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By J S-L Chan, J C. T Chu

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. In its industrial days, Hong Kong’s mining industry was thriving, benefitting from the mineral occurrences that are related to the regional Mesozoic igneous and hydrothermal activities.Hong Kong was unique in the mining sector as it was so small in landmass but with such a rich variety of commodities discovered. There are records of commercial exploitation of tungsten, iron, lead, silver, beryl, graphite, quartz, feldspar and kaolin in Hong Kong before 1981. Of these, most of them are located in the New Territories.The Lin Ma Hang lead mine was operated in the 19th century by the Portuguese and was abandoned in 1958. The Needle Hill tungsten deposit was discovered in 1935 during construction of the Jubilee Reservoir. The Ma On Shan iron mine, which operated for 70 years between 1906 and 1976, was the largest mine in the history of Hong Kong. The Mui Wo lead-silver mine on Lantau Island can be traced back to the Ming Dynasty 400 years ago. West Brother Island, which extracted graphite from 1952 to 1973, was levelled in the 1990s to make way for the development of the airport at Chek Lap Kok.Nowadays, these mines are disused and abandoned, but this extended abstract reviews the legacy of the mining industry in Hong Kong to understand the impact that it had on techniques, the economy and culture.CITATION:Chu, J C T and Chan, J S-L, 2015. The history of mining in Hong Kong , in Proceedings PACRIM 2015 Congress, pp 109–114 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

The interaction between ore-bearing fluids and the siliciclastic rocks typically hosting orogenic gold deposits in Phanerozoic metamorphic terrains result in the development of a distinctive alteration halo. Along with petrological changes such as the replacement of chlorite by carbonate and the growth of sericite, characteristic geochemical modifications take place within this alteration envelope. These include variations in elemental abundances and more or less pronounced shifts in the H, C, N, O, and S isotopic signature of the ore system. æFingerprintingÆ these isotopic trends can provide exploration with additional vectors towards the ore zone, and yields valuable information regarding the source of the hydrothermal fluids and the solutes contained therein. Data from radiogenic isotope systems such as Sr-Rb, Ar-Ar, Xe-Ra, Pb-Pb, Re-Os, Sm-Nd, and U-Pb can constrain the kinematic history of ore-hosting structures, provide important clues concerning the absolute timing of gold emplacement, and enable the detailed characterisation of associated intrusives with respect to their magma source(s) and crystallisation age. Although high analytical costs, long turn-around times and the potential for misinterpretation prevent isotope systems from offering a æquick & dirtyÆ analytical method that would provide a significant advantage in exploration for orogenic gold mineralisation, the development of integrated four-dimensional ore genesis models depends heavily on constraints obtained from isotope mass spectrometry.

Jan 1, 2002

By G R. Ballantyne, A N. Mainza, M S. Powell, M Evertsson

Quantifying the performance of a comminution circuit relative to the potential that can be achieved is a standard requirement in justifying operating practice (the stick) and seeking operational upside (the carrot). Historic measures tend to focus on performance relative to laboratory design tests that provide a direct measure of specific grinding energy, such as the Bond Work index; or use dropweight breakage tests calibrated to a substantial database of operating sites, such as the SMC methodology. Although of value, such approaches are flawed in significant aspects. The assumption is that the laboratory prediction is correct and the single sample it is based on is representative. The database benchmarking methods are, by definition, locked into current average operating practice. These approaches do not illuminate upside; can ‘punish’ operations that are actually more efficient, such as grinding finer than standard operation; and reward poor operation that may comfortably produce a coarser grind than optimal for recovery or excess slimes that reduce recovery and increase water consumption and tailings volume. The authors present a set of established and easily applied measures, that draw together daily operation, highlight areas of opportunity and inefficiency, use simple samples and data, and can be used to provide the ‘size of the prize’ in pursuing specific areas of process improvement. These tools include size specific energy (SSE), overall operating effectiveness (OEE) which includes product quality, theory of constraints, and links this to the end objective – maximising the efficient production of valuable metals. Feeds into objective function driven by economics – financial return, energy, environment.

