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By E. Asselin

Passivation of Fe-Ni-Co alloys during the Caron leach process is thought to result in low cobalt recoveries in ammoniacal ammonium carbonate solutions. A brief review of the available thermochemical data for the (Fe, Ni, Co)-NH3-H2O systems has been undertaken. The stability of the Co(II) and Co(III), Ni(II) and Fe(II) am-mines was examined through the use of speciation and Pourbaix diagrams at 298 and 333 K and at 6 M total ammonia. Increasing the temperature reduces the stability fields of the ammines and generally constrains the thermodynamic window for the leach. The Fe(II) ammines are only thermodynamically stable under reducing conditions. Polarization experiments show that these ammines are unlikely to form if oxygen is present. Fe-Ni-Co alloy passivation may be alleviated by careful management of potential.

Jan 1, 2011

By E. Asselin

Passivation of Fe-Ni-Co alloys during the Caron leach process is thought to result in low cobalt recoveries in ammoniacal ammonium carbonate solutions. A brief review of the available thermochemical data for the (Fe, Ni, Co)-NH3-H2O systems has been undertaken. The stability of the Co(II) and Co(III), Ni(II) and Fe(II) ammines was examined through the use of speciation and Pourbaix diagrams at 298 and 333 K and at 6 M total ammonia. Increasing the temperature reduces the stability fields of the ammines and generally constrains the thermodynamic window for the leach. The Fe(II) ammines are only thermodynamically stable under reducing conditions. Polarization experiments show that these ammines are unlikely to form if oxygen is present. Fe-Ni-Co alloy passivation may be alleviated by careful management of potential.

Nov 1, 2011

By Y. C. Guan

The cementation of gold on to copper and zinc in ammoniacal solutions has been studied using rotating disc electrodes. The cathodic reduction of aurous ammine was studied on a gold rotating disc electrode and the anodic dissolution of copper and zinc was studied in the absence of aurous ammine. The cementation rate was found to be a first order with respect to the concentration of aurous ammine and to be proportional to the square root of the disc rotating speed. Based on the results obtained, it was concluded that the cementation reaction was controlled by mass transfer of aurous ammine to the reaction surface under the experimental conditions.

Jan 1, 1995

By Saurabh Rastogi, Vikram Shishodia, B. Pitchumani

Comminution is a unit operation which consumes major part of energy in mineral processing industries such as fertilizer production. Ball mills are widely used for size reduction of a given ore to the liberation size that is required in further beneficiation processes. In grinding of materials much effort is concentrated on control of top size of the product and this results in production of fines, also creates secondary problems of pollution due to the difficulty in the collection of fine particles. The present work has been carried out to control product size distribution for rock phosphate grinding in an Industrial Ball Mill of 600 TPD. The plant data are taken for a given feed distribution and mill operating conditions. The information at various Ball Size distributions are collected. The comminution functions such as specific rate of breakage and breakage distribution functions are estimated by back calculation technique to solve the mass balance equation. A simulation program is written to study the product size distribution obtained for various ball size distribution.

Jan 1, 1993

The dissolution behavior of gold and silver from Au/Ag alloys in aerated cyanide solutions has been investigated using rotating disc electrodes. The variables studied included concentration of cyanide, oxygen partial pressure and rotating speed of the disc. The dissolution potential and the rate of dissolution were obtained in view of the anodic and cathodic current-potential relationships. The results were discussed in terms of a mixed potential theory. The results showed that the dissolution rate of gold and silver from the alloys was partially controlled by chemical reaction, but largely by transport of either oxygen or cyanide, depending on their relative concentration under the experimental conditions employed in this study.

