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By P. G. Barnard

Losses of alloying metals in furnace flue dusts, grinding swarfs, and mill scale produced during the manufacture of stainless steel are substantial. About 25 million lb Cr, 8.7 million lb Ni, and 150,000 lb Mo and other critical metals can be made available annually for recycling by a process developed by the Bureau of Mines. Stainless steel wastes pelletized with a portland cement binder were reduced in a small electric-arc furnace by a two-stage process to produce a recyclable alloy containing Cr, Ni, Mn, and Fe. The initial reduction was with carbon; the second, with ferrosilicon. Results are compared with previously reported laboratory induction melting tests. A 2,000-lb demonstration test of the process in a commercial electric-arc furnace is also described. Data are also presented on three 1,500-lb tests made using various slag conditions in the electric-arc furnace. Recoveries up to 99 pct of the Fe, Cr, and Ni contents of stainless steel wastes were obtained in using the process.

Jan 1, 1977

By George S. Koch

In preparing diamond-drill core samples for assay at the Homestake mine, Lead, S. Dak., 5-foot intervals of core are processed through three stages, crushing, grinding, and pulverizing, and portions of the core material are discarded after splitting at each stage of preparation. Then two 1-assay-ton fractions are taken from the pulverized material and assayed. This report investigates alternative methods of sample preparation. The consequences of crushing, grinding, and pulverizing all rather than part of the core are appraised through the statistical analysis of assay results from 118 5-foot intervals of core. Evidently, a substantial improvement in precision at small additional expense is obtained by grinding most or all of the core before splitting. Pulverizing all of the core would be desirable only if doing-so would cost less than assaying five random splits from each interval. Graphs and tables detail appropriate procedures to obtain specified precisions. The experimental design and methods can be applied to similar problems in preparing core and other geological samples.

Jan 1, 1972

By C. M. Flynn

The Bureau of Mines prepared and investigated xanthated sawdust adsorbents to determine their effectiveness in removing heavy metal ions from dilute aqueous solutions, mine-drainage waters, and brines. Stripping of the metal values from the metal-laden adsorbent was also investigated. The treated sawdusts had an adsorption capacity of 0.3 to 0.4 meg/g dry adsorbent for Mn, Co, Ni, Cu, Ag, Zn, Cd, Hg, or Pb from feed solutions with pH 5 to 6. The feed solutions tested included mine-drainage waters and geothermal brine. Effluent metal concentrations as low as 0.05 to 0.1 mg/l were obtained at effluent pH values of 6 to 9. The order of affinity of metals for the sawdust adsorbent is Na«Ca~Mg~Mn<Zn<Ni<Cd<Pb~Cu. The presence of Ca, Mg, or Na in concentrations as high as 2 g/l does not seriously impair the heavy-metal adsorption. Metals were desorbed from the metal-laden adsorbent by elution with dilute mineral acids, sodium cyanide, or salts of ethylenediaminetetra-acetic acid.

Jan 1, 1979

By Sinisa M. Djordjevic, Isaac A. Zlochower, Kevin J. Liekhus, Cindy A. Loehr, Kenneth L. Cashdollar

An experimental program was conducted to evaluate the accuracy of some current methods for predicting the flammability of gas mixtures containing hydrogen and flammable or nonflammable volatile organic compounds (VOCs) in air The specific VOCs tested were toluene, 1,2-dichloroethane, 2-butanone, and carbon tetrachloride. The lower flammability limits (LFLs) of gas mixtures containing equal molar quantities of the components were determined in a 19.4-1 laboratory flammability chamber using a strong spark ignition source and a pressure criterion for flammability. All but one of the LFL values for the individual components were in agreement with earlier literature values. However, the LFL of l,2-dichlorocthane was found to be significantly lower than the range of values reported for previous determinations in smaller chambers. Two methods for calculating the LFL of mixtures were considered. The Group Factor (atomic) Contribution Method was determined to he generally more accurate than the LeChatelier Method for estimating the LFL of the gas mixtures reported here, although the LeChatelier Method was usually more conservative. The Group Factor Method predicted higher values (nonconservative) for the LFLs of several mixtures than were experimentally measured. For the case of a mixture of hydrogen and carbon tetrachloride, the Group Method estimation of the LFL was seriously in error.

