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By W. C. Hirt

Selective flocculation was used to produce superclean zinc concentrate with minimized silica contamination. Research was carried out on a flotation concentrate from the Jersey Miniere Zinc Company (JMZ) in Gordonsville, Tennessee. The material was first dispersed with sodium silicate and then causticized tapioca starch was used to selectively flocculate the sphalerite, leaving the silica in suspension. This technique has been applied commercially to iron ore beneficiation but has never been used for processing zinc. The feed material assayed 0.45% Si02. Use of 0.56 kg/tonne (1.13 lb/st) of sodium silicate and 0.070 kg/tonne (0.141 lb/st) of causticized tapioca starch resulted in 98.2% zinc recovery in a purified zinc concentrate assaying 66.0% Zn and 0.24% silica. The present target level for silica contamination in JMZ zinc concentrates is 0.3% Si02. This work has shown that selective flocculation offers a potential method for cleaning flotation concentrates, particularly where low silica products are required.

Jan 1, 1993

By John M. Kemeny

This paper describes a practical technique to estimate the size distribution of large volumes of rock fragments, including blasted benches, waste dumps and heap leach sites. Images are obtained from a site using a standard video camera and downloaded onto the computer. Image processing algorithms are used to delineate the individual rock fragments in the images, followed by the calculation of the area and shape of each fragment. Statistical calculations are then performed to estimate the complete size distribution of the fragments. The accuracy of the technique has been assessed with a number of field validation studies.

Jan 1, 1995

By A. Bergmann

Location The Meggen Mine and the concentrator plant of the "Sachtleben Bergbau G.m.b.H." are located in the southern part of the Ruhr-district of the Federal Republic of Germany. The mine has been in operation for more than 100 years, but the concentrator described in this paper was built in 1962 and started up in January 1963. Goelogy and Mining The Meggen ore-body is of sedimentary origin and occurs in a zone of limestones, graywacke and shales of Devonion age. The average thickness of the deposit is 3 meters and, due to an intense folding of the area, the mineralized zone dips very steeply at 800 toward the north. The ore consists of 85 percent of sulfides and 15 percent gangue that mainly contains silicates from the host rocks. The principal ore minerals are pyrite (67 percent), sphalerite (16 percent) and galena (2 percent) with minor amounts of marcasite and only traces of chalcopyrite. As shown in Fig. 1, the sphalerite and galena are very finely disseminated in the massive pyrite of the Meggen ore, and a very fine grinding combined with a special flotation technique are required to liberate the valuable sulfides and to produce separate concentrates of lead, zinc and pyrite. Mining is performed by the sub-level stoping method and employs trackless equipment. Present operations provide ore from the 600 meter level. Annual ore production is 870,000 metric tons.

Jan 1, 1972

By S. Chander

The results of an investigation to characterize the chalcopyrite/solution interface are presented. Several techniques including galvanostatic and steady state polarization, cyclic voltammetry and impedance spectroscopy were used. The results show that the dissolution of chalcopyrite is incongruent. Initially, at low potentials(<O.34V), iron species are released which give rise to the growth of an iron-deficient sulfide (IDS) layer. The dissolved iron might reprecipitate as a hydroxide layer depending on solution composition. Continued oxidation involves diffusion of species through the product layer. At higher potentials (>O.48V) further oxidation leads to dissolution of copper and sulfur species with a resultant breakdown of the IDS layer. The changes in properties of surface coatings resulting from various electrochemical treatments are discussed.

Jan 1, 1991

By Taghi Sherizadeh, Paul Brooks, Dogukan Guner, Samuel Nowak

Large excavations are well known to result in rock mass deformations which can present challenging situations for mine personnel. Most of the currently available ground movement monitoring devices fail to adequately provide mine operators with highly accurate and meaningful insights into rock mass deformation or displacement. The use of distributed fiber optic sensors (DFOS) in industries such as oil and gas and civil engineering has shown the potential of these sensors to deliver real-time, highly accurate, and long-range distributed strain measurements with great success. However, the use of these sensors in underground mining is limited to a few case studies.

