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By D. J. Bosman

Rapid fouling of condenser tubes in underground refrigeration plants is a frequent occurrence. It leads to low heat transfer efficiencies, with consequent serious reduction in capacity and increase in the horse-power requirement of the units. High pressures develop in the condensers, and frequent cleaning of the tube bundles is required. The cleaning operation takes up to 8 hours and in some cases results in significant loss of production. One of the possible causes of fouling is deposition of scale, but this can be readily overcome by controlling the concentration of the water. When water evaporates, the dissolved solids remain behind; thus evaporation increases the amount of dissolved solids per unit volume. If half the original volume evaporates, the concentration of the dissolved solids is doubled and the water is said to have a 'concentration' of two. Concentration may be controlled by regulating the amount of water allowed to bleed from the system. The actual concentration value required is a function of the chemical analysis of the circulating cooling water. In one instance, where the problem of scale formation had been eliminated, fouling still persisted, and the possibility of excessive quantities of dust in the re-circulating water was investigated. A dispersing reagent was added to the condenser cooling water as a means of preventing sludge deposition in the condenser tubes. As shown by curve A in Fig. 1 the reagent addition did not decrease the rate of fouling.

By H. H. McGregor

SYNOPSIS Changes in the national productivity (gross national product per head of the population) have been assessed in order to derive a target figure for the required annual increase. The conclusion reached IS compared with the targets of the economic development programme of the Republic. Productivity and management structure in the gold mining industry is then analyzed together with investment in plant, machinery and equipment for rock handling purposes. The conclusion is drawn that productivity improvement does not appear to have accorded with the massive expenditures in plant and equipment, and in augmented management. The productivity of the manufacturing and construction sectors of the economy has been examined. The principal difficulty is that the main avenue of approach is the value of product divided by the total labour force. This introduces inflationary questions, and the use of a suitable deflator becomes of prime importance. Severa1 different methods of assessing the productivity improvement in the industrial sector have been used with what is regarded as a comparatively high degree of compatibility. Improvements in productivity in the manufacturing industry up to 1966 appear, from the information available, to have substantially exceeded comparable figures for the mining industry. There is however evidence that thereafter productivity of the manufacturing industry has not maintained this satisfactory rate of increase. If the economy is to achieve the planned rate of expansion, there is no doubt that greater attention to this aspect will be required in the future than has been accorded to it in the past.

By C. E. Dohm

The paper serves to show the importance of both a geological model and geostatistical model that support one another in mineral resource evaluation. It highlights the advantage of reference models for the geometry, the geological, statistical and geostatistical models of various orebody types and introduces a method for quantifying the combined uncertainty in these models. The example presented reveals how the above levels of information can be applied to add value to a resource evaluation process. It is a generic example in that it is the technique of combining uncertainty in the geological model (boundaries) as well as the grade model to assess the overall risk in the estimation of the resource. Data from the coal industry is used to illustrate the techniques. The geological uncertainty is considered via categorical simulations and these are combined with simulations of the variables (grades, thickness,) being estimated in the resource. The simulation techniques used are based on the application of GSLIB software1and a general discussion of the two simulation processes is included. In conclusion the paper demonstrates how the results of two types of conditional sequential simulation can be combined to produce confidence limits that take both uncertainties into consideration. This technique does not replace the resource estimation; it serves as an additional tool to quantify confidence in the resource evaluation model. The topics considered in this contribution are in terms of continuous improvement of mineral resource evaluation.

Jan 1, 2003

On Friday, 18th April, 1986, Stefen Kenneth de Kok passed away peacefully at his home in Johannesburg after a short illness. New President of FSPE Mr R.G. (Bob) St Leger took office as President of The Federation of Societies of Professional Engineers on 1st July, 1986.

