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By M. Roy, Y. Roux, R. McIvor

"La Compagnie Minière Québec Cartier at Port Cartier. Quebec, utilizes six parallel wet grinding open circuit ball mills to grind iron ore concentrate for the pellet making process. In an attempt to improve grinding efficiency, a mix of 605 25 mm (1 in.) and 405 38 mm (1 ½ in.) grinding balls was charged to mill D while the opposite mix was used in all the other mills. Because media costs were higher for mill D, it was necessary to find out if the smaller balls provided a net economic benefit. Therefore, a test program was undertaken to determine the relative efficiency of the charge in mill D compared to the other grinding mills. Mill F was chosen for comparative efficiency measurements.The first problem was to choose a suitable definition of grinding efficiency. In management's view, previous attempts to quantify milling performance using population balance modelling were ineffective because they were unable to relate breakage rate functions to grinding circuit economical in any meaningful way. Work index analysis was also not favoured because of a number of complicating effects, including the fineness of the feed and product streams and open circuit grinding.It was decided to adopt a recent innovative approach which had been successfully applied to closed-circuit ball milling. For ""functional performance analysis of ball milling"" (McIvor et al., 1990; McIvor et al., 1991), a size criterion is first chosen to define ""fines·' and ~'coarse particles"". In this case 45 microns (325 mesh) was chosen to distinguish fines from coarse material. The relative grinding efficiency of each ball mill environment would then be ~e cumulative grinding (disappearance) rate of coarse (plus 45 nucrons) material per kilowatt hour of energy applied to the coarse material in the mill, divided by the grindability (measured in the laboratory) of the coarse material in the mill feed.Because the disappearance rate of coarse particles is also the production rate of fines, the following equation can be written for the efficiency of the mill environment, Effe, as defined above:"

Jan 1, 1994

By James J. Roettger, Robert J. Mitchell

"The results of a series of model stope pours designed to investigate working pressures on bulkheads during hydraulic pouring of classified tailings backfill are reported. Total bulkhead pressures and fill water pressures were monitored under the condition of a fully saturated backfill. Similitude of the model testing is discussed and equations are developed to estimate bulkhead pressures under prototype conditions. The model results show that good base drainage, combined with a bulkhead setback, can reduce the expected bulkhead pressures to values such that timber or concrete block structures should be capable of supporting a saturated backfill. Introduction Bulkheads are used in underground running operations to block drift openings in order that hydraulically placed sand backfill can be contained in stope pours. Whenever possible, the sand fill is designed to have sufficient percolation rate so that excess hydraulic transport water will gravity drain out through the bulk headed drifts. This avoids costly decanting systems. Early bulkhead design assumed that the bulkhead pressure could be as high as 0h = Hy where H is the fill height and ""y is the saturated unit weight of the fill (Thomas et al., 1979)(1). A typical design pressure for a 50 m fill height would be 1250 kPa giving a design force of 12,500 kN on a bulkhead located in a drift of 10m2 in area . Typical bulkheads were 1 m thick heavily reinforced concrete structures formed and poured into a notched drift. Not only were these expensive structures but the associated problems of inside drainage systems and curing time delays increased production costs. As experience with bulkheads for large bulk pours increased and fill pressure measurements became available [see, for examples, Libby et al., 1975(2), Askey et al., 1978(3)] , 'free drainage' timber and concrete block bulkheads were designed. Substantial savings have been realized using these types of bulkheads but greater engineering design and monitoring of backfill pours is necessary to ensure that backfill pressures do not exceed the bulkhead design pressures.The effective and total stress components of fill pressure, the engineering concepts associated with the 'free drainage' design and some detailed design considerations have been discussed by Smith and Mitchell (1982)(4) . It is important to the safe use of these designs, however, that the basic engineering concepts be demonstrated and communicated to those responsible for the day-to-day backfill operations. This paper describes and explains observations from a series of model studies designed to measure bulkhead pressures in a saturated fill."

