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By Rolland L. Blake

Petrographic methods of examination were used by the Bureau of Mines on a suite of samples of ultramafic rock from Soapstone Ridge, Ga., located about 8 miles south-southeast of Atlanta. The samples were analyzed to determine (1) their potential for releasing regulatory particles upon crushing and grinding and (2) their concentration of fibrous particles that approach the dimensions of amphibole and serpentine asbestos minerals. Such particles might be generated during grading and excavation for housing and industrial development and could become a health concern. Light optical microscopy, scanning electron microscopy, and X-ray diffraction were the techniques used to examine the samples. Six of the twelve samples contained amphibole as a major mineral; in five, it was a moderate to minor mineral. One sample contained no amphiboles, and serpentine was not observed or identified by X-ray diffraction in any of the samples. In nine of the samples, the amphiboles exhibited a habit that was either prismatic or acicular, but not asbestiform. Two of the samples did contain asbestos, occurring as small veins or fracture fillings, which represented only a minor percentage of the total sample. Similar petrographic screening is recommended for examining any rock deposit or mine location to delineate hazardous and nonhazardous mineral areas.

Jan 1, 1982

By M. L. Wouden

In the late 1970's, the Bureau of Mines began to examine the criteria for reestablishing vegetative cover on coal strip mine spoils near Glenrock, WY. A 9-acre plot, consisting of (1) spoils covered with topsoil, (2) spoils without topsoil, and (3) spoils treated with sewage sludge, was constructed. These plots were seeded with Tegmar intermediate wheatgrass (Agropyron intermedium), Fairway crested wheatgrass (A. cristatum), and Critana thickspike wheatgrass (A. dasystachyum). After 5 yr, the topsoil had about 70 pct plant coverage. Revegetated spoils, without topsoil addition, averaged approximately 30 pct plant coverage, and sewage sludge-treated spoils had about 45 pct plant coverage. Comparison of grass types showed the intermediate wheatgrass produced greater surface coverage.

Jan 1, 1986

By C. W. DeLong, L. L. Farnham, L. A. Stewart

This paper is one of a series covering mineral resources of the Nation . It describes briefly most of the known manganese deposits of eastern Arizona , which for the purpose of this report includes the counties of Navajo , Apache , Gila, Graham, Greenlee , Pinal , Pima , Santa Cruz , and Cochise . With few exceptions , these descriptions are the result of field examinations by the writers . Work on this paper was begun in May 1956 , and in the following 18 months 151 deposits were examined . The distribution of the deposits by counties is as follows : 1 in Navajo , and 1 in Apache , 37 in Gila , 4 in Graham, 13 in Greenlee , 25 in Pinal , 13 in Pima , 12 in Santa Cruz , and 45 in Cochise . In surveyed areas the locations of the deposits are described by section , township , and range and in unsurveyed areas , by approximate projections of these subdivisions . The township and range numbers refer to the Gila and Salt River base and meridian . The history, production, ownership , geologic setting , and mining methods used are discussed for most of the deposits that were visited . Probably , some occurrences have been overlooked , but all of the principal ones have been examined . Ore dressing studies were made of typical ores from several of the larger districts . The work was performed in the laboratory of the Bureau of Mines Tucson Metallurgy Research Laboratory . The results of these studies are given with the descriptions of the deposits from which the samples were taken .

Jan 1, 1961

Toward the goal of maximizing minerals and metals recovery from domestic resources, the Bureau of Mines, U.S. Department of the Interior, has conducted in situ corrosion studies at the Salton Sea Known Geothermal Resources Area (KGRA) in the Imperial Valley, Calif., to evaluate and characterize materials of construction for geothermal resources recovery plants. General-, pitting, and crevice-corrosion characteristics of 13 commercially available alloys were investigated for periods of 15 and 30 days in seven process environments expected to be found in typical geothermal resources plants. Stainless steel alloy 29.4, Inconel 625, and the Hastelloys G, S, and C-276 were the most resistant to general corrosion, did not pit, and exhibited little susceptibility to crevice corrosion. Stainless steel alloys 430, E-Brite 26-1, and 6X had low general corrosion rates, but pitted and were susceptible to crevice corrosion. Stainless steel alloy 316 L had a low corrosion rate, but corroded intergranularly, pitted, and was susceptible to crevice corrosion and to stress-corrosion cracking. Titanium-1.5 nickel and TiCode-12 had low corrosion rates, did not pit, and were not susceptible to crevice corrosion. Carbon and 4130 steels had high corrosion rates, pitted, and had high susceptibilities to crevice corrosion. The major scale-forming mineral on the corrosion samples in most of the process environments studied was galena mixed with lesser amounts of other minerals.

