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By Liu Tao, Wang Wei, Liao Wenjiang, Yang Weiyan, Tang Bin

Side-blown Furnace technology is a developing technology and was developed very quickly in China in recent years, dozens of reference smelters can be found for the treatment of copper concentrate, copper slag, Lead slag, zinc leaching slag and different kinds of slurry. This paper introduces the working principle of the technology, displays the innovations and specifications of China Nerin's SBF technology, gives examples of the typical reference smelters, and looks ahead to future applications. INTRODUCTION Side-blowing furnace smelting process The side-blowing furnace smelting process (SBF process) is one of the bath smelting process with independent intellectual property rights of China Nerin. This process was originally applied to treat copper concentrate and high-lead slag. The SBF process includes two categories, i.e. to treat copper concentrate and to treat industrial solid waste. Up to now, the SBF process has been applied in around 5 million tons of copper concentrate processing capacity and 20+ plants with high-lead slag reduction process. In recent years, SBF process has been gradually used in zinc leaching slag, electroplating sludge, industrial solid waste (e.g., various metallurgical slag), and electronic waste disposal. The basic principle of SBF process is that the material to be treated is directly charged to bath through charging hole with crushed coal and flux, then, enriched oxygen air would be sent to slag level (Vanyukov/Jifeng style furnaces)or matte level (Baiyin style furnaces) via primary tuyere. In this case, the material completes matte/slag metallurgical reaction of gas-liquid-solid interaction under vigorous mixing, and separate matte and slag at the bottom of furnace hearth. With the help of secondary tuyere, the low-pressure air or enriched oxygen would be provided for secondary combustion in the freeboard. The core of SBF process is process parameter control and engineering design of SBF. Presented as a fixed rectangular type, the SBF is a metallurgical furnace consisting of copper water jackets and refractory material. The SBF is consisting of hearth, middle of furnace and furnace top with the sequence from bottom to top. The middle of furnace itself can be further divided into bath area and post-combustion area with primary tuyere and secondary tuyere at both sides. The furnace hearth is made of refractory bricks, which are fused and rebonded Mg-Cr brick, Mg-Cr brick and clay brick from inside to outside. The furnace top adopts a steel water jacket with charging hole and uptake shaft. The water-cooled partition wall is placed at uptake shaft and near charging hole.

Jan 1, 2019

By K. N. Subramanian, H. Kanduth

"It is well known that chalcopyrite can be dissociated into simple sulphides by heating with elemental sulphur at about 475°C:CuFeS2 + S -> CuS + FeS2Experimental work was undertaken to determine whether this ""activation"" could be used to advantage in the selective leaching of copper from chalcopyrite concentrate.A method of treating copper concentrate with molten sulphur was developed and the activated product was leached in dilute sulphuric acid using oxygen, ferric iron or manganese dioxide as the oxidant. The object was to obtain a solution suitable for electrowinning with minimal purification, but it was impossible to obtain rapid extraction of copper without simultaneously dissolving a large proportion of iron. This was attributed to the fact that some of the copper was present as a low iron-copper sulphide (idaite) and that the pyrite formed during the ""activation"" step was more easily oxidized than natural pyrite."

Jan 1, 1973

By V. M. Robb, F. Walraven, L. J. Robb

"The old Albert Silver Mine is a polymetallic deposit comprising concentrations of CuPb- Zn-Ag-U-F within a set of sub-parallel quartz-hematite veins which occur within the fine-grained apical phase of the 2050 Ma old A-type Bushveld granites. Mineralization occurs as an early pyritechalcopyrite- arsenopyrite-galena-sphalerite-(argentiferous) tetrahedrite paragenesis followed by a later, more oxidized assemblage comprising chlorite-hematite-fluorite-pitchblende. Accumulation of metals appears to have taken place at the interface between a coarse-grained porphyritic granite and an overlying fine-grained phase: veins occur in the latter and represent leakage of magmatic fluids from the differentiated, water-saturated, subjacent granite.Mineralization processes in the Bushveld granites are believed to be related to long-lived circulation of dominantly magmatic fluids stimulated by the high heat productive capacity of the host rocks. Endo- and exogranitic tin-tungsten and base metal mineralization formed during an evolving hydrothermal system that lasted for several hundred million years, forming innumerable small- to mediumscale polymetallic deposits. At the Albert Silver Mine, unroofmg of the cover sequences at circa 1600 Ma to 1700 Ma resulted in the incursion of lower-temperature, high-f02 meteoric fluids which remobilized the earlier sulfides and introduced the paragenetically late U-F mineralization."