Jan 1, 1984

By R. Stauber, B. Friedrich, S. Hilgendorf, G. Homm, C. Gellermann

Due to recent regulations limiting tolerated lead concentrations in copper alloys, new recycling strategies have to be considered. This study investigates the suitability of technical approaches in order to recycle leaded copper alloys exemplified by CuZn39Pb2 and produce an alloy in compliance with future lead regulations in the European Union. Three pyrometallurgical methods are considered to achieve this goal, namely vacuum distillation, intermetallic precipitation and fractional crystallisation. The impact of essential process parameters i.e. pressure, temperature, time, atmosphere and quantity of additives are identified using thermochemical and kinetic modelling. An experimental implementation reveals a general suitability of all three refining processes. However, the individual efficiency of the different methods strongly differs. Thus, a detailed assessment is carried out in order to provide an evaluation on the efficiencies of these methods from a technological, economical and environmental point of view. Taking a possible industrial realisation into account, the authors recommend the approach of vacuum distillation, although the energy demanded is comparatively high due to the enthalpy of evaporation for zinc, or rather, lead. However, required lead concentrations can be reached quickly without introducing an external element to the material. The prediction of selectivity and evaporation speed, which are immanent variables for a successful implementation, can be validated experimentally. INTRODUCTION In 2016 approximately 1 million tonnes of leaded copper alloy semi-finished goods with an average lead content of 2.1 Ma% have been produced in the European Union (EU). The global production in the same period exceeded 5.5 million tonnes, while the lead concentration has stayed constant at around 2.4 Ma% for the last 50 years. Up to 80 % of the current production volume is covered with end-of-life scraps, which are used for direct re-melting, depending on the alloy composition. Lead has been a popular alloying element in copper alloys in general, and in particular in brass due to its positive impact on various mechanical, physical and chemical properties, especially machinability. Health and environmental concerns were drivers for many governments to implement limitations on lead. In order to further utilise the resource potential of leaded copper scrap, it is inevitable to develop methods to efficiently eliminate lead from circulation as far as possible. (Glöser, Soulier, & Tercero Espinoza, 2013; Soulier, Glöser-Chahoud, Goldmann & Tercero Espinoza, 2018)

Jan 1, 2019

By J. W. Senn

A magnesium alloy modeled after commercial alloy WE54 was thermomechanically processed and characterized to understand the mechanisms by which its texture can be randomized, as reported by Ball and Prangnell [1]. Samples were deformed in plane strain compression to prescribed strain levels at temperatures high enough to prevent cracking and then recrystallized. The deformation texture is very similar to that observed after plane strain compression (e.g., rolling) of other Mg alloys, such as common AZ31. However, the texture can radically evolve during recrystallization. Annealing above the precipitate solvus temperature results in a nearly random recrystallization texture where the initially strong basal texture is completely eliminated. Annealing below the solvus temperature produces a recrystallized texture similar to conventional Mg alloys, i.e., a weakened basal texture. If this same material is then annealed above the solvus to promote grain growth, a randomized texture evolves, which is similar that of samples simply recrystallized above the solvus. It is hypothesized that a sort of preferred growth mechanism, whereby grains with random orientation grow faster than those with the original basal texture, contributes significantly to the texture randomization observed in wrought magnesium alloys containing rare earth elements.

