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By Nar S. Dalal, Xianglin Shi, Val Vallyathan

"INTRODOCTIONIn an earlier communication 1 from our laboratory it was reported that mechanical crushing of coal and quartz under normal air atmosphere generates of free radicals on the particle surfaces, and that these radicals decay with time, hence pointing to a higher toxicity of fresh dusts in relationship to pneumoconiosis and silicosis. More recently Fubini et al.2 have also reported the detection by electron spin resonance (ESR) of the formation of SiO. and Si-type of radicals from quartz particles crushed under atmospheric conditions. In agreement with earlier ESR studies on single crystals of quartz crushed under high vacuum ( -10-10 torr>3 and subsequent exposure to air,3 and to other gases,4 these radicals were identified2 as being formed by the homolytic cleavage of the Si-0-Si bonds and the reactions of the Si• and SiO- radical with atmosphere. Fubini et al.2 also suggested that these radicals might be involved in the mechanism of the fibrotic action by silica, either by transforming the particle surface into a selective oxidating agent or as an initiator of a sequence of reactions leading to fibrosis. Earlier Gabor and Anca5 bad reported that lipid ·peroxidation caused by free radicals on the silica surface might be involved in the red blood cell membrane damage. Thus far, however, no parallel cytotoxicity, fibrogenicity, and free radica1 studies on a given quartz dust sample have been reported, except for some earlier work from our laboratory.1·6·7 We now present more recent results obtained from parallel cytotoxicity, fibrogenicity, and free radica1 measurements on a freshly made quartz dust. The dust's free radica1 content was measured using ESR spectroscopy while its cytotoxicity potential was estimated via hemolysis. Hemolysis was employed as the toxicity test because it is a widely used method for estimating the potential of a dust for disrupting the cell membrane. 8 The fibrotic potential was followed by measuring the dust-induced lipid peroxidation, using linoleic acid as a model lipid. As discussed below, the results obtained suggest new clues to the mechanism of the quartzrelated cytotoxicity and fibrogenicity. MATERIALS AND METHODSReagentsCrystalline quartz particles with a size range of 0.2-2.5 mm were obtained from the Generic Respirable Dust Technology Center, Pennsylvania State University, University Park, Pennsylvania. These particles were crushed in air to obtain quartz dust samples with particle sizes smaller than 20 microns. We chose to work with a dust with mixed particle sizes, rather than a specific range, as an effort to simulate the mining atmosphere. An agate mortar-pestle arrangement was used for the crushing and grinding because of the close similarity of the structure of agate to that of quartz. Diethylenetriaminepentaacetic acid (DETAPAC) were purchased from Sigma. All other chemica1s were purchased from Fisher or Aldrich.Hemolysls ExperimentsHemolytic activity of silica was measured, following an established procedure,9 as the amount of hemoglobin released from a 2 % suspension of sheep erythrocytes after incubation with 10 mg of silica dust for one hour at 37 °C. The hemoglobin release was estimated via the absorbance at 540 nm using a Gioford spectrophotometer. The procedure was calibrated by substituting the silica dust by a phosphate buffer solution as a negative control (background) and O.S % Triton-X-100 as a positive control (100% hemolysis). The percentage of hemolysis was calculated as follows:"

Jan 1, 1990

By J. C. Fowler

[This i.untra t hds bmii III c'IIILt fur till- past 1':?:u yrlr;, Till-- wurir pnrfor rw:it '. ,JS hlui.rn dawn Ilttf lit Iu i eel i ih?IS( S. 1 hesrt aIII, Phase I Candor tlri I a lest It) donurnSlrale SeiSrrlir nurihudS to hu USi!d lot ttlr? rti?tei thin and Iu" ainnl ul trapped rrlinc:rs hitting (-)it the roof with a harnrner, Phase I' Design and cunStrur.t a permanent Seismic monitor System to rrlunrtur roof (ails arm r:xploslun', III ,r 'Vol king mine. Phase III - Ire dII an an i i irr for sVstl rtl Ii i`'Smltur air quality in till, niitii iiH II ? ir,iti tin; niln !III ;I I ,, i; Phase I V - Conduct 11(21 d tests of the seismic IT IUnit UT ieq system fur a period nl two 11IUIIIIIS. Phase, V - Condirct three test periods of the seismic system over a period of six mimilis. Detailed reports covering the wurk. done in Phases I, 11, and IV have been i : . r tr I - i t report will, therefore, cuni.entrate on the work perfurmed in Phases III anti V.]

