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By John Rowson, Caitlin Brown, Kebbi Hughes, Joseph Esslifie-Dughan

The McClean Lake mill in northern Saskatchewan, Canada, is operated by Orano Canada Inc. and has been in production for the last 20 years. The tailings preparation process at the mill has been designed with decommissioning in mind, to produce tailings that are geochemically stable over the long-term within the site’s tailings management facility. Twenty years of study have contributed to a detailed understanding of geochemical and geotechnical properties of the McClean Lake tailings. Validation of the tailings properties has occurred through in-situ sampling campaigns conducted initially every year, and later every five years. Each sampling campaign has applied the same rigorous sampling procedure to provide data with useful correlations year over year. Each campaign result compares elements such as the inherent variability of the tailings, consolidation of the tailings and variations in the tailings placement methods. We will discuss lessons learned from seven sampling campaigns over 20 years and present data to show the reliable tracking of geochemical evolution of the in-situ tailings over time; providing opportunities for continuous improvements.

Jan 1, 2020

By Ken J. Brouwer

Stillwater Mining Company commenced construction and development of the East Boulder underground mine in 1998. This new PGM mine is situated adjacent to the East Boulder River approximately 35 miles south of Big Timber, Montana. Project planning and development incorporated detailed collaboration between the regulatory agencies, concerned citizens and mine personnel. A unique ?good neighbour agreement? was established with a local environmental group who have become actively involved in the review of ongoing site development and the implementation of environmental and compliance monitoring. Environmental management systems allow for integrated management of tailings, waste rock and water in order to minimize surface disturbances and to prevent adverse impacts to the East Boulder River. Long-term site development plans contemplate implementation of comingled waste rock and paste tailings. Water management capabilities allow biological treatment of all excess mine water in order to reduce nitrogen loadings prior to land application disposal by means of spray evaporation, snow making and land application. The comprehensive waste and water management plans have also been integrated with staged mine development and interim reclamation requirements.

May 1, 2002

By Carmen M. Neculita

Optimizing the long-term efficiency of passive systems for the treatment of highly contaminated acid mine drainage (AMD) is still a challenging issue. The optimization lies, among others, on improving the understanding and quantification of metal removal mechanisms in order to predict and enhance the stability of neo-formed minerals in secondary phases. Sorption, and precipitation as oxides-hydroxides, carbonates and bio-sulfides are likely the most important metal removal mechanisms involved in passive biotreatment of both slightly and highly contaminated AMD. In the same time, the preferred mechanism is precipitation of metal sulfides that are more stable and less pH dependent than carbonates and oxides-hydroxides. However, results of relatively recent research studies performed at laboratory scale showed that sulfides accounted only for up to 15% of total metals removed in passive bioreactors treating highly contaminated AMD dominated by iron (around 500 mg/L). Several approaches were used in the aforementioned studies to understand and quantify metal removal mechanisms in spent reactive mixtures collected from long-term (12-15 months) operating column bioreactors. These included: thermodynamic equilibrium modeling and various chemical extractions and mineralogical analyses (such as single and sequential extractions, acid volatile sulfides-simultaneously extracted metals determination, scanning electron microscopy, X-ray diffraction, and thermo-gravimetric analysis). The large proportion of metals (85%) removed by sorption and precipitation as oxides-hydroxides and carbonates suggests a relatively high mobility of the neoformed minerals, especially in low pH conditions. However, no data is available on the long-term stability of spent reactive mixtures and, on the implications for the sustainable management of this type of solid waste. Lately there is almost a consensus that the efficiency of highly contaminated AMD treatment is warranted by the use of multi-step passive systems, including both chemical and biological units, installed sequentially. However, very few well-documented studies are available on the design, construction, operation and long-term efficiency of these multi-step systems. A leading example is the tri-unit passive system installed on the abandoned Lorraine mine site (Québec) to treat a highly contaminated AMD dominated by iron (about 2,500 mg/L). This tri-step system (160 m3), consisting in two bioreactors separated by a unit filled with wood ashes, achieves to date a satisfactory removal of iron (up to 99%). Moreover, based on the data collected during laboratory testing, iron was mainly removed in the wood ashes unit (from around 3,200 mg/L to 10 mg/L) by precipitation of oxides-hydroxides as predominant mechanism and only partially by sorption. However, no data is available on the actual metal removal mechanisms in the field. Overall, theses multi-step systems are more complex and their long-term performance is even less predictable than the single unit systems. This paper presents the current knowledge and the research needs on metal removal mechanisms in passive bioreactors and multi-step systems for the long-term treatment of highly contaminated AMD. KEYWORDS

