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By K. Sugawaral, W. Tongampl, K. Hiruta, Takasaki Y., A. Hosoi, T. Katol, A. Shibayamal

Printed circuit boards of discarded personal computers, televisions, mobile phones and so on contain a significant amount of valuable metals. For the recycle of valuable metals contained in the printed circuit board wastes (P CB W), the effect of temperature on chlorination-volatilization of metals under chlorine gas flow was studied. The experimental sample used was powder of two types: crushed PCBW (Sample 1) made from PC and industrial machines, and crushed-combusted PCBW (Sample 2) made from Sample 1. The principal element in Sample 1 and Sample 2 was copper, about 13 wt% and 20 wt% respectively. Sample 1 was composed of pure metals such as copper, tin and lead. In comparison, Sample 2 consisted of oxide metals such as copper oxide, tin dioxide and silicon dioxide. The two samples were heated at predefined temperatures (ranging from 300 °C to 900 °C) in chlorine gas. The chlorine gas flow into the furnace was set at a rate of 100 mL/min. As a result, copper in Sample 1 began to volatilize at 600 °C and completely vaporized at 700 °C. While in Sample 2, copper started to volatilize at 600 °C and reached 100% vaporization at 800 °C. For Sample 1, zinc finished volatilizing at 500 °C, while for Sample 2, zinc volatilization reached only about 80% (maximum). Also, lead, nickel and titanium showed similar results. Consequently the volatilization rate of Sample 1 is higher than Sample 2 and the temperature dependency was verified for copper, lead, zinc, nickel, antimony, titanium and chromium. In fact, the volatilization rate of these metals increased with the temperature. This result reflects the difference between pure metal and metal oxide, as Sample 2 was combusted before the chlorination-volatilization test. Moreover, the chlorination reaction may be accelerated by a reductive atmosphere because Sample 1 contains carbon. In this study, the volatilization behavior of some valuable metals in PCBW by chlorine gas was observed. Further improvement in the rate of volatilization can be achieved by optimizing the experimental conditions.

Jan 1, 2011

By D. M. Morrison

"The most important factor in Canadian mining is not the operating cost of current projects but the availability of capital for future projects. The future of mining at depth will be producing ore from the top of the orebody working downward with very effective, tightly controlled mining methods, i.e. either selective mining or bulk mining with well controlled dilution and fragmentation. The key characteristics of future mines will be smaller access excavations, more effective ground support, very precise blasting techniques and more efficient and reliable materials handling systems. Equipment will be smaller and designed for high efficiency and low maintenance, reducing both the capital and operating cost. This means there will be fewer scoops, more continuous mucking machines and conveyor belts, both lateral and vertical.Orepass failures have become accepted and the resultant redevelopment and retramming has become common. The capital investment in so-called permanent ore passes and crusher stations becomes questionable, particularly when crushers are only necessary for less than 10% of the ore going through the system. The best way to solve the chronic instability of ore passes is, as with all of the stability problems at depth, by reducing the excavation size rather than increasing ground support. Smaller access drifts would reduce the capital cost and increase the rate of development as well as reduce the amount of waste to be handled, reducing the ground support and the ventilation requirements. Large drifts and ore passes are essential only for the equipment needed to handle large pieces of ore and the productivity of scoops is very expensive when the requirements for ventilation and large access drifts are taken into account. The key issue is the fragmentation generated by primary blasting.The future of mining in Canada will depend on simple and robust technology geared to the environment in which it will have to operate. Its survival will depend on some-thing much more fundamental and difficult to accomplish than a technological advance — it will require a dramatic change in the way the mining process is managed, how work is organized, how effort is rewarded and how costs are measured — a complete change in mind-set."

Jan 1, 1996

By H. J. Meyer

"A hydrostatic elevation difference meter has been developed for use in measuring elevations along gravity traverses. Elevations of stations 100 feet apart can be obtained at a rate of 1/2 mile per hour and to an accuracy better than 1/3 foot. This can be done along traverses which have not been cut and chained. The instrument is durable, lightweight and constructed of materials which will withstand any temperature encountered in field work.It is believed that this device will more than double the rate at which gravity surveys over mining prospects can be carried out."

