factors contributing to the initial background stress are gravity and tectonics; the principal stress values would drop in fault zones; the angle between the maximal horizontal stress and the axis of Wushaoling tunnel is acute; Wushaoling tunnel tends to become stable when this tunnel has 2:1 ratio of the height to its width; the possibility of rock-burst exists under high stress.INTRODUCTIONStress state of engineering region is an important factor affecting the stability of project. Geological disasters in the project area are closely related to their stress environment. Wushaoling tunnel which is 20,050 meters long, lying along Lanzhou-Wuwei segment of Lan-Xin Railway in China, is the key project of Lan-Wu double-track railway. The region surrounding this tunnel is under a high stress environment. Accurate identification of the stress environment of the engineering area and the interaction between geomaterials and geotechnical engineering construction holds significant scientific and practical value for engineering design, construction, and operation.Many scholars explored and discussed the present-day tectonic stress through investigations of tectonic evolution history (Ding, & Lu, 1986), crustal deformation (Zoback, 1992), focal mechanisms (Yang et al., 2003, Xie, Cui, & Zhao, 2004), and so forth. However, the above methods would only provide the approximate direction of the principal stress in a broad region, and could not give the absolute stress values. In-situ stress measurement is one of the primary means to directly gauge the current crustal stress. However, in-situ stress measurement can only be applied in small number limited by measurement conditions."

Jan 1, 2015

By T. Lux, H. -J. Krassnig, I. Filzwieser, E. Hecker, R. Degel, A. Filzwieser

Non-ferrous metals find their applications in smartphones, tablets and computers. These materials with their particular properties are the basis of our modern life. SMS group is well prepared for this huge market and for growing future challenges. A large contribution here is the new joint venture PolyMet Solutions that was founded by SMS group and Mettop, an Austrian engineering company, with the objective to develop new technical solutions for the primary copper production lines as well as for non-ferrous metals starting with the primary smelting of concentrate and ending with the electrolysis. PolyMet Solutions provides the process know-how whereas SMS group supplies the plants and equipment and Mettop the key components. SMS group and Mettop also cooperate in the field of tankhouse technology. Together with Montanwerke Brixlegg AG, Mettop has developed together with a parallel flow technology (METTOP-BRX Technology), allowing a current efficiency of above 98 % at a current density of 420 A/m², which is a milestone in copper electrolysis. For the secondary copper production route, SMS group and PolyMet Solutions developed an innovative refining furnace (PolyRefine) for the smelting and refining of copper scrap. The refined copper is directly charged to the Contirod line to produce copper rods and wires. The innovative cooling solutions of SMS and PolyMet Solutions come into play where furnaces have to stand the highest loads and stresses, for instance in areas of very high temperatures or temperature fluctuations, aggressive exhaust gases and slags, or at critical spots such as taphole areas. Custom-tailored cooling systems for furnace vessels make sure varying loads are compensated in a targeted and effective manner. The solutions include air cooling, spray cooling, cooling technologies with integrated copper elements such as CFM (Composite Furnace Modular) cooling systems, plate and finger coolers. The major innovation in the field of furnace cooling is the ILTEC (Ionic Liquid Cooling) Technology which paves the way for increased plant safety. This revolutionary, patented cooling technology is jointly marketed by Mettop and SMS group. It permits water-free cooling to be implemented and thus makes operation safe wherever it is applied. INTRODUCTION Non-ferrous metals or NF metals are changing the world. There is no modern industrial sector that can do without these valuable metals. Non-ferrous metals find their applications in smartphones, tablets and computers. These materials with their particular properties are the basis of our modern life. The importance of the non-ferrous metals market is reflected by two figures. In 2018, the production of non-ferrous metals was worth more than 237 billion Euros. This contrasts with 255 billion Euros of the value of iron and ferro- alloy production in the same year (International Organizing Comittee for the World Mining Congresses, 2018). Hence, the NF metal industry is almost as important as the iron and steel industry. SMS group is well prepared for this huge market and for growing future challenges. A large contribution here is the new joint venture PolyMet Solutions that was founded by SMS group and Mettop, an Austrian engineering company, with the objective to develop new technical solutions and to enhance customer value. The prices of nearly all metals have come under pressure during the past few years. Therefore, competitive technologies are regarded a crucial factor to achieve success in this critical market situation respectively to stabilize the market position.