Jan 1, 1975

By Lucia Kuizon

The Pinnacles Wilderness Contiguous Wilderness Study Area (WSA) (CA-040-303) is 30 miles south of Hollister, CA, in San Benito and Monterey Counties. It is composed of five parcels of public land totaling 5,838 acres adjacent to the Pinnacles National Monument. The U.S. Bureau of Land Management later reduced the size of the Recommended Suitable Area (RSA) to 2,200 acres. U.S: Bureau of Mines personnel examined the entire WSA in May 1984. The WSA is underlain by Tertiary sedimentary and Cretaceous plutonic rocks. Diatoms occur in interbedded tuff, shale, and sandstones in the northern part of the WSA, but outside the RSA. In 1984, there were no mines, prospects, mining claims, leases, or mineral resources in or within one mile of the study area. No energy minerals were identified; however, an oil well was drilled in 1951 in the northern part of the WSA, but outside the RSA; it was a dry hole.

Jan 1, 1985

By F. Keith Shelton

"INTRODUCTION Cobalt is an essential metal in the normal industrial ac¬tivity of the United States. Being an important constituent of high-speed steels and other cutting-tool materials, it becomes of critically essential importance during periods of national emergency. 3/ The Presidential order of December 20, 1940, included cobalt among other essential commodities that could be exported only under license. The Executive order 4/ listed cobalt metal, cobalt oxide, and alloys containing more than 5 per¬cent cobalt as being within the licensing requirements.There was no domestic marketed production of, cobalt products from 1931 until 1940 when the Pyrites Co. 5/ produced some cobalt oxide. The major portion of the domestic cobalt requirements has been obtained from Northern Rhodesia, the Belgian Congo, and French Morocco. 6/ The uncertainty of sea transportation from those sources of supply demanded that steps be taken to obtain from domestic raw materials an adequate supply of cobalt for use in the materials required for production of indispensable machined war metal products. In connection with the national policy for attaining self-sufficiency of strategic and critical materials, the Bureau of Mines, Boulder City, Nev., Experiment Station initiated studies to recover cobalt from the low-grade oxidized cobalt deposits in the Goodsprings district, Nevada. Hewett 7/ reported occurrence of cobalt specifically in the Blue Jay, Columbia, Copper Chief, and Highline mines and generally over a widespread area in the district."

Jan 1, 1946

By Donna lynne Anderson

This report documents the status of a laser-based underground guidance system for tracking and controlling the movements of underground mobile mining equipment. This research is part of a multiple project effort at the U.S. Bureau of Mines to increase mine safety and efficiency by developing technology for computer-assisted mining. Guidance systems, which can track and control the movements of underground mining equipment, are essential during computer-assisted mining operations. A continuous mining machine at the Bureau's surface test facility served as the test-bed for initial development and experimentation of this guidance system. Subsequently, a continuous mining machine in an underground mine served as the platform for in-mine experimentation The first section of this report includes details of the laser sensors, communication network, and computer hardware. The next section includes experimental results, which show the system capable of accurately tracking and controlling the tram maneuvers of a continuous miner underground. The final section discusses conclusions and recommendations.

Jan 1, 1992

By Thomas J. Peters

The U.S. Bureau of Mines and the U.S. Geological Survey are responsible for the evaluation of the mineral resources and potential of further planning areas included in the U.S. Forest Service Roadless Area Review and Evaluation (RARE II) program. The Bureau of Mines primarily evaluates mineral deposits and prospects within the areas. The Geological Survey naps the area's geology and conducts geochemical sampling. Evaluations are in conformance with the Forest and Rangeland Renewable Resources Planning Act of 1974 as amended by the National Forest Management Act of 1976. The Hauser RARE II area, which consists of 7,600 acres (3,100 ha) within the Cleveland National Forest, is in southern San Diego County, California. The area, which forms the north slope of Hauser Canyon, ranges between 1,600 and 3,919 ft (490 m) in elevation. It is sparsely to densely covered with desert shrubs. The area is underlain by granitic rocks of the Peninsular Ranges batholith.