Jan 1, 1979

By G. W. Marks, A. H. Roberson

"Previous investigation 4/ has demonstrated that some of the aliphatic amines are suitable absorbents for 302, This paper reports the results of physical studies of a number of such amines with the object of determining which is most favorable as an absorbent.Monoethanol amine, diethylene triamine, and triethylene tetramine appear to be the most promising of all the amines studied, and most of this report has been devoted to studies of the physical properties of their aqueous solutions, which contain varying amounts of SO2.PURITY OF MATERIALSAll of the amines used were of commercial grade, because the primary object of this research was the investigation of a proposed works process rather than the accumulation of scientific data.The aminoethyl derivitives of ethylene diamine, namely, diethylene triamine, triethylene tetramine, and tetraethylene pentamine, only recently have been produced commercially. The chemistry of aliphatic amines is complex, and these newer derivitives have not been investigated, completely. Chemically pure material is not on the market, and since definite physical standards have not been published, one could not be assured of a pure product even if the commercial material was refined.The compilation of physical constants for the pure amines would involve much time—consuming effort without materially enhancing the value of this paper, as this work was not devoted to the development of fundamental standards."

Oct 1, 1938

By C. R. Hubbard

The Bureau of Mines investigated the mineral resources of the Upper Missouri River Basin as a part of a comprehensive water and related land resources study by six Bureaus of the Department of the Interior, coordinated by the Department's Missouri River Basin Field Committee. The mineral resource study covers an area of about 18,000 square miles within the Great Plains physiographic province of central Montana. Exposed Formations in the plains are chiefly flat-lying Cretaceous sediments. Plutonic rocks crop out in the central parts of the mountain uplifts, with steeply tilted Paleozoic sediments exposed around the margins. Oil and gas have been produced from several fields in the study area; total value exceeds $45 million. Coal-bearing formations of Upper Jurassic and Cretaceous age cover approximately 45 percent of the study area. Total production of coal since 1880 has been between 40 and 50 million tons, exceeding $75 million in value. Total metal production has been about $52.5 million. Industrial mineral production from 1925 through 1960, is valued at $24 million.

Jan 1, 1964

By C. R. Hubbard

The Bureau of Mines investigated the mineral resources of the Upper Missouri River Basin as a part of a comprehensive water and related land resources study by six Bureaus of the Department of the Interior, coordinated by the Department?s Missouri River Basin Field Committee. The mineral resource study covers an area of about 18,000 square miles within the Great Plains physiographic province of central Montana. Exposed formations in the plains are chiefly flat-lying Cretaceous sediments. Plutonic rocks crop out in the central parts of the mountain uplifts, with steeply tilted Paleozoic sediments exposed around the margins. Oil and gas have been produced from several fields in the study area; total value exceeds $45 million. Coal-bearing formations of Upper Jurassic and Cretaceous age cover approximately 45 percent of the study area. Total production of coal since 1880 has been between 40 and 50 million tons, exceeding $75 million in value. Total metal production has been about $52.5 million. Industrial mineral production from 1925 through 1960, is valued at $24 million.

