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By B. J. Dalton

This report gives general expressions for evaluating various thermo-dynamic properties applicable to a two-component system, including liquid-vapor equilibria. In addition, expressions are developed for some of the quantities useful in making thermodynamic consistency checks on phase equilibria data. These formulas were developed from the general principles of thermodynamics and are expressed in terms of the compressibility factor, which is assumed to be an explicit function of the molal density, the absolute thermodynamic temperature, and the composition.

Jan 1, 1968

By R. L. Montgomery

Electronegativities of the rare-earth elements were calculated from heats of formation. The values obtained from different compounds varied widely. The postulates of Pauling's electronegativity theory were interpreted for bonds that are primarily ionic; the study showed that many compounds obey rules of the form expected. Revised electronegativity values are given for the more electropositive elements, including the rare-earth metals (which are near magnesium in electronegativity). Estimates of un-known heats of formation are made from electronegativities and are compared with other estimates. INTRODUCTION Calculation of the electronegativities of the rare-earth elements is interesting to show how these metals stand relative to the other metals and to each other, and also possibly to systematize the thermochemical data on them.

Jan 1, 1960

By Larry G. Stolarczyk

This report deals with the creation of an efficient method to determine if command, control, communication and monitoring (3cm) equipment in coal, metal and non-metal mines is susceptible to Radio Frequency Interference (RFI) from the Medium Frequency (MF) radio communications system. A qualitative and quantitative RFT test plan was developed for in-mine and laboratory evaluation of the equipment. The laboratory testing was accomplished using the TEM Test Chamber. Detailed information on the Test Plan and the TEM Test Chamber is included. During in-mine testing of the MF System some underground equipment malfunctioned when the transmitter's radiating antenna was in close proximity. Electromagnetic Compatibility (EMC) testing was done on three levels; Component (circuit or box), subsystems and system. Nine tables are included which show the results of testing various equipment for RFI.

Jan 5, 1986

By Douglas Talley

This report describes a 4-inch diameter borehole probe which contains a low light level TV camera, magnetic compass, light illumination source, bottom/water detector sensor and a pointing angle sensor. The camera viewing angle is at a right angle to the probe's body. All data from the sensor is multiplexed into the closed circuit camera video for transmission on a single 50 ohm coaxial cable to a surface control unit. Likewise control of the probe's power, zoom lens, focus, panning and aperture is accomplished via a down-link multiplexed on the same cable.

Jan 9, 1984

This is an audience, I know, that shares my interest in a subject that is currently getting a lot of attention -the tendency of our Nation to draw increasingly on overseas supplies of certain mineral commodities, and proportionately less on domestic sources for these minerals. That we do obtain substantial quantities of some essential minerals from abroad is easy to demonstrate. That we will continue to do so in the foreseeable future is not in doubt. Uncertainty begins, however, when we try to interpret the significance of these facts. As with many phenomena, their meaning is open to a variety of interpretations.

Jan 1, 1980

By d&apos, Kathleen J. Amico

This summary appears in Minerals Year-book volumes I-II, and III, which cover mineral production in the United States, its island possessions, the Canal Zone, and the Commonwealth of Puerto Rico, as well as the principal minerals imported into and exported from the United States. The sections of this chapter and the area chapters in volume III contain further details on production. A summary table comparing world and U.S. mineral production also is included. Mineral production may be measured at any of several stages of extraction and processing. The stage of measurement used in the chapter is normally what is termed "mine output." It usually refers to minerals in the form in which they are first extracted from the ground, but customarily includes for some minerals the product of auxiliary processing operations at or near mines.

Jan 1, 1967

Graduate education is an integral part of the Center's research program. The scope of. work and the duration of each research project is calculated, in part, by taking into consideration the needs of the graduate research program and graduate training. Full development of student involvement, as demonstrated by the research practicum which is offered to qualified senior undergraduates at Penn State University and is designed to acquaint them with research methods and techniques and inform them of the opportunities available in this field. and the fulfillment of graduate program requirements are of the utmost concern. The Pennsylvania State University and West Virginia University have accredited mining engineering curricula and rank among the schools with the largest enrollment in this area in the nation. The number of undergraduate students enrolled in mining engineering at Penn State and West Virginia University account for nearly 20%, of the total undergraduate enrollment in this discipline in schools across the United States. The Pennsylvania State University. West Virginia University, Massachusetts Institute of Technology, University of Minnesota, and Michigan Technological University, have granted a total of thirty-five (35) doctorate and masters degrees which can be directly attributed to research conducted in the Center.' Of these graduates, fifteen(15) have found employment in the mineral sector of the economy, i.e., in private industry, with government agencies, and at various universities, worldwide. In addition, a number of those graduating with masters degrees are currently pursuing a doctorate degree.