Jan 1, 2019

By Nick Vayenas, Ming Cai, Hongbin Zhang Lorrie Fava, Enrique Acuña

"A hybrid methodology is proposed to improve the accuracy of Diesel Particulate Matter (DPM) concentrations simulated in a ventilation network model by using Computational Fluid Dynamics (CFD). DPM, as a primary concern for underground hard-rock mines, has been studied in two dominant numerical models, ventilation network solvers and computational fluid dynamics. Ventilation network solvers are efficient, but they are not able to provide three-dimensional DPM concentration contours and only accept area-average DPM data as input. CFD simulations are time-consuming, but generating DPM concentration results with high accuracy. Besides, both monitoring points and planes can be created in a CFD model, which can take both point data and area-average DPM data as input. The hybrid methodology is intended to combine the advantages of the two by using the CFD results to update the network model results at key locations. A field study was conducted in a dead-end heading in an underground gold mine in the United States. Real-time DPM monitors were used to collect data. A CFD model and a network model were built for the experiment area. The CFD model was calibrated to the experimental data. In the study presented here, results from a calibrated CFD model are converted to equivalent diesel emission rates in the ventilation network model at a shared outlet. The hybrid methodology is used to provide better input for the network model. INTRODUCTION Mine ventilation system is one of the most important parts for an underground mine. It not only provides fresh air to the personnel but also helps clear the contaminants generated from the diesel-powered equipment. For most underground metal and non-metal mines, diesel particulate matter is the main contaminant. It is also the focus of this paper."

Jan 1, 2019

By K. J. Fair, G. Van Weert, J. E. Schneider

"IntroductionCyanidation is the principal process for extracting gold from ores . Many primary gold ores, however, are partially or totally refractory in the conventional cyanidation process.Considerable success has been achieved with new gold leaching techniques, such as intensive cyanidation, pressure cyanidation, carbon-in-leach cyanidation, etc. These techniques however, do not offer substantial gains in gold extraction from refractory pyrites.The more drastic pretreatment processes such as roasting, chemical oxidation, autoclave oxidation, and bacterial oxidation all utilize oxidation to break down the structures of pyrite and arsenopyrite. This generally renders the gold amenable to cyanidation.Comparative cost studies indicate that the oldest commercial pretreatment method, i.e. high temperature roasting, is currently the least expensive option if the sulphuric acid can be sold. It operates with air at atmospheric pressure and is characterized by fast reaction rates. For an alternative hydrometallurgical con centrate treatment method to be competitive, it too should operate with air at atmospheric pressure and with fast reaction rates. The NITROX process meets these conditions."

Jan 1, 1986

By A. J. Naldrett

"Sulphurization of peridotite, that is 'to say reaction between sulphur from an external source and iron and nickel in the silicate minerals of the peridotite or in partially consolidated magma, is believed to be the me-chanism by which the small iron-nickel sulphide deposits associated with the ultrabasic rocks of the Porcupine district have formed.The pyrrhotite-pentlandite ore at the Alexo mine, Dundonald township, is localized by a shear that closely follows the lower contact of a peridotite lens. In the past, to account for this orebody, the magmatic segregation hypothesis has been advanced on the basis of textural evidence and the presence of the sulphides at the base of the lens. The nickel sulphide de-posits of the Porcupine, however, are not characteristically found along the basal contacts of bodies of peridotite. Furthermore, this study has shown that textures formerly thought indicative of magmatic segregation have been formed in certain deposits by the selective replacement of silicates by sulphides.At the Alexo mine, very minor amounts of pentlandite and heazle-woodite (Ni3S2) occur in the peridot-ite hanging wall adjacent to the ore. These sulphides are interpreted as having formed by sulphurization, the sulphur involved coming from the pyrrhotite-pentla.ndite ore emplaced along the shear. This reaction aureole raises the question of the role of sulphurization in the formation of the main mass of the sulphide ore. The very localized equilibrium that has been found to exist between sulphides and silicates in deposits throughout the area, the results of nineteen sulphur isotope determinations, and the abundance of pyrite and pyrrhotite in the volcanic country rocks of the Porcupine indicate that these deposits were formed by sulphurization rather than magmatic segregation."