Jan 1, 1964

By X. Shi, K. S. Kaspnak

"The generation of free radicals from reactions of nickel (Il)-thiol complexes with molecular oxygen and model lipid hydroperoxides was investigated by electron spin resonance (ESR) utilizing 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) as a spin trap. Incubation of nickel (II) [Ni(II)) with cysteine in an aerobic environment generated hydroxyl (·OH) radical, which then reacted with cysteine to generate a carbon-centered alkyl ( · R) radical. Radical generation was inhibited under a nitrogen atmosphere. Model lipid hydroperoxides, cumene hydroperoxide, and I-butyl hydroperoxide enhanced the yield of these radicals and also generated an alkoxyl (·OR) radical. Radical yield decreased by approximately half under a nitrogen atmosphere. Although histidine did not cause radical formation in the reaction between Ni(II) and cumene hydroperoxide under aerobic conditions, the addition of histidine to a mixture containing Ni(ll), cysteine, and cumene hydroperoxide under the same experimental conditions increased the yield of · R radical but lowered the yield of ·OR and ·OH radical adducts. It thus appears that histidine caused the ·OH attack to be more site-specific. Similar results were obtained utilizing 1-butyl hydroperoxide. Penicillamine or N-acetylcysteine yielded similar results except that under aerobic conditions, reaction between Ni(ll) and N-acetylcysteine without hydroperoxide did not generate a significant concentration of free radicals. Under the same experimental conditions, cystine did not generate any detectable free radicals, suggesting an important role of the -SH group in Ni(II)-mediated free radical generation. The results indicate that free radical generation from the reaction of Ni(Il)-thiol complexes and molecular oxygen, and/or lipid hydroperoxides, may play an important role in the mechanism(s) of Ni(II) toxicity and carcinogenesis. INTRODUCTIONWhile nickel is a well-recognized carcinogen [l, 2]. the underlying biochemical mechanisms remain unclear (3, 4). Recent studies suggest that these mechanisms may involve oxidative DNA damage through free radicals, especially the hydroxyl (•OH) radical [5-13]. The mechanisms of nickel carcinogenicity and toxicity may also involve lipid peroxidation [14-21]. Unlike ferrous ion [Fe(II)], the Ni(II) cation itself does not directly react with 02, H2O2, or lipid hydroperoxides to generate free radicals [12, 21]. However, it has been reported that Ni(II) complexes with certain synthetic oligopeptides, e.g., tetraglycine or glycylglycylhistidine, make Ni(II) reactive with 02. This reaction results in transitory formation of Ni(III) and degradation of the organic ligand via free radical reactions [22]. Such Ni(II)-peptide complexes are also capable of reacting with H2O2 to produce oxygen free radicals [11, 12]. Although the cellular environ¬ment may not contain these particular peptide ligands that are known to render Ni(II) redox active in vitro, it does contain a variety of oligopeptides that are capable of forming Ni(II) complexes at physiological pH, and thus may facilitate Ni(II) redox activity in vivo. These oligopeptides include glutathione (y-L glutamylycysteinylglycine), carnosine (homocarnosine (y aminobutyryl-L-histidine), and anserine ( B-alany1-3-methyl-L-histidine)."

Nov 1, 1995

By Roger M. Sherman

[Investigation of mine land characteristics, evaluation of irrigation systems, and evaluations by the mining industry, determined that irrigation is a feasible method for aiding revegetation of coal mined lands in western arid and semi-arid regions. The various regions studied displayed a commonality of characteristics which enables, independent of the site or region, the recommendation of solid set irrigation. Irrigation should be supplemental by complimenting natural precipitation and be should implemented on a temporary basis.]

Jan 1, 1980

By McClelland. John J.

This Bureau of Mines report discusses recent applications of water in-fusion technology to control dust in U.S coal mines and presents recommended guidelines for determining coal seam infusibility. The techniques required to use water infusion are presented in detail. A Bureau case study indicated that water infusion reduced dust levels by 68 pct along a longwall plow face, bringing this section into compliance with the Z.0-mg/m3 Federal dust standard. Similar studies conducted by Occidental Research Corp. under a Bureau contract show water infusion at two longwall double-drum shearer operations produced dust reductions ranging from 38 to 50 pct. Water infusion was found to be cost effective, aver-aging 5 cents per ton.

Jan 1, 1987

High resolution seismic refraction tomography has proved to be a useful tool to effectively estimate depth of blast induced damage in a mine face. Excavation blast damage can be as shallow as 1 to 2m and requires resolution at a fraction of a meter for effective imaging. We used an accelerometer with flat frequency response to 1000Hz to record data at spacings of approximately 0.25 to 0.5m along mine walls. First arrival times from the seismic data were used to produce P-wave velocity tomograms. The tomograms show transition from low velocity zones to velocity associated with competent rock. We interpret the low velocity zones to indicate residual fracturing from blasting. Experiments on a concrete test block and at two underground mine locations give results that are consistent with fractured rock transitioning to competent rock. Our method can be applied efficiently in an underground environment to provide continuous velocity information with depth into a mine wall over a span of approximately 10m.