Aug 31, 1989

By Bruce D. Sartwell

The Bureau of Mines is using characteristic X-rays produced by proton bombardment of a solid surface to provide quantitative compositional analyses of surface layers of metals. An integral X-ray yield equation has been developed that quantitatively relates the measured X-ray yield to the thickness of thin films ranging from less than a monolayer to several thousand angstroms. The use of the integral yield equation is demonstrated for the growth of a thin film by vacuum evaporation. Results are presented that show haw proton-induced X-ray emission (PIXE) has been used to determine the oxidation kinetics of iron that had been implanted with several different species of heavy ions. The sensitivity of PIXE for the measurement of very-thin-film growth kinetics is demonstrated from studies of the effect of fractional mono-layer coverages of sulfur on the initial oxidation kinetics of iron. Results are also presented in which PIXE has been used to study the redistribution of alloying elements in components of a gas turbine that had fractured due to corrosion fatigue. By combining PIXE with low-energy ion sputtering, quantitative composition depth profiles of surface layers are obtained. Examples are presented for the profiling of iron samples implanted with 25-kev nickel ions and for a platinum coating on an Fe-5Cr substrate.

Jan 1, 1980

By Jozef S. Stachulak

In This Chapter [Ore pass dust control Drill dust control Blasting dust control Conveyor belt dust control Transfer point and crusher dust control Roadheader dust control and How much ventilation air to use] This chapter discusses respirable dust control in underground hard-rock mines. These mines use a wide variety of extraction methods, but they have many common dust sources and dust control needs. Ore passes, drills, blasting, conveyor belts, transfer points, crushers, and load-haul-dump operations can be major sources of dust. Roadheaders, which are sometimes used in hard-rock mines, produce dust in large quantities. For the most part, dust in hard-rock mines is controlled with ventilation air, water sprays, and dust collectors. It is also important to prevent dust from getting into the air in the first place. Good dust control practices will reduce overall mine ventilation requirements. [Lack of maintenance is the main source of dust problems in hard-rock mines according to Rodgers [1974], who conducted a dust survey of hard-rock mines several decades ago. Rodgers found that spray systems had clogged sprays, dust enclosures had improperly fitted skirts, and ductwork was plugged and had leaks. Today’s mines have better maintenance programs (we think), but when dust levels are high, maintenance is still the first topic to address.] The Mining Association of Canada [MAC 1980] and Knight [1980] provide good general information about hard-rock dust control. For conveyor belt dust control, Goldbeck and Marti [1996] and Swinderman et al. [1997] are valuable sources of information.

Jan 6, 2003

By J. A. Organiscak

Enclosed cabs are a primary means of reducing the silica dust exposure of equipment operators at surface mines. The National Institute for Occupational Safety and Health (NIOSH) has investigated various factor effects on enclosed cab air filtration system performance. Factors experimen­tally investigated were intake filter efficiency, intake air leakage, intake filter loading (filter flow resistance), recirculation filter use and wind velocity effects on cab penetra­tion (inside to outside cab concentration ratio). Adding an intake pressurizer fan to the filtration system was also investigated. Results indicate that the intake filter efficiency and recirculation filter were the two most influential factors on cab penetration. Use of a recirculation filter significantly reduced cab penetration over the intake air filter by itself due to the multiplicable filtration of the cab interior air. Cab penetration was also affected to a lesser extent by intake filter loading and air leakage. Adding an intake pressurizer fan notably increased intake airflow and cab pressure while providing only minor changes to cab penetration.