Jan 1, 1995

By M. C. Baumann

The Getchell Mine is located in Humboldt County, Nevada, approximately 70 km northeast of Winnemucca. Slope management has been a critical factor in the feasibility of mining operations since they began in the early 1930's. Although underground entries began in 1937, underground production was limited because hanging walls consisting of clay gouge and crushed rock tended to collapse into the workings. Controlling these collapses required extensive timbering. Due to these poor ground conditions, surface open-pit mining was the primary mode of production from 1938 to 1967 with only minor contributions from underground operations. Mining was suspended in 1967 due to economic pressures. From 1960 to 1967, the previous operator mined the property in three open pits. Initially, these pits were constructed with footwall benches, but these failed. These failures were aggravated by construction of 60° slopes in footwalls with shale partings dipping into the pit at 43° to 60°, resulting in large planar failures and wedge failures. In response, the previous operator adopted a slope parallel to the bedding planes.

Jan 1, 1993

By Peter Zhang, Daniel Su, Bo Kim, Berk Tulu

This paper summarizes significant findings from the ongoing NIOSH Gas Well Stability research over the past decade; in particular, the important ground control engineering considerations. Longwall-induced surface and subsurface deformations may induce gas well casing deformations and stresses, depending on a few parameters such as overburden depth, overburden geology, topographic relief, strata dip, gas well setback distance, and a gas well casing cementing alternative. Overburden depth to the mining seam is one of the most influential factors; shallow overburden depth induces large horizontal displacement and resulting casing deformation and stress, while deep overburden depth induces large longwall-induced vertical pressure. Overburden geology is another important factor affecting the longwall- induced casing deformations and stresses; the large contrast of bending stiffness at the soft-to-hard rock interfaces tends to induce large casing deformations and stresses. Large surface topographic relief and the presence of soft-to-hard rock interfaces below the stream valley bottoms may shift longwall-induced subsurface gas well casing deformations closer to the surface, thus having less impact on underground. mining operations. Strata dip magnifies longwall-induced deformations by 20% per degree of strata dip for down dip longwall excavations. The gas well setback distance is also a critical geometric parameter; the effect of longwall-induced deformation decreases exponentially as the setback distance increases. Longwall-induced casing deformation and stress will be mitigated or totally uncoupled for uncemented production casing.

Jun 25, 2024

By D. W. Hendrickson

Cliffs views the process as extending from mine planning to cargo loading including auxiliary systems such as material handling and plant utilities. Process automation is recognized as an area that can provide significant improvement opportunities with less capital requirement than major flowsheet modifications. This paper discusses the development and results of a strategy to allow and promote implementation of process automation improvements at individual mines based on their economic priorities taking advantage of common systems and concepts for use at multiple mines where practical. Specific process control upgrade projects a Hibbing Taconite Company and the Empire Mine are reviewed in detail.

Jan 1, 1998

By Lech Bolinski, Joe Shirley

Over two dozen Resin-in-Pulp (RIP) plants have been in operation in the fonner Soviet Union since the beginning of 1970. Currently approximately 50% of the gold produced in Russia, Uzbekistan and Kazakhstan, which equates roughly to 10% of the total world output, is recovered using the RIP technology. An alternative to activated carbon, ion-exchange resin has several advantages for the recovery of gold. Resins are less prone to clay or organic foul­ing and do not require thennal regeneration. They also have poten­tially higher loading capacities, faster adsorption kinetics, and are more resistant to abrasion. The original Russian RIP process was based on engineering expertise developed for uranium ore pro­cessing and has a few major drawbacks. The biggest problem is an 18-30 day resin stripping process, which results in a huge gold lock-up. The problem was recently overcome by the development of a new stripping technology which cuts the time to 12-24 hours. Currently, there is rather limited practical knowledge of the Russian RIP process in the West, but often Western mining com­panies developing gold mines in the fonner Soviet Union are hard pressed by their local joint venture partners to take a serious look into RIP. It is probably only a matter of time before one of these companies will cross Soviet technology with Western engineering and develop a modem RIP process as an attractive option to the current CIP and CIL technologies.