Aug 1, 2013

By Seungwoo Park, Whuisu Shim, Roe-Hoan Yoon, Kaiwu Huang

"A comprehensive froth model has been derived from first principles. It is based on predicting the kinetics of film thinning in the presence of particles of varying sizes and surface hydrophobicity. According to the Reynolds lubrication theory, the thinning of a horizontal film is driven by the excess film pressure (p), which is determined by the capillary pressure (pc) and the disjoining pressure (II). In the presence of particles, macroscopic capillary pressure (pc) is affected by the local capillary pressure (pc,local) in the vicinity of a particle and the number of particles in the film (N1,film), which in turn vary with the hydrophobicity and size of the particles. The Reynolds equation corrected for pc,local and N1,film is then used to predict the time (or froth height) at which a film is thinned to a critical rupture thickness (hcr), which in turn can be predicted using the Vrij’s capillary wave model (1966) after a modification to incorporate the contributions from hydrophobic disjoining pressure (IIhp). The model can predict bubble coarsening represented by the bubble size ratio between the top (d2,t) and bottom (d2,b) of a froth as functions of particle size and hydrophobicity, ? -potentials, frother dosages, froth height, gas flow rate, salt concentration, etc. The model predictions have been verified in experiments.INTRODUCTIONFroth flotation is regarded the best available technology today for upgrading minerals and coal fines. In the pulp phase of a flotation cell, air bubbles collect hydrophobic particles dispersed in it and rise to enter the froth phase on the top. Once in a froth phase, the bubbles coalesce with each other and become larger, resulting in a decreased bubble surface area. Under conditions of limited surface area, less hydrophobic particles drop off the bubble surface and return to the pulp phase. Thus, bubble coarsening provides a useful mechanism of increasing product grades. On the other hand, uncontrolled coarsening results in a decrease in bubble carrying capacity and hence throughput."

Jan 1, 2016

By J. W. Reynolds

Use of crushed waste rock recovered by sink-float separation from normal ore production for backfill is an established procedure at Commco's Sulhvan mme, Kimberley, British Columbia. Need for a safe method of placement in voids which were difficult to reach by gravity methods led to a co-operative venture with Radmark Engineering Ltd. in the development of a workable pneumatic transportation system for rock material. This paper reviews work done to date in a current program, and includes comments on the nature of the fill so placed, options for cementing such fill, implications for other aspects of mining and references to other applications of the system by other organizations who exchanged experiences with the Sullivan mine staff during the five-year period reviewed.