Jan 1, 1986

By A. O. Filmer

An account is given of a study on the non-oxidative dissolution in aqueous acidic solutions of nickel sulphides of different stoichiometric composition, in which a rotating ring-disc electrode was used. The rate of dissolution was found to depend on the potential of the sulphide and the nickel-to-sulphur stoichiometric ratio. A maximum rate for the dissolution of nickel from nickel sulphides containing an excess of nickel was recorded at potentials around -0,2 to -O,3V. The rate decreased markedly at more anodic potentials. For nickel-deficient nickel sulphides, the nonoxidative dissolution rate increased with a cathodic shift in potential. Under open-circuit conditions, a nickel sulphide of a composition approximating Ni ,S. reacted most rapidly. The dissolution rate was controlled by either a chemical or an electrochemical reaction at the electrode surface, had an activation energy of between 50 and 65 kJ.mol-1, and was independent of stirring speed.

Jan 1, 1980

The Annual General Meeting of the South African Institute of Mining and Metallurgy was held in Kelvin House on Wednesday, 25th August, 1976. Dr R. E. Robinson, (President) was in the chair, and declared the meeting open at 16h00. Obituaries The president: It is my sad duty to announce the death of the following members of the Institute : P. A. Creewell, Life Fellow; A. S. Davis, J. S. Hay, P. O. Large, N. McCaskell, and H. G. M. McKerrow, Life Members; C. L. Bererge, Fellow; T. Bulloch, G. Douglas, R. W. Forrester, and C. G. P. Sack, Members; P. R. Garcia, W. A. Naude, and J. P. Slager, Associates. As a mark of respect to the memory of the deceased and in sympathy with the bereaved, I ask you to rise and observe a few moments' silence. Minutes The President: May we confirm the minutes of the General Meeting held on March 17th, 1976, as published in the June issue of the Journal? Agreed. Welcome The President: It is my pleasant duty to welcome a number of guests and distinguished visitors this evening. First, I would like to welcome Mr R. Plumbridge, the President of the Chamber of Mines, and Mrs Plumbridge. We have had very close co-operation with the Chamber of Mines, and it is particularly gratifying that Mr Plumbridge has had time to be with us this evening in spite of very heavy engagements. Ook 'n spesiale woord van verwelkomirg aar mrr. N. Orsmord, die Staatsmyringerieur, en mev. Orsmord. Ors wil hierdie geleertheid gebruik om mrr. Orsmord geluk to wens met sy aarstellirg as die Staatsmyrirgerieur en die hoop uitspreek dat dit baie jare van samewerkirg met hierdie Irstituut sal beteker. We also welcome guests who, in one way or another, have been able to attend most of our Annual General Meetings, the Honourable I. B. Dillon, the Minister of Mines of Rhodesia, and Mrs Dillon. Once again we welcome them most heartily to our Annual Meeting. I would also like to welcome the representatives of many of our sister institutions : the Honorary Treasurer of the AS & TS, Mr D. G. Maxwell; the President of the South African Institution of Mechanical Engineers, Mr A. R. Adams; the Vice-President of the South African Institute of Electrical Engineers, Mr K. A. H. Adams, and Mrs Adams; the President of the Institute of Certificated Mechanical and Electrical Engineer s, Mr Martin and Mrs Martin; a member of the Executive of the South African Institute of Civil Engineers, Professor G. Bright ; the President of the South African Chemical Institute, Mr Vic Shuller, and Mrs Shuller; the President of the Institute of Welding, Professor F. P. A. Robinson, and Mrs Robinson; the President of SACPE, Mr M. R. Gericke ; the President of the Institution of Metallurgists, South African Branch, Mr D. R. Allen; the President of FSPE, Dr P. J. D. Lloyd, and Mrs Lloyd ; Mr A. J. H. Pole of the Association of Mine Managers, and Mrs Pole; and Mr M. D. Hoskin of the South African Institute of Foundrymen. A special word of welcome to Mr G. C. Young of our Orange Free State Branch, and Mrs Young ; and to Mr E. J. Jackson of our Witbank/Middelburg Branch. We have great pleasure in welcoming Dr F. M. Naude, the Scientific Adviser to the Prime Minister, and Dr W. C. J. van Rensburg, Technical Director of the Minerals Bureau. The latter is a new organization, and we hope their attendance here this afternoon forecasts a long period of co-operation between the Minerals Bureau and this Institute. Ook wil ek hartlik hier verwelkom die Rektor van Die Randse Afrikaanse Universiteit, professor G. van N. Viljoen. Ors het baie noue samewerking met die Universiteit gekry, en ek wil ook bier verwelkom die twee verteenwoordigers van die Geologiese-afdeling en die Chemie-afdeling, naamlik, dr C. Roering en professor G. W. Holzapfel. Last, but by no means least, a word of welcome to a very old friend, Mr Eric Boden, the Manager of AS & TS. To all our guests, a very hearty welcome to this our Annual General Meeting. Membership The President: It is required by our Constitution that I announce the names of a number of candidates who have been elected to various grades of membership. The list is a very long one, and I suggest that we simply record that these names will be published in the Journal. Any one who wishes to comment on these members should do so in writing to our Secretary. Agreed. Fellows: G. Paterson, P. H. Adler, F. W. G. Schoning, J. P. de Villiers, F. I. de Waal, J. R. H. Shaw. Members: C. J. Slavin, P. J. Perkins, R. J. I. Butler, A. M. Hattingh, C. E. Alvey, J. A. Engelbrecht, P. L. Gouws, J. P. Martin, J. F. Taylor, K. A. G. Blendulf, A. R. Gibb, W. E. Smith. Associate Members: D. R. Broderick, D. F. Cilliers, D. N. Stuart, P. Kraus, B. G. Pinder. Associates: D. E. Gibbon, D. F. Jacobs, R. F. W. Swanepoel, R. D. H. Bebb, H. H. Vernall, R. D. Gibson, J. P. van Wyk. Graduates : A. N. Morris, D. J. Payne, G. S. Worthington, A. S. Dennison, A. R. Godfrey, N. Holloway, W. J. Rankin, G. S. Lyndon, R. J. van Proctor, J. J. Versluis, G. M. Miller. Students: B. J. Rabie, G. D. Webber, W. L. Blair, I. D. Mathews, K. McVey, S. W. Beer, R. W. J. Bentley,

