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By R. Asamoah, P. Forson, S. Xu, W. Skinner, M. Zanin

In most auriferous hydrothermal deposits, gold is preferentially associated with pyrite and arsenopyrite minerals, with higher economic gold values noted for the latter and arsenian pyrite minerals. In this paper, surface (Cryo-XPS) and solution (EDTA extraction) analysis were used to characterise pyrite and arsenopyrite minerals under different aqueous conditions involving electrokinetic study and collector interactions to better understand ways of improving the separation of pyrite and arsenopyrite. The evidence showed higher surface oxidation at solution pulp pH values in the range of 4-11 for arsenopyrite relative to pyrite. The observed highest ratio of pyrite to arsenopyrite selectivity was 1.7 at collector concentration of 50 g/t and decreased with an increase in collector concentration. Keywords: EDTA extractable iron, selectivity index, differential flotation, grade engineering

Jan 1, 2020

THE THIRD INTERNATIONAL GEOCHEMICAL EXPLORATION SYMPOSIUM (Summary Account) This Symposium, co-sponsored by the Canadian Institute of Mining and Metallurgy and the Society of Economic Geologists, was held in Toronto, Canada in April, 1970. Over 700 delegates attended from 26 countries. Ninety papers were presented at the symposium and another 18 papers were read by title. The programme included: An Opening Session, Five General Sessions, a session on Remote Sensing Methods, a session on Geochemical Prospecting for Petroleum and Natural Gas, a session on Primary Halos and Lithogeochemical Methods, and a session on Statistics and Evaluation of Geochemical Data. The delegates were welcomed by Dr J. M. Harrison, President of the Canadian Institute of Mining and Metallurgy and Dr C. H. Smith, Regional Vice-President, North America of the Society of Economic Geologists. Dr D. R. Derry of Toronto delivered the opening address to the Symposium entitled 'Geochemistry-the link between ore genesis and exploration'. Dr Derry considered the various hypotheses on the origin of economic mineral deposits and expressed his belief that the next ten years will show evidence of an increased proportion of ore bodies that owe their origin, at some stage in time, to supergene agencies. He stressed that 'there are no sharp divisions between processes that form and destroy ore bodies at or near surface and those that form or destroy them at a depth of 20 kilometres in the earth's crust. The more we understand about the migration and concentration of metals the more accurately we can apply this knowledge to searching for unknown concentrations, whether at rock surface or at depth. To learn more about these processes of ore genesis we must rely on geochemical studies co-ordinated with field observations'. The five general sessions included accounts of progress in geochemical prospecting in different countries of the world, case histories describing the application of soil, stream sediment, geobotanical and biogeochemical techniques, papers on the behaviour of different elements under varied environmental conditions, discussions on analytical methods and the use of stable isotopes in mineral exploration. It is anticipated that the proceedings of the Symposium will be published late in 1970 or early in 1971 as a Special Volume of The Canadian Institute of Mining and Metallurgy. All registrants at the Symposium will receive a copy of this publication and copies will be available for purchase. At a special meeting called during the Symposium, charter members of the Association of Exploration Geochemists approved a constitution and elected an interim Council which will organize procedure and formulate policy during the coming year. The interim president of the Association is J. Alan Coope, Newmont Mining Corporation of Canada Limited, Toronto, Canada. More information on the constitution and membership in the Association will be distributed to learned societies and technical magazines in the near future. Membership will be open to exploration geochemists in all countries of the world. SOUTH AFRICAN COUNCIL FOR PROFESSIONAL ENGINEERS Report on Registration The Professional Engineers Act (Act 81 of 1968) came into force on the 14th February, 1969. At the time it was recognised that the success of the Act would depend in large measure on the extent to which engineers in South Africa would become registered professional engineers in terms of the provisions of the Act. The promulgation of the Act and its provisions relevant to registration were the subject of considerable publicity during 1969. This has resulted in a rate of application for registration far beyond the capacity of the very active committees set up for this purpose by the South African Council for Professional Engineers (SACPE). To give some idea of the task before these committees and before SACPE itself, which must ratify each case,