Jan 1, 1972

By Terry J. Briggs, Ian J. Kelso

"Abstract- The Century mine in northwest Queensland,Australia, is a major sediment-hosted zinclead- silver orebody, located within the western Mount Isa Basin. Stratiform, carbonaceous shalehosted mineralization is developed within Proterozoic shale and siltstone sequences of the Lawn Hill Formation. CRA Exploration Pty Ltd (CRAE) discovered the Century deposit in 1990 and open pit mine development commenced in 1998 under the ownership of Pasminco Century Mine Limited (PCML). The deposit contains an identified mineral resource of 105 Mt @ 12.1% Zn + 1.7% Pb + 46 g/t Ag (Broadbent and Waltho, 1998) which is currently being mined at a rate of 5 Mt/y.In December 1998, an exothermic reaction was observed between explosives spilt onto shale drill cuttings from a blasthole. This reaction is referred to as ‘reactive ground’ and has the potential to cause premature detonation of explosives in a charged blasthole with catastrophic consequences. The incident led to a subsequent geological and geochemical assessment of the different rock types at the Century deposit and their potential reactivity with ammonium nitrate-based (AN) explosive products. This assessment was conducted in an attempt to characterize zones safe for blasting with uninhibited AN-based explosive products. A direct result of this study is a set of procedures outlining the use of different AN-based explosives in areas defined as potentially reactive or non-reactive for the different lithologies present. Black shales contained in both the waste and mineralized sequences contain the sulfide mineral pyrite (FeS2), which is thermodynamically unstable with AN contained in commonly used explosives. The potential reactivity of partially weathered pyrite can ultimately result in the decomposition of an AN-based explosive. It was determined that only pyritic black shales showed any potential to react with AN, irrespective of their position in the stratigraphic sequence. Other lithologies present at Century, including Proterozoic sandstone and Cambrian limestone, are classified as non-reactive with AN. This is a geological risk management situation present at the Century mine."

Jan 1, 2001

By E. R. Mitchell

When we grow up in an urban environment and choose to become a part of a way of life, it is sometimes difficult to appreciate the cost of this decision in terms of pollution. Explained in this article is our dependence on technology and the amount of pollution that technology produces. Inventories of air pollution on both a personal and a national basis are given so that the reader may judge the magnitude of the problem. In doing so, it is hoped that the reader will understand the need for a responsible attitude toward pollution by everyone and how he can make a personal contribution.

Jan 1, 1971

By C. G. Anderson

As the global demand for copper and gold steadily increases and the need for environmentally sound processing also grows, successful hydrometallurgical treatment of enargite (Cu3AsS4) concentrates has come to the forefront. This type of concentrate contains considerable arsenic so that successful arsenic fixation, for example as scorodite, is of the essence. This paper outlines the successful application of low temperature and low pressure nitrogen species catalyzed (NSC) hydrometallurgical pressure oxidation of enargite concentrates. The successful stabilization of the arsenic as an iron arsenate compound is discussed. Also, the use of experimental design software is highlighted as a process application and optimization tool.

Jan 1, 2006

By G. Cailletaud, I. Guillot, D. Larouche, R. Martinez, D. Massinon

The precipitation of Al2Cu particles in a 319 T7 aluminum alloy has been modeled. A theoretical approach enables the concomitant computation of nucleation, growth and coarsening, based on an implicit scheme using the finite differences. The equation of continuity is discretized in time and space in order to obtain a matricial form. The inversion of a tridiagonal matrix allows us to determine the evolution of the size distribution of Al2Cu particles at t + dt. The fluxes of solute in-between the boundaries, as well as the ones at the boundaries, are computed in order to respect the conservation of the mass of the system. The main results of the model are compared to TEM measurements. Simulations provide quantitative features on the impact of the cooling rate on the size distribution of Al2Cu particles in good agreement with the TEM measurements. This metallurgical model is integrated into FEA software in order to perform mechanical computations. This kind of multiscale approach allows new perspectives to be investigated in the process of designing cylinder heads. It enables a more precise prediction of the microstructure, its evolution as a function of continuous cooling rates and its impact on the integrity of the structure.

Jan 1, 2015

By J. M. B. Scarborough

This paper deals with measures taken to maintain effective operation of heavy-duty equipment in open-pit mining. at Pine Point, N.W.T., during periods of extreme cold weather. The points covered include equipment modifications designed to improve cold-weather performance, effective lubrication of machinery that is vulnerable to extreme cold and operating procedures designed to prevent equipment damage.

