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By R. P. Beyer

A FORTW IV computer program has been written to calculate thermodynamic properties over a desired temperature range from spectroscopic data. This program computes heat capacities, enthalpies, and entropies for monatomic, diatomic, linear, and nonlinear polyatomic gases. This research is part of the Bureau of Mines effort to provide thermodynamic data for the advancement of mineral technology.

Jan 1, 1981

By W. Wallace, T. Ong, M. Gautam, M. Keane, S. Xing, J. Harrison

"Diesel exhaust soots were assayed in the Ames Salmonella typhimurium histidine reversion assay system using TA 98, the soots being applied as the following preparations: dispersion in dipaimitoyl glycerophosphoryl choline (DPL), dispersion in dipalmitoyl phosphatidylethanolamine (DPP!), and dispersion in dipalmitoyl phosphatidic acid (DPPA) in physiological saline, and in physiological saline without added surfactant. The extracts of soots by dichloromethane / dimethylsulfoxide (DCM/BHSO) were also assayed. Studies were performed both with and without :IQ microsomal activation of the soot preparations. The DPP! and DPPA surfactants were chosen as phospholiridz with two palmitic acid moieties esterified to a glycerol as is the case with DPL, but with hydrophilic groups having different electrophilic characters. The soots, without S9 activation, showed mutegenic activity when extracted in the conventional procedure with DCM/DMSO. The mutagenic activity of soots dispersed in DPL was quantitatively comparable to, and in some cases greater than, the activity expressed by an equal mass of soot extracted by DCM/DMSO. Soots in other surfactantpreparations, DPP! and DPPA, also expressed positive mutagenic activity. Praincubation with S9 microsomal enzyme fraction reduced the activity of solvent extracted soots, and greatly diminished the activity of DPL dispersed soots. Initial sister chromatid exchange (SCE) assays using the Chinese hamster V79 cell line indicated DPL dispersed soot also can cause SCR in mammalian cells. Results thus far suggest that surfactant suspended or ""solubilized"" respirable soot particles could provide a mechanism for transport and expression of mutagens in the lung."

Jan 1, 1989

By Thomas M. Barczak

he stiffness characteristics of longwall shields were investigated in this Bureau of Mines study. Since longwall strata activity is characterized by roof-to-floor and face-to-waste displacements, a model with two degrees of freedom was used to describe the load-displacement relationship of the shield structure. The model considers the support as an elastic body and relates horizontal and vertical resultant forces acting on the support to associated displacements as a function of the stiffness of the support structure. Stiffness coefficients under full canopy and base contact configurations were determined by controlled displacement loading of longwall shields in the Bureau's Mine Roof Simulator (MRS). Three two-legged longwall shields of different manufacture were investigated. The stiffness characteristics of these shields were evaluated relative to two parameters, namely, shield height and setting pressure. The test results indicate a reduction in shield stiffness for increasing height. Setting pressure was found to have less of an effect on shield stiffness, producing only a slight increase in stiffness as setting pressure increased. Similar trends were observed for all three shields, indicating a similarity in stiffness characteristics for shields of the same basic configuration.

Jan 1, 1988

By H. H. Schrenk

[A calorimetric method3/ for the determination of benzene in amounts as low as 0.001 m has been developed recently at the U.S. Bureau of Mines Pittsburgh Experiment Station by the authors, with the assistance of chemical personnel from the Allegheny County (Pa.) Relief Works Division. The method is based on the direct nitration of either liquid or gas - phase benzene, followed by neutralization, extraction with butanone, and final treatment with sodium hydroxide which produces a violet color. The color is matched with color standards of known values. Although the method is adaptable to many conditions the primary objective was a procedure that would be suitable for hygienic investigations.]