By J. Rajala

The Kupol mill facility processed a high grade free milling gold/silver ore containing 28.2 g/t Au, 324.8 g/t Ag and approximately 0.5% pyrite during 2008 operation. Gold predominantly occurs a selectrum in the ore and silver is predominantly present in the forms of acanthite, stephanite, pyrargyrite and proustite. Mill start-up was in mid-May 2008 and the mill reached the design throughput of 3 000 tpd in October. The ore was ground to approximately 70%?53 microns. A Knelson Concentrator recovered 9.8% gold and 0.5% silver. The gravity tails reported to a cyanidation circuit that has 14 hours pretreatment and 116 hours leaching. The slurry from cyanidation was then processed by counter current decantation (CCD) thickening to wash and separate the leach residue from the pregnant leach solution. Precious metals are recovered fromthe pregnant solution using the Merrill-Crowe process. The washed CCD leach residue slurry is treated with calcium hypochlorite to destroy cyanide and then sent to the tailings impoundment. Leaching is performed with a new technology called ?CELP? (CANMET Enhanced Leach Process). The Kupol mill overall gold and silver recoveries for 2008 were 95.4% and 85.6% respectively, which were 2.8% and 7.5% higher than targets. Gold and silver extractions in the leach circuit were 94.2% and 84.5% respectively. Leach profiles indicated that gold extraction reached a plateau in the 4th tank while minor silver dissolution occurred in the 5th tank. With the CCD circuit included, total gold and silver extractions increased to 95.4% and 86.6%, respectively. Optimization of the leaching strategy made it possible to reduce sodium cyanide concentration to as low as 410 ppm without compromising precious metals extractions. Silver was effectively leached from the refractory silver minerals because CELP produced more oxidized mineral surface relative to the conventional cyanidation leached mineral surfaces. The average cyanide consumption for 2008 was 1.3 kg/t. The new leaching technology proved to be very robust and performed efficiently even with changes in feed grade and ore mineralogy. Laboratory experiments produced results that were indicative of plant performance. The robustness of the technology and the laboratory test work contributed to the success of the Kupol mill start-up.

Jan 1, 2009

By G. Lyman

The cross-belt sampler is a device that is very widely used even though it has not been ratified by the Standards associations. This paper is concerned with the bias testing of two cross-belt sampler designs against stopped belt samples and a cross-stream cutter at the belt end. The bias analysis is carried out using size distribution as the analyte and conventional t-testing and the Hotelling T squared test, which are compared for their effectiveness. The paper considers the issue of detectable bias and the statistical planning of bias tests.

Jan 1, 2009

By D. R. Hardman, J. W. Oberholzer

Based on information supplied by South African collieries to the Coal Mining Laboratory of the Chamber of Mines since 1978, the paper outlines the general performance of the continuous miners used and gives the results more-detailed studies of the cutting, loading, and transportation processes. On average, the continuous miners produced coal at a rate of 76 t per operating hour, which, at an average machine availability of 67 per cent, resulted in a production of 51 t per total hour. The cutting rates varied between and 250 t/h but, owing to machine and system inefficiencies, the overall production rate varied between 92 and 48 It is concluded that, if the collieries concentrated on improving their machine utilization procedures and operating practices, they could increase the overall production from their continuous-miner sections.

Jan 1, 1987

By J. Gilliland

The Grootegeluk coal-beneficiation plant was erected in the Waterberg coalfield, near Ellisras in the Transvaal, to supply Iscor's steelworks with a predetermined tonnage of coking coal in accordance with strict quality requirements. This plant has to handle a high tonnage of raw coal, which is not easy to beneficiate, in order to produce 1,82 X IQ6t of coal. Extensive tests were conducted on borehole cores and a mass sample of coal obtained from the area. These tests were carried out on a laboratory and pilot-plant scale, and were aimed at the establishment of the most effective beneficiation methods and the choice of suitable equipment. This led to the completion of a full set of design and manufacturing drawings that resulted in the project approach . described in this paper.