Jan 1, 1994

By Jaroslaw W. Drelich

Despite the success of DLVO and extended-DLVO models that have been developed for homogeneous and smooth surfaces, a vast majority of practical surfaces encountered in mineral ore beneficiation are typically rough at various scales; they are also typically heterogeneous. The interactions of gas bubbles with particles having rough and heterogeneous surfaces are much more complex than the commonly used DLVO or extended-DLVO models predict. The effects of surface roughness on flotation and colloidal interactions have been reported many times in the past, although a clear understanding of their origins has been lacking. To explain differences in colloidal interactions for spherical hydrophobic particles, a theoretical analysis of the interaction potential was carried out for a model rough particle interacting with a bubble surface in an electrolyte solution in this study. The attractive hydrophobic interaction potential was added to repulsive retarded van der Waals and repulsive electrical double layer interaction potentials. The rough microscopic particles were modeled as spheres decorated with nano-sized asperities. Parameters that reflect common flotation separation systems were selected for testing this theoretical model and computation of the energy barrier applicable to particle – flat bubble surface interactions. It was found that hydrophobic asperities with the height of only several nanometers can reduce the repulsive interaction energy by an order of magnitude. Theoretical analysis also reveals that surface coverage of microscopic particles by nano-sized asperities is important as well. The findings of this research suggest that manipulating and engineering the particle surface topography could lead to better control over flotation separation.

Jan 1, 2016

By Liguang Wang

The froth phase in flotation has received much less attention than the pulp phase despite the fact that froth stability plays an important role in determining flotation performance. Froth stability is largely determined by the stability of thin foam films, which in turn has a strong correlation with the critical rupture thickness (Hcr) of the films. In the present work, a new approach to predicting the Hcr values of thin foam films in flotation froth phase was proposed and examined. The Hcr values were calculated using an advanced capillary wave model with input parameters being surface tension, film radius, capillary suction pressure, and intersurface force. The intersurface force was estimated by using the Stefan-Reynolds lubrication approximation to fit the measured thinning rates of single foam films formed in a Scheludko ring cell, where the film radii were less than 50 microns and were kept constant during the film-thinning process. A comparison between the predicted and experimental Hcr values was made for the films with the use of sodium chloride as background electrolyte and in the presence of various frothing reagents such as methyl isobutyl carbinol (MIBC), polypropylene glycol with an average molecular weight of 400 (PPG400), and sodium dodecyl sulphate (SDS), at different concentrations and film radii. It was found that the model correctly predicted the trends of Hcr-versus-concentration and Hcr-versus-film radius curves. Moreover, the predicted Hcr values matched well with the experimental ones of the foam films containing either SDS or PPG400. For the foam films containing MIBC, however, the model overpredicted the Hcr values. The reason for this discrepancy was discussed.

Jan 1, 2016

By Tom Shumka

INTRODUCTION ?This bull gear inspection technique was developed to provide more accurate data and faster inspection times than current techniques used today. ?Eddy Current Array (ECA) is a non-destructive testing technique that provides the ability to electronically drive multiple eddy current coils, which are placed side by side in the same probe assembly. Each individual eddy current coil in the probe produces a signal relative to the phase and amplitude of the structure below it. ?This data is referenced to an encoded position and time and represented graphically as a C-scan image. Most conventional eddy current flaw detection techniques can be reproduced with ECA inspections; however, the remarkable advantages of ECA technology allow improved inspection capabilities and significant time-savings.

Oct 1, 2010

By Kai Bartram

The successful application of color sorting machines has established sensor-based sorting in the mineral industry in recent years and is considered today as a significant innovation in processing technology. However, we are only at the beginning of (market) introduction. New sensor systems have been developed, which exploit material properties such as electrical conductivity, magnetization, molecular structure, thermal conductivity etc. This opens up new exciting preconcentration and upgrading possibilities for many applications such as nickel, gold, copper and other ores as well as for industrial minerals, diamonds and other gem stones.