By S. P. Kinney, A. C. Fieldner, S. H. Katz

"1 Introduction The regrettable death of James S. Cunningham, Foreman Miner, attached to Bureau of Mines Rescue Car No. 2, while wearing a half-hour type oxygen breathing apparatus in a gasoline storage tank at Trinidad, Colorado, raised the question as to the possibility of gasoline vapors permeating the rubberized fabric of the breathing bags of such apparatus.It is known that most gases and especially certain organic vapors permeate rubber, by solution or a similar process. The rubber becomes saturated with the gas and if a concentration of gas is maintained on one side of the rubber sheet it slowly gives off gas from the other side. It of course takes some time for the gas to diffuse through the rubber and the length of time before it reaches the other side is proportional to the thickness of the rubber. The amount of gas that passes through per unit of area in unit time increases with the concentration of gas and also varies with the structure and composition of the rubber.It has been suggested that the gasoline vapor could not have penetrated into the interior of an oxygen breathing bag because the pressure is greater on the inside, but this is not true as the process of permeation by solution in the rubber is affected only by the difference in the partial pressures of gasoline vapor on the inside and outside of the bag. The positive oxygen pressure on the inside can only prevent the entrance of gasoline vapor through measurable holes, and has no effect on permeation by diffusion through the rubber."

Dec 1, 1919

Although early Spanish settlers used coal several centuries ago, significant commercial coal mining in New Mexico began in 1861, when the U.S. Army opened a mine to supply Fort Craig. Since then, coal from the state has been used to fuel railroads, lead and copper smelters, and other local industry. In recent years, lower-cost strip mining methods and an increased demand for coal by electric utilities in the Southwest have caused an increase in New Mexico coal production. The coal-bearing regions of New Mexico underlie about 25,000 square miles or20.6 percent of the total area of the state. However, the majority of coal-bearing regions lie under Indian lands that are regulated by the Office of Surface Mining (see Navajo and Hopi data on pages 72-75). Today, most of the coal produced in New Mexico comes from the San Juan Basin in the northwest part of the state and the Raton Area in the north central part. New Mexico&apos;s reserves are estimated to be 4.6 billion tons, about one percent of the national reserve. New Mexico&apos;s permanent regulatory program was conditionally approved December 3 1, 1980. Its Abandoned Mine Lands Program was approved July 17,198 1.

Jan 1, 1992

By E. C. Lane

"INTRODUCTION This is the fourth in a series of reports on properties of commercial motor fuels, made in accordance with a cooperative agreement between the Cooperative Fuel Research (C.F.R.) Committee and the Bureau of Mines of the Department of the Interior. The first report gave data on motor gasolines sold during the winter of 1935-36 3/. The second resort gave the same data for motor gasolines sold during the summer of 1936 4/. The third report of the series gave the same data for motor gasolines sold during the winter of 1936-37 5/.This report covers 63 brands of gasoline represented by 1,136 samples excluding the Pacific Coast. Those from the Pacific Coast were averaged by the Pacific Coast technical group before being submitted and are published exactly as they were submitted. In some areas reports were received from five or six companies on the same brands of gasoline, whereas in other areas only one company reported on a brand. Thus, it can be seen that some of the data are more representative than others."