Jan 1, 1982

A brief overview is given of the issues regarding the processing of waste electrical and electronic equipment (WEEE). The printed circuit board component of WEEE is an exceptionally complex feed to possible recycling processes. Scrap printed circuit boards were selectively smelted at 1 200°C to produce a metallic alloy. Iron and aluminium were found not to be part of the alloy. The alloy was characterized by SEM-EDS, and three phases were identified: alpha and delta bronzes, and a lead-rich phase. Calculations show that about 56 mass per cent of the alloy is the alpha phase, 35 per cent delta phase and 9 per cent lead phase. A simplified approach using appropriate binary phase diagrams was used to derive a phase composition for the alloy. This was further backed by FactSage calculations, which showed that the simplified approach was appropriate for this alloy. The experimental findings and theory were found to agree well.

Jan 1, 2009

The kinetics of cyanide loss were found to be first order under any given set of conditions, allowing rate constants to be easily determined. At room temperature and in the absence of activated carbon, some cyanide is lost by hydrolysis to hydrogen cyanide, but this does not occur to any significant extent at pH values higher than about 10. A higher rate of hydrolysis occurs when air agitation is used. When activated carbon is present, an additional carbon-catalysed oxidation reaction is responsible for a fairly high loss of cyanide. The evidence indicates a reaction mechanism that consumes oxygen and produces cyanate ion. Some of the cyanate thus produced decomposes to form a mixture of ammonia, carbonate, and urea, depending on the solution conditions. Additional cyanide is lost as a result of the adsorption of sodium cyanide by the activated carbon. At high temperatures, an additional hydrolysis reaction, which involves the formation of ammonium formate as an intermediate, occurs an/j is responsible for. a high loss of cyanide, leading ultimately to the formation of ammonia, hydrogen, and carbon dioxide. The presence of activated carbon has no effect on the rate of this reaction.