May 1, 2009

The successful application of color sorting machines has established sensor-based sorting in the mineral industry in recent years and is considered today as a significant innovation in processing technology. However, we are only at the beginning of (market) introduction. New sensor systems have been developed, which exploit material properties such as electrical conductivity, magnetization, molecular structure, thermal conductivity etc. This opens up new exciting pre-concentration and upgrading possibilities for many applications such as nickel, gold, copper and other ores as well as for industrial minerals, diamonds and other gem stones.

Oct 1, 2009

By A Smirnov

The problem of thin and very thin coal seam extraction is examined in a long perspective of Ukraine?s fuel and energy industry development. The technical and economic benefits of the coal seam selective mining technique are described, including beneficial environmental impact.

Aug 1, 2013

By P. Turcotte, E. Karampinos

"Construction of underground excavations in squeezing ground conditions faces several technical challenges that can result in delays in production and high costs due to rehabilitation. A review of the behaviour of drifts under squeezing ground conditions was undertaken at the LaRonde mine. In particular it focused on implemented strategies to control the observed large deformations. The mine experiences a large range of squeezing ground conditions, mostly driven by the presence of foliation and high stresses. This results in large deformations over one meter in radius. A comprehensive ground control strategy has been implemented with the aim to manage, rather than arresting drift closure. The evolution and effectiveness of the employed support strategy are discussed based on documented field observations. In complement to the field implementation numerical models are used to provide further insight on the observed squeezing conditions.INTRODUCTIONThe development of underground excavations under squeezing ground conditions is usually associated with excessive rehabilitation and significant failure of ground support due to large deformations. Cost research case studies have concentrated on squeezing ground conditions in tunnelling. An overview of the methods used for the identification and quantification of squeezing and the numerical methods for the simulation of these conditions in tunnelling has been provided by Barla (2002). Numerous support systems that can manage ground deformation are available for civil engineering tunnelling. Nevertheless, the use of these systems in mining would result in high support cost and production delays. Mining operations have higher development rates and shorter service life. This study focuses on the behaviour of underground excavations under squeezing ground conditions in hard rock mining.In a mining context, the magnitude of deformation is usually higher than in civil engineering tunnelling as there is a higher tolerance for operation purposes. Potvin and Hadjigeorgiou (2008) noted that in mining, squeezing is encountered when the total displacement of an excavation reaches at least tens of centimeters over the life expectancy of a supported drive and is associated with considerable damage to the ground support."

Jan 1, 2015

By L. Xia, B. Hart, J. Nigim, Z. Chen

"Grinding ore is an important step in the flotation process. Not only does grinding reduce particle size and liberate minerals, it also creates conditions for reactions to occur on particle surfaces that can aide or inhibit flotation. There have been numerous studies examining various grinding regiments and the effect on flotation pulp chemistry, including autogenous grinding and using media of variable composition. There have been however, few studies looking at the effect of variability in grinding media size on pulp chemistry and subsequent flotation. This study attempts to link changes in pulp chemistry in response to variations in grinding media size to flotation recovery. It uses probes mounted in the grinding chamber (pH, Eh, DO, and conductivity) to monitor pulp chemistry changes during grinding of a Cu-Zn ore. Surface chemistry analysis by ToF-SIMS was performed on sphalerite from the mill discharge. Activator and depressant species were monitored on the mineral surfaces and their presence was evaluated in the context of variability in pulp chemistry linked to differences in grinding media and its ball size.INTRODUCTIONIt has been widely recognised that not only does grinding reduce particle size and liberate minerals but the grinding environment has a large effect on the flotation of sulphide minerals. This effect is attributed to Eh change, iron hydroxide coating on surfaces, oxygen reduction, precipitation from solution and galvanic coupling (Grano, 2009). As early as 1960, it was reported that after grinding the ores in an iron mill the natural floatability of sphalerite was reduced significantly (Rey and Formanek, 1960). Kocabag and Smith (1985) studied on the industrial circuits showing that the depression of sulphides flotation in a steel mill is possibly due to the coating of iron oxidation products. Peng, Grano, Fornasiero, and Ralston (2003a, 2003b) found that iron contamination from grinding media plays a dominant role in depressing galena and chalcopyrite flotation. Huang, Grano, and Skinner (2006) reported the same observation in the flotation of arsenopyrite."