Jan 1, 1935

By L. W. Kelly

The purpose of this paper is to describe several methods that have been employed in successfully recovering roof bolts in Indiana, Illinois, and western Kentucky coal mines, the States where successful roof-bolt recovery was started. As far as is known, the first bolts were recovered in a mine in western Kentucky in January or February 1951. In April 1951 a meeting was held at that mine to discuss the recovery of roof bolts. The meeting was attended by A. D. Sisk, former Chief, Kentucky Department of Mines and Minerals; and L. W. Kelly, Federal Bureau of Mines; and officials of the coal company. Inasmuch as roof bolting was in its infancy, the thinking regarding roof bolts at that time was on the problem of getting them in, not getting them out; consequently, the thought of recovering them was revolutionary. The subject was discussed at length from all angles, and it was finally agreed that, if certain safeguards were taken, no agency represented at the meeting would oppose the practice. That this decision was sound has been proved, as thou-sands of bolts have been recovered in the Middle West without a lost-time accident. Recovering roof bolts is a simple operation; consequently, no complicated equipment had to be designed or built for this purpose. However, about 5 years ago, officials of the Traux-Traer Coal Co. conceived the idea and constructed a mechanical device for recovering bolts that has been very successful and has been copied widely in this area. This device will be discussed in detail in part II of this paper.

Jan 1, 1958

By George C. Branner

This Bureau of Mines report presents information on the origin, collection, movement, and consumption of iron and steel scrap in California and Nevada. As far as practicable, information is presented on a grade basis. The iron and steel scrap industry in California is important from the standpoint of employment, economic essentiality, and dollar value. About 16,000 persons are either directly or indirectly employed on a full- or part- time basis in the collection, preparation, and sale of iron and steel scrap in California; in 1957 about 70 percent of the tonnage of products of California steel mills, valued at $271 million, was derived from scrap; the value of scrap in 1957 ($117 million) is about $10 million greater than the value of portland cement produced in California that year. The iron and steel scrap industry in Nevada is small.

Jan 1, 1960

By E. D. Gardner

A custom gold and silver plant is one that treats ores for a fee. Usually such plants are located in mining districts and treat local ores. Ores of milling grade generally can stand only moderate transportation charges. These plants are scattered throughout the West. Most plants now doing a custom business originally were built by mining companies to handle ores from their own mires. As excess mill capacity became available ores from neighboring properties were treated, vainly as an accommodation. Later, as their own ore bodies became depleted, the mills were operated entirely on a custom basis. A few plants pull ore from their own mines only when the supply of custom ore is insufficient to keep the mill operating. Some of the present custom plants were built for custom work alone. Although built originally to treat the ores of the Golden Cycle mine, the Golden Cycle plant at Colorado Springs, Colo., soon became a custom mill and has been operating successfully for many years. It is the largest gold mill in the Western States and. treats Cripple Creek ores, from which most of its tonnage still comes. The plant is equipped to treat a great variety of ores and receives shipments from a wide area. It competes with smelters in Colorado, as it has a roasting plant to prepare sulphide concentrates for treatment in its cyanide plant. Most custom mills, however, are not adapted for more than one or two kinds of ore. Gold occurs in its ores both in the metallic state (free) and locked up in sulphides. It also occurs in a few places, notably at Cripple Creek and a few other Colorado districts, as tellurides. Mien the gold occurs in the native state, the ores is said to be free-milling and can be recovered by amalgamation. Usually, however, some subsidiary treatment is required to make a satisfactory extraction. Amalgamation generally was followed by tabling in the earlier mills; at present, flotation has replaced tables at many places. As depth is reached in raining and the workings extend below the oxidized zone the character of the ore usually changes, or, as the miners say, "it gets base". Since the advent of flotation, the average recovery of gold in base ores has been improved-greatly. Cyanidation is applied to some types of both gold and silver ores. The recovery by cyanidation is in general considerably higher than by other methods in vogue and in addition has the advantage of making a finished product which can be sold directly to the mist, thus obviating smelting charges on concentrate and discounts

Jan 1, 1935

By A. F. Colombo

The differences in starch demands that occur between ore types subjected to the anionic flotation of calcium-activated gangue and the range of residual starch contents expected to give the best metallurgical response were evaluated on a batch and pilot plant basis. A phenol-sulfuric acid procedure was used to determine the residual starch contents in the iron ore slurries. Three pilot plant campaigns on samples from a group of orebodies located on the Marquette Range, Michigan, showed that in the rougher flotation pulp, a residual carbohydrate range of 25 to 100 ppm, which is equivalent to a 0.5 lb/short ton spread, yielded optimum results. Concentrates assaying at least 65 percent Fe and less than 6.0 percent Si02 and containing more than 80 per-cent of the recoverable iron were obtained. Both batch and continuous research indicated that starch adsorption is calcium modulated and relatively unaffected by the fatty acid additions employed. Residual starch level is not a critical control factor, but the addition must be adjusted to about 25 to 50 ppm residual starch and kept in this range for most effective utilization of the added tapioca flour.

