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By R. R. Hornor

BIBLIOGRAPHY OF ARTICLES RELATING TO THE PRESERVATION

Apr 1, 1922

By A. J. Kraemer

"During the past several years a great deal of discussion has centered around the question of the permissible limit of sulphur content in fuels for automotive and aviation motors. Under certain conditions of operation, sulphur in motor fuels causes the formation of corrosive substances which attack bearings, wrist pins, and other parts of engines. On the other hand, in making gasoline from certain stocks, the gasoline fraction normally contains a relatively large proportion of sulphur compounds. By the generally used processes of reducing the sulphur content, a significant part of the gasoline fraction is lost as motor fuel, and added expenses are entailed for chemicals, labor, and other process costs. This condition has been an economic burden to some refiners of high-sulphur crudes. In some instances the treating losses have been rather severe and the treating costs relatively high, but the data presented in this paper indicate that the reduction of sulphur content of motor fuel is a problem to a relatively small number of refiners and of little or no concern to the remainder; in fact, more than 90 per cent of the 153 samples analyzed passed the Federal specification requirement, Which limits the sulphur content to 0.10 per cent. 3This report is based upon the results of an examination for sulphur content, Doctor test, copper strip corrosion, and color of the samples collected during January, 1930, for the twenty-first semiannual gasoline survey of the Bureau of Mines. The results of the gravity ad distillation tests of the survey were published as Report of Investigations 2995. The numbering of the samples given in this report is the same as in Report of Investigations 2995; for example, No. 25 of this report is the same sample as No. 25 of Report of Investigations 2995."

Jun 1, 1930

By D. R. Tesarik, M. K. Larson, D. K. Denton, J. B. Seymour, R. L. Rains, T. J. Williams

Because backfill has occasionally collapsed into an active working area, posing a hazard to miners, engineers from the Spokane Research Laboratory of the National Institute for Occupational Safety and Health and Hecla Mining Co. installed instruments in a cemented, backfilled, stope-ramp intersection at Hecla’s Lucky Friday Mine, Mullan, ID. The purpose was to measure stress and strain changes in the backfill and reinforcing members during undercut mining. The instruments were monitored for 6 months while three successive cuts were mined below the intersection. Readings showed induced loads up to 3450 kPa (500 psi) in the backfill as stope walls converged 2.5 to 12 cm (1 to 5 in). The backfill then deformed against the top and bottom plates of the 2-m- (6-ft-) long vertical rock bolts installed as reinforcement, producing loads to 177 kN (40,000 lb)on the rock bolts. We hypothesize that a compressive zone was created in the backfill that allowed the backfill to remain stable as long as the compressive zones from adjacent rock bolts overlapped. This hypothesis is presented in graphical form. Of particular interest was the effect of loading on trusses installed to augment the vertical rock bolts and wire mesh typically installed in backfill. Data from the instruments indicate that wall closure perpendicular to the vein induced loads in truss legs parallel to the vein and in the rock bolt driven through the center of the truss, but, because they are designed to function under tension, truss legs perpendicular to the vein supplied in significant support as a result of compressional forces from wall closure. Based on this study, use of trusses was discontinued, and an alternative support system of wood beams and posts was installed as needed to ensure the safety of miners working beneath the backfill in stope-ramp intersections.

Jan 7, 2001

By D. E. Hirsch

The Bureau of Mines, as a part of American Petroleum Institute Research Project 60, Characterization of the Heavy Ends of Petroleum, has made extensive use of gel permeation chromatography (GPC). Data developed in this study were used to develop several correlations that greatly expanded the usefulness of GPC and the data have been used as an aid in the interpretation of mass spectra (MS). GPC retention volume data on pure compounds were used with molecular structure to develop correlations that can be used to accurately predict retention volumes, molecular volumes, densities, chain lengths, and ring numbers of many components of petroleum without resorting to further laboratory experimentation. Conversely, the correlation can be used to select or reject some compounds from several possible compounds that are indicated on the basis of MS analysis. The utility of these correlations in compound type characterization is demonstrated by showing their application to 330° to 550° C fractions from a low-sulfur and a high-sulfur crude oil.