Jan 10, 1976

The following corrections should be made to pages 346 and 347 of the December 1981 issue (vol. 81, no. 12) in the paper by O. L. Papendorf entitled 'A note on rapid determinations of present values in the presence of growth and inflation'. (1) Equation (2) on page 346 should read as follows:

Jan 1, 1982

By B. Kruger

After the milling and flotation of the platinum bearing ore, the flotation concentrate is electrically smelted in 6-in-line electric arc furnaces and the resulting furnace matte treated in Peirce Smith converters to remove the iron. The iron-free (less than 1% Fe) converter matte is granulated and sent to the base metals and precious metals refineries for further processing. During the smelting and converting processes two distinct gas-strength gas streams are produced: ?The Peirce Smith converter off-gas contains 4%?9% SO2which is treated in a conventional sulphuric acid plant to produce 94% H2SO4. ?The electric furnace off-gas contains 0.9% SO2which was (until September 2002) vented through a 91- metre high stack to atmosphere. In October 2002 Impala Platinum commissioned a SULFACID® plant at its smelter in Rustenburg, which recovers the SO2from the electric furnace off-gasses into a weak sulphuric acid solution. The SULFACID® technology utilizes wet activated carbon to oxidize the SO2toSO3. The SO3reacts with the water on the catalyst and is washed off the catalyst bed as a sulphuric acid solution with up to 13 wt. H2SO4. The plant operates at 60ºC and at atmospheric pressure. The SULFACID® technology is widely used in the pigment industry. This is, however, the first application of the technology on electric furnace off-gas. Keywords: SO2, sulphuric acid, electric furnace, off-gas, SULFACID®

Jan 1, 2004

By K. A. Moxham

The ARM 1100 was described in a paper presented at the 6th International Symposium on Mine Mechanization and Automation in September 2001. It started operation underground at Rowland Shaft in early 2002. This paper covers the results of those trials that resulted in more than 1 100square metres of UG2 being mined.