Jan 1, 2006

By T. Sugawara, H. Sekimoto

Electrorefining of low-grade copper alloys containing various amounts of nickel, lead, antimony, bismuth, arsenic, selenium, silver, and gold in sulfamic acid media was demonstrated. The copper concentration of the alloys used as an anode was 70–90 wt%. The electrolyte contained 100 g L-1 of free sulfamic acid and 40 g L-1 of cupric ion. Galvanostatic electrolysis was conducted at 200–300 A m-2 in the electrolyte using a low-grade copper alloy anode and a stainless steel cathode at 25C. The terminal voltage was approximately 0.8 V at the start of the electrolysis, although it increased periodically to approximately 2.0 V and then shortly returned to its initial value. Nickel, lead, and arsenic from the anode dissolved in the electrolyte and were removed. Antimony, bismuth, selenium, and silver were removed as solids. Consequently, a dense copper cathode was obtained, and the concentration of copper was evaluated by inductively coupled plasma – optical emission spectrometry to be 99.82–99.99 wt%. INTRODUCTION Electrorefining of copper is conventionally carried out in a sulfuric acid electrolyte using crude copper assaying at 99.5 wt% Cu as the anode (Biswas & Davenport, 1994). Elements more noble than copper do not react anodically, and consequently, they are distributed in anode slimes. Elements less noble than copper dissolve from the anode. Nickel and arsenic are stabilized as aqueous species. Lead, antimony, and bismuth react with water, sulfuric acid, or arsenic acid to form barely soluble compounds; thus, they are distributed in anode slimes. An emerging issue in the electrolytic refining of copper is an increase of impurities in crude copper used as the anode (Moats et al., 2013). This is due to an increase in the content of impurities in copper concentrates as well as an increase in the types of secondary copper feedstocks (e.g., E-Scraps, automotive shredder residues, and smelting residues) treated in the copper pyrometallurgical process. An extreme case is a copper smelter that does not use copper concentrates as feedstocks. In such a process, copper-bearing feedstocks are smelted in a top submerged lance furnace to prepare low-grade copper alloys assaying at 80– 90 wt% Cu (Sekimoto et al., 2013). Such low-grade copper is not acceptable as an anode in the conventional copper electrolytic refining process because it is easily passivated during electrolysis. Consequently, electrolytic copper is produced by leaching the atomized low-grade copper in a sulfuric acid solution with oxygen, followed by electrowinning. However, electrowinning should be avoided whenever possible because the electrical energy consumed in electrowinning is 5–10 times higher than that consumed in electrorefining. Therefore, the development of technologies for electrorefining of low-grade copper alloys is desirabl.

Jan 1, 2019

By G. Vibert Douglas

Introduction A preliminary paper dealing with the subject of ore-shoots was presented to this Society at its Annual Meeting last year (1). The present paper records the attempts which have been made during the interval to further this study. In reporting this work, I wish to state that I do not consider the investigation complete; many more experiments will have to be carried out, and more field data will have to be recorded, before the geologist can say with confidence an ore-shoot should start at this point and pitch in that direction. The aim of these experiments is to find some criteria which will serve the mining engineer and mining geologist concerned with ore-shoots in hydrothermal veins.

Jan 1, 1935

By M. Hajian Heidary

In this investigation, effect of pressure depth on the globulizations of AZ91 magnesium alloy was studied. Cylindrical samples of AZ91 alloy with 1 cm and 2cm in height and 2.5cm in diameter (H/D = 0.4 and 0.8) were prepared, then the samples were hot pressed at 10 and 30% strain at a constant temperature of 200°C; subsequently reheated at 555°C in different times. Results obtained from optical microscopy (OM) showed that the thickness of the samples and consequently, depth of strain affected regions have remarkable effect on the degree of globulization. In addition, it was found that at a constant strain and holding time, structure of thinner samples is more globular than thicker ones.

Jan 1, 2007

By R. Butar-Butar, J. Mosher, G. Banini, J. Hollow, A. Villanueva

The effect of High Pressure Grinding Rolls (HPGR), as a preceding stage to a conventional ball mill circuit at PT Freeport Indonesia’s C1/C2 concentrators, has been studied in terms of downstream grinding efficiency and circuit performance. When milling the product from the HPGR, mill capacity increased by 21% for the same product grind size, when compared to processing similar ore from a conventional crushing circuit. This achievement is a result of several reasons, among them: reduction in feed size (F80), fines generation beyond the proportional reduction in F80, reduction in ore hardness induced by HPGR comminution mechanism, optimization of the recycle system of the HPGR and ball string optimization in the ball mill circuit given the new feed to the mill.