Jan 1, 1996

By Earl Cook

A high-energy economy based on fossil fuels is in fundamental conflict with an ideal of clean air, clean water, undisturbed scenery, and maintenance of fragile ecosystems. There is an inevitable trade-off between the material standard of living of a modern society and the conservation of its environment. During the past four years, some of the costs of environmental protection have been internalized in the energy-flow system of the United States. The cost of bituminous coal and fuel oil usable under new air-quality standards has doubled or more. The cost of mining coal underground has risen because of a 20-30 percent reduction in productivity resulting from new environmental health and safety legislation; the economic impact of proposed surface-mine regulation may be equally severe. The cost of producing electric power has been rising at a 12 percent annual rate because of environmental costs, and would be climbing still more steeply were it not for the continued forced subsidy of natural-gas consumers by natural-gas producers. The efficiency of the automobile, already a monument to the triumph of self- indulgence over economy, is being further decreased by addition of anti-pollution devices. Part of the recent sharp rise in agricultural costs stems from the fact that five energy units of fossil fuel go into U.S. agriculture for every energy unit of raw food that leaves the farm; further large injections of fossil-fuel energy occur in the transport, processing, and refrigeration of farm products.

Jan 1, 1974

By Peter Zhang

The immediate roof at the test site consisted of laminated clay shale that is likely to be susceptible to weathering. With seasonal dry-wet cycles in the mine ventilation air, the roof in the intake air would deteriorate and lose integrity over time. In many instances, the weathering-prone roof would gradually scale off piece by piece between bolts and over the entry corners. In some long-term entries, roof weathering could develop up to 2-3 ft deep with columns of bolted roof hanging under the upper intact roof. If wire mesh is used, the roof bags down and reduces the entry height, and the weight of the bagged roof tends to pull the bolts out and poses a safety hazard. An effective measure is always sought to support this type of weak roof that is sensitive to moisture degradation. One solution is to seal the roof shortly after entry development to prevent moisture penetration so that roof integrity can be maintained for the long term. In this application, a polymer-based sealing material was tested in the Rockspring mine for weathering protection and reinforcement. The material is a one-component polymer powder for spray application onto the roof and rib. The sealant material is mixed with water in the spraying nozzle to apply to the roof and rib as a paste. The product sets within 5-10 minutes and forms a membrane as thin as about 1/8-in. The membrane will quickly develop tensile and bonding strength within minutes and completely cure within a few days. Through sealing, bonding and lateral reinforcement, the integrity of the weak roof can be maintained. The material has been tried in a long-term evaluation over several months in a set of main entries in the Rockspring mine owned and operated by Rockspring Development, Inc., affiliate of Foundation Coal. Preliminary evaluation has shown that the material is an effective and economical solution to ensuring the long-term stability of weathering-prone roof.

Jan 1, 2009

By H. S. Duzgun, N. Demirel

Estimating productivity of a walking dragline is of paramount concern to mining engineers and mine planners. Risk based evaluation of the dragline productivity is a valuable tool to estimate the dragline’s long-term availability, to develop preventive maintenance plans and to make future projections about the dragline’s performance. This paper aims to provide mining professionals with an overview of risk assessment methodology for productivity of two walking draglines, Page 736 and Marion 7820, which have been operating in the Tunçbilek openpit coal mine of Turkish Coal Enterprises (TKI) in Turkey. The study encompasses three main stages: (i) acquiring of monthly maintenance records, operating hours, mechanical and electrical failure hours between 1998 and 2009; (ii) reliability modeling using mean time between failure data and (iii) determining hazard rate and consequences to compute risk associated with dragline productivity. The results showed that that Page 736 (15.29 m3) seemed to be more reliable and less likely to fail when compared with Marion 7820 (30.58 m3). The operating hours without failure range from 41 to 51 hours with 50% reliability.

Jan 1, 2011

Maximizing margins in competitive markets demands superior productivity. Unfortunately, management systems developed early this century for other industries often drive counterproductive behaviors choking mining productivity. Many executives and managers waste valuable time and effort relying on simply training and communicating to improve managerial practices and attitudes. In covering practical human behaviour, the paper explains why this fails -and explains how to use systems to successfully drive improved managerial practices and attitudes. It highlights use of modern performance Measurement, Analysis and Reporting systems to drive behaviors and improve margins -without capital investment -and make executive and managerial work easier and more effective.