Dec 1, 1937

By John C. Edwards

Several experimental programs were conducted at the Pittsburgh Research Center to investigate the level of mine fire detection and alarm capability possible using state-of-the-art technology. These programs involved comparison of the response and alarm time of optical and ionization type smoke sensors to smoldering and flaming coal combustion in a smoke chamber. Coal combustion experiments conducted in the smoke chamber demonstrated that a CO concentration of 5 ppm above ambient corresponded to an optical density of 0.022m1. For the four smoke sensors for which a continuous analog signal was available, a smoke sensor alarm was defined as the average background signal plus ten times the peak-to-peak noise. This alarm criterion resulted in the association of the alarm for three of the four sensors with a smoke optical density of 0.022m-1. and 0.033m-1 for the fourth smoke sensor. The smoke sensors used in the smoke chamber studies were incorporated into large scale diesel fuel fire experiments conducted under normal ventilation conditions in the Safety Research Coal Mine (SRCM) at the Pittsburgh Research Center. These experiments showed that a diffusion mode smoke sensor alarmed earlier than a diffusion mode CO sensor; and, based upon the measurement of the optical transmission at the location of a pump mode ionization type smoke sensor that a pump mode ionization smoke sensor alarmed at an average smoke optical density of 0.021m" for the twelve experiments conducted. A series of 30 and 330 kW diesel fuel fire intensity experiments were conducted under zero airflow conditions in the SRCM. It was determined that :(I) thermal sensors are inadequate at 30 m from a 300 kW fire;(2) a diffusion mode ionization smoke sensor can be more effective for mine fire detection than a diffusion mode CO sensor;(3) recommendations can be made for sensor spacing in a mine entry based upon the measured CO buoyancy induced spread rates along the mine roof and the time for a developing coal fire to ignite a conveyor belt.

By J. H. Perkins

The Bureau of Mines has conducted desorption work on fine coal particles at near atmospheric pressure. An apparatus Iris been developed that uses a capacitance manometer to measure desorption of methane from coal particles up to, 2 inches in diameter and pressures up to 1,000 psi. This will make it possible to duplicate the desorption process as it occurs in its natural underground environment.

Jan 1, 1969

By R. F. Abernethy

A small-scale method was developed for determining the free-swelling index of coal samples of limited quantity, especially the macerals. Results of a series of tests using a 0.3-gram sample correlated well with those by the standard method using a 1-gram sample. The standard and small-scale methods are modified to give unrestricted swelling for those coals having swelling index numbers above 7.

Jan 1, 1971

To improve electrical safety and lengthen light bulb life on trolley haulageways. Approach A resistor inserted in series with each pair of light bulbs, decreases the voltage applied to the bulbs and eliminates heavy arcing when voltages rise. How It Works Under certain conditions, incandescent light bulbs connected directly to a 300-volt d-c trolley wire can be a hazard, particularly during weekends when electrical equipment is nut in use. When little electrical power is being used, the voltage (on the trolley lines and at the substation) can rise to a value which will destroy the bulb filament, cause arcing, and damage the bulb holder. In one coal mine where light bulbs in certain locations fre¬quently failed, the problem was overcome by inserting a 100-ohm, 50-watt resistor in series with each pair of light bulbs. The light bulbs are rated at 300-volts and 100-watts. Figure 1 shows the light bulbs and resistor circuit. This resistance was added in order to reduce the current through a short circuited bulb holder, from several hundred amperes to a much safer value of 3 amperes. However, the resistor in series with each pair of light bulbs, also reduces the voltage across the lighted bulbs to approximately 240 volts during periods when the trolley line voltage is up to 300 volts. With this arrangement, no light bulb failures occurred over a 6-month period. The resulting light reduction has not been objectionable.

Jan 1, 1976

By G. T. Brow

An experimental method is described for testing diffusion of gases in crude oils at pressures and temperatures up to 3,000 psia and 200° F. A sampling technique was developed to withdraw by constant-pressure mercury displacement about 60 µl of oil from the diffusion cell through any of several 1/2-in vertically spaced capillary tubes and to trap about 4 µl of the oil in a specially designed microsampler. Oil trapped in the microsampler can be completely inserted in the sample inlet of a chromatograph. From analysis in a three-stage chromatograph (GLC), gas concentration in a sample is determined from the ratio of gas peak heights to area of peaks of reference components (hexanes or heptanes) in the oil. A diffusion coefficient is calculated from measured concentration profiles with known equations for diffusion in finite or semi-infinite systems, depending on whether the gas has or has not reached the end of the oil column. Results are given for a test of methane diffusing at 2,560 psia and 160° F in crude oil from the Weber Sandstone reservoir in the Rangely field, Colorado. A constant diffusion coefficient of 3.34 X 10-5 cm2 per sec was obtained which gives a good fit between calculated and experimental profiles determined at six times after start of diffusion. The maximum standard error of gas concentration determinations experienced with this method was ±0.88 ml per ml of gas-free oil.