Jan 1, 1972

By C. Caballero, A. Warczok, K. Itagaki, A. Moyano, J. Font

The Codelco Norte Smelter process 2,500 tpd of arsenic-bearing concentrates with an arsenic content of up to 1.5% in one of its two main smelting units, the Teniente Converter. The product, 1,100 tpd high-grade matte or white metal, is traditionally fed to the PS converters, while the 1,700 tpd of slag is fed to the slag cleaning electric furnace for copper recovery. This is achieved in a very reductive environment which reduces the viscosity of the slag and enhances the sedimentation of the high-grade matte droplets. The behavior of arsenic in this non-oxidative environment was studied at lab-scale and fundamental thermodynamic data were obtained. Based on these data a thermodynamicbase model to assess the arsenic behavior in reductive environment was developed. It is based on a mass balance for the reduction and sedimentation stages performed in an electric furnace which allows the recovery of high-grade matte droplets after decreasing the viscosity of the slag. This model can be a very suitable tool for predicting fractional distribution of arsenic in the slag cleaning electric furnace, when the distribution ratio, vapor saturation degree, temperature, y As and pO2 are given.

Jan 1, 2007

By G. Avramovic-Cingara, H. J. McQueen

The microstructure of commercially pure aluminum was investigated by using polarized optical microscopy (POM), orientation imaging microscopy (OIM), and transmission electron microscopy (TEM) techniques. Specimens were deformed in torsion at 400°C and equivalent strain rate of 0.1 s-1, to various strains of 0.2, 0.5, 1, 4, and 6. The results indicate that POM can usefully reveal grain and subgrain structures over a large field in aluminum. TEM is most suitable to study dislocation substructure and evolution of subgrains. While TEM microscopy and OIM are capable of resolving individual subgrains, OIM can not reliably distinguish subgrains with small misorientations, particularly in samples with low strain. On the other hand, the OIM technique is very useful in the analysis of many regions surrounded by high, medium, and low angle boundaries (HAB, MAB, LAB). Various misorientation maps were studied using different data processing methods. The analysis revealed that the subgrain size is relatively insensitive to strain. The fraction of low LAB ( < 5°) decreased and HAB (>15°) increased conversely with increasing strain, whereas MAB (5-15°) remained stable. The development of an increasingly bimodal grain boundary misorientation distribution is consistent with the predominance of dynamic recovery (DRV) in the evolution of microstructure, combined with geometrical dynamic recrystallization (gDRX), now called grain-refining DRV.

Jan 1, 2006

By O. Kangal, G. Önal, G. Bulut, A. Gül

The recovery of copper and cobalt from the ancient copper slags, located in Küre-Turkey, is investigated. Fayalitic type of ancient copper slags containing 1.41% Cu, 0.53% Co and 53.16% Fe were subject to the experimental study. Magnetic separation, gravity concentration and flotation test were conducted. The results of magnetic separation and gravity concentration were not satisfactory. However, a concentrate containing 9.57% Cu could be produced with 44.7% recovery by flotation. Copper and cobalt that remained in the flotation tailings was recovered by roasting with sulfuric acid followed by hot water leaching. Complete cobalt dissolution was observed in 1 hour of roasting at 150°C and 3:1 acid/slag ratio, whereas the copper recovery was 83%.