Jan 1, 1983

By James C. Barker

Unverified reports of rare earth element (REE) concentrations in gold placers and radioactive mineral prospects in the Zane Hills were investigated by the U.S. Bureau of Mines as part of the Alaska critical minerals program. REE is reported to occur in dredge concentrates at the Hogatza mine and up to 1.2 pct REE was previously analyzed in alkalic syenite (bostonite) dikes marginal to the pluton. In addition, numerous thorium-rich veins, explored for their uranium content but unevaluated for REE, occur on the western margin of the Zane Hills. The Bureau mapped and sampled all of the reported or suspected REE occurrences. Dredge concentrates contain abundant uranothorianite, a mineral species which incorporates cerium subgroup REE. Bostonite dikes occur in conjunction with a multi-phased zoned alkalic intrusion, however, no significant REE concentrations were found. Thorium-rich veins contain nil to 0.5 pct Y but resource potential is limited by this relatively low grade, the ultimate low tonnage potential, and the lack of uranium as a major economic element. The Zane Hills exhibit attractive exploration targets for uranium deposits, primarily in a sedimentary form. Gold may be found peripheral to the pluton in both placer and lode deposits. Resource potential of REE, however, appears limited to a placer by-product of REE-Zr-Ti that is recoverable only during large scale gold placer mining. Placer exploration of the lower Wheeler and Dakli Creeks is suggested.

Jan 1, 1991

By David A. Lipton

U.S. Bureau of Mines personnel examined mines, prospects, and mineralized areas to determine the mineral resources and potential of the Moses and Dennison Peak RARE II areas in Tulare County, California. These areas, along the west slope of the Sierra Nevada, are underlain by grarnitic rocks of the Sierra Nevada batholith and contain numerous metasedimentary roof pendants. Silver, copper, and zinc occur in contact-metasomatic deposits within the metasedimentary rocks. In the Moses area, the Powell Mine (fig. 1) contains an estimated 90,000 tons (82,000 t) of subeconomic silver, zinc, and copper resources. The King Solomon Prospect has 3,000 tons (2,700 t) of silicified phyllite containing zinc. On the Helen-Joyce Prospect, 44,000 tons (40,000 t) of gossan occur above a poorly exposed silver-zinc rich zone. Potential exists for additional mineral resources and occurrences at each of these properties.

Jan 1, 1983

By Jerome Apt

This manual has been prepared fur the help and guidance of underground coal mine operators. It details both common and unique engineering methods by which the respirable dust, which is generated in coal mines, can be controlled. This document was compiled by Apt, Bramer, Conrad and Associates, Inc. under contract number H0111464, issued by the U. S. Bureau of Mines and forms Volume II of the final report. This contract was authorized by and executed pursuant to the Federal Coal Mine Health and Safety. Act of 1969 (P. I. 91-173; 83 Stat. 742).

Jan 1, 1972

By R. R. Sayers

The contemplated use of dichloro-difluorco methane in domestic and commercial refrigerating appliances and in air-conditioning equipment for public buildings and possibly homes, brims attention to the health hazards involved in a wide potential exposure of the public to vapors of another new product, and for the first time to vapors of an organic fluorino compound. The objective in the development of this new refrigerant, however, has been the mitigation of health and explosion hazards in automatic refrigeration, and accordingly these factors have been given primary attention. Early in the development, the Bureau of Mines as requested to make a laboratory study of the toxicity and potential hazard, and it was ca the oasis of the results is of this work and the results of a preliminary investigation made in another laboratory6 that the compound has been selected for commercial use. The investigation conducted by the Bureau of Mines is still in progress, enough information has been obtained to indicate the order of the toxicity and the magnitude of the health hazards involved in the use of dichloro-difluoro methane as a refrigerant. The following is a summarized report of the work completed to date:

Jan 1, 1930

By Terry R. Neumann

During 1983, U.S. Bureau of Mines personnel examined mines, prospects, and mineralized zones to evaluate the mineral resources and potential of the Funeral Mountains Wilderness Study Area (WSA), Inyo County, California. Eleven mineral properties and two mineralized zones were examined during this study. Of these, six are within the study area and seven adjacent. There are no active mines, in the WSA, nor is there evidence of past production from any claim within the study area. The WSA contains no identified mineral resources. However, occurrences of bentonite, zeolites, and strontium were found in the area. There is little likelihood for resource development of any occurrence in the WSA. The area, in the Basin and Range Physiographic Province, is dominated by a Paleozoic marine sequence. Segments of Tertiary continental fluviolacustrine sediments, including volcaniclastic rocks, abut and overlie the Paleozoic rocks in fault controlled basin areas. Significant concentrations of bentonitic clay and zeolites occur as alteration products in Tertiary tuffaceous sedimentary rocks. However, they are generally low-grade, thin, and discontinuous, precluding commercial development. Limestone, quartzite, and sand and gravel in the area are suitable for many types of construction uses, but similar deposits outside the WSA are closer to markets. No energy resources have been identified in the WSA.