Aug 24, 2022

By J S. Dunlop

At its most basic level, minerals project management may be broken down into a series of logical chronological phases, described in this paper as: exploration, discovery; scoping and pre-feasibility; feasibility and approval; project financing and commissioning; operation; expansion and closure. Each phase has its own peculiarities and challenges, any one of which can potentially upset the forward progress of a minerals project.Reference is made to each of these project phases based on the authorÆs many years of first-hand experience, in an attempt to identify issues within the project management spectrum where additional caution may be warranted. Left un-addressed, these issues can cause undue delays in the project timeline, ultimately delaying approval at significant project cost.Finally, reference is made to the Mine ManagerÆs Handbook recently published by the AusIMM which is an excellent project management resource, considered to be very relevant for minerals treatment plant managers, whether the context be constructing, operating, expanding or shutting down.CITATION:Dunlop, J S, 2013. Mineral project management - A perspective from four decades in the industry, in Proceedings MetPlant 2013 , pp 13-27 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013

Real Time and In Situ Measurement of Elemental Composition Using Lasers

Sep 13, 2010

A Simulation Study on Two-Stage Grinding with High-Pressure Roller Mills By the application of high-pressure roller mill (HPRM) in the field of mineral processing, computer simulation can be used to predict overall performance of a grinding circuit based on data obtained from HPRM comminution test in pilot scale or industrial scale. Using the model developed by Klymowsky and Liu for HPRM comminution and an extended Plitt's model for classification, steady-state of a closed circuit grinding can be calculated by means of a virtual locked-cycle-test conducted on computer. This paper presents the result of a simulation study on two-stage grinding with HPRM as the comminution device. The emphasis is put on the influences of circuit-configuration and way of recirculating classifier's coarse-product on the overall circuit performance. The results show that two-stage grinding with HPRM has its merit and flexibility in meeting demands of various grinding tasks in mineral processing.

Sep 13, 2010

By F T. Suorineni, L Baird, A Papaioanou, D Hines

The Mathews et al (1981) stability graph was developed to provide guidance in the determination of stope sizes to control dilution in bulk mining of large orebodies. Longhole and sublevel open stoping (LHOS and SLOS) are the lower end in scale of underground mass mining with panel and block caving (PBC) at the higher end. Currently, the stability states of stopes in the stability graph are described qualitatively as stable, unstable or cave. The alternative quantitative option to the qualitative stability graph is the Equivalent Linear Overbreak Slough (ELOS) stability graph. The ELOS stability graph only applies to narrow vein orebodies. It is easy for the Mathews et al (1981) and the ELOS stability graphs to be applied outside the limits of their databases. What is currently referred to as ‘stable’ in the present stability graphs has diverse interpretations at different mines depending on their acceptable dilution values. In 2014, a research program was conceptually conceived at the UNSW Australia School of Mining Engineering to develop a quantitative dilution-based stability graph independent of orebody width to address some industry concerns on the use of the stability graphs. A dilution-based stability graph provides the mining engineer the flexibility to determine open stope sizes based on what dilution amounts are acceptable. The graph also unifies both the Mathews et al (1981) and ELOS stability graphs for wide and narrow vein orebodies, thus, eliminating their potential misapplications. To date, the concept is proven with case studies from metalliferous underground mining operations located across Australia. This paper presents the dilution-based stability graph concept, the initial results and future plans to account for other critical factors and increase confidence in its application with the addition of more data outside Australia.CITATION:Suorineni, F T, Papaioanou, A, Baird, L and Hines, D, 2016. A dilution-based stability graph for open stope design, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 511–522 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By Hindmarsh J. W, McCoy A. E R