Jan 1, 2004

By J. F. Henderson, N. H. . C. Fraser

"Camlaren Mines, Limited, owns a group of claims near Gordon lake, in the Northwest Territories about 45 miles northeast of Yellowknife. The Hump vein on the property was explored continuously from the summer of 1937 to December, 1938, when all work was stopped. The two-compartment vertical shaft sunk near the vein is 380 feet deep and drifts and cross-cuts on the 200- and 350-foot levels total 2,241 feet . This exploration indicated 13,177 tons of ore with a gold content of between ½ and 1 ounce a ton1GEOLOGY AND STRUCTUREThe property is underlain by remarkably fresh greywacke and slate of the Early Precambrian Yellowknife group. The thickness of the b ~ds averages 1 to 2 feet, although that of the coarser greywacke may be 10 feet or more. Most of the greywacke beds show a gradation in grain from sandy at the base to slaty at the top. They are composed of chlorite, sericite; carbonate, and detrital quartz and feldspar grains.The structure of the greywacke and slate underlying a part of the property of Camlaren Mines, Limited, is shown in Fig. 1. The beds are isoclinally folded so that they dip at steep to vertical angles and at many places are overturned. The axes of the folds are 50 to several hundred feet apart, and generally plunge at angles of 45° or steeper. The beds along the axes of the folds generally meet to form a sharp V, and at the point of the V, or axial part of the fold, the beds are commonly ruptured . Minor faulting movements along the broken crests of the folds in many cases result in well-defined shear zones. Discontinuous quartz veins and irregular lens-like masses of quartz lying more or less parallel with the bedding are plentiful throughout the sediments, but tend to be concentrated along the ruptured and sheared, anticlinal and synclinal fold axes ( Fig. 1)."

Jan 1, 1954

By Eric Best

"In the past two to three years, all continuous mining machines at the Potash Corporation of Saskatchewan Mining Limited, Lanigan Division, have been changed over to a new cutting pattern using 1 -inch- and 1-3/l6-inch-diameter self-sharpening pencil bits. The bits are arranged in a cone-type pattern across the face on 2 1/2 -inch and 3-inch spacing. The result is that the ore is removed by chipping and flaking. Previously, rap-lock bits were used, with the pattern being several bits in single rows at wide spacings. The cutting action was grinding and breaking.Besides improved penetration rates and lower bit costs, there are many other advantages. The ore size is much smaller, resulting in less wear and tear on conveyors and other associated equipment. Feeder-breakers are no longer routinely set up at the head end of every extensible belt, as the banana-shaped chunks of ore that used to require breaking are no longer produced. Also, less dust is generated by the cutting heads and fewer stops are required for bit changes. Even the mill operation has been improved, as fewer fines are produced.Further improvements are still sought after, but, all in all, the new cutting pattern is considered to be a giant step forward from the old method."

Jan 1, 1981

By R. Farhat

Coating systems that yield a thermally grown oxide (TGO) protective layer have been proposed as a potential method for extending the lifecycle of components exposed to high temperature corrosion. This is particularly relevant to the petrochemical industry, where any reduction in corrosion rates can yield substantial cost reductions. The primary goal of this project is to develop a coating repair procedure and to investigate the oxidation performance of the repaired location. Electrospark deposition (ESD) was used to repair spalled segments of TGO grown on MCrA1Y substrates using various electrodes possessing mixed crystal structures. Specifically, electrodes of NiCoCrA1Y (BCC-FCC mixtures) and CoNiCrA1Y (FCCBCC mixtures), were deposited and oxidized to develop the TGO using a heat treatment of 24 hours at 1000°C in air. This presentation will focus on the microstructural evolution of the base metal and ESD repair on damaged area, in both as- deposited and oxidized forms. Results of SEM and XRD analysis will be presented.

