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By M. B. Cortie

The historical development of materials engineering in the mining industry Is briefly reviewed, and some of the factors currently influencing the industry in South Africa are discussed. Material usages in various parts of the mining operation are surveyed. The predominant mechanisms in the degradation of materials in mines are wear, corrosion, and fatigue. The issue of corrosion-abrasion Is considered, but it Is concluded that abrasive wear predominates in most rock-handling and comminution applications and that, in general, little economic benefit Is to be gained in those applications by the use of existing corrosion-resistant alloys. However, alloys with a measure of corrosion resistance find profitable application elsewhere in the mining environment. The use of other engineering materials such as polymers, ceramics, al1l1inium, and various ferrous alloys may be economically viable in a variety of niche situations. Identification of the most cost-effective material in each case calls for a systematic approach and some patience.

Jan 1, 1996

By J. W. van der Merwe, C Strydom, D. C. Odendaal, M. I. Sampson

Keywords: Sphalerite, Bio leaching, Chemical leaching Sphalerite concentrates were prepared from tailings dam samples obtained from Rosh Pinah Mine in Namibia. The samples were subjected to froth flotation and concentrates containing between 7% and 14% Zn were prepared. Leaching of these froth flotation concentrates were studied in ferric chloride solutions at different Fe3+ concentrations for different times at different temperatures with the influence of other species on the kinetics in mind. Complementary to this research, GeoBiotics, LLC and Exxaro Resources have developed proprietary bioleaching technology for the oxidation of base metals concentrates using GEOCOAT bio heap leaching technology in a sulphate medium. The ferric chloride laboratory work was performed in a fluidising leach reactor. The studied material was obtained from flotation concentrate produced during an investigation into the recoverability of a tailings pile at Rosh Pinah mine in Namibia. The optimum conditions for the laboratory investigation were found to be a Fe3+ concentration of 0.3 mol/dm3 at 80°C. A control was performed by using synthetic zinc sulphide. GEOCOAT evaluation tests are performed for the purpose of evaluating the bioleaching of ore and flotation concentrates by means of mesophilic bacteria, Column tests were carried out on the flotation scavenger concentrate from Rosh Pinah to assess the application of the GEOCOAT® process for the oxidation of a low grade zinc concentrate. In this study an attempt was made to demonstrate the relationship between the Kinetic models and the experimental data by plotting the fraction of Zinc leached against time and applying the different equations to the data. The kinetic models were applied to the data obtained from both the test regimes. Habashi (1999) proposed that if a process is controlled by a chemical reaction at the interface (phase boundary controlled reaction), the following equation applies. kCt =1 ? (1-R) 1/3 Alternatively a process is controlled by diffusion through the product layer the following equation applies: [kt = 1 23- X (1 ? X) 2/3] As the anodic dissolution reaction progresses, reaction product forms either a more or less dense reaction product layer on surface As this product layer forms, a diffusion problem develops governed by the nature of the product layer. The conclusion from the study was that the kinetics is very dependent on the type of ore processed relating to the mineral composition of the ore body.

Jan 1, 2007

A method is proposed for the evaluation of the influence of grout prestressing systems on the support resistance offered by timber packs. It is shown that, in order not to reduce the load-carrying capacity of timber packs, grout prestressing systems need to be at least as stiff as a single timber rise. The method was used to establish strength specifications for the grout prestressing systems to be used under non-seismic and seismic conditions. For non-seismic requirements, the 24-hour grout strength needs to be at least 1,7 MPa, and the 7-day grout strength 4,9 MPa. The investigation showed that the proposed strength specification is realistic in the light of current grout-strength capabilities. For seismic requirements, the grout strength needs to be at least 4 MPa and 8 MPa to prevent extensive damage to the grout during seismic events with a peak velocity of 1m/s 3 m/s respectively.