Jan 1, 1970

By D. Litton, H. Dobroski, J. G. Kovac

Since 1910, the U.S. Bureau of Mines (USBM) has investigated practical ways of dealing with the consequences of major fires and explosions in underground mines. The results of this research have had a significant positive impact on the mining community by enhancing mine workers’ chances of surviving an underground mine disaster. Today, the Bureau continues to conduct research in mine disaster mitigation. Much of this work has direct application to search and rescue situations, such as: emergency evacuation through smoke-filled or otherwise unbreathable atmospheres, locating and rescuing survivors from rubble piles, and fire fighting in confined spaces. Three USBM research areas are discussed: (1) Life Support -- This effort is directed toward research into and development of closed-circuit breathing apparatus for use in hazardous environments which are likely to be encountered in the aftermath of a mine disaster. (2) Trapped Miner Location -- A mine disaster may result in the entrapment of miners whose normal escape routes are cut-off. This research activity resulted in the development of transportable seismic technology that can be used to locate trapped miners. (3) Mine Fire Diagnostics -- This research involves developing practical techniques for remotely monitoring how the atmosphere inside a mine changes during a fire, in order to estimate the spread and severity of an underground fire. This information is critical in deciding how best to fight a mine fire, or whether it is safe to mount a rescue and recovery mission.

By L. D. Tracy

"Introduction In the course of the investigations by the Bureau of Mines into the various causes of coal-mine explosions, the fact that several gas explosions had occurred during or very soon after a mine was being un-watered, attracted the attention of the Bureau's engineers. The apparent coincidence was so marked that there appears to be an extra hazard present, whenever water, which has been standing against the face of the coal for some time, is suddenly removed either by natural drainage or by mechanical means.Actual Occurrences Case 1. - A typical illustration of this hazard is shown in a gas explosion which occurred in a mine in Central Pennsylvania. Four main entries, 50 feet apart with an average grade of 6 per cent, had been driven with the dip of the coal, and from these mains 7 pairs of entries, at intervals of 800 feet, had been turned at such an angle that their grade was slightly rising. Prom these latter pairs of entries, rooms were turned practically at right angles.The main entries had been driven for 4,500 feet and at the face there was 400 feet of cover. As far as could be observed, the roof was of sandstone and the floor of clay.The coal bed being mined was the Lower Kittanning, which has a thickness of about 4 feet. A typical analysis of the coal in that section is as follows:"

Oct 1, 1924

By Robert C. Hickman

"INTRODUCTION Two holes were drilled on the G. S. Stiner zinc prospect, in the Lead Mine Bend area of Union County, Tenn. The holes were drilled in the vicinity of an area of gossan float and were bottomed in the Maynardville formation of the Nolichucky shale. Drilling was started January 24 and completed February 16, 1947. The total footage drilled was 421.2 feet.ACKNOWLEDGMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, does the actual investigative Work, and prepares the final report. The Metallurgical Branch, Cliver C. Ralston, chief, analyzes samples and makes beneficiation tests.The project was under the general supervision of Mitchell H. Kline, chief, Raleigh Division, Mining Branch, Raleigh, N. C.LOCATION AND ACCESSIBILITYThe prospect is located approximately 20.5 miles southwest of Tazewell, Tenn. It is reached from Tazewell by driving 13.8 miles southwest on State route 33, thence 6.8 miles over graveled roads in a northwesterly direction to Stiner's general store. The drill holes are located in the bottom land northeast of the store (fig. 1 and 2)."

Feb 1, 1948

By Joseph Cervik, J. H. Perkins

The Bureau of Mines has conducted desorption work on fine coal particles at near atmospheric pressure. An apparatus has been developed that uses a capacitance manometer to measure desorption of methane from coal particles up to 2 inches in diameter and pressures up to 1,000 psi. This will make it possible to duplicate the desorption process as it occurs in its natural under- ground environment.