Jan 1, 1966

By K. Iturralde

Dense transport infrastructure areas lack green facilities, they produce annoying noise and they are big energy consumers. As far as there is no free land or space, adding a vegetal covering to existing infrastructures has become a choice in order to get a more pleasant and comfortable environment. Noise barriers are getting spread all over the highways and sometimes they install photovoltaic panels. Is this just a hype or are there real causes? A green acoustic barrier with an energy generator could be interesting for covering the existing urban transport infrastructures. The specific geometry of the infrastructures requires a personalized product. If we measure the infrastructure environment's characteristics, which are humidity, temperature, sunlight and size, we can create an accurate 3D model. This model would be used for various purposes. For instance, it could be a useful tool to design and fabricate the customized prefab acoustic barriers and plant containers. And it would be helpful for adjusting efficiently the future performance of the vegetation and photovoltaic panels. But the insertion of vegetal elements in infrastructure surroundings can be a tough operation. It requires special skills and techniques. Nowadays, those tasks are performed almost manually and they require a big effort. The prefab containers for vegetal elements would ease the robotic assembly on site.

Aug 1, 2013

By A. Koning, P. Lauzon

Pressure hydrometallurgy operations require vessels to be lined with an impermeable membrane for corrosion protection and one or more courses of refractory or ceramic brick. Examples of unit operations that utilize composite lining systems include pressure oxidation autoclaves, sulphide precipitation autoclaves, chloride leach reactors, flash vessels, cyclone separators, and direct contact condensers (heater vessels and quench vessels). The refractory lining must satisfy multiple requirements: it must thermally insulate the membrane from process fluid, be structurally stable, provide erosion resistance, be chemically compatible with process fluid, and provide an economic service life. New hydrometallurgical processes are pushing the pressure, and temperature, with each new generation of plants. A fundamental understanding of all factors affecting the mechanical stability of the lining system is essential as lining designs move further away from the industry's experience base. The impact of irreversible chemical swell, operating factors, design factors, and installation factors are presented based on modifications to the traditional one-dimensional mechanical stress model. A new stability criterion - that the brick lining remain in contact with the steel shell membrane - is presented. This new stability criterion imposes new restrictions on the lining design.The effect of geometry and adding additional degrees of freedom to the analysis is explored using two-dimensional and three-dimensional Finite Element Analysis (FEA). The effect of these additional degrees of freedom on the results of the one-dimensional model are discussed.

Jan 1, 2004

By Minerals Refining Company, Gerald Luttrell, Biao Li, Robert Bratton, Roe-Hoan Yoon, Stan Suboleski, Nikhil Gupta

Flotation is regarded as the best available method of upgrading coal and mineral fines in the mining industry. However, its efficiency deteriorates rapidly with decreasing particle size. Furthermore, ultrafine concentrates are difficult to be dewatered economically. Due to these technological problems, some operators are forced to discard at least part of the ultrafine materials to tailings (or refuse) ponds, causing significant losses of valuable resources and creating environmental concerns. To address these technological issues, a new separation process named hydrophobic-hydrophilic separation has been developed on the basis of the recent advances in the science of hydrophobic interactions. The results obtained to date show that the process can recover and dewater ultrafine particles simultaneously with high separation efficiencies. Following a series of extensive laboratory tests, the process has been scaled up to proof-of-concept and pilot-scale continuous tests. The results obtained with desliming cyclone overflows, screenbowl effluents, and by-zero coal flotation feeds can be cleaned to less than 4% ash and moisture with over 97% organic matter (or coal) recoveries. The results obtained with mineral fines also showed encouraging results.