Jan 1, 1966

By Zhen Lei

In Alberta, Canada, heavy industrial projects are constructed using a prefabrication approach: spools and pipes are produced in the factory, and are assembled into modules that are transported to the industrial plants for installation by mobile cranes. Planning the onsite mobile crane operations is critical to the project budget and schedule. However, due to the large magnitude of industrial projects, manual heavy lift planning is tedious, and the results are not particularly responsive to site changes. This paper introduces an integrated mobile crane management system developed by PCL Industrial Management Inc., in collaboration with the University of Alberta, which investigates crane location selection and path checking for field module assembly. The project information is stored in a database, and the proposed system retrieves data, performs the calculations, and records the results back to the database; the calculations involve automatically selecting locations for the mobile crane, considering the crane capacity, lifting range and utilization. Lift paths for modules are checked for feasibility based on selected locations, satisfying the site and crane configuration constraints, and crane walking paths are planned if needed. The designed system is tested in an industrial project to validate the effectiveness of the system.

Aug 1, 2013

By Gil Espejo, Denise Duncan

"In Alberta, several initiatives are under way to form partnerships between educators and industry to work together in preparing a skilled and technically competent workforce for the future. One successful initiative is the Teachers in Business program which provides high school teachers one month paid internships in Alberta businesses. Initiated by the Science Alberta Foundation in 1992, this program has offered participating teachers a variety of work experiences and job shadowing tours in industry.A Growing Need of Education and Industry PartnershipsIn our ever evolving world, industry is in a tight race to keep up to date with new technology and to remain competitive. Industry is relying on the education system to provide them with the core base for their future workforce. To accomplish this, the education system needs the support of industry to develop the right focus to prepare its students for the race. What skills will our future workforce need? How can we best prepare our students for these needs?Teaching the latest in technology, especially at the high school level, is a major challenge. It is difficult for educators to keep abreast of the rapid changes in technology. High school graduates need exposure to the latest advancements. And so do their teachers. Students must be prepared to adapt to the challenges of the future, Le. global competition, rapid technological change and an expanding knowledge base."

Jan 1, 1995

By R. Argane

In this work we assessed the geochemical behavior of concentrator tailings deposited at the abandoned mines of Zeida and Mibladen (Upper Moulouya, Morocco), using physico-chemical analyses, mineralogical characterization, acid base accounting and weathering cell tests. The aim of the study was to evaluate mine drainage quality and to assess metal mobility from these concentrator tailings. Chemical analyses show that the Upper-Moulouya abandoned tailings contain relatively high quantities of lead (0.261 to 0.594 % wt). Mineralogical analyses reveal the abundance of neutralizing minerals (calcite, dolomite, ankerite, and aluminosilicates) which influence mine drainage and metal mobility in mine tailings. Leachate analyses from weathering cell tests show alkaline conditions, small conductivity values, and low solubility of Pb-mineral phases. According to these results, abandoned mine tailings in the Upper-Moulouya district have very low potential for generation of contaminated mine drainage and for leaching of heavy metals. However, the inhalation of tailings exposed to winds generate dust problem facing the local population and may cause health consequences.

Aug 1, 2013

By Z. S. Shao, X. Z. Li

"Sub-critical crack growth plays an important role in long-term creep failure in brittle rock. Based on micromechanics established by using relationship between micromechanical wing crack growth model and macroscopic strain, and comparing theoretical model with testing results, a method, which applies the theory to real rock, is suggested in this paper. Using this method, properties of creep, damage and progressive failure in brittle rock are investigated. Effects of stress state on creep failure time and steady-state creep rate are analyzed and graphically presented. The results are helpful to support structure design and service life evaluation of underground structures with high geostatic stresses. INTRODUCTIONDuring the long-term operation in underground space with brittle surrounding rock, due to chemical action between pore water and rock, the failure of rock often occurs at stresses below its short-term failure strength, which brings serious effect on the long-term stability of underground structure. Thus, the long-term strength of brittle rock attracted wide interests of scholars around the world. The static fatigue limit was predicted by exponential function that is derived from abundant experiment data of stress level and failure time(Schmidtke & Lajtai, 1985), and similar result by relationship between stress state and failure time was also suggested (Lau & Chandler, 2004; Aubertin et al., 2000; Sangha & Dhir, 1972). According to relationship between steady creep rate and stress state during creep, a critical stress that transforms steady-state creep to accelerated creep was studied and the long-term strength was suggested (Tsai et al., 2008; Ma & Daemen, 2006; Lajtai et al., 1991). Based on the results of experiment in compression, the long-term strength of rock was defined by stress at volume strain reversal. When applied stresses are larger than the long-term strength, the microcracks in the rock will grow constantly, damage of rock will increase and failure of rock will occur finally (Chandler, 2013; Bieniawski, 1967; Brace et al., 1966)."