Jan 1, 1996

By T. Ito, N. Tokashiki, H. A. Bilgin, Ö. Aydan, T. Akagi

This study is concerned with the electric potential induced by deformation, fracturing and sliding of non-piezoelectric geomaterials. In experiments, the acoustic emissions together with electric potential measurements were also measured in order to see how the so-called seismic electric signals are associated with new fracture occurrence and propagation and sliding in case of existing discontinuities. The outcomes of this experimental study may explain why such electric potential variations may occur during the fracturing and sliding of non-piezoelectric geomaterials. On the basis of these outcomes, their possible implications in geo-engineering and geo-science are discussed. Ce travail concerne 1e potentiel électrique produit par la déformation, 1a fracture ou le glissement du matériel géologique non-piézoélectrique. Aux expérimentations, on a mesuré 1es émissions acoustiques avec le potentiel électrique afin de constater la relation entre les phénomènes de glissement ou de formation et de propagation de nouvelles fractures le long des discontinuités existantes. Les résultats de ce travail expérimental expliquent pourquoi de telles variations de potentiel electrique se produisent durant le glissement ou la fracture du matériel non-piézoélectrique. Sur la base de ces résultats, on a discuté de leurs éventuelles implications dans les domaines de 1a géologie et de 1a géo-ingénierie. Diese Studie befasst sich mit dem elektrischen Potential das durch die Deformation, Bruchbildung und Gleiten von nicht-piezoelektrischen Geomaterialien induziert wird. In Experimenten wurden die akustischen Emissionen zusammen mit elektrischen Potentialmessungen gemessen, um zu sehen, wie die so genannten seismischen elektrischen Signale mit neuer Bruchbildung und Ausbreitung sowie Gleiten im Falle von vorhandenen Diskontinuitäten verbunden sind. Die Ergebnisse dieser experimentellen Untersuchungen könnten erklären warum elektrische Potential Schwankungen während der Bruchbildung und dem Gleiten von nicht-piezoelektrischen Geomaterialien entstehen. Auf der Basis dieser Ergebnisse, wurden ihre möglichen Implikationen in Geoingenieurwissenschaften behandelt.

Jan 1, 2003

By N. B. Strydom, P. L. Jooste, H. F. Kotze, W. H. Van Der Walt

Note: A revised method of heat acclimatization by N. B. STRYDOM, W. H. VAN DER WALT, P. L. JOOSTE, and H. F. KOTZE INTRODUCTION Climatic-room acclimatization was introduced in the gold-mining industry in 1965 and was rapidly adopted by all mines because it reduced the number of days required for heat acclimatization from 12 to 8. The method has been adequately described in previous papers1, 2 but, briefly, requires four hours of heat exposure per day while the work rate is progessively increased from 35 W on Day 1 to 70 W on Days 7 and 8. Several attempts to shorten

Jan 6, 1976

By G. D. Rosales, P. F. A. Braga, S. C. A. França, C. P. Pinto

The growing market demand for lithium is mainly due to its use in the manufacture of batteries for electric or hybrid vehicles and portable equipment (smartphones, tablets, power tools, notebooks, etc.). Currently there is great interest in finding new sources of lithium and technologies for its utilisation. Li-S batteries have received attention due to their theoretically high specific energy density, which is 3 to 5 times greater than that of Li-ion batteries. Unlike Li-ion batteries, of which the main raw materials are lithium carbonate and lithium hydroxide, the main raw material for Li-S batteries is lithium chloride. The anode used in Li-S batteries is metallic lithium, produced by a molten lithium chloride electrolysis process. The extraction of lithium from pegmatites such as spodumene, previously abandoned in the 1990s for being uneconomical, has become attractive due to the increase in prices as well as the need for greater lithium purity of products made from lithium-bearing minerals. The main methods used for lithium recovery from spodumene ore include the sulfuric acid process, the alkaline process (lime or limestone as raw material) and the chlorination roasting process. Thermodynamic modelling using HSC software 5.1 was conducted to predict different reactions that could occur during chlorination roasting of the spodumene/MgCl2+CaCl2 system. Lithium extraction from the solid obtained after the chlorination roasting was also investigated. The results of thermodynamic analysis provided a better understanding of the chlorination roasting process for lithium extraction. Metallurgical tests with a mass ratio of 1:6 (spodumene:chlorides) and molar ratio of 2:1 (MgCl2:CaCl2) allowed over 95% recovery of the lithium contained in the spodumene concentrate. Keywords: Spodumene, lithium chloride, chlorination roasting