Jan 1, 2012

By J. G. Pharoah

Over the last two decades a variety of models for solid oxide fuel cells (SOFCs) have emerged ranging from one dimensional (1-D) to 3-D models, from steady-state to transient models; single- and half-cell and entire stack models. A majority of these models have focused either on the transport processes or on the chemical/electrochemical processes. The approach taken by our research group is to develop a comprehensive SOFC model framework based on the considerations of detailed electrochemical reaction mechanism and by accounting for complex transport processes occurring in the porous media at the micro-scale level. In this paper, we review the state-of-the-art in SOFC modeling and identify the existing gaps that need to be filled in.

Jan 1, 2005

By Qing-hua Tian, Xue-yi Guo, Fei Li

A novel process for the preparation of a-Al2O3 from secondary aluminum dross was studied. Factors including alkali dross ratio, salt dross ratio, smelting temperature, smelting time, leaching temperature, leaching time, and the solid-liquid ratio, which possibly influence the transfer of Al into water were studied, and the feasibility of using seed precipitation as a treatment technology of the leachate was discussed. The optimum condition of the process was determined as: alkali dross ratio 1.3, salt dross ratio 0.7, smelting temperature 500°C, smelting time 60min, leaching temperature 60°C, leaching time 30min, solid-liquid ratio 1:4. The results show that using the seed precipitation method, the leaching of aluminum reaches 92.71%, demonstrating the technique as a feasible and effective treatment technology of the leachate.

Jan 1, 2011

By Z. Trojanová

The deformation behaviour of ternary magnesium alloys AJ (Mg-Al-Sr) and AX (Mg-Al-Ca) were investigated in tension as well as compression tests. The samples were deformed at temperatures between 20 and 300 °C and at an initial strain rate of the order 10-4 s 1. The flow stress decreases with increasing temperature. The macroscopic work hardening rate decreases with increasing flow stress and temperature. The stress and temperature dependence of the work hardening rate is a result of the hardening and softening processes. Stress relaxation experiments were performed in order to reveal features of the thermally activated dislocation motion. Internal and effective stress components of the applied stress were estimated. A decrease in the internal stress was observed at elevated temperatures, which indicates recovery process (-es). A more detailed analysis of the estimated values of the activation volume and activation energy helped to interpret the thermally activated processes during plastic deformation. It is concluded that the deformation behaviour of the alloys depends on the activity of non-basal slip that is strongly influenced by temperature.

Jan 1, 2007

By J. A. Finch

Solvent-coated air bubbles in the Air-Assisted Solvent Extraction (AASX) process achieve the dual role of high solvent specific surface area and ease of phase separation. The thickness of the solvent film is of fundamental interest but difficult to measure directly in the process itself. As an approach interferometry (in the UV-vis region) was used to measure the time dependent thickness of a film formed by blowing an air bubble in kerosene-based solvents. The film was stabilized by the presence of 1.5 ppm silicone oil, as employed in AASX. The film appears to comprise two layers; an outer "free" layer of almost constant thickness and an inner "bound" layer which decreased in thickness with time. The bound layer is considered relevant to AASX. For a 20 mm diameter bubble blown in LIX/kerosene solvent the initial thickness was ~ 3 um which decreased over 10 minutes to a final rupture thickness of 500 nm. The bound layer thickness and time to rupture decreased with decreasing bubble size. Correspondence to prior indirect estimates of solvent layer thickness is examined.