Jan 1, 1990

2nd CONGRESS OF THE INTERNATIONAL SOCIETY FOR ROCK MECHANICS The 2nd Congress of the International Society for Rock Mechanics will be held in Belgrade, 21-26 September, 1970. The Congress will include: working sessions, study tours, receptions, excursions introduced in the working sessions and post-congress excursions and special programme for accompanying persons. Anyone interested in rock mechanics and its applicarion may take part in the 2nd Congress. Official languages of the Congress are: English, French and German. Simultaneous translation service will be provided during the Congress. All the correspondence concerning the 2nd Congress of the International Society for Rock Mechanics should be addressed to: Sekretarijat 2. kongresa Medjunarodnog drustva za mehaniku stena Institut za vodoprivredu "Jaroslav Cerni" Bulevar vojvode Misica 43, Postanski fah 530 Beograd - Jugoslavija NINTH INTERNATIONAL SYMPOSIUM TECHNIQUES FOR DECISION MAKING IN THE MINERAL INDUSTRY The Symposium which is to be held in Montreal during the week of June 14-19, 1970, follows the Computer Symposium held in Salt Lake City this year. The purpose of the Symposium is to define the role of decision making techniques within the mineral industry and to stimulate the development of specific applications. The subject of the Symposium-mathematics, operations research and computers as applied to the mineral industry-allows a complete picture of the mineral industry in its public policy, corporate, financial and technological environment to emerge. This is another of the series of symposia on this and related subjects started in the early 1960's at the University of Arizona. Sponsorship has included a number of Universities and the Society of Mining Engineers of the American Institute of Mining. This 1970 symposium is the first to be held outside of America, and is being sponsored by the Canadian Institute of Mining, McGill University and Ecole Polytechnique. A number of delegates from South Africa have participated in these symposia and several have already arranged to attend this symposium in Montreal. Enquiries should be directed to: Secretariat, The 9th International Symposium, Department of Mining Engineering, Ecole Polytechnique, P.O. Box 50l, Snowden, Montreal 248, Quebec, Canada. 24th INTERNATIONAL GEOLOGICAL CONGRESS This Congress is to be held in Montreal, Canada, from August 21 to 30, 1972. A very detailed and extensive programme has been proposed, and includes a number of excursions. Copies of the first circular are obtainable from: The Organizing Committee, 24th International Geological Congress, 601 Booth Street, Ottawa 4, Ontario, CANADA. SYMPOSIUM ON THE RECOVERY OF PYRITE The proceedings of the Symposium on the Recovery of Pyrite, held in Johannesburg on 12th to 13th June 1969 are now available. Copies may be ordered from the Secretary, S.A.I.M.M., P.O. Box 61019, Marshalltown, Transvaal at a cost of R10.00. Papers and addresses presented at the Symposium were: Opening Address by Mr J. K. E. Douglas (President). 'The world sulphur position,' by W. C. J. van Rensburg (Member). 'The South African sulphur position,' by D. L. Taylor (Member). 'The recovery of pyrite at Government Gold Mining Areas Limited,' by R. J. Westwood (Member), G. S. Stander (Affiliate) and H. R. Carlisle (Member). 'Recovery of pyrite concentrates from colliery-waste discards-A preliminary assessment,' by W. A. Gilbert (Visitor) and E. A. Nugent (Member). 'The role of pyrite in upgrading the uranium content of Witwatersrand conglomerate ores by means of the heavy-medium separation process,' by D. J. Tutt (Associate Member). 'Pyrite recovery by jigs at Durban Roodepoort Deep Limited,' by E. J. Dominy (Affiliate), F. Diamond (Affiliate) and A. D. Graham (Affiliate). 'The storage of pyrite concentrates,' by Joan C. Campkin (Visitor) and P. J. Lloyd (Member). 'The flotation plants of the Anglo- Transvaal Group,' by L. A. Bushell (Member). 'Pyrite flotation with amines and cyanidation of the products,' by E. H. D. Carman (Member). 'Gold recovery by cyanidation from mill products obtained after pyrite flotation,' by P. G. Mrkusic (Graduate), M. Sciarone (Visitor) and H. E. Simonsen (Visitor). 'The influence of sulphydral and cationic flotation reagents on cyanidation of native gold,' by K. G. Ashurst (Visitor) and W. P. Finkelstein (Member). 'Laboratory tests on the flotation of pyrite from Witwatersrand gold ores by cationic collector,' by J. Levin (Member), and M. L. Veitch (Visitor). Closing Address, by Dr R. E. Robinson (Director, National Institute for Metallurgy).

By I. H. Clark

A variety of backfills is presently being placed in different gold mines. The backfills are pumped as slurries to stopes where they are discharged into some form of retaining paddock. The effectiveness of fill as a support medium will depend on a number of factors. These can largely include (i) inherent properties of the material, e.g. particle size, shape, distribution and com- position, and (ii) conditions of placement. The terminology required for describing backfills is introduced, and the various laboratory-measured properties are presented for a variety of fills. Finally, the properties of the fills as they are placed underground are discussed.

Jan 1, 1988

ERRATA-AUTHOR'S REPLY IN SEPTEMBER, 1970, JOURNAL: PAGE 52 I. Left half of the page, 4th paragraph, fifth line from the bottom: for 22 / 5 1/2 %, read 22 / 5 1/2 %. 2. Right half of the page, fifth paragraph from the bottom, third line from the bottom: for N(l - p), read N(1 - p)x. 3. Right half of the page, fourth paragraph from the bottom, second line: for: at time t after time zero, read: at time x after time zero. NOTICE TO ALL STUDENT MEMBERS OF THE SOUTH AFRICAN INSTITUTE OF MINING AND METALLURGY The Institute offers each year for competition among Student Members of the Institute a prize, or prizes, should entries so warrant it, of up to the value of R100 to be awarded to the Student Member or Members who submit the best paper or dissertation on a topic appropriate to the interests of the Institute. In the case of Student Members who are in full time study at a university the dissertation or thesis which they may have to write in part fulfilment of their university curriculum may be accepted provided it is presented in a manner and on a topic suitable for publication in the Journal. The closing date for the receipt of papers shall be 31st December each year.