Jan 1, 1984

By E. H. Izen

A thermal imaging borehole probe was designed and fabricated for the purpose of obtaining thermal images, through smoke, of objects and people in underground mines. The effort was basically unsuccessful; electrical noise, and possibly thermal noise, interferred with the desired signals to the extent that spatial resolution in the images was unacceptable.

Jan 1, 1980

By C. Melvin Lepper

The Bureau of Mines has developed an improved earth resistivity field system which employs a novel technique for obtaining null measurements. The instrument is designed to operate reliably in high-noise environments such as those found in the vicinity of operating mines. The system consists of a low-frequency transmitter, a sensitive receiver and an external battery pack, each in its own case to provide protection from the elements. The receiver and transmitter units have self-contained recharge-able batteries to supply power to the circuitry and separate built-in battery chargers that operate on standard 115 Vac power. The system is portable and simple to operate. Measurement accuracy, reliability, and dynamic range are superior to most commercially available equipment even though less time and effort is required to make null readings. Unlike some commercial systems, long integration times are not required to enhance signal-to-noise ratio in areas of high background noise.

Jan 1, 1974

During the initial portion of the contract several alternative designs were considered, as set out step by step in the monthly reports. The conclusions reached during this period were - to use on INTERDATA Model 70 as the system minicomputer - to drop the idea of multiplexing and digitizing the inclinometer outputs downhole due to the greater complexity and cost that that alternative would imply - to use a multitasking software monitor to enable synchronization of the several tasks that the system would have to perform simultaneously - to use a common controller for all I/0 devices except those which were available off the shelf from Interdata - to use a sheave counter to meter off equal increments of probe travel, but to supplement this information with the use of an encoder on the winch drum in order to be able to measure total probe travel unambiguously. - to place all I10 device interfaces in a bin connected to the common controller. During this period considerable attention was dedicated to the design of the mechanical components contemplated it the original contract. Of these, only those required for vertical probe was complete at the time that it was decided to forego the mechanical subsystem and concentrate on developing the necessary electronics and software to interface with the probes being developed by the Bureau of Mines.

Jan 1, 2012

By E. G. Valdez

Three cryogenic systems that utilized liquid nitrogen, dry ice, and methanol with dry ice were investigated in conjunction with crushing and classifying techniques. The systems were used to aid in separating and reclaiming the metallic components contained in insulated wires, shredded automobile nonferrous metal concentrates, small motors, generators, and rubber tires. Wire strands, 2 to 6 inches long and insulated with polyvinyl chloride and neoprene, were chilled at -60° and -195° C, then roll-crushed and processed by water elutriation; this procedure resulted in two products--a sink fraction that was 99 percent metallic and a float fraction that was 99 percent nonmetallic. Excellent separation of zinc die-casting alloys from copper and aluminum contained in shredded automobile nonferrous metal concentrates was attained by chilling at -72° C for 1 minute, crushing in a grateless hammer mill, and screening. From the screened products, 97.2 and 100 percent of the copper and aluminum, respectively, were recovered in the plus Pinch fraction, and 100 percent of the zinc was recovered in the minus 1-inch fraction of over 97 percent zinc die-cast purity. Laboratory experimental results comparing direct and indirect chilling indicated that a sufficiently low temperature could be attained by indirect chilling to permit use of a liquid C02-dry ice system on insulated wires and mixed nonferrous metallic concentrates.

Jan 1, 1973

By Thomas A. Giordano

Portable communications equipment is becoming increasingly important in underground mining. Proper selection of microphones and hearing devices to be part of these communication systems is essential if the messages are to be transmitted intelligibly. In this program a thorough study of the requirements for these transducers was made with respect to intelligibility, mechanical configuration, human factors and safety. A computer analysis was made to predict how several combinations of transducers would perform at typical mining noise levels. A survey has been made of those microphones and hearing devices on the market today that might be applicable to the miner communication system. Several systems are proposed and evaluated.