Jan 1, 1972

By H. H. Lowry

Abstracts of papers on low-temperature tar published since 1942 are included in this selected bibliography. Abstract journals -including Chemical Abstracts, Fuel Abstracts, and B.C.U.R.A. Monthly -have been consulted through 1957. Abstracts of papers on low-temperature carbonization are not included unless information is given on composition, economics, processing, or utilization of the tar; thus, papers reporting only yields of tar from assay tests, pilot plants, and commercial operations are excluded. Listing in the bibliography is alphabetical by authors; arrangement under each individual is chronological. Secondary authors are cross-indexed to the main entry. The subject index uses the main entries: Composition, economics, processing, and utilization with appropriate subheadings. A code letter following the abstract number indicates the country where the paper originated.

Jan 1, 1959

By Hendrik Gerritsen

The research to be described is directed to the construction of an instrument that detects methane in air. The principle on which it is based is that methane gas absorbs infrared radiation in the wavelength range of about 3.2 to 3.4 micron. Solid state p-n junctions of composition In, .97Ca.03As emitting radiation in a band centered at 3.3 micron were grown by liquid epitaxy on InAs. Fight separate growth cycles and a total of 200 diodes were measured to determine total power, wavelength peak, spectral. half width and reproducibility of the method. In order to compensate for temperature changes, dual emitter systems (one InGaAs, and one InAs diode) mounted on the same TO-5 header were made. These devices were imaged, using a folded optical path cell, on large area InAs detectors, grown by a planar diffusion technique. In the 0-50°C range the primary temperature sensitivity is in the InAs detector rather than in the emitters. Several methods to reduce the overall temperature sensitivity to within acceptable limits were demonstrated. Humidity was shown to have a negligible effect on the measurements.

Jan 1, 1976

By R. L. Crosby

The effect of indium on the solid solubility of calcium and of silicon in magnesium was studied using metallographic, X-ray diffraction, and electrical resistivity techniques. The addition of 2 weight-percent or more of indium reduced the solid solubility of calcium in magnesium by forming a compound containing indium and calcium. Indium additions have no perceptible effect on the solid solubility of silicon in magnesium.

Jan 1, 1963

By Thaddeus B. Evans

This information circular is one of a series describing mining methods and costs, being published by the Bureau of Mines. The Sunbright mine of the Foote Mineral Co. at Sunbright, Va., is the southernmost underground limestone mine in the State. It is a comparatively recent operation, and a description of its rapid development to production stage may have particular interest for the limestone-mining industry. ACKNOWLEDGMENTS Acknowledgment is made to the executives of the Foote Mineral Company including F. B. Shay, vice president in charge of production, W. B. Towner, general production manager; and to the members of the company staff at Sunbright for their assistance in preparing this paper.

Jan 1, 1957

By Eric E. Cather

A mineral investigation by the U.S. Bureau of Mines revealed no mines or prospects and no past or present mining claims in the Agua Tibia Wilderness Study Area (WSA). The area is underlain mainly by weakly foliated gabbro similar to rock that has hosted gem- and lithium-bearing pegmatites in the Pala district about 6 mi to the south. However, no gem- or lithium-bearing pegmatites have been discovered in the WSA. Nearby quarries in the gabbro have yielded rock for facing and dimension stone. No sand, gravel, or energy (oil, gas, coal, or geothermal) resources were identified.

Jan 1, 1984

By G. W. Jones

Phthalic anhydride is a solid having the formula C8H4O3. It is an important intermediary in production of anthraquinene, alkyd reins, and plasticizers. The combined annual production of phthalic anhydride reported by 10 major manufacturers for 112,250 tons. The raw materials in the manufacture of phthalic anhydride have been the source of numerous fires and explosions. Consequently, the need was felt to determine the temperature flammability and the ignition temperatures crude basic raw material in most phthalic anhydride production crude phthalic anhydride, and pure phthalic anhydride.