Jan 1, 2015

By C. J. K. Purdy, H. E. Jamieson

"The comprehensive assessment of the environmental impacts of mining rare earth element (REE) deposits depends on a sound knowledge of the mobility of REEs in low-temperature aqueous environments. Temperature, pH and water chemistry are important factors controlling the aqueous mobility of REEs, while REEs are known to readily form complexes with both inorganic and organic ligands, and it has been shown that sorption and colloid formation may play an important part in dictating REE transport in the low temperature weathering environment. Ore and host rock mineralogy is also a key factor controlling the extent to which REEs are leached from mine waste. INTRODUCTIONThe aqueous mobility of rare earth elements (REEs) has commonly been explored in the past due to their potential application as tracers of geochemical processes in aqueous systems. REE mobility in low-temperature solutions has been shown to be dependent on the pH, temperature, ionic strength, and solution chemistry. For example, the aqueous transport of REEs can be modified by complexation with organic and inorganic ligands (Johannesson & Zhou, 1999; Klungness & Byrne, 2000; Luo & Byrne, 2004; Schijf & Byrne, 2004; Tang & Johannesson, 2010; Wood, 1990, 1993), or through sorption to suspended particles and colloids (Bau, 1999; Quinn, Byrne, & Schijf, 2004, 2006a, 2006b, 2007; Sholkovitz, 1995). Here we review the coordination chemistry, sorption behaviour and potential colloid association of REEs with respect to low temperature aquatic settings.RARE EARTH ELEMENT CHEMISTRYREEs include lanthanum to lutetium of Group IIIA in the periodic table. All share very similar chemical and physical properties. Often included in REE studies is another Group IIIA element, yttrium owing to its similar properties, and occasionally scandium, although its considerably smaller ionic radius makes for different properties and will not be discussed further here. The REEs are often subdivided into the light REEs (LREE), La to Sm, and the heavy REEs (HREE), Eu to Lu, which also usually include Y (hence are often referred to as YREE). The REE may be subdivided further into the LREEs, middle REEs (MREEs), and HREEs, in which case each classification includes La-Nd, Pm to Ho, and Er to Lu as well as Y, respectively, although definitions vary throughout the literature."

Jan 1, 2012

By C. T. Harper, B. J. Fryer, R. P. Taylor

"IntroductionThe Maurice Bay deposit is one of a number of uranium deposits that have been found in recent years in the Athabasca Basin of northern Saskatchewan (Tremblay, 1982). This deposit, along with the others, belongs to the unconformity type deposits (Beck, 1977). They are, for the most part, polymetallic, being characterized by a suite of metals which include U, Ni, Co, Cu, Pb, Zn, Mn, V, Ag, Au, Pt-group elements, S, As, Bi, Se, Te, and Mo, some of which, besides U, are present in economic concentrations (Amok, 1974; Ruzicka, 1975; Tapaninen, 1976; Hoeve and Sibbald, 1978; Dahlkamp, 1978). The Maurice Bay deposit was known to be a small low grade deposit in which the ore was essentially monomineralic, consisting mainly of pitchblende (Harper, 1978). However, the occurrence of trace amounts of some of the elements common in the larger polymetallic ore bodies (e.g. Key Lake, Cluff Lake D) was anticipated. Thus a lithogeochemical sampling project was undertaken in 1979 across part of the Maurice Bay deposit (Harper, 1979). Major oxides (SiO2, Al2O3, FeO, Fe2O, MgO, CaO, K2O, Na2O, MnO, P2O5, and TiO2) and a group of the most common trace metals (U, Ni, Co, Cu, Pb, As, Au, V, and Se) were analyzed to determine whether any elemental patterns (halos or depletions) could be detected which would reduce the number of pathfinder elements needed for exploration purposes. In addition to the above metals, Th was also checked because some conglomerate strata in the Maurice Bay area are known to be thorium-enriched (Harper, 1978). Only the trace metal distributions will be discussed in detail in this report.General GeologyThe Maurice Bay area is underlain by three major groups of rocks, the White Lake metamorphic complex, an unnamed granodiorite complex, and the Athabasca Group, described previously (Fig. 1; Harper, 1979). Table 1 summarizes the stratigraphic features as deduced by geological mapping and the examination of drill cores."