Jan 1, 2009

By Thomas J. Peters

The Lime Creek study area lies 100 air km east of Boise, and 70 air km northeast of Mountain Home, Idaho. The eastern boundary of the 28,000-hectare, east-west-elongate study area lies 0.2 km west of the 3,077-m-high Smoky Dome. The area is mainly underlain by Cretaceous granitoid rocks of the Idaho batholith. No mineral resources were identified, but two mines and one prospect were found in the study area. At the President and the Last Chance mines, in the southwest corner of the study area, gold mineralization occurs along steeply dipping east-northeast-trending faults and associated quartz veins, and within adjacent Cretaceous granitic rock. The mineralized material is not rich enough to mine underground, and near surface, open-pit-mineable deposit areas could not be identified. The third prospect, the Ventura, is within altered pink granite of probable Tertiary age, but metal concentrations are very low. Geothermal activity was not observed within the study area, but hot springs do occur in the Vicinity. Bedrock observed is only suitable for the most basic high bulk and low end value applications, such as crushed aggregate. Numerous sources for crushed stone occur closer to markets. Alluvial concentrate (placer) samples did not contain free gold, and no substantial alluvial bars were seen; deposits were too small to contain resources.

Jan 1, 1993

Control shearer-generated airborne respirable dust on longwall mining sections. Approach Previous Bureau studies have shown that using high-pressure water can have a significant impact on the amount of airborne dust released into the face airflow while cleaning and controlling the airflow in the immediate cutting zone. The basic concept to improve the drum water spray system was to utilize high-pressure (1,200 psi) inward-facing drum sprays to improve the dust knockdown efficiency of the spray system and confine the dust to the face area. This system would minimize the exposure of the shearer operator through dust avoidance and decrease face dust levels by suppressing the amount of respirable dust that becomes airborne. System Design In-mine tests were designed to provide information that would permit evaluation of the operation with different spray orientations and water spray pressures. This was achieved by comparison with a conventional baseline wet-cutting system consisting of 26 low-pressure bit sprays, located on the hit blocks to provide pick-point flushing. Total drum water flow was 60 gpm and was maintained continuously throughout all tests. The high-pressure inward-facing drum water spray system consisted of sprays located in each bit block, oriented 15° and 30° toward the face. The inward-facing water spray system was operated at either 800 or 1,200 psi.

Jan 1, 1989

By T. S. Chen

A study was made by the Bureau of Mines of the temperature and thermal stress distributions in thin circular disks subjected to peripheral thermal shock at various rates of heat transfer. The theoretical analysis is based on one-dimensional radial heat flow by conduction in the disk, and on heat exchange by convection between the disk and its surroundings. Preliminary experimental data obtained from shock tests on thin circular disks of basalt, quartzite, and taconite show reasonably good agreement with theory. The case of constant properties and plane stress is treated. Solutions of the stress distribution are presented for both cooling and heating shocks. The elastic energy stored at fracture is examined, and on this basis an average stress theory is formulated. Physical properties vital to the studies include thermal conductivity, thermal diffusivity, tensile strength, Young's modulus, and linear coefficient of thermal expansion. This work is of importance in predicting the thermal shock responses of a rock body of finite size.

Jan 1, 1966

By Wallace W. Key

This report concerns types, quantities, specifications, and uses of non-metallic minerals as a basis for improving their supply, conservation, and utilization. Supply-demand details concerning mineral fillers, roofing granules, and roofing rock used in asphalt are incorporated in this report, along with highlights on production and sales of roofing, floor tile, and other related asphalt products of California. Comparable data for the United States are included. Although large quantities of commercially prepared mineral fillers are used in asphalt for paving and related applications in other States, addition of commercial fillers for these uses rarely is required in California because of the natural fines available. On the other hand, California manufacturers of asphalt products other than paving utilize about 300,000 tons of asbestos, diatomite, limestone, mica, soapstone, slate, and other nonmetallic minerals as filler, mainly for roofing and flooring. Also, about 500,000 tons of roofing granules is produced in California, most of which goes into roofing manufacture in California. In addition, a significantly large and growing tonnage of relatively coarse mineral aggregates are used on low-angle, built-up, asphalt roofs to produce an attractive surface and offer protection against the elements. Nearly all minerals used in asphalt products manufactured in California come from local sources, except asbestos and mica--and there are indications that local deposits of these commodities could be utilized in some use categories.