Jan 1, 2016

By K. Reinharter, J. Schmidl, D. Gregurek, A. Spanring

Copper smelting furnaces are typically lined with magnesia-chromite refractories, which are exposed to multiple and complex stresses. The selection of the processing route, furnace type and slag system will be dictated by the specific ore type available, this will determine the individual refractory wear. This paper evaluates the common refractory wear mechanisms as observed in the copper Peirce-Smith converter and in the copper anode furnace. The chemical factors include corrosion caused by fayalite type slag and sulfur supply, as well as, by Cu-oxide attack. Changes in the temperature during the furnace operation (thermal-shock) create stresses in the brick lining which can only be absorbed in limited extent. Mechanical factors include erosion, caused primarily by the movement of the metal bath, slag and charging material, as well as, stresses in the brickwork due to punching. Finally improper lining procedures can also effect the service life. All these wear parameters lead to severe degeneration of the brick microstructure and a decreased lining life. Therefore, a detailed investigation and understanding of the wear mechanisms through “post mortem studies” together with thermochemical calculations by FactSageTM software is an important prerequisite for the refractory producer. Based on these research results, combined with specific process knowledge, appropriate brick lining solutions for copper processing furnaces can be recommended. INTRODUCTION The refining of copper includes converting of matte or black copper into blister copper for final fire refining process in the anode section. Typically Peirce-Smith (PS) converters are in use. Other technologies include Hoboken Converter, TBRC but also Flash Converting Furnace and bath smelting furnaces (ISA, Ausmelt) (Davenport et al., 2002). For fire refining two types of furnaces are used – the rotary furnace type is dominantly used in the primary production route while secondary smelters tend to use hearth refining furnaces which are more suitable for scrap melting. Installed working linings are based on magnesia-chromite bricks but especially in the anode refining section the application of alumina-chromia bricks have become more popular in the recent years. It comes without saying that, to some extent, large variations in the slag composition can be observed from the data provided to RHI Magnesita during post-mortem studies of used refractory samples and this needs to be addressed properly during the selection process of refractory linings.77

Jan 1, 2019

By H. O. Olsen

"GeneralTHE IRON ORE at Marmora is a replacement deposit of Precambrian limestone and is overlain with Palaeozoic limestone. It is a low-grade magnetite deposit and the ore will require concentration be-fore it can be used economically for the production of iron and steel.Present plans estimate an annual production of 500,000 tons of concentrate in the form of pellets. This will require mining approximately two million tons of ore and\ waste annually. Shipment of pellets from Marmora to a ship-loading dock at Picton will be made by rail on a year-'round basis. Shipments from Picton to the Lackawanna plant of the Bethlehem Steel Company at Buffalo, N.Y., will be carried on during the Lake shipping season.LocationThe mine, located a mile southeast of Marmora village in Hastings county, Ontario, is 31 miles north of Belleville and 3•7 miles east of Peterborough. Marmora is 130 miles from Toronto and 150 miles from Ottawa. Highway No. 7 passes half a mile north of the mine and Highway No. 14 half a mile west of the mine. The Canadian National railways' branch line between Trenton and Bancroft passes through the property just east of the open pit.HistoryThe Ontario Department of Mines conducted an airborne magnetic survey of the district during 1948 and 1949. Maps of this survey were released to the public early in 1950. Bethlehem representatives carried out ground surveys in the Marmora area shortly thereafter and in June, 1950, commenced diamond drilling."