Aug 1, 1970

By C. B. Manula, R. L. Sanford, R. A. Rivell

A central requirement for using simulation models is the need for retrospect testing to validate experimental conclusions. Acceptance of a model by managers and safety practitioners is more likely to depend on its tested performance in-the field rather than on the underlying logic or the validity aspects of the model itself. It is here that simulation bridges the gap between theory and useful design procedures. The original version of the rail haulage sub-assembly was success¬fully tested in the field (Sanford, 1969). However, the case studies that were described here involved single-stage haulage and restricted jobtypes from UGMHS. Since this report together with Volume VI (Production Subsystem) describes extensive changes and modifications to the rail haulage sub-assembly and UGMHS, field tests were necessary to verify both the rail model and the linking concepts to the Produc¬tion Sub-system. Mine Description The candidate mine selected for model verification works the 6 1/2 foot Pittsburgh seam. Shaft openings are used for manways and ventilation and a dual compartment slope for materials handling. In the bottom half of the slope, a hoist with track handles supplies and equipment. In the upper half, a 42 inch belt conveyor travelling at 450 fpm moves coal from a rotary dump to the surface. The immediate roof is shale with the first 12 inches taken during development mining. About 4500 raw tons are produced daily from seven face units and one spare working three shifts. At seven of the sections,

Jan 1, 1974

By Richard V. Ageton

"Everyone admits that there are more accidents in metal mines than there should be but there is much difference of opinion as to the causes of accidents, whether avoidable or unavoidable, and the amount of responsibility attaching to the miner and the mine operator, respectively. However, it seems that one of the main reasons why there are so many accidents, is that there is so little general knowledge regarding their causes and costs. Some information regarding the costs and causes of metal-mine accidents is presented in this paper.The data contained were obtained from a study of the complete accident and medical reports of two large metal-mining companies, which carry their own insurance. Path maintain hospitals with competent medical attendants. One of these companies also maintains a very efficient safety bureau, consisting of a safety engineer, with two assistants who work in connection with the medical department, and with the safety committee made up from among the miners themselves.Daring the year of 1920, ""A"" Company employed approximately 900 men, and these men worked more than 270,000 shifts. There were 373 minor and major injuries, among these 900 men, hence assuming that each injured man was hurt cut once, 41 per cent of the men who worked in this mine received some kind of time-losing injury during the year. On account of these injuries the injured men lost 3731 shifts, and thus the time lost due to injuries amounted to approximately 1.4 per cent of the total number of shifts worked,"

Oct 1, 1923

By Bernard Lewis, Guenther von Elbe

"Explosive gas mixtures are characterized by their ability to undergo a self-accelerating reaction that may culminate in ignition. In the case of methane and air there are two interdependent causes of this acceleration. First, if a sufficiently fast reaction is induced, heat may be evolved faster than it is lost to the surroundings; consequently, the temperature rises and the reaction rate increases. Second, the reaction rate is determined not only by temperature but by the concentration of reactive intermediate products if the latter increases during the course of the reaction the rate will increase. To understand the role of these active intermediates, it should be realized that molecules of methane and oxygen, per se, show little tendency to react with each other even at high temperatures.(1) If, however, free radicals like OH and CH3, are present in the mixture, the methane and oxygen are attacked in the reactions(2):In these reactions the radicals are regenerated, and thus a chain of reactions is set up by an individual radical or chain carrier which is broken only if the latter is destroyed in some process. Not all collisions of a chain carrier with CH4 or 02 result in reaction, since one requirement for a successful collision is that the colliding particles have a certain minimum energy. The percentage of collisions in which this energy condition is fulfilled increases with temperature, so that for equal chain-breaking probabilities the length of the reaction chain increases with increasing temperature. Thus, there exists an interplay of temperature and concentration of chain carriers that determines the reaction rate. To carry the rate to the stage of self-acceleration, higher temperatures are required for lower than for higher chain-carrier concentrations, other conditions being equal."

Sep 1, 1939

By Roy H. Grau, John C. LaScola

This Bureau of Mines report contains a tabulation of methane emissions during 1980 for all coal mines located in the United States with emissions greater than 0.1 MMcfd. Listed for each mine are methane emission quantity, location, and coalbed. The report also compares records of 1975 and 1980 and describes relationships between emissions in 1980 and the Bureau&apos;s coalbed gas content data on 11 mines.

Jan 1, 1984