Instantaneous outbursts of coal and gas have occurred at various times in several working districts of Metropolitan Colliery, N.S.W.They have occurred in headings only, under both hand and mechanised conditions, and with seam gas ranging from mainly methane to nearly pure carbon dioxide. A modification of inducer shotfiring using a shear cut was introduced in 1955, and in 1961 full face firing both to a machine cut shear and off the solid was introduced. The current series of outbursts -1961 to 1963 - has been induced under these systems with full control of the time of outburst, but without prediction, and with some disappointing production features.Various aspects of current conditions and practices at Metropolitan are considered singular, such as the coarse granulometry of outburst coal, the prevalence of floor heave, the absence of strong structures at outburst sites, the possibility of outburst at any stage in pillar formation up to the last few yards, the effect of rate of advance on outburst occurrence, and the mildness of many outbursts experienced.It is concluded that inducer shotfiring is a reliable control but it suffers by comparison with outburst-free conditions, and that control by preyention would be preferable.INTRODUCTIONThe phenomenon of instantaneous outbursts of coal and gas has been described in detail previously (Hargraves, 1958). Briefly, it is a combined gas and stress hazard of deep coal mining, usually occurring in virgin work and during active face advance, when coal and seam gas burst from the face into the workings.Instantaneous outbursts have occurred sporadically at Metropolitan Colliery, N.S.W., since 1895. Early outbursts were recorded as firedamp and recent outbursts are of blackdamp.Mining methods used have been conventional hand work, with progressive and relatively complete mechanisation over the past 25 years to substantially conventional...

Jan 1, 1964

KIeeman (1968) described practice in the Mount Hebbard dump concentrator, Broken Hill, N.S.W. The purpose of this note is to give data on flotation pulp chemistry in the plant for comparison with results of Woodcock and Jones (1970a, 1970b).Ten chemical parameters were measured at ten points in the circuit using the techniques of Woodcock and Jones (1970a, 1970b). Fig. 1 shows a condensed time plot of some continuous measurements in conditioner overflow and rougher feed. Fig. 2 shows average values of selected parameters at the start and end of each of the three rougher flotation stages.DISCUSSIONpH and redox potentiaIsFig. 1 shows that pH and Eh were relatively constant at the start of sulphide lead flotation. There was a fairly steady increase in pH throughout the circuit (Fig. 2), but flotation was always conducted in a slightly acid pulp in spite of the large amount of alkaline reagents added. Eh values became more positive as the pulp progressed through the circuit (Fig. 2) in accord with results elsewhere.

Jan 1, 1973

The following data are put together to assist those who are responsible for ordering stores for mines and works. When making out a list of mine stores for a new plant, one can hardly be expected to remember everything, still it is all the more important that articles should not be forgotten, should the mine be situated in an out of the way place, where the manager has to look several weeks ahead. A man who has been accustomed to buy stores on a small scale, from local merchants, where he could pick out personally what he wanted, may suddenly find himself in a place where he has to order wholesale quantities or make out store lists to send contractors for quotations. As it is of course cheaper to purchase stores by the hundredweight, coil, barrel, etc as the case may be, in which they are made up, than to break such a parcel, the way in which the materials are placed on the market is mentioned, so that those who don't know may take full advantage of wholesale terms. The most frequent sizes and brands employed in connection with Australian mining are also mentioned. It would be useless to enumerate all sizes made by the trade, as many would be of no value for our purpose; still I have put down what will serve as a reminder to the manager to mention what size he requires when giving an order, such as the diameter of dynamite cartridges a slight neglect of this sort has often caused serious delay. By mentioning certain brands I do not wish to recommend them in preference to others inadvertently omitted they are simply mentioned as some of those frequently met with.

By D Porta, E Grigolato, K Behrens

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Aug 12, 2013

By J Wei, A Yo, R Levy

Waste water reuse from municipal and industrial effluents is becoming increasingly important in many areas around the world. Water scarcity, local regulation and environmental impact are driving many industries like coal and copper mines to reuse the large volume of waste water they produce. For example, the Chinese coal industry generated about 4.2 billion tons of mine waste water in 2005 of which only approximately 30 per cent was reused. Coal energy represents 76.6 per cent of the total energy generated in China in 2007 and most of the coal-fired power plants are located in north-west of China, which is a water stressed area.The selection of mine waste water treatment process is challenging as the effluents typically contains high levels of organic compounds and salinity and their composition can vary significantly. In recent years there has been a growing interest in the integration of ultrafiltration (UF) and reverse osmosis (RO) membrane technologies for mine waste water treatment and reuse.In this paper, an overview of the design and performance of ultrafiltration and RO membranes applied for reuse of mine waste water are discussed. A study was carried out in two effluents treatment plants treating copper and coal mine waste water, which are located in Chile and China respectively. The following topics will be discussed to demonstrate the performance of an integrated membrane system in mine waste water reuse: The main challenges from copper mine waste water treatment: high level of chemical oxygen demand (COD); high level of total suspended solids (TSS); high salinity; high concentration of silica, sulfate, iron and other contaminants; and fluctuation of raw water quality. The main challenges from coal mine waste water treatment: high level of total dissolved solids, and waste water quality fluctuation. Design parameters for waste water treatment systems: Selection of pretreatment for dual-membrane system in the copper mine: Clarifier with coagulation and flocculation to remove high TSS; Dissolved Air Flotation (DAF) to remove non-settling solids; Media filtration to handle fine solids and particulate organics; Activated Carbon filters (ACF) to remove dissolved organics, colour and odours. Selection of UF and RO membranes and specific design of their recovery, flux, chemical dosage and cleaning regimes. Finally, the performance of UF and RO, including the main fouling factors and efficient cleaning procedures, will be presented and compared to the design parameters to demonstrate the efficiency and performance of the selected integrated membrane systems in each case.