By L. E. Kun, R. O. Oelofsen, E. J. J. van Vuuren

High-rate floc-blanket clarification of gold pregnant rotary filtrate was introduced at the Vaal Reefs South gold plant of the Anglo American Corporation during February 1978. A. daily 12 000 to 15 000 t of filtrate, with an average suspended-solids concentration of 350 mg/I, is continuously clarified to a concentration of less than 2S mg/I of suspended solids in a modified plant pachuca (10 m in diameter) at throughput rates of 7,7 to 8,5 ma/m2.h by the addition of 5 g/t of ferric chloride inorganic coagulant and 0,2 g/t of Superfloc NI00 flocculant. The pachuca overflow is then clarified further in seven Stellar candle pressure filters of 54,S m2 surface area to under 5 mg/I of suspended solids. The combined clarification cost when the hopper clarifier is used in conjunction with the Stellar filters is R0,0032 per ton of liquid treated, which is approximately 60 per cent lower than the cost of Stellar filtration on its own. The savings are mainly due to the reduced use of filter pre-coat, the consumption of which has dropped by 70 per cent since the introduction of hopper clarification.

Jan 1, 1979

By E. T. Boome, A. C. Schmidt

P .E.R. T. and how P .E.R. T. techniques can be used in modern mine management by E. T. Boome and A. C. Schmidt Published in the Journal, December 1972 DISCUSSION A. E.W. FLETCHER A.c.S.A.* In making this contribution to the authors paper, I should first like to congratulate them on the clear and yet detailed way in which they have illustrated their subject. I should also like this contribution to be linked with Mr Hazell's paper "Mine Management by Objectives".

By D. H. Diering

Definition of mineral resources and reserves forms the basis for effective mine planning and reliable public reporting of mineral assets. Historically the mineral resource and reserves declaration process has been the domain of the geology and surveying disciplines, with the declaration of the reserves by the surveyor being based on the application of modifying factors to the declared resources available for mining. As part of an ongoing process to improve efficiency, reliability, and reproducibility of results, this approach has been revised and enhanced through the introduction of a revised process and reconciliation tools. The revised approach to reserve definition is based on the definition of scheduled resources, at an appropriate confidence estimate in the context of an approved business plan, over the anticipated life of the mineral asset being applied to define reserves. This planning and scheduling is developed, during the annual business planning process, by the mine planning department using tools such as CADSMine?. The scheduled area together with the application of revised modifying factors is tabulated in the BME (basic mine equation) and reflects the mine production plan over time. Simplification of the modifying factors to dilution and losses underpins the simple yet robust approach to improved definition of reserves in this process and in the basic resource to reserve equation (BR2RE). Dilution intrinsically affects grade but not metal content, whereas the losses reflect both the efficiency of mining and planning and are reflected in metal losses, area losses, or both. Reconciliation of the derived ?resource converted to reserve? area, (which is based on the business plan from CADSMine?), versus the ?resource available for mining?, (which is derived from Datamine?), underpins the robustness and auditability of the reserves declaration. This R&R accounting and reconciliation approach is transparent and facilitates interrogation of the logic and rationale of long-term business planning and project strategy. These numbers are processed and reported in the logic of the basic resource equation (BRE), which also addresses aspects such as white areas (future and historic), tail management, and partial extraction (non-scheduled pillars, etc.) in compliance with SAMREC definitions. Areas that do not have the necessary confidence and data support to be declared as resources find their space as pre-resource (outside the domain of public reporting), outlining existing potential for future extraction and reporting. Use of the BRE leads ultimately to a complete, refined accounting and reconciliation-oriented approach for all production entities. The revised resource and reserve process includes the discipline of mine planning as intrinsic to the definition and declaration of resources and reserves. Subsequent to the change in process, the resources and reserves have truly become the domain of the mineral resource management discipline. This paper defines the logic of the basic resource equations and outlines their application in the definition and reconciliation of mineral resources and reserves at Anglo American Platinum Limited.