Jan 1, 1974

By Kenneth L. Rubow, Virgil A. Marple

"INTRODUCTION Respirable dust is defined as the dust which penetrates to the alveolated regions of the lungs. Due to the size selective nature of the particle removal mechanisms in the nasal passages and lung airways, criteria defining respirable particles must be a function of the particle size. Three criteria defining respirable particle penetration are shown in Figure 1. These criteria have been defined by the British Medical Research Council (BMRC), the American Conference of Governmental Industrial Hygienists (ACGIH) and German TBF 50-11 (1).The quantity of respirable particles in an aerosol can be measured by use of two-stage samplers. The first stage consists of a particle preclassifier with penetration characteristics corresponding to one of the respirable penetration curves in Figure 1. The large nonrespirable dust particles are removed from the airstream in the preclassifier and the smaller respirable dust particles pass on to some device which can measure their concentration (the respirable dust concentration).Instrumentation for the measurement of respirable coal mine dust has been limited by the severe conditions existing within the coal mine. The conditions of particular importance are the methane atmosphere, high humidity, and the general non-laboratory type environment. The most severe of these conditions is the methane atmosphere since any electronic or electric powered instrumentation must be intrinsically safe to operate in such an atmosphere.In spite of the difficulty of sampling respirable dust within the mines, many instruments have been developed for in mine use. Although these instruments operate under a variety of principles they generally fall within two categories: personal samplers and area samplers.A personal sampler is worn by the mines while he is performing his duties in the mine. These devices are generally small, light weight and require little power so as not to interfere with the miner's ability to work."

Jan 1, 1988

By Richard J. Mainiero, Marcia L. Harris

The New York State Department of Transportation recently commenced highway widening and drainage improvement projects in Clarence and Amherst, NY. Drainage improvements including the installation of storm sewer lines required excavation to a depth of 2.5 m (8.2 ft). In September 2002, NYSDOT stopped further blasting when 800 ppm CO was detected in the basement of a house near the blasting site. At the insistence of NYSDOT, the general contractor developed a new blast plan with the assistance of an environmental consultant. The plan provided for the installation of multi-gas monitors in buildings of special concern and/or with basements and residential type CO monitors in all other buildings within 100m (330 ft) of the blast. The multi-gas monitors would be remotely monitored. The plan provided action levels which would ensure public safety. The blast design was also modified to allow for better venting of CO. Blasts were limited to 20 ft lengths. The overburden was to be removed from the rock and blasting mats put in place to prevent flyrock. Approximately twenty feet of trench adjacent to the blast was left open to allow ground movement and gas release. The use of CO monitors was effective to alert occupants of a building to the presence of CO. The most effective appeared to be the residential type CO alarms with digital readouts. They were simple and easy to use and allowed the public to participate in the process. False alarms were repeatedly received with the more sophisticated instrumentation. Residential type CO monitors are preferable to warn people near blast sites. More sophisticated instrumentation should be avoided unless personnel are experienced in its use. A general overview of the blasting and monitoring is presented and discussed. The use and effectiveness of residential type CO monitors and multi-gas monitors are discussed.

By J. B. Zadra, S. M. Shelton, M. M. Fine

"Ferrograde manganese ore or its equivalent is essential to the manufacture of every ton of steel produced; although it is well known that there are large deposits of low-grade ore in the United States, the production of substantial amounts of ferrograde material from domestic sources presents a problem that becomes more and more critical as the stockpiled ore is depleted through inability to procure adequate supplies from foreign sources. Consequently, a program of laboratory and pilot-plant investigation designed to solve the problem of obtaining a domestic supply of manganese has been undertaken by the Metallurgical Division, Bureau of Mines.This paper is one of a new series that will include reports of results obtained in the various investigations conducted under the manganese program. The scope of the program and the organization that woo set up to direct and supervise the work were discussed in the foreword of the first paper of this series, Report of Investigations 3606, Manganese Investigations. 1. Concentration of Manganese Ores from the Drum Mountain District, Utah, by S. R. Zimmerley, J. D. Vincent, and C. R. Schack. Other reports will be published as the work progresses."