Jan 1, 2009

By B Yang, S M. Aminossadati

Transporting coal by means of conveyor belts is very common in Australian underground coal mines. Major conveyor belt-related mining incidents are now relatively infrequent as a result of recent improvements in engineering standards and use of fire-resistance materials. However, conveyor belts have the potential for incidents capable of causing either personal or structural damage. In addition, any unexpected break down of rolling components or failure of belts creates a significant interruption to the production that is a major concern for operators whose responsibility is to achieve the optimum mining production.Currently, underground coal conveyor belts are examined for the presence of any overheating, smouldering or unsafe conditions likely to cause a fire. Periodic inspection of operating conveyor belts is carried out with the aim of detecting any local heat sources in an early stage. This includes temperature measurements of the driving head, idlers and rollers using hand-held temperature sensors such as infrared cameras or laser temperature sensors. The disadvantages of current conveyor belt temperature monitoring systems include high labour and equipment costs, safety risk to personnel who are in close proximity to moving conveyors, the ability to take line of site measurements only and potential for missed overheated idlers. Some of the conveyor idlers in underground coal operations cannot be accessed for traditional temperature measurements. This introduces a significant risk to the operation of critical infrastructure.A distributed temperature sensing (DTS) system can be used to develop an advanced conveyor belt temperature monitoring system that provides real-time, accurate and continuous temperature measurements along a conveyor belt particularly at the rolling components. The DTS system comprises of fibre optic detection cable, DTS controller and interfacing module. The advantages of the system include the accuracy, low-cost, easy installation, robustness, safety, immunity to radio frequency and electromagnetic interference, real-time data collection, and secure data transmission. This paper presents a scoping study on the development and utilisation of a fibre optic-based DTS system for underground coal conveyor belts. The mechanism of heat generation, the operation temperature range and the installation issues of fibre optic cable along the conveyor belt particularly in close proximity to each end of the spindle on every idler will be discussed.CITATION:Aminossadati, S M and Yang, B, 2013. A scoping study on fibre optic-based temperature monitoring of underground coal conveyor belts, in Proceedings The Australian Mine Ventilation Conference , pp 35-42 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 1, 2013

The information age has definitely arrived and in fact has only begun to affect our business processes. Traditionally mining companies have been innovators and leaders with technology, but applying information technology systems to machines directly working on the mining extraction process poses challenges to those introducing the technology. Caterpillar is now presenting machine guidance and information systems for dozers, graders, blast hole drills, shovels, excavators, wheel loaders and trucks. These systems simply increase the flow of real information in real time and deliver it to the end users who can make informed decisions that effect real productivity gains and at the same time eliminate the role of the middle manager who used to monitor and control these activities. Technology also offers cultural changes that appear intangible, but offer significant gains to those that implement technology. Critics state that these intangible benefits are still available to traditional processes, however these intangible elements are never identified nor managed without the introduction of technology enhanced processes. The benefits of these technologies are real and dramatic, existing users offer impressive testimonials, but still the technology can be disproportionate in the time it takes to introduce to an operation. Caterpillar finds that senior to executive management needs to be a part of the technology introduction, to coordinate all departments and set technology strategies.  