Jan 1, 2011

By Roger J. Goodman

"Major industrial restructuring, which started to manifest itself in the mature economies of the Western World and Japan in the 1970s, will accelerate in the 1980s and 1990s. Conventional heavy manufacturing industries will continue to lose ground to lighter processing/assembly operations and the new wave of high technology, information and service sectors. The decline in heavy manufacturing has severely impacted on the steel industries of Western Europe, the U.S.A . and Japan.World trade in metallurgical coal has shifted correspondingly, with declining demand in the mature developed countries being only partially offset by large increases in the steel intensity of the newly-industrialized countries (NICs) of the Far East, Latin America and, to a more limited extent, the Middle East and Africa. These trends will be accentuated in future years with direct implications for the distribution of metallurgical coal trade. This paper discusses, in quantitative terms, such changes in the 1980s and 1990s, and examines the implications for, and impacts on, Canadian metallurgical coal exporters.IntroductionThe twenty-year period from the early 1950 s to the early 1970s was characterized by inexorable growth in consumer demand and industrial expansion in most of the advanced countries of the western world. Long- term forecasting during this period typically used linear extrapolation techniques which , despite their simplicity, invariably ended up predicting future demand and production level s with uncanny accuracy. Times have changed!The last decade has been characterized by a n abysmal failure of our economies to respond to simple long-term, linear growth patterns. We appear to have entered a new world in transition, where we can observe a wave of dying or sunset industries reluctantly being submerged by a wave of emerging or sunrise industries.This paper is aimed a t examining the evidence for long-term industrial restructuring trend s. For want of a better word, these so -called, megatrends are then used to predict future demand level s and spatial distribution of steel development and , hence, metallurgical coal trade. It is tempting to correlate the decline in economic activity in the western world with the first Organization of Petroleum Exporting Countries&apos; (OPEC) crisis of 1973. This crisis was probably no more than the straw that broke the camel&apos;s back, as the megatrends and embryo s of major industrial restructuring were already evident. Today these megatrends are merely more apparent and transparent than they were ten years ago.While the concept of industrial restructuring is the new economic buzz word, the process was at work, to a lesser degree even throughout the period of strong economic growth of the post-Second World War boom. Many people still remain convinced that our present-day sluggish economy is just part o f the typical , though rather more prolonged, recessionary cycle. Yet, we have always been part of a dynamic economic system and industry throughout history has been the subject of a continuous process of evolution, restructuring and reconstitution . Now the time is ripe to examine the evidence for such restructuring in order to develop coherent policies of adjustment in this transition from one industrial regime to another."

Jan 1, 1985

By J. F. Nie

Mechanical properties of precipitation hardenable magnesium alloys depend critically on the chemistry, structure, morphology, orientation and distribution of strengthening precipitates. It is therefore important to gain an improved understanding of these information and their correlations with mechanical properties. Our recent studies indicate that additions of 1-2 wt% of Zn to a Mg-6wt%Gd alloy result in a substantial enhancement in precipitation hardening and in creep resistance. If the strength and creep resistance of the resulting ternary alloy are to be further enhanced for commercial applications, then a detailed characterisation of the strengthening precipitates in these alloys is required. In the present study, the precipitates formed in a Mg-6Gd-1Zn-0.6Zr (wt%) alloy, peaked aged at 250°C, have been characterised in detail using transmission electron microscopy and 3-dimensional atom probe field-ion microscopy. It is found the peak-aged microstructure contains a dense and uniform distribution of precipitate plates that form on the basal plane of the matrix phase and are typically less than 1 nm in thickness. Detailed analyses of the structure and composition of these basal precipitate plates will be presented and discussed in the context of previous work on other Mg-RE¬Zn alloys of similar compositions.

Jan 1, 2006

By Mary Kama, Kaul Gena

"Magnetic skarn ore (MSO) is one of the major copper bearing ore extracted by the Ok Tedi Copper Mine in Papua New Guinea. Copper minerals are recovered by flotation while the iron not associated with copper are discarded as tailings. The objective of this investigation was to determine the iron ore reduction kinetics for the Ok Tedi MSO and ascertain if it can be processed to produce sponge iron for a mini steel plant in Papua New Guinea.SEM-EDAX analyses of the Ok Tedi MSO indicated 10.1% C, 30% O, 0.6% Mg, 1.1% Si, 21.1% S, 0.8% Ca and 36.2% Fe. Most of the iron is in sulfide form. Both naturally occurring and roasted sinters of Ok Tedi MSO samples of different particle sizes were reduced by charcoal carbon at three different temperatures and seven different reduction times. Analyses of the reduced products indicated a metallic iron content of more than 65 wt.% on average.Results showed that there was no significant difference in reduction between fluxed and control materials. Only a slight increase in kinetics with reduced particle size, hence the reaction rate constant (K) did not vary much within the temperatures investigated. Reaction kinetics increases with increasing reduction time at 900°C. Therefore, more iron reduction is observed with particles of 106 µm size. In addition, the results also confirmed that the reduction energy used was higher at 800°C and lower at 1,000°C. In summary, iron reduction can be improved but close monitoring of temperature and reduction times are essential to determine the reaction kinetics of the Ok Tedi MSO. INTRODUCTIONMost mines in Papua New Guinea mine large quantities of iron in the form of sulfides, carbonates, oxides and sulfates that are eventually disposed off as tailings. The Ok Tedi magnetic skarn ore (MSO) contains a significant amount of hematite, magnetite, siderite, ilmenite and pyrite that can be a source of iron. The mineralogical compositions of Ok Tedi MSO reveals more iron minerals than copper, yet all iron containing minerals are collected in the tails from the main copper production stream. Therefore, this study is conducted to investigate the possibility of producing direct reduced iron (DRI), or sponge iron, from the MSO. Such sponge iron may serve as the feedstock for electric arc/induction furnace based mini steel plants in Papua New Guinea."