Jan 1, 2012

By H. M. Friede

Iron Age metal working in the Magaliesberg area by H. M. FRIEDE, Ph.D. (Visitor) Evidence of smelting and metal working in the Magaliesberg comes mainly from three sites: Broederstroom (Pretoria District). Uitkomst Cave (Krugersdorp District), and Olifantspoort/Olifantshoek \Rustenburg District). The analyses of copper ores found at or near these sites are reported. as are the analyses of twenty-six samples of slag from the Magaliesberg area and other sites in the Transvaal. Iron implements and copper ornaments found at the Magaliesberg sites are described. and the analyses of some of these specimens are reported and discussed. A metallographic report on two iron objects from Broederstroom points to similarities in the smelting and forging techniques that were practised in the Transvaal and Nigeria during the Early Iron Age.

Jan 6, 1977

By Y. Yang, L. Li, X. Liu

Coal mining in China is facing the transition from output to quality. Based on the total mining capacity and average production, the current situation of coal mining at mine, city, and province levels is analysed, and data in support for the layout of sustainable mining development and the optimization of output provided. The results show that 87% of China's coal is mined by underground methods, with an average production capacity of 0.93 Mt/a per mine. Open pit mining accounts for 13%, with an average mine production capacity of 5.73 Mt/a. The average mining capacity of coal mines in China is 1.05 Mt/a, with 1181 coal mines with an average capacity less than 0.3 Mt/a, accounting for 35% of the total coal mines but contributing only 4.51% to output. They are distributed in about 48 cities in six provinces, seriously restricting the transition to green coal mining. The coal industry should speed up the closure of small coal mines in key provinces and cities, eliminate outdated production capacity in the central region, increase the speed and proportion of coal resources moving westward, and promote high-quality development of coal mining.

Jan 26, 2023

By S. C. Maji, U. S. Chattopadyay, S. Chaudhuri, T. Gouri Charan

India is devoid of coking coal resources, which is a vital raw material for coke making. As a result it has to import about 80% coking coal for steel making. Indian National Steel Policy, 2017 has envisaged crude steel production around 300 million tonnes Mt) by the year 2030-31 and forecasts coking coal demand of 161 Mtpa (million tonnes per annum). One way of improving the indigenous resources is to study the performance of existing washeries and to improve the clean coal recovery by adopting suitable technology. A study was carried out, mainly to focus on the fine coal circuit of an existing coking coal washery, to generate the desired quality of clean coal. The operating coking coal washery being studied is presently feeding coal from nine different sources with varying feed ash contents. The coal fines varied in ash content ranging from 19.5% - 43.6%. For treating the coal fines, the washery has operated a spiral for the past few years. Performance studies were carried out, and it was found that the spiral is not efficient in recovering the cleans. Detailed investigations were carried out on the coal fines using flotation techniques, and it was found that to achieve a low ash clean coal, the froth flotation is a much better beneficiation option than a spiral, The studies showed that the recovery of clean coal through a spiral is 67.7% at ash content of 27.0%, while flotation tests showed a recovery of 68.1% at 16.5% ash content. Keywords: Coking coal washery, near gravity material, spiral washer, froth flotation