Jan 1, 1999

New Mexico?s active coal mines have reclamation challenges that are being successfully resolved through the application of geomorphic grading methods. Soils and overburden material are often of poor quality, and annual precipitation is low. Revegetation on south and west aspect slopes often failed to persist. The New Mexico Mining and Minerals Division had therefore been encouraging topographic diversity on reclamation to improve water harvesting and reduce the percentage of south aspect slopes. Steeply dipping, multiple coal seams may be mined by open pit methods. Structurally-controlled trellis drainage patterns that exist premine have to be replaced with dendritic drainage patterns on reclamation where the overburden had been pulverized. Sodic spoil material is prone to differential settling and the creation of piping features in areas where runoff ponds, which may lead to downslope instability. In each of these scenarios, the approximation of natural drainage patterns on the reclamation has reduced erosion and sedimentation by creating shorter slopes with correct profiles, and by improving conditions for revegetation establishment.

Jan 1, 2010

By P. R. Thomas

This paper addresses the relative long-term cost and resource position of new and existing ferrochromium production in selected Market Economy Countries (MEC'S). The market impact of new ferrochromium production in nations such as India and the Philippines and the continuing change in international trading patterns are also evaluated. This paper draws upon the data and analyses of a recent Bureau of Mines, Department of Interior, Minerals Availability Program appraisal that evaluated the cost and availability of chromite and ferrochromium production from the demonstrated resources of 80 producing or potential mining operations in 10 market economy countries.

Jan 1, 1984

By Roger N. Kust

Because ammonia can form complex ions with certain of the transition metals, such as copper and nickel, it has long been of interest to extractive metallurgists interested in leaching or separating these metals. Although it is a relatively expensive reagent, ammonia is amenable to recycle because of its volatility. In development of processes utilizing ammoniacal leaching or separation schemes, information regarding solution vapor pressures, pH and solubility limitations is needed. There is voluminous literature on ammonia-water systems generated by the urea industry. However, frequently the systems of interest to metallurgists differ significantly in concentrations of ammonia used, the temperatures of interest. Furthermore, the differences arising from the presence of metal values in solution must be comprehended. There is surprisingly little information readily available regarding systems of practical interest to metallurgy. As a result, those interested in ammonia-based processes end up either doing expensive laboratory research to obtain necessary data or overdesigning the process. Another approach to obtaining desired information about ammoniacal systems is to attempt to calculate from first principles the various solution properties. This paper is being presented to illustrate what can be accomplished by estimating the state of equilibrium in an ammoniacal carbonate system from available thermodynamic information making simplifying assumptions when needed.

Jan 1, 1976

By F. Milton Lewis

In 1977 a paper was presented which reviewed the cost trends in producing copper by conventional processes for five years, 1972 through 1976. In this paper these costs have been updated to include the years 1977 and 1978.