By D. K. Dysinger

The U.S. Bureau of Mines investigated leaching of chalcopyrite with sulfuric acid-oxygen under conditions anticipated during in situ leaching. A central composite experimental design was chosen to study oxygen pressures of 150, 300, and 450 psi, leach temperatures of 35?, 65°, and 95° C, oxygen-to-chalcopyrite mass ratios of 0.5, 1.0, and 1.5, leach times of 8, 16, and 24 hours, initial acid strengths of 0.6, 1.2, and 1.8 g H2SO4/g chalcopyrite and pyrite to chalcopyrite mass ratios of 0, 1, and 2. The leaching kinetics were consistent with the shrinking core model. A quadratic response surface model was used to determine linear and interaction effects of the design factors on rate constants from Arrhenius correlations.

Jan 1, 1993

By PEILIN LAN, LEONARD HILL, SIMON TIMBILLAH, BERNARD FOSU, CESAR SOSA-BLANCO

The use of sodium hydrosulfide (NaHS) in most of the operations in byproduct molybdenum flotation comes with safety concerns and, in some instances, a high reagent cost. Engineered solutions at the various operations where NaHS is used have immensely reduced the possibility of hydrogen sulfide (H2S) gas evolution. However, the threat of exposure remains, and this, coupled with the high dosages of NaHS consumed, supports the continued search for alternative depressants. This paper focuses on efforts to study the applicability of disodium carboxymethyl trithiocarbonate (DCMT), an organic depressant, as an alternative to NaHS. Bench-scale rougher flotation results for samples from the Sierrita copper–molybdenum (Cu–Mo) plant showed the best DCMT performance at 8 kg/t of DCMT, pH 10.5, 30 min of shear conditioning and 10 min of flotation conditioning. The Aminpro plant model simulation confirmed that 4 to 8 kg/t DCMT under certain shearing and conditioning times achieved superior or equivalent Mo–Cu separation efficiencies when compared\ to NaHS.

By R. P. Fischer

Traditionally, molybdenum and vanadium have been used chiefly as alloy metals in steel. They impart similar characteristics to most steels, and to some extent one can be substituted for the other. In the United States during the 1950&apos;s the production of steel increased about 5 percent, and the reported consumption of both of these alloy metals in steel increased some 40 percent. In Europe during the 1950&apos;s the production of steel in¬creased nearly 100 percent. Data on the actual consumption of these alloy metals in European steels are not available, but production and trade records show that the European supplies of molybdenum increased about 150 percent and those of vanadium about 350 percent during the 1950&apos;s. If most of the molybdenum supplies in Europe are being added to steel, as seems likely, then the European steel industry has nearly caught up with the United State in the rate of consumption of molybdenum in steel. The vanadium supplies, on the other hand, are puzzling--unless Europe is adding mach more vanadium to steel than is done in the United States, it seems reasonable to assume that other uses are consuming moderately large quantities of this metal or that appreciable amounts of it are being transshipped from Europe. To the extent that a changing volume of supply signifies a changing pattern of use, the increased demand for molybdenum and vanadium in Europe should be of interest to domestic producers and consumers of these metals.

Jan 1, 1964

By R. M. Yeates

Public concern over possible degradation of groundwater resources has resulted in an array of Federal laws and corresponding state laws to regulate contaminates from solid and hazardous waste. A mine owner must be familiar with environmental regulations which could impact his operation and must know what precautions and corrective actions to take in order to protect his mining operation from potentially expensive remedial actions. The Environmental Protection Agency (EPA), has issued few regulations controlling the management of mining wastes. Federal regulation of mining came primarily under the Surface Mining Control and Reclamation Act (SMCRA) administered by the Office of Surface Mining (OSM). Waste generated from the extraction, benefication and processing of ores and minerals was exempt from regulation under the Resource Conservation and Recovery Act (RCRA), which is EPA&apos;s major instrument in controlling surface contaminates. On December 31, 1985, EPA submitted to Congress a report entitled "Wastes from the Extraction and Benefication of Metallic Ores, Phosphate Rock, Asbestos, Overburden from Uranium Mining and Oil Shale", which will be referred to, henceforth, as the Congressional Report. This Congressional Report assessed the possible adverse effects of mine associated wastes. This report is the first step toward developing regulations with which EPA can regulate waste from the extraction, benefication and process of mineral ores.