Jan 1, 2008

By Sabri Ergun

The method of constant compositions involves the determination of the time required for the attainment of a given conversion at various temperatures. Heretofore, it has been used in evaluating the energy of activation only. A development of the method, made in the present study, makes possible the evaluation of the functional dependence upon composition and the frequency factor in addition to the energy of activation. INTRODUCTION Kinetics of reactions are best analyzed in the light of the mechanism, energy requirements, and forces involved in the reaction. Such physico-chemical information is not often available in solid state phase transformations. The reaction rates are followed by changes in a physical property during the course of the reaction, and repeating the experiment at different temperatures permits the determination of activation energy only. The possibility of a complete kinetic analysis by such a purely "phenomenological" approach has been questioned.4/ In this report a method is developed making possible the evaluation of the functional dependence upon composition and frequency factor in addition to the energy of activation. The application of the method to a study of solid state order-disorder changes is demonstrated.

Jan 1, 1960

By J. R. Wait, D. A. Hill

A survey of the literature on ELF and VLF atmospheric noise has been made. Most measurements have concentrated on the vertical electric field and the horizontal magnetic field rather than the vertical magnetic field which is of interest in transmission between horizontal loops. The limited vertical magnetic field data indicates that the vertical component is generally 10 to 20 dB below the horizontal component. Three laterally inhomogeneous earth models have been analyzed for conversion of horizontal to vertical magnetic field. The rough surface model examines surface effects, the inhomogeneous thin sheet model treats volume effects, and the buried cylinder model treats localized man-made effects. All three models predict the possibility of significant conversion from horizontal to vertical magnetic field. A thin sheet model has also been used to examine transmission from a buried magnetic dipole source. It is found that the pre- dicted fields more nearly model the measured data than does the homogeneous half-space model.

By Lisa Steiner, Robin Burgess-Limerick

In 2004, underground coal mines in the United States reported 3,405 injuries to the U.S. Mine Safety and Health Administration (MSHA). Of these, 17 percent were associated with the use of bolting machines, 8 percent with continuous miners, and 4 percent each with scoop/load-haul-dump (LHD), shuttle cars and personnel transport. Analysis of the injury narratives identified five hazards that required attention. They are rock falling from supported roof inadvertent or incorrect operation of bolting machine controls, handling continuous miner cable, collisions while driving underground vehicles and driving or traveling in underground vehicles on rough roadways. The rate of lost-time injuries has steadily decreased during the past 10 years (from more than 10 per 100 FTE in 1995, to six in 2004). However, underground coal mining remains a hazardous industry. One of the contributors to this elevated injury risk is working with or near underground coal mining equipment. Roof bolting machines and continuous miners have been consistently identified as high risk equipment. They account for approximately 24 percent of all injuries to underground coal miners (Sanders and Shaw, 1989). LHD's, shuttle cars and personnel transports are also associated with injuries in underground coal mines (Burgess-Limerick, 2005). Conventional analyses of injury statistics typically provide tables detailing the breakdown of injuries by body part nature of injury or mechanism of injury. Such analyses are worthwhile and may be helpful in tracking broad trends over time. Further information is available in the narrative text field completed for each injury reported. The detail contained in these narratives varies. However, they generally provide some insight into the causes of the injury, such as the activity being performed at the tune of

By Thomas E. Marshall, Gerald L. Finfinger

The Bureau of Mines has developed a practical methodology for deter- mining occluded gas contents of domal rock salt samples. The method, which is portable and field worthy, provides results in 5 min or less and does not require a laboratory environment or specially trained personnel to obtain meaningful results. The results can be used to identify gas-enriched zones, and thus may aid mine operators in production planning or ventilation design. The test method is based on the relationship between gas content and the acoustic response of salt samples as they are dissolved in water. The relationship is defined by an equation, and the results are repeat- able. The equation was derived by testing a series of rock salt samples collected from domal salt mines in Louisiana.

Jan 1, 1987

By Ted C. Briggs

Equations for the elastic pressure distortion of the volumes of a Burnett compressibility apparatus are developed and presented in this report for volumes under internal and external applied pressures. An experimental method for the determination of the external pressure distortion coefficients is presented. Young?s modulus and the internal-pressure distortion coefficients are computed from the experimentally determined external-pressure distortion coefficients. The temperature dependence of the pressure distortion coefficients and of Young's modulus is evaluated for the temperature range 0° to 80° C.