Jan 1, 2004

By J. L. Taylor, E. B. Viljoen, W. M. Craig, A. M. McIntosh

The Chemwes uranium plant treats old gold-plant residues from the Sttifontein and Buffelsfontein Gold Mines by acid leaching, belt filtration, countercurrent ion exchange (ClX), and Bufflex solvent extraction (SX). The uranium is recovered by precipitation as ammonium diuranate. Absorption and elution in the CIX section are achieved in four NIMCIX columns operating as two parallel streams. Each loading column is 4,85 m in diameter and contains 12 absorption stages. The elution columns are 3 m in diameter and contain 8 stages. The eluant used is 10 per cent sulphuric acid at ambient temperature. During the commissioning and initial operating periods reported here, the plant yielded an average barren solution of 1,6 p.p.m. of U3O8 from a feed with a mean U3O8 concentration of 132 p.p.m. The U3O8 concentrations in the barren solution were better than 2 p.p.m. some 85 per cent of the time, and better than I p.p.m.73 per cent of the time. Investigations are underway to institute an automatic control system that will result in the U3O8 values on the resin and in the barren solution being maintained at or near the target values in spite of changes in the concentration of uranium in the feed solution.

Jan 1, 1982

By J. Witley

"Narrow tabular platinum group element deposits in the Bushveld Complex of South Africa are typically evaluated by diamond core drilling from surface. Several short deflections are drilled from each mother hole in order to obtain multiple intersections at a close spacing (less than 1 m). Examination of the intersections from deflection drilling revealed the importance of these deflections in understanding the representivity of the borehole, obtaining an estimate of the nugget effect, and mitigating the undesirable effect of the high grade variability at the ultra-short range that is a characteristic of these deposits. The use of deflections in estimation was investigated by means of a number of techniques and scenarios in order to find the most appropriate way to use them in an estimate. A significantly improved level of confidence was gained from using multiple close-spaced intersections rather than a single borehole intersection. IntroductionThe Upper Group 2 chromitite layer (UG2 or UG2 Reef) is known for its remarkable geological continuity, being traced almost uninterrupted for tens of kilometres. However, what is often less well emphasized is the high variability in platinum group element (PGE) grade and thickness (and therefore PGE content) and internal reef stratigraphy over very short distances (several metres or even tens of centimetres).This paper examines the application of short drill-hole deflections in evaluating UG2 PGE mineral resources at Marikana in the western Bushveld Complex of South Africa."