Jan 1, 2006

By L. S. Trenholme

"Belleterre Quebec Mines, Limited, is a subsidiary of Mcintyre Porcupine Mines, Limited. The property is in Guillet township, Quebec, 45 miles due east of Haileybury, Ontario. It is accessible by 72 miles of gravelled road from New Liskeard, Ontario (Fig. 1).Gold production at the property commenced in 1936 and to March 31st, 1945, had exceeded $9,000,000. For the past 3 years the milling rate has averaged 325 tons a day and the gold recovery about $14 a ton.GENERAL GEOLOGYThe rocks of the district consist of Keewatin-like volcanics conformably overlain by Timiskaming-like sediments. Together they form the remnant of an easterly plunging anticline engulfed by granite (Fig. 2). The pregranite intrusives consist of diorite, gabbro, and ultrabasic rocks, occurring as dykes, sills, and irregular stocks. Dykes of porphyry and lamprophyre presumably related to the batholithic intrusive are common in this area. The veins of quartz are also probably derived from the batholithic intrusives. A few dykes of Keweenawan-type diabase have been observed."

Jan 1, 1954

By G. N. Carlson, C. H. Hazelroth, D. R. Dorrance

"Located on the north shore of the St. Lawrence River at Pointe Noire, Quebec are the agglomeration and ship-ping facilities of the Wabush Mines complex. Here, the specular hematite concentrate from the Scully Mine is received for further processing. Modern facilities for handling the ore, either to the 1plant or to stockpile, provide quick and efficient operation of the ore receiving station. Physical preparation of the ore for balling is accomplished with regrind ball mills, filters, bentonite crushing and drying facilities, pumps and related conveying circuits. Rotating table feeders deliver the reground and de-watered ore from storage bins to balling drums, where green ball or green pellet formation is achieved. The green balls are then conveyed to the indurating section. Three Dravo-Lurgi travelling grates, producing a total of 6,000,000 long dry tons of pellets per year, are used in the indurating phase of the operation. These grates, having 38 windboxes and firing at a temperature of 2,500°F, harden the pellets for shipment to various blast furnaces throughout the world."

Jan 1, 1969

By V. Prodanovic, M. Militzer

Production of advanced linepipe steels with strength levels of 685MPa (100ksi) and higher requires excellent control of runout table cooling to produce the desired final fine-grained microstructures, which may include acicular ferrite. Cooling is exerted on the runout table by applying water jets onto the hot surface of the strip and heat is removed from the steel by forced convective boiling. The associated boiling mechanisms are complex and include film, transition and nucleate boiling. A pilot-scale runout table test rig has been built to systematically study boiling heat transfer from a moving steel plate by employing industrial scale headers. Experiments were conducted using test plates moving at speeds between 0.3 m/s and 1.4 m/s. The plates were cooled down from 850°C to temperatures below saturation by a single water jet supplied through an industrial size circular nozzle. Based on these experiments heat fluxes were determined and further used to develop improved runout table cooling models.

Jan 1, 2005

By C. A. Godden, T. N. Atkinson

Metallographic techniques developed from studies of corrosion films and electroplated coatings on aluminum alloys, are discussed. These methods, the result of work at the Naval Research Establishment, give extremely flat fields at the interface despite the large difference in hardness, in cases where electrolytic polishing could not be used. Techniques to overcome the similarity in refractive index of immersion oil, aluminum ox1d~, and mounting plastic are also considered, as are methods for improving visual and photographic contrast in areas of interest. A device for marking specimens is also de-scribed. ELE•CTROLYTIC polishing is inapplicable in the study of surface films on aluminum, whether corrosion films or electrodeposits. Mechanical procedures must there-fore be followed. Sample flatness and edge retention are of paramount importance. Special measures are required in the study of oxide films, because of the close proximity of the refractive indices of aluminum oxide, mounting plastic, and immersion oil.

Jan 1, 1962

By Robert B. Parsons

"First down and four to go. In the game Of football, this is not a bad position to be in. However, in this game of political football, it means that there is still a long way to go. The government in Ottawa has concluded an important agreement with one producing province, and now has at least four more provinces to deal with-B. c., Saskatchewan, Nova Scotia and Newfoundland.On September 1, 1981, the federal and Alberta governments took a significant step forward in formulating an oil and gas policy for Alberta and the rest of Canada on signing a comprehensive five-year agreement that covers taxes, prices, incentives and other fiscal matters related to the production and marketing of oil and gas.This month, Tax Notes examines the main features of the agreement, and offers some eye-opening observations of what the new accord could mean for the future of the Canadian petroleum sector in particular and Canadian business in general."