Jan 1, 1986

By L. H. Thorleifson

Demand for both gem and industrial diamonds is very strong. Synthetic production supplies industrial uses, but synthetic gems remain inferior and expensive, so the large gem market is supplied by mining. Several major mines have been depleted, and the market is receptive to new sources of high quality gems. Canada's Precambrian terrane, extending across the Canadian Shield and under the Phanerozoic cover of the Plains and Hudson Bay, has excellent potential for diamonds, but exploration conditions are difficult due to recent glaciation. Early world exploration relying on recognition of diamond in alluvial sediments was adequate to launch pre- 1900 production from India, Brazil, and Africa. Exploration success in Canada, as was the case in Russia and other more recently discovered sources, however, had to await large investments in effort supported by advanced science and technology. Canadian exploration in many ways is similar to that in other regions, relying on analysis of tectonics, indicator minerals, geophysical surveys, and multiple stages of drilling and sampling. Very different from other regions, however, is Canada's surficial environment, in which recent glaciation has caused fresh indicator minerals to be transported hundreds of km. Exploration accelerated in Canada after 1960, first in Ontario and the Arctic Islands, then in Saskatchewan in 1988, and most importantly after the Chuck Fipke - Stew Blusson discovery at Lac de Gras, Northwest Territories, in 1991 that led to the billion-dollar BHP - Dia Met Ekati Mine that opened in 1998. In 2003, production from Ekati will be supplemented by that from the similar and nearby Diavik Mine of Rio Tinto and Aber. These mines will bring Canadian output to over 10% of world supply, and will position Canada with Botswana and Russia as world leaders in production of high quality gem diamonds. There could be other mines as well, as sites across the Arctic and in the south from Alberta to Québec are being explored by an array of companies, including De Beers, other majors, and several juniors.

May 1, 2003

By K. A. Mackinnon

The choice of fan type (axial flow, centrifugal or mixed flow) most suited for a mine ventilation application depends on a number of technical and economic factors. For each project, the relative importance of these factors will vary. It is worthwhile to carry out an assessment on a case by case basis. The paper, by discussing a number of technical and economic factors and their interactions, will provide the ventilation official a methodology to easily and methodically undertake such an assessment.

Aug 1, 2013

By C. Rodgers, E. (Ted) Warren

"LocationThe Key Lake operation of Cameco Corporation is located at latitude 57°N in northern Saskatchewan, within the southem boundary of the Athabasca formation. The nearest city is LaRonge, located 240 km to the south. Access to the mine is by all-weather road and by private airstrip.Description of OperationThe mill was designed to produce twelve million pounds of uranium oxide (U3O8) a year from a feed grade of 2.4% U3O8. Current production is fourteen million pounds from 2.0% feed.Following grinding, the uranium is leached using sulphuric acid and oxygen in autoclaves. An eight thickener counter current decantation (CCD) circuit is used to separate the uranium-bearing solution from the solid waste residue. The uranium in solution is further purified in a solvent extraction circuit. The purified uranium is then precipitated using ammonia, calcined at 840°C, and packaged in drums for shipping to refineries. There is a crystallization circuit to recover excess ammonium sulphate produced in the process, and a waste treatment circuit.HistoryUranerz Exploration and Mining discovered the Gaertner and Deilmann orebodies in 1975 and 1976, respectively. Between 1975 and 1977, Uranerz conducted laboratory studies and delineated a process for the Key Lake ore known as the ""Bonn process."" In 1977, Sherritt Gordon Mines Ltd. was retained to conduct further studies in cooperation with U ranerz. The technical feasibility of the Bonn process was generally confirmed. Howeve1~ alternative processing methods also appeared feasible, and over the period 1978-1979, a detailed research and development program was conducted to finalize the processes to be used and to provide data for design of the plant."