Jan 1, 2017

THE BRITISH COUNCIL AWARDS 1971-1972 The British Council invites applications from permanent residents of the Republic of South Africa and South West Africa, for the following awards: SCHOLARSHIPS Scholarships are available to such permanent residents who hold university degrees or comparable professional qualifications. The scholarships are tenable for postgraduate study at universities and other educational establishments in Britain for the academic year of approximately ten months beginning 1st October, 1971. BURSARIES Bursaries are available to such permanent residents who hold university degrees or who, being already established in their professions or trades, hold other qualifications. The bursaries are tenable at British educational institutions or other suitable establishments in Britain for a course of training, study or research lasting not less than two months or more than six. The British Council may, at its discretion, bear the cost of single or return fares to Britain. The closing date for applications is 31st July, 1970. TRAVEL GRANTS Travel grants each of £300 are available in respect of journeys to Britain undertaken between 1st April, 1971 and 31st March, 1972 and are provided to facilitate visits to British universities by persons holding staff appointments or graduate research posts at South African universities. Visits must normally be of at least six months duration. The closing date for applications is 31st October, 1970. For further particulars and the relevant application forms please write stating the type of award for which you wish to apply to: The Cultural Attache, British Embassy, Pretoria. THE SECOND INTERNATIONAL CONFERENCE ON THE PROPERTIES OF LIQUID METALS Tokyo, September 1972 The Second International Conference on the Properties of Liquid Metals will be held under the auspices of The Japan Institute of Metals and The Physical Society of Japan from 3rd to 8th September, 1972 in Tokyo. The purpose of this conference is to continue and extend the efforts towards the objective of the First International Conference on the Properties of Liquid Metals at Brookhaven, 1966. The tentative Conference subjects presently planned are: Structure of Liquid Metals and Alloys; Atomic Transport Properties (Diffusion, Viscosity, etc.); Electronic States and Transport Properties; Thermodynamical Properties; Melting and Phase Transitions. Correspondence regarding the Conference and the request for the First Notice should be addressed to: Professor S. Takeuchi, Chairman of the Organizing Committee, The Research Institute for Iron, Steel and Other Metals, Tohoku University, Sendai, 980, Japan. PROCEEDINGS OF THE NINTH COMMONWEALTH MINING AND METALLURGICAL CONGRESS 1969 Volume 4 of the Proceedings of the Ninth Commonwealth Mining and Metallurgical Congress 1969- Physical and fabrication metallurgy-contains the 24 papers presented under this general heading at the Congress. Also included are discussion, authors' replies, name and subject indexes, and plenary addresses by Sir Val Duncan, O.B.E. and Sir Ronald L. Prain, O.B.E.

By G. F. Balderson

In response to the written contribution made by G. J. C. Young to the above paper, I would like to make the following points. Paragraph 1 The build-up of oxidized coatings on cone surfaces has not been a problem in other applications similar to that at President Steyn. The following companies have commented.

Jan 1, 1982

By B. Orgilbayar, B. Unursaikhan, S. Sukhbat, Ts. Zagarzusem, D. Baasanjav, L. Jargalsaikhan, E. Otgonjargal, N. Sugir-Erdene, Ts. Soyolmaa

This study has investigated the efficacy of the gravity beneficiation method based on gravitation and centrifugal forces for manganese ore. Powdered samples of manganese ores from the Unagad deposit in Mongolia were analysed for their element and mineralogical composition using ICP-MS and X-ray powder diffraction (XRD). The analysis presented the mineralogical compositions of the ores as hydro goethite, manganese minerals and magnetite, gangue minerals as quartz, albite, orthoclase and microcline of manganese ore. Manganese minerals are white in colour and have micro-veinlet, fine grained-aggregates associated with gangue minerals. The most important manganese minerals are hausmannite, pyrolusite, rhodochrosite, and manganosite. The composite of feed containing 17.31 % Mn and 36.3 % SiO2 was processed in a shaking table. In the experiment, a concentrate assaying 41.37% Mn was obtained from this composite with 65% recovery. In another experiment, f80=0.074 mm particle size ore was used in the MGS concentration test. A concentrate containing 38.34 % Mn with 75.2% recovery was produced in this experiment. The results showed that it is possible to obtain concentrate through gravity processing of manganese ore, which is an economically beneficial process for producing a product of a standard requirement. Keywords: Manganese ore, gravity separator, centrifuge, shaking table 1. Introduction

Jan 1, 2020

By W. K. Brisden

The SAG Milling Seminar, which was held at Murdoch University in Perth on 30th November and 1st December, 1989, was a very successful technical seminar. Organizer Dr Norm Stockton reported a total attendance of 130, which was higher than the 70 expected: 20 delegates came from the eastern States and the remainder were from Western Australia.