Jan 1, 2020

By N. V. Nemchinova, A. A. Kozlov, A. V. Epiforov

The gold dissolution in sulfuric acid media during industrial oxidative leaching test of sulfide gold-copper flotation concentrates has been achieved. The reason for this was using technological water containing thiocyanates and cyanides, which can dissolve gold under these conditions. The carbon in column (CIC) process for gold recovery from these solutions was proposed. However, significant amounts of copper and iron were adsorbed onto the carbon during CIC technology industrial tests. This resulted in a decrease of the gold content in the loaded carbon up to 0.5 kg/t. Further development of the technology was conducted by optimisation of gold and impurities stripping and implementation of carbon reactivation. It was shown, that the copper extraction from the loaded carbon during cyanide treatment was about 95%. The copper content in the stripped carbon after cyanide treatment was 1.76 kg/t. The gold recovery during high-pressure elution by caustic solution was 98%. The hydrochloric acidic treatment with thermal pre-treatment (reactivation) for removing iron and calcium from gold-free carbon was proposed. In this case, the iron and calcium extractions from carbon were 40-45 and 50-55% respectively. These tests showed that for carbon recycling the sequence operations of ‘cyanide treatment, gold elution, thermal pre-treatment, hydrochloric acidic treatment’ can be used. Keywords: Thiocyanate leaching, recovery of gold, carbon adsorption, gold elution, copper stripping, thermal reactivation of carbon, activated carbon, carbon-in-column

Jan 1, 2020

By M. B. Shongwe

Pt-based alloys are being developed for high-temperature applications with the aim of replacing some of the currently used Ni-based superalloys (NBSAs) in the highest temperature applications. The Pt-based alloys have a similar structure to the NBSAs, and since Pt is more chemically inert than nickel and has a higher melting point, they can potentially be used at higher temperatures, up to 1300°C, and in more aggressive environments. Several experimental Pt-based alloys were studied at Mintek, and an optimum composition was found to be Pt84:Ahi:Ru2:Cr3 (at.%). On the basis of hardness and microstructure, a later study identified a new optimum: Ptr8:A111:Ru5:Cr6 (at.%). There are at least two Pt3A1 allotropes, and the high-temperature cubic structure has better properties than the lower temperature tetragonal form, and so needs to be stabilized. This work describes the latest results obtained in transmission electron microscopy (TEM) studies of the quaternary Pt-based superalloys. These results are both interesting and important, because the samples have a higher precipitate density compared to those from earlier work. The precipitate morphology is mainly cubic, with minor areas having irregular-shaped precipitates. The high volume fraction of the precipitates is a major breakthrough, since the objective of this work is to improve the alloys. A prior disadvantage was that the proportion of the precipitates was too low in samples before this work, especially compared with the work from Germany on Pt-Al-Cr-Ni¬based alloys as well as the NBSAs. TEM -Pt3A1 diffraction patterns were studied, and for each diffraction pattern, many possible lattice point combinations were tried, with the angle between the lattice spots as well as interplanar spacings being calculated for each phase (cubic or tetragonal) to match the measured results. An overall analysis of the diffraction results indicates that the cubic phase fitted the experimental lattice points with much lower errors compared to the tetragonal phase. Thus, with the close match achieved with the cubic structure, the structure of -Pt3A1 precipitates is likely to be cubic. X-ray diffraction has been carried out on selected samples, and the results confirmed the presence of cubic -Pt3A1 and (Pt). Different X-ray diffractometers were used to further verify the results, and the results were also compared with those from TEM.

Jan 1, 2012

By I. J. Kotzé, R. T. Jones

Conventional PGM matte smelting requires the presence of a certain quantity of base metal sulphides in order to collect the platinum group metals in a molten sulphidic matte phase in the furnace. Furthermore, the quantity of chromium oxide in the feed materials is controlled in order to avoid the build-up of high-melting chromite spinels in the furnace. Mintek has developed a process for smelting difficult PGM-containing feed materials that contain low amounts of sulphur and/or high amounts of chromium oxide. A DC arc furnace is used to provide the appropriate conditions to generate an iron alloy that collects PGMs very effectively, leaving extremely low residual quantities of PGMs in the slag. Various feed materials have been treated successfully in furnace campaigns running at power levels up to 1.5 MW. The longest of these campaigns was run continuously for more than four months, treating more than two thousand tons of materials such as low-grade concentrates, revert tailings, and converter slag. The campaigns demonstrated the robustness and versatility of the process, and proved that it is possible to sustainably produce a PGM-containing alloy and discardable slags containing an average of less than 1.4 g/t of PGMs over the entire campaign. Keywords: DC arc, smelting, furnace, platinum, PGM, revert tailings, converter slag, ConRoast

Jan 1, 2004