Jan 1, 2020

By J. L. Louw

The utilization of centralized blasting systems is progressively becoming a feature of the South African mining industry, owing to increased pressure from the Department of Mineral Resources (DMR) to ensure safer blasting conditions. The purpose of a centralized blasting system (CBS) is to ensure reduced blasting-related incidents and to improve the underground working environment for the mine?s employees. The brief from Samancor Western Chrome Mines (WCM) pertaining to this study was to explore?at a conceptual level?all variables pertaining to the implementation of the CBS. Studies have indicated that Sasol?s SafeBlast? was preferred due to low overall risks and user-friendliness. Empirical observations, however, indicated that attention should be given to the current shaft-clearing procedure and to the installation of additional transformers. This is required to co-ordinate the power supply from 2 level to 10 level with the required supply of the network slave station. A cost analysis indicated that an electronically initiated CBS will result in a R24 cost increase per panel, which relates to a mere 1% cost increase per panel. This cost, in addition to the R1.1 million capital cost, proved to be negligible in comparison to the possible direct and indirect costs incurred by the mine in the event of a blasting-related incident. It was found that Samancor should conduct further studies incorporating the necessary requirements to ensure a successful transition, while considering all stakeholders on the mine. This study proved that the transition to a CBS would ensure safe and efficient blasting at Samancor?s Mooinooi Mine.

Jan 1, 2012

1. Book reviews Quantitative texture analysis, edited by H. ,}. Bunge and C. Esling. Deutsche Gesellschaft fur Metallkunde, 1982. 551 pp. Reviewer: L. 1\'1.Matthews Boundary element methods in solid mechanics by S. L. Crouch and A. M. Starfield. Reviewer: J. A. C. Diering World mineral statistics 1976-1980. Produdion,' exports,' imports, by Institute of Geological Sciences. London, Her Majesty's Stationery Office, 1983. £18.00 Reviewer: R. P. King 2. New publications Canadian mines,. perspective from 1982. Mineral Bulletin MR 197. Supply and Services Canada, Hull, Quebec K1A 059, Canada. Copper' s changing cost structure, by Commodities Research Unit Ltd (31 Mount Pleasant, London, WClX OAD, England). Petrology of metamorphic rocks, by M. Suk. New York, Elsevier, 1983. 320 pp. U.S. $68.00. Applied geomorphology, by H. Th. Verstappen. New York, Elsevier, 1983.442 pp. U.S.$95.75. Tin and its uses, no. 137, by the International Tin Research Institute. Greenford, the Institute (Fraser Road, Greenford, Middlesex UB6 7AQ, England), 1983. 3. New journals Mining Science and Technology, edited by C. 0, Brawner and B. N. Whittaker, is to be published quarterly in one volume per year by Elsevier. Aluminium, published monthly by Aluminium -Verlag GmbH, P.O. Box 1207, D-4oo0 Diisseldorf 1, F.R. Germany. DM 690.00 per annum. Rock mechanics The South African Institute of Mining and Metallurgy is to hold two schools on 'Rock Mechanics in Mine Management' at the University of the Witwatersrand, Johannesburg, from 23rd to 27th January, 1984, and from 30th January to 3rd February, 1984. The Federation of Societies of Professional Engineers The Federation of Societies of Professional Engineers (FSPE) has been a member of the World Federation of Engineering Organisations (W FEO) for many years and has regularly sent delegates to the biennial conference of that organisation. Second progress report by ASRET The Professional Engineers Joint Council was estabislhed in 1960 and initially its main fWlction was to represent the interests of engineers. Explosives technology The Center for Explosives Technology Research (CETR) has been established at the New Mexico Institute of Mining and Technology (Tech) in Socorro, New Mexico. International Tunnelling Association A conference entitled 'Ita Tunnels 1984' will be held in Caracas, Venezuela, from 2nd to 7th June, 1984. Automation The IFAC Symposium on Automation for Mineral Resource Development is to he held in Brisbane (Australia) from 9th to nth July, 1985.