Jan 1, 1981

By R. H. McCorkell

Radon emanation rates. J. and compositions of materials from the Canadian Certified Reference Materials Project (CCRMP) indicate that the fraction of the Rn produced that escapes, E, is usually 1% to 8% and the 238U decay chain is nearly in secular equilibrium. For some Chinese ore standards, E values are higher than f or the CCRMP materials. Standard ore tailings have 2/oPb concentrations higher than expected from their 226Ra concentrations and Rn escape rates (12 - 34%) . Biological materials have E ˜100%, their ash E ˜0%. Pelletizing ore powders at 20 000 lb/in2 reduces J by only 20 - 40% but only 2% of Rn escapes from pressed Li2B4O7 pellets and 0.01 - 0.04% from fused Na2B4O7 or Li2B4O7 discs. Large, difficult-to-explain random variations in J are observed in some situations but several highly reproducible ways of measuring emanation rates have been found.

Jan 1, 1986

By P. B. Demarsh

"Location: - On highway 59, 17 miles east of Val d 10r near junction of Montreal highway in Northwestern Quebec.Life; - Started production 1952, ceased 1965.Ore: - Pyrite, chalcopyrite and small amounts of free gold and goldsilver tellurides in narrow quartz-carbonate-tourmaline veins in granodiorite. Specific gravity 2, 70.Capacity: - 700 tons daily Bevcon ore supply, l 000 tons daily when custom ore available.Assay: - Heads 0 .140 oz. per ton; tails 0. 009 per ton; extraction 92.5%.Grind: - 75% minus 200 mesh at 700 tons; 68% minus 200 mesh at 1000 tons. Detention time 28 hours and 21 hours respectively.Treatment: - Cyanidation process.Reagents: - Per ton. Aero Cyanide (NaCn) 0, 50; crushed unslaked lime 1. 75; zinc 0. 03; litharge 0. 10; steel consumption 2. 25.Water: - Pumped from land-lock spring fed lake l 1/2 miles distant.Cost: - Per ton. Crushing 0. 13; grinding 0 .32; filtration 0. 07; cyanidation 0.14; miscellaneous 0.29; total 0.95.Power: - Hydro-electric, 25 cycle, 12, 000 volts reduced to 550 volts.Labour: - Predominantly French Canadian, nucleus English Canadians.Tailings: - Impounded low lying pond.Personnel: - 15 including supervision.Flow sheet: - Canadian Mining Manual l 9 5 6 .Building: - Wood truss construction: 3/ 4 in. siding, ten test and 1/ 4 in. transite outside. Corrugated galvanized iron roof. Ground level foundations. Internal self induced heating. Wood stave tank equipment."

Jan 1, 1966

By G. H. Faye

The prospect of obtaining high-grade concentrates from Canadian pyrochlore ores is rather unlikely, and experimental beneficiation pro-cesses ?appear to have yielded products in the range of 3 to 20 per cent N'b205? A possible solution of the problem is to find an economical chemical method for recovering high-purity Nb2?05 from such concentrates. A technically feasible but economically unproved process is outlined in this paper, in which the concentrate is decomposed by an acid attack and the oxides of niobium and tantalum are isolated and then separated by liquid-liquid extraction. The solution of the ore is adjusted to 7 M HF-5 M HNO3 and the niobium and tantalum are extracted from this solution with methyl isobutyl ketone. The mixed oxides of niobium and tantalum are recovered from the oxdanic phase and dissolved in 0.5 M HF-1.0 M HNO3. Tantalum is extracted preferentially from this solution with methyl isobutyl ketone, leaving niobium in the aqueous phase. By the use of this process it is possible to produce niobium pentoxide and tantalum pentoxi.de in 99.5 per cent purity with a recovery of approximately 95 'per cent, under lab-oratory conditions.

Jan 1, 1957