Jan 1, 1966

By W. M. Dressel

The Federal Bureau of Mines has obtained data by differential thermal analysis of the various minerals that represent the nation's resources in manganese. These data are supported by X-ray diffraction analysis, chemical analysis, mineralography, and optical mineralogy, and provide fundamental information on the response of each mineral to thermal treatment in oxidizing, reducing, and neutral atmospheres. The information can be applied advantage¬ously in the identification of manganese minerals. Its greatest potential value, however, lies in the application of the quantitative data on the reaction temperatures, rates, and products to the more efficient extraction of manganese from U.S. ores. Thermal analysis curves are presented for certain manganese minerals, namely hausmannite, bixbyite, braunite, pyrolusite, lithiophorite, cryptomelane, hollandite, manganite, rhodochrosite, and rhodonite. The original minerals and the products of their thermal decomposition were identified by X-ray diffraction analysis, supplemented by chemical analysis and mineralogical identification.

Jan 1, 1961

By Gary L. Hundley

The Bureau of Mines has devised and demonstrated an ammoniacal sulfate leach process for recovering nickel and cobalt from low-grade domestic laterites. Solvent extraction of cobalt, one of the process steps, requires the reduction of hexammine complexes of C03+ to C02+ in an ammo-niacal leach solution. Previously, reduction was accomplished using cobalt metal shot in a column. This report presents experimental results and an economic evaluation comparing two alternate techniques with the shot column: (1) an electrolytic reduction cell with an extended surface area cathode and (2) direct electrowinning from purified leach solution using a cell with a fluid bed cathode. The second alternative eliminates the conventional solvent extraction-electrowinning steps. The costs of the three methods, based on the requirements of a pro-posed commercial-sized plant, including all unit operations, were deter-mined by the Bureau's process evaluation group. The operating costs for the shot column, $1.19/kg Co, and for electrolytic reduction, $1.20/kg, are essentially the same, but the cost of direct electrowinning, $3.77/ kg Co, would eliminate this method as a practical alternative. The cap-ital cost of approximately $14.4 million for reduction in a shot column is much higher than the approximately $4.4 million for electroreduction.

Jan 1, 1985

By R. J. Pokora

This Bureau of Mines report is an applications manual that can be used by the nonmetallic mining industry for guidance in installing noise control materials into crushing and screening plants. These noise control modifications were installed and successfully tested at three operating quarries. This report identifies the major noise sources that can be encountered in crushing and screening plants, and discusses the applicable noise control materials and techniques that a plant operator can utilize on a retrofit basis to reduce equipment noise.

Jan 1, 1984

Since its creation in 1910, the Department of the Interior's Bureau of Mines has pioneered in the development of mineral technology, through research. From the very beginning, research on mine health and safety has been a dominating concern, and a responsibility that expanded markedly as a result of the Coal Mine Health and Safety Act of 1969. Until the mid-1970's research on fuel technology and coal production also was an important part of the Bureau's work. But in the four years following the 1973 oil crisis, Congress established a reorganized Federal energy research apparatus in which all fossil fuel research-encompassing extraction, use, and conservation-was centralized. Today, the Department of Energy houses Federal research on coal mine production technology, while research on coal and noncoal mine health and safety and environmental technology, and on noncoal mine production technology, remains in the Interior Department as a continuing responsibility of the Bureau of Mines. In carrying out its authorized research programs, the Bureau conducts both short- and long-term re-

Jan 1, 2012

By A. L. Engel

[Thi;. re:9ort presents re3ults of investigations of problema a3signed as ore-testing projects to the Ore-Dressing Section, t.fetal1urgica.l Div:biion, of the Bureau of Ii.fines at the .fississippi?Valley E>"'1lcrimcnt Station in rtolla, Ho., durine the fiscal year ended June 30, 1940.]

Jan 1, 1941