Jan 1, 1987

By T. McCallum, C. Cooper, C. Lewis

"Following a successful solvent extraction (SX) pilot plant demonstration in 2016, CYANEX® 600 has been used commercially to recover molybdenum from concentrate leach liquor since March 2017. Consistent with the piloting results, the commercial plant has achieved expected molybdenum recovery, a significant reduction in base consumption, and a step-change improvement in physical performance. This paper highlights the optimization activities and plant performance from startup through normal operation. INTRODUCTION Historically, tertiary amines have been the most commonly used extractant for molybdenum and rhenium recovery. Tertiary amines utilize a protonation of the ligand combined with an anion exchange mechanism as proposed in equations (1-2). R3N + H+ ???R3NH + (1) 4R3NH+ + Mo8O264- ???(R3NH+)4Mo8O264- (2) In addition to the transfer of Mo and Re, the amine transfers acid and other anions to the strip liquor. The undesirable transfer of other species increases base consumption during stripping, impacting operating costs. Additionally, lower solubility of molybdenum-amine complexes create operational challenges, resulting in diminished physical performance. The presence of colloidal Si in concentrate leach liquors and the formation of Pickering Emulsions adds to the physical plant performance challenges with the amine extractant. CYANEX® 600, a phosphinic acid-based extractant, uses a cation exchange mechanism proposed by equation (3). 2(H2R2) + MoO22+ ??(HR2)2MoO2 + 2H+ (3) The cationic exchange mechanism eliminates chemical transfer of acid and other anionic impurities and avoids some of the physical challenges of the amine extractant (emulsion and 3rd phase formation). In addition, the reagent offers high selectivity for Mo over Re, which may be desirable in certain moly pressure oxidation (POX) flowsheets. Alkali base (ammonium hydroxide, sodium hydroxide, sodium carbonate, etc.) is used for molybdenum stripping. Therefore, reduction or elimination of chemical acid transfer from extract can significantly reduce base consumption in strip. Extensive laboratory and pilot plant testing was completed to evaluate the use of CYANEX® 600 for molybdenum recovery at Freeport-McMoRan’s Bagdad operation. The test work and pilot demonstration confirmed a reduction in base consumption along with improved selectivity. In addition, the evaluation highlighted a step-change improvement in physical performance over the incumbent amine extractant. The decision was made to convert the commercial operation to CYANEX® 600 in March 2017."

Jan 1, 2018

By J. S. Chung

As part of ongoing deep-ocean mining research, hydraulic transport systems as well as status of deep-ocean mining systems are reviewed in the aspects of manganese nodules and crusts from 800-6,000-m depth. The emphasis of the investigation of hydraulic transport is placed on the shape effect of particles on the pressure gradients and flowrates. Series of tests are being conducted to study the lift characteristics of a 2-phase vertically upward hydraulic transport of 2 types of small solid particles in a PVC pipe of 1-in (2.54 cm) diameter: irregular-shaped silica sands and equivalent spherical glass beads. Pressure drops and mass as well as volumetric flow rates were measured by electromagnetic (EM) flowmeter and mass flowmeter. The particle sizes used are 8-10 mesh. The results in turbulent flow range of 104 < Re < 105 show that pressure gradients or friction factors are smaller for the spherical beads than the sands. The larger the concentration of the particles are, the larger the pressure gradients become. The larger the particle concentration is, the less the effect of particle shape on pressure gradients becomes. The shape effect is greater for the minimum particle transport velocities than for the settling velocities.