Jan 1, 1955

By Desmond M. Connor

"The State of the EnvironmentRecent data from a State of the Environment report prepared in January 1991 and released in April (see references) , indicates that the physical and biological environment across Canada is deteriorating in some important ways. For example: • emissions and atmospheric levels of CO2 are rising at a rate more than 50% of the U.S. increase; global temperature continues to rise, especially during the last decade;• while S02 emissions have been falling since 1984, NOz has declined only slightly since that time; N02 in Canada rose 43% during 1970-87, compared with a 7% rise in the U.S.;• municipal discharges of phosphorus and BOD (biochemical oxygen demand) to fresh water have been rising steadily since 1983);• pulp and paper mill discharges to fresh and Pacific coastal waters have been rising, 1970-87;• migratory game bird populations (Prairie Mallard, Northern Pintail) have been declining for the last 20 years;• total per capita energy use continues to climb.The State of the PublicSimilarly, data from recent public opinion surveys shows that public concerns about the environment are either rising, or are remaining at a high level despite the competing claims of the economy and political events for attention.For example, Professor Reginald Bibby's national survey this year shows that Canadians rank our top three issues as theeconomy, the environment and government incompetence.An Angus Reid survey commissioned by the Mining Association of Canada and other mining organizations in 1989 showsthat, despite general support for its economic benefits:• 67% of the general public perceive the mining industry to be a major source of pollution and environmental contamination;• 68% believe that a new mine should not be developed if it will disturb local wildlife;• 52% would prohibit a new mine if it required a road through a national park;• 49% would disallow mine development if it took as much land as an average farm in an agricultural area or if it limited sports fishing in a local lake."

Jan 1, 1991

By G. Vibert Douglas

It has long been recognized that there are considerable difficulties connected with the physical and chemical explanation of shoots of ore. The literature of Mining Geology has frequent references to this subject; but the reasons given for the actual location of primary ore-shoots have been very tentative. In practice, the geologist or miner depends to a great extent on sampling and assaying to determine the boundaries of profitable ore within the mineralized zone. An ore-shoot is a portion of a mineralized zone which has a sufficient concentration of valuable minerals to make it ore. Ore deposits have been classified according to many schemes. There are classifications based on morphology and on genesis. However, it is also possible to classify hypo-gene hydrothermal ore-bodies in terms of ore-shoots or vice versa. A.-Ore-deposits in which the whole of the mineralized zone is ore, which is the same as saying that the ore-shoot extends throughout the mineralized zone. An example of this type of deposit would be the pyritic mineralization of Rio Tinto. B.-The second type would comprise those deposits in which the ore-shoots bear some relation to the geological structure of the area: all deposits in which 'bonanzas' occur in folds in the zone, at the intersection of veins along certain fault (or joint) features and other such controls. There are a great many examples of this type: (a) The Rhodesian copper lodes, where Bancroft and Gray have pointed out the association of the shoots of ore with drag folds. (b) A similar association has been pointed out by Faribault for some of the gold veins of Nova Scotia, e.g., Mount Uniacke. (c) The great bonanza of the Comstock lode in Nevada. C.-Deposits in which the localization of ore has been effected by the chemical character of the wall-rock. Examples of this type are the Fahlbands of Scandinavia, and the 'indicator' deposits of Ballarat, Australia. D.-Lastly, deposits in which there is apparently no structural and no chemical control.

Jan 1, 1934

By Michael S. Moats, Addin Pranowo, Gerardo R. F. Alvear F., Nigel Aslin

The toxicity of arsenic is well known and documented. However, the presence of arsenic in copper electrorefining anodes and electrolyte is critically necessary to produce high quality cathode. Arsenic as well as antimony and bismuth concentrations vary depending on their relative concentration in the anode copper received from the smelter. This paper will discuss the behaviour and benefits of arsenic in copper electrorefining and the detrimental effects of antimony and bismuth on cathode quality and tankhouse performance. This will include the minimization and mitigation of problems associated with arsenic, antimony and bismuth including cathode contamination, floating slimes, scaling and anode passivation.

Jan 1, 2014

By W. H. Hastings

Introductory In the amount of her coal reserves, Saskatchewan ranks third among the provinces of the Dominion, with a total, as estimated by D. B. Dowling, of 59,812,000,000 tons. All the coal so far discovered in the Province is lignite, and it would appear unlikely that bituminous or higher grade coals exist. General Occurrence of the Coal The location of the coal-bearing formations in Saskatchewan is shown on the accompanying map. It will be seen that the areas lie principally in the southern part of the Province. The more darkly shaded areas indicate locations where development is taking place, or where coal-seams are known to occur, either through outcrops in valley-sides or through having been encountered during boring operations. The coal-seams are not necessarily continuous throughout the shaded areas, but in all pans of these there are coal possibilities. It is quite possible that small outliers of the coal-bearing formations may occur further north in the Province, but, generally speaking, coal is not likely to be found outside the shaded areas.