Jan 1, 1968

By Frank A. Peters

This description of process evaluation techniques used by the Bureau of Mines for studying proposed processing techniques has been prepared to provide those interested in using these studies with an understanding of the methodology. The methods used for preparing both capital and operating cost estimates are described. Each step in preparing the evaluations is described. Types of equipment costs are shown and factors used in the estimates are defined. Uses of the estimates are suggested and several examples are included. The accuracy of various types of estimates is discussed, along with an explanation of the reason for selecting the type used in the Bureau's process evaluation studies.

Jan 1, 1987

By J. A. Organiscak

Enclosed cabs are a primary means of reducing the silica dust exposure of equipment operators at surface mines. The National Institute for Occupational Safety and Health (NIOSH) has investigated various factor effects on enclosed cab air filtration system performance. Factors experimen­tally investigated were intake filter efficiency, intake air leakage, intake filter loading (filter flow resistance), recirculation filter use and wind velocity effects on cab penetra­tion (inside to outside cab concentration ratio). Adding an intake pressurizer fan to the filtration system was also investigated. Results indicate that the intake filter efficiency and recirculation filter were the two most influential factors on cab penetration .Use of a recirculation filter significantly reduced cab penetration over the intake air filter by itself due to the multiplicable filtration of the cab interior air. Cab penetration was also affected to a lesser extent by intake filter loading and air leakage. Adding an intake pressurizer fan notably increased intake airflow and cab pressure while providing only minor changes to cab penetration.

Jan 1, 2008

By E. G. King

Cerium and thorium sulfides have found use as crucible materials for melting certain radioactive metals. However, thermodynamic treatment of these sulfides has been hampered by lack of experimentally derived entropy values. This Bureau of Mines report describes heat-capacity measurements between 51° and 298° K, and entropy evaluations at 298.15° K, for cerium monosulfide (CeS), cerium sesquisulfide (Ce2S3), and thorium disulfide (THS2). The entropy values, with Literature results for the heats of formation, are used to obtain free energies of formation at 298.15°K. MATERIALS The samples used in this work were supplied by Prof, Leo Brewer of the Department of Chemistry, University of California. The methods of preparation and some of the physical and chemical properties of these sulfides were given by Eastman and coworkers.3 4/ Chemical analyses, conducted in our laboratory, gave the following results:

Jan 1, 1959

By O. P. Hood

The smoke problem means different things in different places . In the neighborhood of industrial plants , especially smelting plants and cement plants , the term " smoke " is applied to material discharged from these plants , consisting of a mixture of solid particles ( dust ) , fume which has condensed from vapors , and gases of various kinds that are produced in the operations . In the ordinary use of the word , however , " smoke" refers to the visible material which escapes from the burning of coal . White smoke usually owes its color to small drops of water which have condensed from the water vapor that it formed in the burning of coal . When smoke is black, the color is due to unconsumed particles of carbon and usually when the smoke problem is spoken of , it is this black smoke produced in the burning of coal that is referred to , Many inquiries in regard to smoke are addressed to the Bureau of Mines , and the following brief summary has been prepared as covering the usual questions . For references to the smoke problem in England , I am indebted to a recent interesting paper on this topic by David Brownlie .

Feb 1, 1922

By F. L. Wideman

SPURRED by demands of a buoyant economy for mineral products, output from mines in the United States established a new record. Removal of waste material, necessary for the extraction of economic minerals, kept pace with mine production. Earth moving by these two activities exceeded 3 billion tons, an increase of 5 percent over that of 1963. Crude materials from which metal or nonmetal products were derived accounted for 75 percent of the total. The remainder, mostly worthless, was classified as waste. Changes in the minerals industry result from many causes. Technological trends and labor productivity are among several significant and interrelated indexes that assist in the analysis of the changes. Therefore, a. study of productivity is helpful in measuring technological growth in mining. Concepts of productivity tend to vary with the purpose for which the term is used; frequently, productivity is expressed in terms of units of output per unit of labor, such as tons of ore per man-hour or man-shift. Comparisons of levels of productivity for a group of products are usually made using composites of output. Data for all metal and nonmetal mines except gold, silver, mercury, platinum metals group, and sand and grave were used to compile the composite for determining productivity for 1960-64. Copper ore, iron ore, and phosphate rock are mined mainly by surface methods, but characteristics of the deposits and differences in processing the crude material affect production of the commodities. Therefore, productivity data for these selected segments of the minerals industry reflect the influence of physical conditions on the exploitation of them.

Jan 1, 1965