Jan 1, 1950

By John Gross

"Introduction.Southern Illinois and Kentucky are credited with approximately 90% of the fluorspar production of the United States. A small amount of high-grade acid, spar is obtained from the ore by band sorting; the greater part, however, is recovered by jigs and tables as gravel spar containing approximately 85% calcium fluoride. In the jigging and tabling operations, galena is recovered, and enough silica and calcite are removed to raise the calcium fluoride content of the gravel spar to 85%. However, the removal of silica and calcite results in a large loss of spar. With increasing depth in the mines, zinc sulphide, sphalerite, is encountered in increasing quantity and the removal of this has become a serious problem. While the sphalerite can be fairly well removed from the spar by present milling methods, a marketable zinc concentrate can not be made. The experiments described below were made on fluorspar ore from Southern Illinois, by the mining experiment station of the U. S. Bureau of Mines, at Rolla, Mo., in cooperation with the Missouri School of Mines and Metallurgy.The ore tested contained. 7.3% lead, 27.9% zinc, 35.7% calcium fluoride, 9.5% silica and 4.7%. calcite.Tests and Results. In some preliminary tests it was noticed that a portion of the finely crushed ore adhered strongly to the sample pans, and upon investigation it was found that the adhering material was practically clean spar. By utilizing this property of adhesion 46.8% of the spar was recovered as a product containing 98.3% calcium fluoride. This suggested the possibility of using electrostatic separation."

Jul 1, 1921

By E. J. Kloos

The Bureau of Mines devised a new machine-test method for measuring carbon dioxide inspired by a wearer of self-contained breathing apparatus. The new method compares favorably in speed and precision with standard man-tests in which the apparatus is tested while actually worn, and is scheduled for use in future approval tests for facepiece carbon dioxide 'measurements. However, man-tests will still be used to measure the efficiency of the carbon dioxide sorbent materials in closed-circuit breathing apparatus.

Jan 1, 1966

By E. H. Denny

The coal and metal mines of the United States furnish this country with a large part of the fuel and material necessary to support our industries and thus make possible the welfare and prosperity of our people and even the continuance of our present-day scale of civilization. Mining companies furnish material to industry with one general purpose in mind -- the making of a profit on their work. Efforts are being made successfully and continually to reduce operating costs, to increase production per man, and to perform work as far as possible mechanically and with more efficiency. These efforts are made primarily to reduce costs, to increase production, or to do both - in other words to make more profits or more certain profits. In the endeavor to reduce expense companies are considering more and more the factors which enter into costs of production, among them the factor of accidents and their cost. This paper endeavors to estimate the approximate cost of accidents to the mining industry in order to present the saving possible through accident reduction or elimination.

Jan 1, 1929

By H. H. Schrenk

[A colorimetric method5/ for the determination of benzene in amounts as low as 0.001 mg has been developed recently at the U.S. Bureau of Mines Pittsburgh Experiment Station by the authors, with the assistance of chemical personnel fro a the Allegheny County (Pa.) Relief Works Division. The method is based on the direct nitration of either liquid - or gas - phase benzene, followed by neutralization, extraction with butanone, and final treatment with sodium hydroxide which produces a violet color. The color is matched with color standards of known values. Although the method is adaptable to many conditions the primary objective was a procedure that would be suitable for hygienic investigations. The development worth included a study of possible interference by chemicals that be present in those situations in which the method. would be employed. In this study it was found that a specimen of hexane prepared by the Gulf Research Laboratory, Pittsburgh, by fractionation of West Virginia natural gas gave positive result for benzene, whereas a specimen of pentane prepared in the same manner showed only a trace, and specimens of n -heptane and octane (2,2,4 trimethylpentane) supplied by Eastman Kodak Co. save a negative result. According to information obtained from the Eastman Kodak Co. the latter two compounds were highly purified, the n-heptene being prepared from line and the octane synthesized in the laboratory. On nitration of a larger amount of tae natural hexane a visible quantity, of needlelike crystals which resembled those of m-dinitrobenzene was obtained. The hexane from this nitration was recovered by distillation and again nitrated, but no crystals or colorimetric indication of benzene was obtained. This imitated that the specimen of natural hexane contained a substance which at least had the chemical behavior of benzene.]

Jan 1, 1935

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Jan 1, 2012

By John S. Berber

Tar produced as a byproduct from low-temperature carbonization of coal contains only small amounts of valuable lower boiling tar acids but relatively high percentages of high-boiling tar acids. These high-boiling tar acids are characterized by a high degree of alkylation and can be converted into the lower boiling homologs by catalytic treatment to remove the alkyl groups or decrease their chain lengths.

Jan 1, 1965