Jan 1, 2016

By H. E. Wilde

"Zinc has been used for many years as a galvanic coating for the protection of steel. Electrochemical measurements show that zinc actually overprotects steel. The corrosion rate of DQSK (drawing quality semi-killed) steel in air saturated salt water was determined as a Junction of applied cathodic potential. The resulting data indicate that at a critical cathodic over potential of - O. 725 Vsce an acceptably low corrosion rate of less than 1 mpy occurs. Using the developed criterion, alloys of Zn/X and AL/X were produced and evaluated in galvanic contact with steel in a standard laboratory test. The results indicate that Zn /Mn, Zn /Co, AI/Mg/Si and AI/Mg/Ge alloys offer excellent galvanic protection along with (a) no hydrogen evolution, and (b) improved dissolution life over Zn coatings.IntroductionZinc coated (galvanized) steel has been successfully used in applications where bare (or painted non-galvanized) steel would suffer corrosive attack. In general, galvanic coupling to zinc, as either an anode or a coating, is an effective means for combatting steel corrosion. Because of this, the use of galvanized steel has increased markedly, stimulated primarily by automobile manufacurers seeking to extend the corrosion warranties on automobiles(1).Although effective, zinc coatings are not without a number of drawbacks which warrant efforts to improve them. For example, because of the widely differing electrode potentials between zinc and steel ( - 1.05 Vsce and - 0.60 Vscc, respectively, in air saturated NaCl solutions), the zinc corrodes at a rapid rate to protect the steel. This is reflected in the limited lifetimes of galvanized unpainted siding. The basic electrochemistry controlling the situation is shown in Figure 1, for a system controlled by oxygen reduction. The zinc corrodes sacrificially to protect the steel, while cathodically polarizing the steel to a potential near that of zinc&apos;s open circuit anode potential."

Jan 1, 1990

By Gaoming Wang

Outline 1. The Gangdese porphyry Cu-Mo belt 1.1 Regional geological background 1.2 Cu-Mo-bearing porphyries 1.3 Mineralization and alteration 2. Dating methods and results 2.1 Qulong porphyry 2.2 other porphyries 3. Geodynamic implications 4. Conclusions 5. Acknowledgements

May 1, 2004

By M. K. Aly

"ABSTRACTThis paper briefly describes the mining method proposed for the iron ore deposits in Wadi Shatti, western Libya. The iron ore produced will be used in the steel plant at Misurata on the Mediterranean coast. GeologyThe Wadi Shatti is located in the central part of western Libya. Flat iron-bearing sedimentary rocks are exposed with remarkable regularity in this valley. It occupies an area 200 km long by approximately 20 km wide trending in an eastnortheast direction between Jabal Fazzan in the north and Zel1af Sand Dunes in the south (Fig. I). Only a part of this valley has been ful1y explored by drilling on a 400- by 200-m pattern in an area of 18 km2 south of the town of Taroot. Farther to the south, no exploration by drilling can be done due to the presence of sand dunes .The iron-bearing bed is about 10to 15m thick, with a dip of 2 to 4 degrees in a southerly direction . The overburden consists mainly of clayey sandstones, 4 to 5 m thick, in the northern part, increasing to 35 m in the southern part. The iron ore bed consists of three different layers, from the floor upward: (1) Lower Reduced Ore (LRO), having a varying thickness of 1 to 7 m; (2) Magnetic Ore (MO), with a thickness varying from 4 to 12 m mainly in the central part of the area; and(3) Upper Reduced Ore (URO), with a bed thickness varying from 0 to 7 m."