Jan 1, 1979

By S. Bhattacharyya

"Coal bearing rocks are low in strength and have geological discontinuities and moisture sensitivity. Roof and rib falls have been a major cause of fatalities in underground coal mines. Mine engineers design ground control plans for regulatory approvals. A number of tools are available from the National Institute for Occupational Safety and Health to design and assess these plans. Quite often there is not enough geotechnical input information available and databases are used. The Appalachian coalfields have extensive scientific studies to provide reliable regional inputs. Coal mines in the western United States and Canada have different geological and geotechnical conditions, and less available data. Use of inappropriate inputs in the tools like Analysis of Retreat Mining Pillar Stability, Analysis of Longwall Pillar Stability, and Analysis of Roof Bolt Systems may result in unsafe designs or over conservative designs. The tools are convenient but thorough understanding of the inputs, calibration with local test results, and operating experience are important for effective designs. The current paper contains examples of difficulties faced during mine planning using the above tools. INTRODUCTION Sedimentary rocks hosting coal are low in strength. Scientific studies have placed the uniaxial compressive strength (UCS), triaxial strength, tensile strength, and shear strength of sandstone, shale, siltstone, and claystone in lower range of strength among engineering materials (1). Coal bearing rocks are most often weakened by the presence of faults, folds, slickensides, bedding planes, fractures, and other geological discontinuities. The host rocks and coal are often moisture sensitive. The geological discontinuities allow water to enter the strata from surface and underground sources. This combination of low strength, structural weakness, and presence of water results in difficult ground control situations for the coal mines. Roof (2) and rib falls have been a major cause of fatalities in the U.S. coal mines. Modern underground coal mines necessitate wide entries to accommodate large production equipment. The gate roads, section entries, and the mains entries of a highly productive coal mine are as wide as twenty feet (6.1 m). The actual intersection width is nearly thirty feet (9.1 m). Adequate ground control is a key to maintain safe production in such mines. Mine engineers and their consultants routinely submit ground control plans to the regulatory authorities. While working out the necessary roof control system the mine engineers are required to demonstrate the adequacy of the proposed system. There are multiple ways to demonstrate this. Some engineers use traditional load calculation approach of roof bolts (3). Some engineers use numerical methods. Yet a large number of professionals resort to a suite of ground control design software offered by National Institute for Occupational Safety and Health (NIOSH) commonly referred to as “NIOSH Ground Control Toolbar.” These software tools are free and easy to download from NIOSH website. The software included in this package are: Analysis of Longwall Pillar Stability (ALPS), Analysis of Retreat Mining Pillar Stability (ARMPS), Coal Mine Roof Rating (CMRR), Analysis of Roof Bolt Systems (ARBS), Analysis of Horizontal Stress Effects in Mining (AHSM), Analysis of Multiple Seam Stability (AMSS), Analysis of Retreat Mining Pillar Stability - Highwall Mining (ARMPS-HWM). These tools are relatively simple to install and use in planning and designing coal mines and prospective coal mines. They accept a number of geotechnical inputs which are collected from either an existing mining operation or from exploratory boreholes. In the absence of necessary input parameters, the programs use default values which are drawn from databases of geotechnical properties built by NIOSH."

Jan 1, 2015

By Ronald A. Crowson

Detailed stratigraphic studies of the overburden at North Carolina Phosphate Corporation new South Creek Mine have delineated several aquifers and acquicludes within the 30-meter-thick overburden section of late Pleistocene sands and clayey sands. A major aquifer occurs in the 10-meter-thick sequence of shelly sands of the early Pleistocene Croatan Formation. The water-charged Croatan sands thicken into a paleodrainage surface on top of the Pliocene Yorktown Formation, a major aquiclude. A three-phase dewatering program is projected: 1) improve surface drainage around mine perimeter to reduce both flowage into the pit and rainfall recharge; 2) use a wellpoint system to dewater the upper 8 meters; and 3) use recharge wells along the axis of the paleo- drainage to dewater the overburden below 8 meters.

Jan 1, 1983

By Thomas H. Ferrigno

Modern Plastics (July, 1983) reported that about 2.2 million tons of mineral fillers were expected to be consumed by the plastics industry that year, of which 7096 was limestone derived. The combination of fillers and polymers is called a composite and, in the more general sense includes continuous and discontinuous components in a matrix. The only significant technical advance in the fillers industry has been the greater general availability of surfied (Ferrigno 1959), an acronym for surface modified, fillers. The many reasons for this occurrence will be given in detail later, but the primary reason lie with differences between inorganic filler surfaces and the polymers which bind them together to form the composite. Minerals and glasses (fiberglass, fly-ash and beads) have surface tensions in excess of 200 dynes/cm, whereas organic materials have surface tensions less than 75 dynes cm. Water has a surface tension of 72 dynes/cm and is always present as an absorbed layer on high surface tension materials to reduce the surface tension. Although almost any organic liquid or polymer has a surface tension low enough to displace the water layer, the highly polar nature of filler surfaces requires highly polar agents to produce a permanent effect, and frequently the water is so tightly bonded or so much more active that the displacement is temporary. Furthermore; the water layer causes tiny particles to adhere to each other (agglomerate) to make sepaartion or dispersion of the individual particles very difficult. The solution to these problems is then to form a chemically bonded layer on the filler surface similar to that of the polymer so that immediate wetting, dispersion and uniform distribution of the filler particles is obtained.

Jan 1, 1985