Mar 1, 1942

By Thomas M. Barczak, Christopher Mark

Roof supports can only be understood in conjunction with the rock structure that they support. The strength of the rock depends on geology, and the loads are applied primarily by the in situ and mining-induced stresses. Other factors, such as wider spans and retreat or multiple-seam mining, can also reduce the stability of mine openings. Roof supports are used to help stabilize these openings, but their performance characteristics must be properly matched to the loading environment and ground behavior if they are to succeed. Roof supports include both intrinsic supports, such as roof bolts, and standing supports. The key characteristics of any support include its maximum load-carrying capacity, stiffness, and residual strength. Other important factors are the timing of installation, the stability of the support as it is loaded, and the capability of the support system to provide skin control. This paper explains in practical terms how supports work and the important factors in ensuring that a good support design and application strategy are developed.

Jan 10, 2000

By J. D. Marchant

Solid-state electrotransport of impurities in cerium, lanthanum, and praseodymium, using a pulsed current, was investigated. The results were compared with those of using a steady current. Impurities that showed appreciable movement with the pulsed current, but not with the steady current, were as follows: Molybdenum and oxygen in cerium, aluminum, iron, and molybdenum in lanthanum. The use of a pulsed current enhances the practical application of solid-state electrotransport to remove a wider variety of impurities from the host metals.

Jan 1, 1971

By Nicholas Kyriazi

A performance comparison of 14 rescue breathing apparatus was undertaken as an assessment of past and present worldwide technology. Rescue breathing apparatus are self-contained, closed-circuit breathing apparatus used for entry into areas having atmospheres that are immediately dangerous to life and health. Apparatus tested were the Biomarine BioPak 45, 60, and 240; the Draeger BG 4 and BG-174A; the Litton LITPAC II; the MSA Custom 4500 II Air Mask, Chemox, and McCaa; the Sabre Selected Elevated Flow Apparatus (SEFA); the Scott Rescue-Pak; the Siebe Gorman Aerorlox and Proto Ten; and the SurvivairLP-120. The apparatus were tested on an automated breathing and metabolic simulator at the Pittsburgh Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH). Physiological parameters monitored during the testing were average inhaled CO2 and O2, minimum inhaled CO2, inhaled wet-and dry-bulb temperatures, and peak inhalation and exhalation breathing pressures. The metabolic demand on the apparatus was 1.35 L O2/min for most of the test with two 5-min intervals of 2.5 L O2/min, the first beginning 10 min into the test and the second beginning 10 min before the end of the rated duration of the apparatus. Results presented include apparatus service life and test-averages of monitored physiological parameters. Schematic drawings and photographs of the apparatus are also included. The Draeger BG-174A and BG 4 had the highest durations—295 and 291 min, respectively. The BG 4 hadthe lowest minimum inhaled CO2 levels, attesting to the effectiveness of its CO2-absorbent canister. The SabreSEFA had the lowest average inhaled CO2 levels, due mostly to the apparently low-dead-space mask andnose cup. The MSA Air Mask, the only open-circuit device tested, had the lowest wet- and dry-bulb temperatures, with the liquid-O2-source Siebe Gorman Aerorlox having the next lowest temperatures. The only apparatus with a CO2-absorbent not in a packed-bed design, the BG-174A, had the lowest exhalation pressures. The BG 4 had the highest level of positive pressure, with the Biomarine BioPak 60, Survivair LP-120, SEFA, and Litton LITPAC II nearly as high. The BG 4 had the lowest pressure swing, with the SEFA a close second.

Jan 10, 1999

By J. D. Marchant

The Bureau of Mines studied solid-state electromigration to determine the value of the technique as a method of purifying cerium metal. Cerium metal in bars 6 inches long and 1/2 inch in diameter was refined at 600° C by solid-state electrolysis to remove iron, copper, and manganese. Iron and manganese were electrotransported to the anode and copper was electrotransported to the cathode. The concentration of iron at the anode of a cerium bar was 800 times greater than the concentration at the cathode. The concentration of manganese at the anode was twice the value at the cathode. The concentration of copper was 170 times greater at the cathode than at the anode. A radiotracer technique was used to follow the iron migration in the cerium metal. Molybdenum, silicon, and aluminum impurities were not electrotransported.