Jan 1, 1976

By Jesse L. Hoyer

A Bureau of Mines turbomill was evaluated for use in the production of high-purity, ultrafine x-Sic powders suitable for advanced ceramics that could substitute for high-temperature alloys containing critical materials such as chromium, cobalt, and nickel. The effect of milling param-eters, such as type of dispersant, temperature, pH, and gas environment, on the milling of x-SiC was studied. The addition of dispersants improved the grindability of x-SiC. Of the six dispersants studied, the best results were obtained with Mara-sperse N-22. Grinding efficiency was also increased when the x-SiC was milled in a basic slurry and at elevated temperature. Gas environments did not appear to affect grinding of x-SiC. Optimum grinding efficiency was obtained at 50° C in a slurry at pH 9.5 with Marasperse N-22 as the dispersant. Under these conditions, minus 100-plus 200-mesh x-SiC was ground to 80 pct less than 1 um in 4 h.

Jan 1, 1987

By Steven W. Schmauch

A mineral survey by the U.S. Bureau of Mines and U.S. Geological Survey indicate the Blanco Mountain RARE II area has low potential. Lode deposits consist of small, mineralized quartz or quartz-gossan veins. The veins are sparse and widely separated and lead, silver and gold content is restricted in amount and concentration. No gold or other potentially economic minerals were found in a placer deposit. There is no evidence of industrial mineral, geothermal, or energy resource potential in the study area. INTRODUCTION A mineral resource survey of the Blanco Mountain RARE II area (No. 5059), Inyo and Mono Counties, California was conducted in July 1981. This report summarizes the results and interpretations of the Bureau of Mines investigation.

Jan 1, 1982

By H. R. Babitzke

The purpose of this investigation was to develop an alloy of columbium for use at high temperatures and for nuclear applications. The properties of possible alloys were determined, and the more promising ones were selected for further improvement. Criteria for selection were machinability, hardness, workability, tensile strength, and oxidation resistance. Thirteen 100-gram ingots, ranging from 100 percent columbium to 100 percent vanadium, were prepared and subjected to various tests. Also included for comparison were zirconium and the zirconium alloy, zircaloy-2. Test results showed that a columbium alloy, containing 10 atomic percent vanadium merits further development. Besides being workable at room temperature, the columbium-10 atomic percent vanadium alloy has oxidation resistance superior to the other alloys of the series and is also superior to zirconium or zircaloy-2. The latter two materials have comparable neutron-absorption cross sections. The strength and hardness values of the alloys tested were found to increase with increasing vanadium content, reaching a maximum at 50 atomic percent vanadium and decreasing with further increase in vanadium. This behavior is typical of binary alloys wherein each element will retain any proportion of the other in solid solution. INTRODUCTION There is an increasing need for alloys for service at high temperatures. Since current world reserves of columbium metal approximate 1,500,000 tons (1),4 this metal is now readily available. Columbium can ties; be considered a practical base material for high-temperature alloys required in nuclear reactors and in aircraft and space vehicles. General requirements chosen are: (1) Workability, (2) satisfactory mechanical properties at temperatures approaching 1,000° C., and (3) resistance to oxidation at such temperatures.

Jan 1, 1962

By James W. Hendrix

A survey of endomycorrhizal fungi occurring on orphan coalmine lands in Western and Eastern Kentucky revealed a great diversity of species present. Thus a large number of fungi are available for isolation and evalution for enhancing revegetation of mined land. Endomycorrhizal fungi isolated from orphan mines stimulated growth of sweetgum seedlings on mine soil at low fertilisation but inhibited growth at high fertilization; this growth inhibition at high fertilization did not occur with plants growing on peat-perlite. Banding of endomycorrbizal inoculum was not advantageous, compared with incorporation of inoculum throughout the growth medium, for production of mycorrhizal sweetgum seedlings. Newly reclaimed mine spoils were nearly nonmycorrhizal, compared with land reclaimed four or eight years earlier. A procedure for isolation of single-spore cultures of endomycorrhizal fungi was developed; this procedure is necessary for studies of ecotypic variability. A practical procedure using container-grown Pisolithus tinctorius-infected shortleaf pine seedlings for production of large numbers of bareroot pine seedlings infected with P. tinctorius for mined land reclamation was demonstrated.

Jan 1, 1982