Jan 1, 1983

Dr T. F. Muller (Honorary President): "Mr President, gentlemen. May I congratulate the Institute on its 75th birthday, and your President on his comprehensive review of the Institute's 75 years. It is an interesting commentary on the affairs of the Institute that your President should refer to a speech made by a founder member 25 years ago on the occasion of your 50th Anniversary and then say there is no need to repeat what was given there, but that he would confine his remarks to bringing the Institute's history up to date. To me this suggests a remarkable continuity of thought and ideals-a welcome island of stability in an ever-changing world. One can somehow picture another future President, perhaps one of the younger and tougher members here today, doing the same thing in 25 years when you celebrate your centenary-and again someone doing the same in the year 2094 when your Institute is 200 years old! I hope they will recognise their debt to the early pioneers of the Institute gathered here today. In any event, this review of the fine achievements of the past 75 years is certain of an honoured place in the annals of the society. Here is a record of the onward march of technology in South Africa and a tribute to a long line of mining engineers, of chemists, metallurgists and geologists who made a greater contribution to the well-being and the prosperity of South Africans than South Africans generally are aware. Your Institute started off as a 'gold and cyanide club', peopled largely by chemists and metallurgists who made a signal contribution to the industry from the earliest times. Despite the addition to their ranks of ever-growing numbers of mining engineers, the metallurgist members have continued to make notable contributions. One recalls, for example, the manner in which they rose to the occasion to resolve the problems associated with the establishment of the uranium industry in this country. The creation of a major industry based on the existence of low grade uranium ores in the conglomerate reefs of our low grade goldfields is a classic example of the manner in which a new large industry can be rapidly created through the combined endeavours of all concerned. I noted with pleasure your remark, Mr President, that members of the Institute would like to keep up to date with recent progress in nuclear fuel matters and that members should be given the opportunity to study developments in their journal. I am sure that the National Institute of Metallurgy which conducts fuel research on behalf of the Atomic Energy Board and of the Uranium industry, and NUFCOR, which co-ordinates the uranium research programme, would be glad to co-operate if invited by the Institute to make periodical contributions to its journal. You have referred to the building up of our research organization and its dynamic approach to mining problems. I understand that the expenditure of the mineral industries on research exceeds one-third of the entire research expenditure of the private sector. South Africa is in the forefront of mining development and the focus of world attention is on the achievements of our scientists and mining engineers. We can look forward to continued advances in mining technology based on their vision and expertise. I share your disappointment, Mr President, that the Base Metals Division has ceased to exist; and that there is a resultant dearth of papers offered to the Institute on these important sections of mining and metallurgy. We are seeing some remarkable developments in the mining and beneficiation of base minerals, and it is in this area that I see the greatest potential for future expansion. If we can grasp the opportunities

The annual General Meeting of the Branch was held in the St. Helena Club on Wednesday, 4th August, 1971 at 8.00 p.m. Mr N. A. Honnet (Immediate Past Chairman) was in the chair. There were also present Mr V. C. Robinson, President of the South African Institute of Mining and Metallurgy. Nine Fellows: Messrs J. R. F. Handley, C. J. Isaac, J. Lorenzon, J. M. Meyer, C. Mostert, D. A. Smith, S. L. S. Swart, I Thomas and R. G. Williams. Five members: Messrs R. Campbell, A. H. Edwards, K. Pearce, G. P. Rundle and R. B. Sutherland. Five graduates: Messrs J. E. Andrews, E. J. Shillaber, M. H. Smith, T. R. Stromsoe and D. J. van Niekerk. Two associates: Messrs A. Paschalides and D. S. Robinson. Eight visitors. Total present: Thirty-one. MINUTES OF THE PREVIOUS GENERAL MEETING As the minutes of the General Meeting held on the 16th June, 1971, had not been published in the Journal, the Chairman moved that the adoption and discussion thereof be deferred to the next General Meeting. This motion was adopted unanimously. The minutes of the General Meeting held on the 10th February, 1971, were taken as read. The adoption, which was proposed by Mr D. A. Smith and seconded by Mr J. M. Meyer, was carried unanimously. At Mr Honnet's request, Mr V. C. Robinson took the chair during the presentation of the Chairman's Annual Report. CHAIRMAN'S ANNUAL REPORT 1970/71 1970/71 Committee-Office Bearers: Chairman - J. N. Saunders Vice Chairman - G. Y. Nisbet Immediate Past Chairman- N. A. Honnet. Due to the sudden retirement of Mr J. N. Saunders, the committee, at a meeting on the 3rd February, 1971 elected Mr G. Y. Nisbet as Chairman with Mr J. M. Meyer as Vice Chairman. After the transfer of Mr Nisbet to C.D.M., the committee, as a meeting on the 12th May, 1971, decided that Mr Meyer hold the Chair in an acting capacity for the remainder of the year. Committee members: Messrs C. J. Isaac, J. G. Kirchener, L. O. W. Leimer, R. S. Pearson, I. G. Thomas and A. von Holdt. Transfers of several office bearers and committee members resulted in Messrs J. M. Meyer, D. N. Smith and G. C. J. Young being co-opted onto the committee.