Jan 1, 1980

By L. Kilpinen, K. R. Kay, H. B. Fowler

"FOREWORDThe International Nickel Company of Canada has built four ore concentrating plants since 1950. The fifth and largest is now under construction. In each successive plant, the level and type of instrument control and sophistication of control techniques have increased as experience was gained. The type of control progress is illustrated in Fig. 1.At Frood-Stobie the high degree of instrumentation and the level of control were made possible by the constant evolution of techniques and improved instrument hardware technology. We have established in practice concepts that are sound, although many modifications to instrument sensor types and locations 1-rere often necessary. It is generally true that at other existing Inco mills, it is possible to run ""all manual"" for protracted lengths of time because of operator availability and dependence. The Frood-Stobie Mill is the exception, and it is the degree of reliability of the instrumentation hardware and level of maintenance that has made this possible."

Jan 1, 1971

By Aalbert Zwijnenburg

One of problems connected with the use of gold/titania-based catalyst systems is the low yield in propene oxide (up to 2 wt %). It is shown that the low propene oxide yield is due to product inhibition. New options for propene epoxidation with hydrogen and oxygen are discussed. INTRODUCTION The direct gas-phase synthesis of propene oxide (PO), by the use of molecular oxygen, is still aimed for. Agbased catalysis is in principle possible, but selectivity at present is not promising. Highly dispersed gold on titanium containing catalysts show an extraordinary selectivity in the oxidation of propene to the corresponding epoxide (> 99 %), using a combination of H2 and O2 as oxidation mixture [1]. Additional studies of the epoxidation reaction have indicated several drawbacks of the Au/TiO2 catalyst. Firstly, the low conversion (1- 2 %) obtained under typical reaction conditions (atmospheric pressure, 323 - 423 K) cannot be increased by increasing the reaction temperature, because this leads to extensive by-product formation. Secondly, the low efficiency of hydrogen (relatively large amounts of water are formed) is hard to prevent. Finally, significant deactivation of Au/TiO2 catalysts within several hours on stream has been observed. Deactivation can be almost completely prevented by using dispersed TiO2 supports, such as TiO2/SiO2 and Titanium-Silicalite-1 (TS-1) [2]. In recent literature [2,3] a hydroperoxide-like intermediate has been proposed to be responsible for the selective epoxidation. This oxidising species is said to be formed over gold and subsequently used for epoxidation over the Ti-containing support. The support is responsible for the slow desorption of PO. One of the problems for future industrial application might be the low yield in propene oxide. Furthermore, the presence of minor amounts of by-products, not detected on lab-scale catalyst testing, might complicate the separation unit in an industrial process. The reason for the low PO yield over Au/TiO2-based catalysts will be discussed in this paper. Temperature Programmed Desorption (TPD) and micro-flow experiments have been carried out to study PO desorption and catalyst performance, respectively. A catalytic cycle is proposed together with its consequences for the maximum yield in PO. Finally, several process and catalyst options are discussed in view of potential future industrial application.

Oct 1, 2003

By R. Ricketts, D. G. Vanderveer, F. Kirby

"A program of mapping, sampling and testing to determine the potential of the aggregate resources throughout Newfoundland and Labrador was commenced in 1978. A 6-km-wide corridor parallel to all transportation routes was selected as the study area.The study consisted of a preliminary surficial interpretation followed by field mapping and sampling. Granular resources were sampled at a 500-m interval and non-granular materials were sampled at a 1.5- to 2-km interval. Data were gathered on landforms and stratigraphy as well as a field description of the sample and deposit types. Particle-size and lithologic analyses of the samples were also conducted.The locations of samples and deposits were mapped on 1:50,000 topographic base maps and summarized for publication at a 1:250,000 scale. Surficial geology maps were produced at a 1:50,000 scale. A computer program is being developed for the search and retrieval of field data.The first phase of the Inventory of Aggregate Resources program is nearing completion and to date has collected information on approximately 9,500 samples throughout Newfoundland and Labrador. This data will be used to provide f or the effective management of these vital non-renewable aggregate resources.The mineral aggregate industry in Newfoundland and Labrador is very competitive, but undercapitalized when compared to other provinces. The demand for aggregates is forecasted to increase to in excess of23 million tons per annum by the year 2002.In terms of over-all mineral production, the extraction of sand, gravel and stone has a significant impact when compared to other minerals in terms of value and tonnage produced.IntroductionThe province of Newfoundland has approximately 18,000 km of coastline. A large proportion of the population lives in coastal communities where, traditionally, beaches have been a major source of construction materials. Beaches have, therefore, often been subjected to overutilization, resulting in erosion of back beach areas or adjacent headlands."