Jan 1, 2000

By H Mali, B Kain-Bückner

Different types of lump iron ore-bearing particles were investigated in terms of their raw material properties depending on their behaviour during reduction. To predict the reduction behaviour different types of lump iron ore and pellet brands were characterised by their mineral abundance, texture and pore size. The image processing software VisuMet was developed to semi-automate the evaluation of photomicrographs from polished sections of lumpy iron particles. The results were compared to the standard reducibility test after ISO 4695. The evaluation of lump iron ores is based on the simulation of the transformation of the different iron minerals due to their sequence of reducibility. The progress of the reduction front is simulated and the result is a degradation curve. Pellets were also investigated due to their different pore size distribution. The results indicate that the pore size influences the reducibility in addition to mineral abundance. The evaluation with VisuMet of the lump iron ore and pellet samples correlates with the reducibility provided by the ISO 4695 test. The determination of the mineral abundance by VisuMet is comparable to common point counting with a correlation coefficient of 99.67 per cent.CITATION:Kain-Bückner, B and Mali, H, 2017. VisuMet – analyses of lumpy iron carriers with image processing, in Proceedings Iron Ore 2017, pp 557–560 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By Both R. A, Daily B

The Patawarta Diapir, located in the northern Flinders Ranges (South Australia), has intruded into late Proterozoic Wilpena Group sedimentary rocks. The diapir contains disrupted blocks of a wide variety of rock types, most of which can be correlated with the Lower Callanna Beds of Willouran age, in a matrix of predominantly carbonate and siltstone breccia. Mafic rocks in the diapir appear to predate intrusion of the diapir. As with many other diapirs in the Flinders Ranges, copper mineralization is present in the diapir and occurs as narrow veins consisting essentially of carbonate with chalcopyrite and pyrite that formed after diapiric intrusion.Fluid inclusion studies demonstrate that the mineralizing fluid was a Na-Ca-K-Cl brine; probably derived by expulsion of interstitial water following emplacement of the diapir, with dissolution of evaporites within the Callanna Beds sediments and enrichment in copper by reaction with these sediments and associated basic igneous rocks. Mineral assemblages combined with fluid inclusion and geochemical data indicate a possible environment of vein formation of T ÿ 165°C, pH ÿ 4.3 ± 0.9 and log fO2 ÿ -47.3 ± 0.5. Sulphur isotope analyses indicate d34Sfluid ÿ 10 per mil, suggesting evaporites in the Proterozoic sediments as the major source of the sulphur but with some additional sulphur from an igneous source, possibly leached from the malic rocks of the diapir.

Jan 1, 1986

Maintaining high carbon activity is vital to the efficiency of any Carbon-In-Leach or Carbon-In-Pulp process. Reduced activity can lead to longer residence times or gold losses in the tails. Regenerated carbon from the CIL circuit at Macraes Gold Mine was analysed for kinetic activity and composition over a 15 month period. An increase in kinetic activity during the time period was recorded, which was linked to reduced Na and Ca loadings. A laboratory simulation of the loading, stripping and regeneration of gold was developed and tested. Kinetic activities were obtained for synthetically fouled carbons following three circuits of the laboratory simulation. It was shown the competitive gold adsorption ability of xanthate fouled carbon (previously reported as a serious deactivator) could be significantly recovered following effective thermal regeneration. This ability was maintained in a subsequent circuit loading.

Jan 1, 1993

The dissolution of gold in cyanide has been studied, using both chemical and electrochemical techniques. The electro-chemical studies have confirmed that gold may become passive in cyanide solution if its potential becomes more positive than -O· 5 V v. saturated calomel electrode (S.C.E.). The results of the conventional solution rate tests suggest that, although the solution rate is controlled by the rate of diffusion of oxygen at low oxygen and agitation levels, when these are increased the gold may become passive and its solution rate approach a steady value, or even decrease with increasing oxygen level. The passivity of gold has been shown to be of importance in the solution of small spheres of this metal, and in the extraction of gold from a calcined auriferous pyrite concentrate.INTRODUCTIONAlthough it has been appreciated for many years (McLaurin, 1893, 1895) that dissolved oxygen is a necessary adjunct to the solution of gold by the cyanide process, attempts to quantitatively assess its effect have led to conflicting results. For example, Barsky, Swainson, and Hedley (1934) reported that an increase in oxygen concentration improved the solution rate, but Beyers (1936) claimed that such an increase would reduce the rate at which the gold dissolved.By using an electrochemical approach Kudryk and Kellogg (1954) showed that the diffusion rate of either the cyanide or the oxygen was a controlling factor, and that, if the mole ratio of cyanide to oxygen concentration was greater than 10, the solution rate was proportional to oxygen concentration.These results, although they represent some of the most careful work available, were in direct contradiction to the findings of Mills (1951), who found that gold may become passive in cyanide solution, with a resultant decrease in solution rate.