Jan 1, 1990

By H. J. Swanepoel, N. B. Strydom

Groups of up to twelve new recruits to the industry were subjected to climatic room acclimatization for either five, seven, eight or nine days prior to being tested for the degree to which they had been acclimatized. These tests were done at 32,2 0C (wet bulb) at a wind velocity of about 0,4 m/sec and the men worked for four hours at a rate of 215,6 kg m/min on one day and at a rate of 431,2 kg m/min on the second day. The results indicated that there is no significant difference between the degrees of acclimatization obtained by the eight- and nineday procedures which confirms the conculsions drawn in a previous report1. The eight-day procedure can thus be claimed to be perfectly adequate and safe. Decreasing the period of exposure to five or seven days would however, not be justified because of the significant differences in physiological responses that were observed on both test days between men acclimatized for these periods and those acclimatized for nine days. It is concluded that it would be unsafe to employ these shorter periods of acclimatization when underground environmental temperatures at which the men are to work, exceed 31 0C (wet bulb).

It is suggested that an increase in the production from thin coal seams in South Africa is necessary, and that a substantial amount of any increase will be mined by the bord-and-pillar method. For the purpose of this study, a thin coal seam was regarded as any seam 1,5 m thick or less to the minimum thickness at which mechanized equipment can operate in bord-and-pillar workings. The equipment being utilized in thin-seam bord-and-pillar layouts includes conventional equipment, load-hauldump cars (scoops), and drum-type and Fairchild-Wilcox continuous miners. Comparisons are made of these types of equipment for bord-and-pillar mining at various seam thicknesses within the thin-seam range. The evaluations involved production rates and the cost of extraction for South African conditions, use being made of an existing computer modelling technique in the generation of production rates. The indications are that, for seam thicknesses greater than 0,9 m, drum-type continuous miners utilizing continuous haulage are the most productive and cost-effective equipment at present operating in thin-seam bord-and- pillar workings. Where seams thinner than 0,9 m are to be exploited, Fairchild-Wilcox continuous miners, particularly the Mark 22, produce the most coal at the lowest cost.

Jan 1, 1984

By deur B. C. Alberts

Graduate engineers are a scarce and valuable resource. The situation is aggravated by the 2 years of national service, resulting in the elapse of 6 years after matriculation before a young engineer can start his practical training. After having started work, it is therefore imperative that employees in this category should be trained as effectively as possible in (1) the specialized activities of the employer and (2)the employer's specific work practices. Knowledge and experience of these two areas are vitally important for productive work performance by young engineers. Consequently, it is Iscor's primary objective to enable young graduates, in this case engineers, to obtain the knowledge and experience necessary for productive work in the shortest possible time. Iscor's training programme is therefore structured to enable the young engineer to - perform high-level engineering work and to make sound engineering decisions as soon as possible, - gain a thorough background of the employer's production processes, plant, and equipment, - become thoroughly acquainted with Iscor's work practices, policies, and procedures, - acquire a sound knowledge of Iscor's management techniques and philosophies, - do productive work during the training period, - obtain the following additional qualifications as soon as possible: . Government certificate of competency (legally required before appointment to certain positions) . registration as a professional engineer. Iscor's training programmes are no longer based on predetermined periods of time for each department and work practice. Neither is it a tour or visitors' programme. This contribution explains how Iscor, and more specifically its Mining Department, attempts to reach its objectives in this regard.