By M. F. Dawson, S. B. Davis

SYNOPSIS This paper describes the size reduction of limestone smaller than 1 mm by attrition grinding, using quartz (1 to 3 mm) as the grinding medium in a laboratory rig. The ore and grinding medium were closely sized fractions, and the particle size of the grinding medium was at least three sizes larger than that of the ore. Batch tests showed that the size reduction of the feed followed two first-order rate processes: one for an apparently fast-breaking ore fraction, and a slower one for most of the ore (86 per cent). The production of fines (material smaller than 10 µm) followed a zero-order rate equation. Continuous runs showed that the process could be modelled as a perfectly mixed system provided that the discharge screen did not selectively retain coarser particles of ore. The ratio of medium to ore (both by mass and by volume) was found to have a significant effect, the most energy¬efficient grinding occurring at ratios between 1 and 2. The solids content of the slurry also had a significant effect, the greatest efficiency being obtained at 50 to 65 per cent solids (by mass). Within these energy-efficient ranges of medium-to-ore and solids content, the lower values resulted in maximum feed breakage and the higher values in maximum fines production. The most important factor in the breakage of feed was the difference in the particle size of the grinding medium and the ore; the amount of ore broken out of the feed size for a given energy input was found to increase linearly with the difference between the size of the grinding medium and that of the ore up to 2 mm. The production of fines increased similarly, but only up to a difference of about 1,2 mm, when it levelled off at about 5 kg/kW ? h. The mechanism proposed for attritioning is mainly the abrasion of 1 µm planes of limestone along the crystal axes, with some fracturing along existing lines of weakness. The energy consumption of nearly 200 kW ? h per ton of product smaller than 10 µm appears to be higher than that in other types of milling. It is concluded that the value of attrition milling lies in its selectivity; in this work, only the softer limestone and virtually none of the hard quartz grinding medium was comminuted.

Jan 1, 1989

By J. G. Ferguson, R. E. Burnton

The nature of the coal and of the roof in No. 3 seam at Coal brook Collieries is such as to preclude the use, during bord and pillar mining, of conventional mining equipment that employs cutting and blasting in its production cycle. Continuous mining machines of the borer type, operating within a mining height range of 1,9-2,3 m, have been successfully employed in No. 3 seam since 1957.The experience gained with this type of equipment, the operational methods adopted, and the results achieved are described. The ventilation method used to eliminate the dust and methane hazards created by this type of equipment is stressed. The limitation on the minimum mining height that can be obtained with the borers in use has lead to the recent introduction of a Rotary Drum type of continuous mining machine. This equipment is capable of operating in areas where the seam width decreases to 1,5m. The production potential of the machine has been proved. The roof conditions created by the cutting action of the Rotary Drum type of miner are not considered satisfactory and a modified drum head profile is to be tried.

"This study examines the problems faced by open pit mine superintendents who make choices about how to direct their materials, either to the waste dump or to the mill. The paper explores the effects of introducing a 10% sampling error and a 0.9-times to 1.1-times sampling bias on positively skewed distributions for precious and base metals, negatively skewed distributions in the case of bulk commodities, and normal distributions as is the case for coal deposits. Parent distributions for each commodity were created on a 25 x 25 m grid using transformations of gold, iron ore, and coal data-sets, spatially based on a nonconditional Gaussian simulation. Ordinary kriging of grades for the three commodities into a 10 x 10 m grid provided the reference case against which the distributions with the sampling error and sampling bias for the commodities were compared. Imposing cut-off grades on the actual-versus-estimated scatterplots of the three commodities allowed the distributions to be classified into components of waste, dilution, ore, and lost ore. Ordinary kriging of values for each deposit type acted as the reference data-set against which the effects and influence of 10% sampling error and 0.9-times to 1.1-times sampling bias are measured in each deposit type. Indications are that the influence of error and bias is not as significant in gold deposits as it is in iron ore and coal deposits, where the introduction of small amounts of error and bias can severely affect the deposit value.IntroductionThe effects of poor sampling and the financial implications for mining companies, traders in mineral assets, and sellers of metal as dore or commodities is documented in a number of studies, the most notable of which is that by Carasco (2004). He examined the financial impact of poor sampling practices in the Chilean copper industry and found that finacial losses due to poor sampling amounted to hundreds of millions of dollars over the life of a mining operation. Holmes (2004) examined the effects of correct sampling and measurement as the foundations of metallurgical balances, and found that revenues from the sales of large iron ore shipments may be profoundly affected by poor sampling practices. In South Africa the way in which sampling of in situ gold-bearing reefs affects the mine call factor has been an ongoing study since the disparity between the estimation of gold in the reef and the actual gold bullion produced was noted by early investigators such as Beringer (1938), Jackson (1946), Sichel (1947), Harrison (1952), and a number of others."