Jan 1, 1999

By J. F. T. Agapito

Two flat-lying trona seams 3-to 3.5-m thick, approximately 10 m apart, and at depths of 250 m are mined by room-and-pillar at OCI&apos;s Big Island Mine in Wyoming. Continuous miners and a yielding pillar system have contributed to improvements in resource recovery and productivity. Long-term stability with minimal subsidence is needed for a large portion of the mine beneath the Green River channel. This was investigated by computer modeling in 1990. Although results of the study indicated good long-term stability, recommendations were made for stress determinations to verify the model. Stress determinations made in 1997 showed pillar stresses 10% to 20% higher than the model stresses, and barrier pillar stresses 10% to 15% lower. This implies that higher panel stresses will be transmitted from the upper to the lower seam. A stability evaluation of the lower seam is planned before two-seam mining to assess entry widths and support requirements.

Jan 1, 1999

By M. C. Rockwell, G. F. T. Lay

Promising placer gold exploration sites offshore Lunenburg County are drowned pre- and post-glacial river channels and auriferous glacial tills. Gold values up to 5.67 9/m3 have been encountered in the vicinity of the Ovens Peninsula offshore Lunenburg County. Moderate gold values associated with notable amounts of heavy minerals were reported from various other exploration sites in this area. This paper highlights the major geological and gemorphological features for placer gold depositions in southern Nova Scotia. The past to present gold exploration activities nearshore and offshore Lunenburg County are summarized and potential areas for placer gold identified.

Jan 1, 1988

Room-and-pillar mining at White Pine started in 1953 from a sub-outcropping orebody that gently dips to 1000 m depths in a distance of about 6 km. High horizontal stresses were recognized in the mid-1960s which had obvious stability impacts when viewed in combination with the increased overburden stresses. Modifications in conventional room-and-pillar design were introduced through the years on a trial-and-error basis to help overcome stability and resource recovery problems. These modifications were based on pressure arch concepts using pillar yielding and/or pillar recovery, and on mine layout orientation to minimize stress impacts. While some of these modifications were successfully applied in some areas, they failed in others. Through the years, visual observations played a major role in panel design with contributions from stress measurements and analyses. However, the down slide in the copper economy during the 1970s and early 1980s resulted in a loss of interest in the application of these concepts. This paper reviews ground control problems and presents the results of recent stress measurements and computer analyses. They shed light on the importance of using yield pillars and mine layout orientation to control stresses at depth.

Jan 1, 1993

By T. Gonzales

Magma Metals Company operates an Outokumpu Flash Furnace, four Peirce-Smith Converters and two Anode Casting Wheels supported by six Anode Vessels. Process gasses from the Flash Furnace and Converters are treated in a two train/double contact sulfuric acid plant. Sulfur capture for the smelter is +98%. The new flash furnace was commissioned on July 7, 1988 and has processed over three million tons of sulfide concentrate without a major rebuild. Magma has gained unique experience in the operation of the flash furnace at high oxygen enrichments with low off-gas dust loadings. New procedures have been developed to maintain secondary material generation at equilibrium and for maintaining metallurgical control of operating parameters. This paper describes all the procedures, operation control parameters and operating philosophy that has allowed Magma to achieve superior performance.

Jan 1, 1992

By Mike L. Aziz, Keith D. Ferguson, Glenda Ferris

The Equity Silver mine has been a severe producer of Acid Rock Drainage (ARD) since 1982. The mine was closed in 1994 and a compacted clay cover installed, but ARD continues to be produced. Three permanent employees manage the collection and treatment system at the site. The site still poses a significant environmental risk to the environment and downstream users and requires a high level of diligence. Various stakeholders&apos; perspectives of the risk posed by Equity, and what constitutes acceptable risk, will be examined in this paper from a company operation staff, corporate environmental manager and downstream environmentalist perspective.