Jan 1, 1987

By Y. Sagawa

The Hishikari Gold Mine consists of epithermal vein type Au-Ag deposits, each of which has several veins standing almost in parallel each other and inclining 70 to 90 degrees. The veins have 1 to 3m widths and are extracted mainly by drifting and bench stoping with waste rock fill. The Hishikari has tried to optimise the stope dimensions by the Potvin’s Stability Graph Method, which is well known as an easy and effective tool to design appropriate stope dimensions. The method, however, has some limitations of application due to its simplicity so that it has been used only in limited cases. The authors developed a new numerical approach, based on 2D FEM solu-tion for the stability analysis. As a result, it has been possible to solve the Hishikari situation. The authors also introduce the concept of the design approach and compare the results obtained by us-ing the approach with the database of the Stability Graph Method for validation. La mine d’or Hishikari se compose de gisements d'Au-AG avec des types de filons épither-maux dont chacun a plusieurs veines qui sont presque parallèle les unes par rapport aux autres et sont inclinées de 70 à 90 degrés. Les veines ont de 1 à 3 m de largueur et elles sont principalement extraites en creusant et en abattant des bancs de roches encaissantes. Hishikari a essayé d’optimiser les dimensions du chantier d’exploitation avec la méthode de graphique de stabilité de Potvin, bien connue comme un outil facile et efficace pour avoir des dimensions de chantier d’exploitation appropriées. Toutefois, la méthode a certaines limites d’application dues à sa sim-plicité de sorte qu’elle a été utilisée seulement dans des cas limités. Les auteurs ont développé une nouvelle approche numérique, basée sur la solution 2D FEM, pour l’analyse de stabilité. Par conséquent, il a été possible d'expliquer la situation de Hishikari. Les auteurs présentent le concept de l'approche et ils comparent les résultats donnés en l'employant avec la base de données de la méthode de graphique de stabilité pour la validation. Die Hishikari-Goldmine besteht aus Au-Ag-Ablagerungen mit epithermalen Adern, die jeweils mehrere Adern aufweisen, die mit einer Neigung zwischen 70 und 90 Grad nahezu parallel zueinander verlaufen. Die Adern haben eine Breite von 1 bis 3 Metern und werden überwiegend durch Vortrieb von Stollen und Bergversatz abgebaut. Hishikari hat versucht, die Abmessungen des Abbauorts durch das Potvins Stabilitätskurvenverfahren zu optimieren, das als einfaches und effizientes Mittel für die Erzielung angemessener Abmessungen des Abbauorts bekannt ist. Das Verfahren weist jedoch aufgrund seiner Einfachheit einige Anwendungsbeschränkungen auf, so dass es nur in einigen Fällen benutzt worden ist. Vor diesem Hintergrund haben die Autoren einen neuen numerischen Ansatz entwickelt, der hinsichtlich der Stabilitätsanalyse auf der 2D-FEM-Lösung beruht. Dadurch wurde es möglich, das Problem von Hishikari zu lösen. In diesem Dokument stellen die Autoren die Grundlagen des Ansatzes vor und vergleichen die erzielten Resultate durch Benutzung der Datenbank des Stabilitätskurvenverfahrens zur Validierung.

Jan 1, 2003

By T. Könighofer

Processing of copper-cobalt orebodies in Africa?s Copper Belt has received much recent attention with various flowsheet options being developed specifically for the refining of cobalt. The upfront leach and copper refining routes are well understood whereas the refining of cobalt is more complex, requiring numerous impurity removal steps to produce high purity metal. This paper describes an investigation into one of the possible processing steps in the refining of cobalt, namely, cobalt solvent extraction. The paper emphasizes the importance of upstream impurity removal to achieve the required cobalt solvent extraction feed composition. 18% (v/v) Cyanex 272 in an aliphatic diluent is used as the organic phase. The pH profiles in the various stages are evaluated in order to obtain a raffinate containing <10 mg/[l] cobalt and with a low magnesium content reporting to the stripping section. The pH profile is also used to minimize the impurity deportment to the cobalt electrolyte. The effect of adding a preneutralization stage before feeding the organic phase to the extraction circuit is investigated. Zinc build-up in the stripping stages is also looked at. It is recommended for the purpose of this study that four extraction stages at an O:A ratio of 1 with a pH profile from 4.9 to 5.7 be employed. The pH is controlled with 40 g/[l] NaOH. A preneutralization stage is required, where the organic phase is contacted with 10 M NaOH. Two scrubbing stages are recommended at an O:A ratio of 40, using the cobalt electrowinning advance electrolyte as the scrub liquor. Three strip stages are to be employed at an O:A ratio of 0.67.

Jan 1, 2009