Jan 1, 2017

By Y. R. Murthy, P. K. Satija, A. Srinivasulu, S. K. Tripathy, A. Ranjan

"In this investigation, we optimize the grinding circuit of a typical chromite beneficiation plant in India. The run-of-mine ore is reduced to a particle size of less than 1 mm in the comminution circuit and concentrated using gravity separation. The comminution circuit comprises two-stage crushing and single-stage grinding in a ball mill in closed-circuit with a highfrequency screen. A detailed circuit audit was undertaken at the plant to understand and evaluate the performance of the grinding circuit. The audit revealed abnormalities in the process and design parameters which caused high energy consumption, lower throughput, and loss of ultrafine chromite. Laboratory studies indicated the differences in the grinding properties (work index, breakage rate, etc.) and liberation sizes of these ores. Studies also revealed that grinding media size, particle retention time, and pulp density are crucial in coarse grinding. Based on the laboratory grinding and characterization studies; simulation studies were performed to optimize the operating parameters of the grinding circuit.IntroductionComminution is a critical process in mineral processing which strongly influences the economics of production. In mineral processing, particles containing valuable minerals must be disintegrated at a sufficiently fine size to liberate valuable minerals from waste constituents, so that they can be easily separated by an appropriate beneficiation method. The Sukinda chrome ore beneficiation plant utilizes different types of run-of-mine (ROM) ore with different physical properties (viz. grindability characteristics, work index, mineral composition, liberation, chemical composition, etc. for the production of chrome concentrate. In the feed preparation circuit, the ROM ore is crushed and ground to below 1 mm. Grinding in the chromite beneficiation plant is a critical unit operation to achieve the desired product size of below 1 mm and to control the generation of the ultrafine particles. Furthermore, about 40% of total power consumption in the beneficiation plant is accounted for by the grinding of the ore. This implies that any improvement of the circuit performance will lead to an overall increase in productivity."

Jan 1, 2017

By M. Wu, X. Zhao

This paper presents an integrated pipeline transport system for thickened coal sludge, which combines pretreatment and pipeline transport with combustion techniques of thickened coal sludge. The pipeline can transport thickened coal sludge with a sufficiently high solids content (about72%?77%) and high apparent viscosity (about 1 000Pa?S?3,000 Pa?S) directly by pipeline having neither use for water nor an addition agent. The transport distance can be as high as 1 000 metres. In particular, the operating principles, key equipment and technical parameters of this integrated system are examined in this paper. The integrated system effectively causes no pollution to the environment because it is completely sealed, and conserves energy over traditional conveyer designs. Keywords: pipeline transport; integrated system; circulating fluidized bed boiler; thickened coal sludge; high solids content

Jan 1, 2007

Contribution by G. Narsimhan It was with much pleasure that I went through D.F. Malan's excellent paper. The following explanatory and critical note has been the result of my deep study of the paper. Although by qualifications and experience I have been a chemical engineer, involved over four decades with problems in the modeling and simulation of transport-limited (heat and mass) chemical reactions in multi-phase systems, I have of and on interested myself in challenging problems in extractive metallurgy. This is the first time I have veered of to continuum mechanics, at the age of 71! Author's reply. I thank Professor Narsimhan for his extensive contribution to the paper. It provided me with the stimulus to derive an extended model. However, there are some inaccuracies in his arguments that need further discussion. Professor Narsimhan's main concern is that there is not a good enough fit between the derived viscoelastic Kelvin model and the experimental data supplied by Güler1 (see Figure l1 on page 218 of my paper). I will therefore explain the choice of a viscoelastic model in more detail and also make specific comments on the arguments given in his contribution.