Jan 1, 1963

By N Belluz, L Johnson, N Wiwoho, P Manning

The Kucing Liar skarn deposit is located in the Ertsberg mining district, which also contains other skarn deposits and the Grasberg porphyry copper û gold deposit. The Ertsberg district is located in the province of Irian Jaya, IndonesiaÆs easternmost province. Mining development began in the Ertsberg district in 1972 with the mining of the Ertsberg deposit. Daily production in the district now averages about 230 000 tonnes of ore, with the bulk of the ore coming from the Grasberg open pit and the balance from underground mining of skarn deposits. During 1998, 45 218 additional metres of drilling were conducted to delineate and understand the Kucing Liar orebody. The deposit was first intersected in drill holes in 1994 and then was intersected in underground workings located about 1000 metres from the discovery drill hole in 1995. Initially, the two intersections were thought to be different orebodies but are now realised to be different parts of the same orebody. The Kucing Liar deposit consists of magnetite û copper û gold replacement and skarn mineralisation in favorable Tertiary and Cretaceous units. The deposit is approximately 2000 metres in length and averages about 200 to 250 metres in thickness. The width varies from 400 to 600 metres. Drilling in 1998 was directed towards delineating the deposit on its NW and SE ends and to determine its down dip extension. Reserves for the deposit at the end of 1998 stand at 320 million tonnes at 1.4 per cent copper, 1.4 g/t gold, and 5.3 g/t silver. Many important questions remain to be answered concerning the relationship of the Kucing Liar orebody to the major faults in the district and to the Grasberg intrusive complex which contains the Grasberg orebody. Continued exciting developments are anticipated as work to understand the deposit by drilling and geologic study continues.

Jan 1, 1999

In 1801, Hatchett discovered the oxide of a new element while he was examining a heavy black mineral from Haddam, America, which had been presented to the British Museum. He named the mineral Columbite and the metal Columbium. A year later a Swedish investigator, Eckeberg, while working with a new mineral resembling columbite-yttrotantalite discovered a new element, to which he gave the name of tantalum.In 1844, Rose announced the existence of two new elements in a sample of columbite from Bodenmais. One was similar to Eckeberg's tantalum and the other was called Niobium. Wollaston, in 1909, attempted to show experimentally that columbium and the tantalum were identical, but it was soon proved that they were two separate elements. Subsequently a number of investigatiors found other "new elements" in tantalum and columbium bearing ores, but these were shown to be mixtures of the twin metals.Since Hatchett's Columbium and Rose's Niobium are identical, it is more fitting to use the name assigned to this element by the earlier investigator. However, the term niobium is still retained in Germany and England.The separation of tantalum and columbium has been one of the major problems for analytical chemists since the discovery of the two elements and it is only in recent years that tantalum of a high degree of purity has been produced. High purity columbium metal is probably still to be obtained.Until 1903 tantalum was merely a laboratory curiosity, but about this time its use in incandescent electric light bulb filaments was discovered. Eight years later it was replaced by tungsten, which was better and cheaper. For a time the electrolytic valve action of tantalum was used in the charging of storage batteries, but the chief uses of the metals' to-day are for corrosion resistant apparatus, in vacuum tubes and as carbides in the manufacture of hard cutting and shaping tools.Most of the recent work on the metals has been done by C. W. Balke, in America. Tantalum has been studied more than columbium. OCCURRENCE OF TANTALUM AND COLUMBIUMI. NATURE OF ORESTantalum and columbium occur, nearly always together, as the oxides in combination with other metallic oxides. The only known exception to this is the reported occurrence of metallic tantalum with gold in the Ural Mountains. Unlike most other metals, no compounds with sulphur are known to occur in nature. Tantalum and columbium minerals occur usually...

Jan 1, 1943