Jan 1, 1929

By A. Ghasemi

An alumina-silica coating was deposited on a nickel substrate by sol-gel process, and the structures and composition were evaluated, The sols were made from aluminium and silicon alkoxide, and an acid catalyst including HCl, To produce adherent silica coatings on nickel, various additives such as surfactant, viscose additive and drying control chemical additives were introduced to the system, and appropriate drying and firing cycles were applied after dipping in solution. The hot corrosion and oxidation resistance of the coating at different temperatures were investigated, The structure and uniformity of the coatings were examined by scanning electron microscopy (SEM), The results indicate that a uniform coating of alumina silica can be produced on a nickel substrate by optimizing the composition and process variables of the sol. Coatings can protect substrates from oxidation and hot corrosion at different temperature up to 1000°C, but is not very effective for hot-corrosion resistance at 1000°C.

Jan 1, 2005

By J. Drenda

The model for methane removal from the workings directly behind an advancing longwall as presented in this paper may be used for U-ventilated cross or length-wise systems of longwall advance, starting from the boundaries of the extraction field. In mines with high methane concentrations, Uventilated longwall extraction from the boundary of the extraction field produces a methane risk. The risk is manifested by a higher methane concentration at the end of the longwall, upper gate and incline. The methane in increasing concentrations, which is emitted mainly from the workings with caved areas, appears towards the end of the longwall and in the upper gate. The graphical model of the longwall provided includes both the workspace of the longwall and the caved area. Based upon a model of the rock distribution in the cave, a ventilation model comprising two standard air splits and large number of crosswise air splits has been constructed. Simulations indicate that if the shearer is not present in the longwall, the air distribution in the caved area is symmetrical. The presence of the shearer, both at the bottom and the top of the longwall, causes an asymmetrical air distribution in the cave, that is the asymmetrical flows in the goaf and longwall workspace and in the inflows and outflow between those regions. This phenomenon causes an increase in methane concentration at the end of the wall and at the upper gate. The methane removal method proposed for workings with a caved area directly behind the advancing U-ventilated longwall, starting from the boundary of the field, consists of the removal of methane-air mixtures from the caved area with the boom pipes. These booms may be of several meters long and may be extended if necessary. The insertion of the boom pipes into the cave towards the end of the longwall and connecting them with the general methane removal system creates negative pressure causing a change in the depression field, which is the aerodynamic potential field in the goaf area around the ends of the boom pipes. This will promote the extraction of the methane-air mixture from voids and the goaf cracks, and the area from which methane is being extracted may extend to the side of the cave. This is a positive phenomenon, which could result in the methane flow from the goaf into the airflow in the longwall workspace decreasing or even stopping. A reduction in the methane flow into the longwall workspace with extractions booms will be advantageous for the production continuity. Based on the floor load model for the rocks in the cave and the methane-removal boom load model, the value of the force required to move the boom behind the advancing wall has been calculated. Strength calculations for the pipe were performed using a finite elements method. The analysis results, as well as the comparison of the pipe material effort to the strength parameters of steel, which can serve as piping material (for the assumed load conditions), lead to a belief that the proposed boom construction satisfies the strength requirements.

Aug 1, 2013

By Karen M. Moffitt

Developments in mining methods and rates have led to an increase in the frequency and size of waste dump failures that have not been adequately predicted or explained in terms of conventional slope stability analysis. Monitoring data and visual observations suggest a unique mode of failure responsible for large runout events. A numerical model has been developed to capture commonly observed patterns of deformation, and investigate the formation of the ensuing failure mechanism. The analyses have yielded a good correlation with observed field behaviour and have provided significant insight into the coincident stresses and deformations within the dump. Results indicate that while creep effects in the waste dump could have a significant effect on the magnitudes of displacement, the overall dump stability is governed by the strength of the foundation soils underlying the toe region. Consideration of both the stress and velocity fields leads to factors of safety for various dump heights and foundation slopes that are considerably less than predicted from limit equilibrium analysis. The results suggest that conventional limit equilibrium analysis techniques may not be adequate when assessing the stability and design of waste dumps on steeply sloping terrain.

May 1, 2001