Jan 1, 1996

By J. T. M. Amphlett, C. A. Sharrad, M. D. Ogden, R. I. Foster

"A renewed interest in nuclear power around the world in order to reduce greenhouse gas emissions is going to increase demand for uranium as fuel. This will result in more uranium being mined, which will in turn increase associated environmental pressures, such as fresh water use. A move to lower quality waters containing impurities such as chloride would help alleviate these pressures. In this work, we determined the uptake characteristics of weakly basic anion exchange resin Ps-EDA towards uranium from saline solutions in a dynamic flow column. Breakthrough curves were produced, with suppression of uptake being observed for chloride concentrations above 5 g L-1. Calculated resin saturation capacities at zero and 5 g L-1 chloride are comparable with literature values for strong-base anion exchange resins, and exceed those published for weak-base resins up to 20 g L-1 chloride. Data has been fitted to multiple breakthrough models, with the modified dose-response model most effectively predicting uranium recovery. The results show that the ethylenediamine functionality could be suitable for use in future uranium processing flow sheets where a high-saline lixiviant is used. IntroductionIon exchange (IX) is a key technology in the uranium mining industry and is well established for the extraction of uranium from both acidic and alkaline leach liquors (Edwards and Oliver, 2000). It was first employed in 1952 at the West Rand mine in South Africa (Ford, 1993; Taylor, 2016). H2SO4 and Na2CO3 are the most commonly employed lixiviants used to solubilize uranium in acidic and alkaline leach conditions respectively. The chemistry of these systems causes uranium to form anionic sulphate or carbonate complexes, which can be taken advantage of by anion exchange resins.Another major technology for the extraction and purification of uranium from leach liquors is solvent extraction (SX). This technique involves the extraction of uranium from the aqueous phase into an immiscible organic layer. Although this is a commonly used method, there are major drawbacks to it, including the use of large volumes of flammable solvents, solvent loss, phase disengagement, third phase formation, and the production of problematic degradation products (Veliscek-Carolan, 2016). These problems can be circumvented through the use of IX resins."

Dec 1, 2018

By M. Nicolle

The Tati Activox® Project will be the first full-scale implementation of the patented Activox® process (The Tati Activox® project was deferred in 2008. Please refer to the Norilsk Nickel press issue on the topic for more info). The process was developed by Norilsk Process Technology and has been tested on Tati mine sulphide concentrates in laboratory, pilot and demonstration plant scales and demonstrated its viability. There are inherent risks to the final scale-up of the process from the demo plant and one of them will be investigated in this paper. Compartment 1 is designed to leach approximately 77% of the total nickel leached. For this reason agitation requirements in the first compartment of the autoclave are reviewed. An attempt is made to minimize the process and mechanical risks associated in achieving oxygen mass transfer into the slurry solution. The agitator powers for oxygen mass transfer are calculated using empirical correlations and compared to demonstration plant testwork. The resulting gassed power per unit volume (P/V) is higher than most commercial autoclaves and raises uncertainty on the viability of using such high unit power inputs. Additionally, there is concern about the ability of the autoclave shell to withstand and support the higher loading of large agitators. An alternative solution to designing for the increased P/V is assessed in which the number of compartments within the autoclave is reduced from 5 to 4 by removing the compartment wall separating compartments 1 and 2. This results in an enlarged first compartment containing 3 agitators instead of 2. Therefore the compartment 1 oxygen demand is supplied through 3 agitators, which lowers the P/V per agitator. The reduction in the number of autoclave compartments raises the potential for short-circuiting the mean flow pattern by slurry particles. Short-circuiting and low velocity zones could result in a lower recovery of metal and localized hot spots, respectively. A computational fluid dynamic (CFD) analysis was conducted to quantify these concerns and also to evaluate further design considerations. The results indicate that the proposed design change to 4 compartments affects short-circuiting. The impact of increased short-circuiting on the overall autoclave recoveries is not quantified, however; it is expected to be negligible based on testwork done in the Tati Demonstration Plant and similar modifications made to another operating autoclave. The CFD analysis also suggests that there will be no low velocity zones within the compartment.