Jan 1, 2000

By D. J. Benton, S. Finley, D. T. Orr, A. J. Chambers, M. A. Stepan

"Corrosion of ground support can lead to falls of ground that pose a significant risk to miner safety. To address this problem, the National Institute for Occupational Safety and Health (NIOSH) is investigating corrosion at the Hecla Mining Company’s Greens Creek Mine, located near Juneau, Alaska, USA. Field studies have used photogrammetry surveys to document welded-wire mesh corrosion, and laboratory studies at NIOSH’s Spokane Mining Research Division (SMRD) have investigated the effects of corrosion on ground support integrity. Findings show that (1) corrosion monitoring through photogrammetric methods may be effective for qualitative measurements of welded-wire mesh corrosion, and (2) there is a relationship between loss of load-bearing capacity and the diameter loss due to corrosion in welded-wire mesh. Photogrammetry results thus far have measured an apparent bulking of the corroded welded-wire mesh, and preliminary laboratory tests have investigated the relationship between the larger bulked and effective wire diameter. If this relationship is verified, these results may indicate that photogrammetry, when combined with the models produced in laboratory tests, could offer a means of monitoring corrosion levels, as well as rock rib deformation. INTRODUCTION Reducing the number of rock fall injuries and fatalities is an important part of the mission of the National Institute for Occupational Safety and Health (NIOSH) Spokane Mining Research Division (SMRD). Ground control using support systems to protect miners from rock falls is one of the oldest mining sciences, and considerable research has led to a variety of modern tools and methods in use today. Among these tools are rock bolts and welded-wire mesh, which are made from increasingly higher-strength steel grades to meet the increasingly demanding requirements of underground mines [1]. However, the benefits of these higher-quality support elements may be negated in corrosive mining environments. A better understanding of how corrosion affects the support capacity of ground support systems will assist engineers in determining when an opening is at a greater risk of falls of ground. Accelerated corrosion has been occurring in some areas of the Hecla Mining Company’s Greens Creek Mine near Juneau, Alaska, USA. Corrosion of ground support has resulted in two falls of ground occurring between April 2015 and March 2016. While these falls of ground did not injure any personnel, mine management recognized the high risk to miner safety and responded by actively undertaking a ground support rehabilitation program. Rehabilitation measures include the installation of both galvanized and coated, corrosion-resistant bolts and welded-wire mesh, depending on local conditions."

Jan 1, 2017

By M. Boucraut

The authors investigate the influence of the basicity index CaO / Si02 on the sintering properties of hematite ore mixtures. The experimentation was performed with three different mixtures of ores from Tazadit, Nimba, Mano-River, Itabira, Marcona, Goa, Mapawa and Cassinga. Increasing the basicity index CaO / Si02 between 0.1 and 3, chiefly through limestone admixture makes possible to reduce the thermal consumption of sintering and to improve the physical and chemical properties of the sinter. In the case of a plant using hematite ores, it seems interesting to produce an hyperbasic sinter and to complete the blast furnace burden with calibrated ore or acid pellets.

Jan 1, 1968

By D. R. Taylor

The use of clay granules as carriers for pesticides dates from the early 1940&apos;s and by the present day represents a business conservatively estimated at between 200 -300 thousand tons / year in the U.S. alone. Aside from economic and specific target pest efficacy advantages, the use of clay granules as pesticide carriers also delivers a number of environmental benefits which will be reviewed. Topics to be discussed will include: I) drift control (versus liquid sprays), 2) mobility (in the environment), 3) worker safety, and 4) transportation (spill) safety.

Jan 1, 1999

By M. S. Celik

Beneficiation of boron minerals by flotation with well defined systems has been very little investigated in the literature. The difficulty arises from the fact that boron minerals cover a spectrum of solubilities. Colemanite, a calcium containing relatively insoluble boron mineral, and borax, a highly soluble boron mineral have been used to exemplify the flotation of boron minerals. The floatability of both minerals using sodium dodecylsulfonate and dodecylamine hydrochloride exhibits considerable differences in their response to flotation. This has been ascribed to variations in the solubilities 0f boron minerals and the presence of the cations in the lattice structure. Flotation tests along with zeta potential measurements are used to elucidate the mechanisms involved in the flotation of boron minerals.

Jan 1, 1992