Jan 1, 1967

By A. B. Coates, J. E. Crawshaw

"The use of such methods and apparatus as the Dautriche method and the Mettegang recorder for the determination of the rate of burning of black blasting powder and other strictly burning explosives has been found to give such erratic results that no reliance can be placed on the data thus obtained. Consequently, investigators of those factors which may affect the burning rate, such as size of grain, absolute density, chemical composition, and means of ignition have had to rely mainly on observations made during practical use for determination of the part played by each. Such tests are very difficult of interpretation.The purpose of this paper is to describe a method used by the explosives division of the Bureau of Mines for the investigation of such explosives and to present the results of an investigation using that method.The investigation was concerned with the effect of grain size, initial pressure, and means of ignition on the rate of burning or rate of pressure development of black blasting powder as compared with pellet powder.The Bichel pressure gauge was used for these tests, with the slight modification to the apparatus and method described in U. S. Bureau of Mines Bulletin 15.4 These modifications consisted of reducing the speed of the revolving drum on which the time-pressure record is taken, measuring the speed of the drum by a belt-driven tachometer, and introducing an induction coil in series with the electric squib or electric detonator to mark on the time pressure record the instant at which the squib or detonator was fired."

May 1, 1929

By Stuart Lipoff, John E. Trombly, Paul Brien, O&apos

System objectives and design criteria for an in-mine ULF radio paging system are discussed. Coding formats, frequency and bandwidth selection criteria leading to the system design are discussed. The prototype call alert transmitter and pocket page receiver is functionally described. The report includes circuit descriptions, schematics, parts lists, printed circuit fabrication and assembly drawings. The report concludes with an estimate of the manufacturing cost for each assembly.

By F. P. Miknis

Previous studies at the Bureau of Mines have shown that broad-line nuclear magnetic resonance (NMR) techniques have potential applications for rapid evaluation of oil-shale deposits. In a continuation of this study the techniques of pulsed NMR have been applied in a similar manner. The basis for the pulsed NMR oil-shale assay method lies in the assumption that the free induction decay (FID) amplitude following a 90° pulse is proportional to the potential oil yield. This assumption was tested on two groups of oil-shale samples, numbering 141 and 263 samples, from two different oil-shale cores. For both groups of samples a small number were selected as calibration samples. Free induction decay amplitude measurements were made on the 141 and 263 samples. The best least-squares regression line was obtained for the calibration samples, and the oil yields of the remaining samples were calculated using the slopes and intercepts obtained in the regression analyses. The agreement between measured and calculated oil yields was good, the indexes of determination being 0.93 and 0.89 for the groups of 141 and 263 samples, respectively.

Jan 1, 1974

By M. I. Copeland

The investigation of the zirconium-gadolinium equilibrium diagram was part of a program to investigate rare:earth alloys for use as nuclear reactor control materials. Investigation of the zirconium-gadolinium equilibrium diagram revealed a eutectic system with limited terminal solubilities and one peritectoid reaction. The eutectic composition occurs at about 82 percent gadolinium, and the eutectic isotherm, which occurs at 1,220 ±5° C., extends from about 12 to 99+ percent gadolinium. A peritectoid isotherm occurs at 890 ±5° C. and extends from about 2 to 99+ percent gadolinium. The solubility of gadolinium in beta zirconium decreases from about 12 percent at 1,220 ±5° C. to about 2 percent at 890 ±5° C. The solubility of gadolinium in alpha zirconium decreases from approximately 5 percent at 890 ±5° C. to between 2 and 3 percent at 600° C. Vary little solubility of zirconium in gadolinium was indicated. An allotropic transformation of gadolinium was observed at 1,260 ±5° C. A change of the gadolinium transformation temperature on alloying with zirconium was not observed.