Jan 1, 1982

By T. L. Carpenter

"The presence of excessive water in the Gibraltar East Stage 1 pit initiated studies into the ground-water conditions that might be expected in mining the Granite Lake and Pollyanna pits. Hydrologic information obtained from a pump test program in 1974 indicated that deep-well dewatering could be successfully achieved. In 1976, a deep-well dewatering system consisting of eight wells was installed on the periphery of the Pollyanna pit . it has been responsible for a significant decrease in mining costs.This paper presents a brief summary of the engineering principles involved in the design of the Gibraltar dewatering system and the problems encountered in the installation and operation of deep-well pumps. IntroductionGibraltar Mines is an open-pit copper-molybdenite mine located approximately 230 air miles north of Vancouver in the central interior of British Columbia (Fig. I). The property consists of three separate major orebodies; Gibraltar East, Granite Lake and Pollyanna (Fig. 2). Mining commenced during the summer of 1971, in the Gibraltar East Stage 1 pit. The Granite Lake Stage 1 pit was mined from mid 1974 to mid 1976. The Pollyanna Stage 1 pit is currently being mined and the Gibraltar East Stage 2 is being developed for production. This report is intended as an outline of the studies and tests leading up to and including the installation of the Pollyanna pit dewatering system, the problems encountered and the results obtained.GeneralIn the summer of 1973, mining in the Gibraltar East pit progressed below ""daylight"" on the down-hill side and ground water very quickly became a costly nuisance in the day-to-day mining operations. Mining, maintenance and blasting costs reflected these problems. Concern was also voiced about adverse effects of ground water on pit wall stability. This concern later became a reality in the Gibraltar East and Granite Lake pits. A study was initiated to investigate various methods and costs of dewatering the pit areas. The study included in-pit sumps, deep peripheral wells and a drainage gallery system located below the pits."

Jan 1, 1980

By E. Ghali, W. Zhang, C. Su, N. Sorour, G. Houlachi

"Zinc electrowinning process is sensitive to the presence of metallic impurities such as lead ions that could substantially and negatively affect the power consumption and surface morphology. Effect of various concentrations of manganese ions and traces of lead ions up to 2.5 mg L-1 added to the electrolyte during electrowinning have been investigated by electrochemical polarization techniques such as galvanostatic, cyclic voltammetry and potentiodynamic. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were applied to examine the surface morphology and crystallographic orientation, respectively. Microwave plasma-atomic emission spectrometry has been used to determine the lead content in the deposit and in the electrolyte after electrodeposition. It was found that lead ions added to the zinc electrolyte led to the increase of cathodic overpotential and current efficiencies of zinc deposit. However, addition of Mn2+ into the zinc electrolyte resulted in the decrease of cathodic potential and current efficiency of zinc deposit. It can be stated as example that galvanostatic polarisation at 40?C and 52.5 mA cm-2 in presence of lead up to 0.1-0.2 mg L-1 in the electrolyte and 8-12 g L-1 Mn could be better considered as practical working parameters for electrowinning process.INTRODUCTIONApproximately 85% of the global production of zinc metal is produced by electrolytic process (Sinclair, 2005). The main goal of the zinc plant is to obtain pure zinc deposits with high current efficiencies. Smooth and pure deposits with high current efficiency (CE) are always obtained from pure electrolytes (Alfantazi & Dreisinger, 2001). The presence of metallic impurities in the zinc sulphate electrolyte is a major problem for the zinc electrowinning industry, since decreases in current efficiency, changes in deposit morphology and cathodic polarization are observed for electrolytes containing small concentrations of impurities (Ault & Frazer, 1988; Muresan, Maurin, Oniciu & Gaga, 1996). Low level concentrations as parts per million of these impurities are reported to influence negatively the zinc electrodeposition (Beshore, Flori, Schade & O'Keefe, 1987)."

Jan 1, 2016