Jan 1, 2009

By J. Nell

Heavy mineral deposits often contain relatively high levels of radioactive elements (thorium and uranium in particular).It is difficult to obtain clean separation of ilmenite and monazite (the main impurity mineral containing radioactive elements), and physical intergrowths of the two minerals are, in fact, not uncommon. As a result, ilmenite concentrates obtained from such deposits often contain high levels of thorium and uranium. Because of the large negative free energies of formation of ThO2and U3O8boththorium and uranium report to the slag during smelting and if an ilmenite concentrate contaminated with monazite is used to make high titania slag, the concentrations of these elements in the slag end up about 40% higher than in the ilmenite feed. Previous work, patented by RGC Mineral Sands Limited, and subsequently confirmed by Mintek, showed that radioactivity may be reduced by roasting an ilmenite concentrate with borax at 1000°C to 1100°C and leaching it with hydrochloric acid1. It is evident that the cost of an ilmenite roast/leach process will be high and there may be economic benefits in removing the radioactive elements from the slag instead (the volume of slag to be treated is smaller than the volume of ilmenite feed). To remove radioactive elements from the slag it is necessary to know how these elements occur in the slag. Inother words, the distribution of uranium and thorium between the various oxide, silicate and metallic phases in high titania slag must be determined. Once the deportment of thorium and uranium between the various phases ha sbeen determined, an appropriate process for slag purification can be developed. Test samples High-titania slag was prepared in a pilot-scale DC furnace from ilmenite concentrates with different levels of uranium and thorium. Subsequently, ten slag samples representing a range of compositions were selected for bulk chemical analysis, scanning electron microscopy and micro-analysis. The samples were crushed to a maximum particle size of 1 mm and from each sample a 20-kg batch was riffled out for analysis. Bulk chemical composition Chemical compositions of the samples selected for test work are given in Table I. TiO2, Al2O3, SiO2, MgO, MnO, FeO and V2O5were analysed by ICP-OES, Na2O, CaO andCr2O3by atomic absorption spectroscopy and U and Th by XRF (the XRF detection limit for U and Th was around 4 ppm). The ?B? series has a higher silica content than the others as a result of small silica additions that were made during smelting. All samples have elevated alumina levels as a result of furnace refractory contamination during smelting. As expected, there is an inverse relationship between the concentrations of TiO2and FeO in the samples (Figure 1).The TiO2and FeO levels are similar to the levels found in industrial slags2. Extreme conditions of reduction under which reduction of more ?refractory? oxides (e.g., chromia, magnesia, silica, alumina and even urania and thoria) might take place were not explored in the study. Note that BB1and BBB1 contain more than 7% combined silica and alumina (SiO2as a flux addition during smelting, and Al2O3from refractory contamination) and they do not fall on the general trend defined by the other samples. The U and Th concentrations of sample E2 is noteworthy. In the preparation of slag E2, monazite concentrate was added to the ilmenite to increase the concentrations of radioactive elements in the slag. This was done primarily to facilitate the detection of Th and U during the phase chemical characterization of the slag. Radioactivity measurements Gamma ray emissions from the samples were measured [ ]

Jan 1, 2007

By D. R. Hardman

South Africa is the third-largest supplier of coal on the world's export markets after Australia and the USA, and the second-largest supplier of bituminous steam coal following Australia. There are many Similarities between the coal industries of South Africa and those of Australia and the USA, in contrast to the coal industries in Europe. For South Africa to maintain a competitive position on the export markets, it must continue to compete against these two countries. It is therefore important that the performance of the loca1 coal industry should against that of the Australian and US coal industries. Although financial performance is the major criterion, financial information is not easily obtained, and the paper therefore uses employee productivity in the form of tonnes per man year as a means of comparison. The paper reviews recent trends in the level of production and numbers of employees prior to review1ng the productivity. The influence on productivity of some mining methods is highlighted. It is realized that published information (information available within the public domain) can contain anomalies, but every effort is made to compare data of a similar type. Notwithstanding possible inaccuracies, it is shown that South African coal-De productivity lags far behind that of Australia and the USA. The significance of the difference is that the South African coal industry is able to apply overseas practices and procedures that have been shown to give improved performance, and that the increased use of more productive extraction techniques has limited application.

Jan 1, 1996