Jan 1, 1961

By S. L. May

Tantalum and columbium can be extracted from several of their ores or concentrates by chlorination procedures. Direct chlorination of high-grade minerals in the presence of carbon at temperatures between 500° and 800° C will extract up to 99 percent of the tantalum and columbium. Metallurgical beneficiation of low-grade source materials by carbothermic reduction produces a ferroalloy that is amenable to chlorination at a temperature of 500° C. Over 90 percent of the tantalum and columbium can be recovered.

Jan 1, 1965

By D. H. Baker

THIS REPORT presents the technique and equipment used in determining the hardness of titanium sponge. Detailed descriptions are given of the methods used in preparing test samples for chemical analysis and hardness testing, the method of melting and surfacing test ingots, and the technique of reading Brinell-hardness impressions. The arc-melting furnace described, for which engineering drawings are included, will produce from 70 to 90 double-melted buttons each 8 hours of operation. Experimental data are also presented depicting the effect on hardness of the methods of surfacing specimens, temperature of test specimens, and the effect of time at test load. These data show that surfacing of the specimen involves no critical machining operations but that the test surface must be paralleled by a relatively flat surface for contact with the anvil of the Brinell tester. The heating of a specimen to 150° C. during surfacing does not materially affect the results if the ingot is cooled to room temperature before the hardness impressions are made. The optimum time at load appears to be approximately 30 seconds, but load times of as much as 1/ ½ minutes will not cause major errors.

Jan 1, 1959

By M. W. Price, Joseph V. Mather, E. H. McCleary

"INTRODUCTION The asphyxiation or poisoning of workmen in underground mines by noxious gases from blasting in adjacent strip mines can be prevented.Considerable progress has been made in eliminating or reducing hazards to the health and safety of underground workmen in anthracite mines, but seldom does a year pass without reported cases of underground workmen being poisoned by the fumes from blasts of explosives in strip-mining operations. In the early days of the anthracite industry, the coal near the surface was only partly mined, and many small stumps of pillars and barrier pillars were left standing; these pillars are now being recovered by stripping. It has become necessary to give more consideration to the effects of blasting at strip mines upon the quality of the air in underground mines adjacent to stripping operations.Special precautions are taken by the .personnel of the Jeddo-Highland Coal Co., whose mines are near Jeddo, Luzerne County, and near Centralia in Columbia and Schuylkill Counties in the anthracite region of Pennsylvania, to prevent asphyxiation of workmen by carbon monoxide or other toxic gases resulting from blasting in strip mines. The procedures established by the Jeddo-Highland Coal Co., are given in this circular so that others may benefit thereby and thus avoid hazards to underground workmen where mining is carried on under similar circumstances."

May 1, 1949

By E. S. Shedd

The Bureau of Mines investigated electrowinning and tapping lanthanum metal from lanthanum oxide in a fluoride bath. The electrolyte was composed of LaF3, BaF2, and LiF. Metal containing 0.2 percent impurities was produced at a rate of over 2 pounds per hour. Principal impurities were carbon, aluminum, and silicon. Low-carbon metal was produced by continually discharging the carbon oxide gases and maintaining 0.1-atmosphere pressure. Anode reactions and cell design were found to be important factors in cell operation. Both frozen electrolyte skulls and tungsten metal crucibles proved satisfactory for collecting the metal and did not react with the molten lanthanum.

Jan 1, 1966

By McHenry Mosier

Mercury is one of the strategic metals the supply of which has been raised from critical uncertainty to more than enough for essential demands. Work by the Bureau of Mines has contributes substantially to increased production of mercury in the United States and to consequent accumulation of Governments stock. Other contributing factors were higher prices for mercury and Government loans to operators. The Bureau has undertaken 15 exploration projects, 13 of which have been completed. This work comprised 40,307 feet of drilling arid 35,082 linear feet of sure ace trenching and has indicated commercial ore containing 37,400 flasks of mercury and marginal ore contain¬ing 29,200 flasks - a total of 66,600 flask , equivalent, respectively, to domestic production at 50,000 flasks per year for 9 months , 7 months, and 16 months. Early in 1944, as Government stocks had become adequate, domestic production was gradually curtailed cancellation of Government contracts for the purchase of mercury and Government control of labor and operating supplies.

Jan 1, 1944