Jan 1, 2000

By R. C. Gilmore, J. F. Brune

"Pulverized limestone rock dust used in United States underground coal mines to prevent and suppress coal dust explosions must easily disperse by forces of a methane or coal dust explosion. Moisture in the mine environment causes caking of the dust. Colorado School of Mines researchers performed dispersibility tests in a full-size explosion test drift. Tests included conventional, hydrophobized, and rock dust approved for German mines. Conventional and German standard rock dust products partially agglomerate, which may not be effective in suppressing a coal dust explosion, while hydrophobic rock dust retains better dispersibility.INTRODUCTIONA coal dust explosion devastated the Upper Big Branch mine in 2010 resulting in the death of 29 miners, the worst mining accident in the United States since 1972. The explosion propagated through approximately 65 km of active mine workings, but was extinguished in areas that had been properly rock dusted (Page, 2011). Researchers have long studied and established the ability of inert limestone rock dust to suppress coal dust explosions, see Richmond et al. (1975), Cybulski (1975), and Sapko et al. (2000).To be effective, rock dust must contribute to a total inert content of > 80% by weight and 100% of rock dust particles must pass through an 850 µm sieve, while 70% of the rock dust must be finer than 74 µm. This is established in US regulations 30 CFR §75.2. Dry rock dust is a nuisance that prevents mining work downwind from rock dusting activities. To overcome this problem, dust manufacturers have proposed applying the rock dust as a wet slurry or foam. After drying, manufacturers expected the slurry or foam-applied dust to have the same explosion suppression capabilities as dry-applied rock dust.Researchers at the Colorado School of Mines (CSM) designed and built a full-scale, underground Explosion Test Facility (ETF) at the CSM Edgar Experimental Mine in Idaho Springs, Colorado about 20 miles west of the CSM Golden, Colorado campus. To disperse the different rock dust products, researchers produced an air pressure pulse using a mesh array of PETN detonation cord. This method is simpler, more reproducible and safer than other methods considered, including methane-air explosions and a compressed air cannon. The detonation cord blasts produce a wind velocity of 30 to 50 m/s, the minimum velocity at which coal dust explosions can propagate, based on research by Nagy (1981) and Cybulski (1975)."

Jan 1, 2019

By E. Hardwick, K. C. Sole, Y. Jurrius

"The Luilu cobalt plant at Kolwezi, Democratic Republic of Congo, has been operating since the late 1950s, using a conventional precipitation flowsheet for removal of impurities from the cobalt process stream. Most impurities are, however, incompletely removed using this technology. Copper and zinc, both of which quantitatively deposit at the cathode in the cobalt electrowinning process, are two of the main impurities contaminating the cobalt metal product. Ion exchange offers a modern approach to removing these impurities from the cobalt advance electrolyte.Following a laboratory testwork programme to identify a suitable ion-exchange system, an on-site pilot-plant trial, treating 1500 to 3000 L/d of electrolyte, was operated for a period of six weeks to optimise the operating conditions and to determine full-scale design criteria. Copper removal was carried out using a fixed-bed lead-polish configuration with the Lanxess iminodiacetic acid resin, TP 207. Zinc removal was subsequently carried out in a similar configuration using the Lanxess aminophosphonic acid resin, TP 260. The optimised system proved capable of removing both copper and zinc from 20 to 30 mg/L to <1 mg/L from plant electrolyte containing ~20 g/L Co. Selective elution allows co-loaded cobalt to be returned to the main circuit and value to be obtained for the copper impurity. The process shows operational and economic advantages over the traditional flowsheet. Full-scale implementation of the developed process is in progress and some design considerations are discussed."

Jan 1, 2014

By H. Jung

The microstructures and grain sizes of nanocrystalline Co and Co-1.1 wt % P alloys were characterized by X-ray diffraction. The corrosion properties of as-deposited and annealed Co-l.l wt % P alloys and pure nanocrystalline Co were studied in a deaerated 0.1M H2SO4 solution using electrochemical measurements and XPS surface analysis. Potentiodynamic polarization testing and impedance measurements revealed that an addition of P to pure nanocrystalline Co improved the anodic-corrosion resistance, however, this enhanced corrosion resistance was compromised by the heat treatment process at 350 and 800°C. The corroded surface of annealed nanocrystalline Co-1.1 wt % P at 350°C exhibited a more porous P-enriched layer compared with the as-deposited case. A sample annealed at 800°C corroded uniformly showing second-phase precipitates. The enhanced corrosion resistance of as-deposited nanocrystalline Co-1.1 wt % P was attributed to the elemental P on the surface that acted to hinder the anodic dissolution kinetics of surface Co following an initial selective dissolution of Co. However, at a higher anodic overpotential region, the superior corrosion resistance of Co-l.l wt% P alloys did not last because of the formation of a non-protective surface film consisting of mainly hypophosphite and phosphate as well as elemental P.

Jan 1, 2005