Jan 1, 2016

By Yves Gagnon, Nicole Gauthier, Daniel Kelly, Michel Rocheleau

"The Larder Lake-Cadillac Tectonic Zone in Rouyn-Beauchastel area (a 20 km long segment) contains distinct lithotectonic units bounded by artastomosing or sub-parallel shear zones. The gold deposits in the area are located within highly strained portions of E-W striking shear zones. The ore-zones are structurally controlled disseminated and vein-type lodes. They are spatially related either to megascopic z-shaped folds which refold E-W shears, or to areas of intersection between E-W shear zones and late NE-striking faults. Several ore bodies are enclosed within ultramafic rock units or at their contacts with adjacent units. All the lenses are elongated down dip and distributed, both loterally and vertically, ""en echelon"" . The ore zones tend to decrease in size and number away from the hinge zone of the megascopic z-shaped folds.Two main styles of mineralization are recognized at the Astoria deposit and at for most of the deposits in the Rouyn-Beauchastel segments a discontinuous ""Carbonate Ore"" and a more continuous, albitic sulphide-bearing ""Flow Ore"" (terminology used at the Kerr Addison mine).The typical ""Carbonate Ore"" zones are found within strongly arbonatized blocks bounded by conjugate late NE or NNW-striking fralls. The carbonatized blocks display features characteristic of llrittle to brittle-ductile deformation developed in shear zone system. Vein systems in the ""Carbonate Ore"" occur within shear fractures(D R)tension fractures (T), or within brecciated rocks adjacent to NS llrilcing faults. The ""Carbonate Ore"" zones are displaced by numer IU lole E-W, NNE, NW and N-S faults.The ""Flow Ore"" zones are found within predominantly ductile portions of E-W shear zones. The sulphide mineralization is finely disseminated and regularly distributed within mylonitic foliation or associated with veins and veinlets sub-parallel or oblique to the mylonitic foliation, in which case the mineralization is coarser grained. The gold mineralization is a late Archean event postdating the formation of the penetrative fabric, and synchronous with the end of the dextral oblique-slip motion."

Jan 1, 1990

By D. Bai, F. Hamad, S. Abraham

For the integrity of welded structures such as pipelines, the toughness of the heat-affected zones (HAZ) is an important property. This property is often specified in terms of Charpy V-notch (CVN) impact toughness and determined by the standard test method. An experimental study has been conducted in an industrial laboratory to measure the impact toughness of the coarse grain heat-affected zones (CGHAZ) of an X80 line pipe material. The field girth welding conditions in terms of heat input were simulated, together with special edge preparation to improve the targeted testing of the CGHAZ. The effect of toughness of the neighboring regions, in particular the weld metal, on measured impact toughness of the CGHAZ was investigated. The fracture paths of the CVN tested samples were examined by both optical and scanning electron microscopy. The deviation of segments of the fracture path into the weld metal was found to have a significant effect on the measured impact toughness of the CGHAZ.

Jan 1, 2005

By Liangtian Liu, Tie Ou, Guangqiang Li, Chenghuan Yu

For stabilizing the production of containing nitrogen steels, a study on nitrogen absorption behavior of killed molten steel has been carried out by means of the RH vacuum device in which nitrogen was used as a driving gas. The results showed that there was an increase of nitrogen content in molten steel under vacuum processing but the rate of nitrogen absorption was slowed down by the surface active elements. Therefore, a kinetic equation for nitrogen absorption of molten steel with apparent first order reaction was derived by constructing a modified model in which the adsorption of closed surface site was taken into account. The experimental results confiimed that the calculated values agreed with the observed ones. This model is suitable for the prediction of nitrogen adsorption operation for containing nitrogen steels.

Jan 1, 2004

By S. Kelebek

Batch flotation tests were carried out using samples from stockpiles that were up to 1.5 months old as well as fresh samples oxidized in the lab for up to six months. Head grades and size distributions of samples were equalized whenever possible. The samples from stockpiles and oxidation experiments produced inferior nickel grade-recovery compared to the fresh sample. The poorer grade-recovery performance was attributable to two factors. First, a significant dilution effect was observed due to complete flotation of pyrrhotite. Secondly, the same stockpiling conditions caused nickel losses that were attributable to non-floatability of some pentlandite. Application of a high pH of 10 compared to the regular pH of 9.2 slowed down pyrrhotite flotation kinetics, but was not able to prevent complete flotation after 8 minutes. The samples oxidized in the lab did not match full characteristics of stockpile samples. They provided somewhat better selectivity for pentlandite. Some correlations were observed on a qualitative basis between surface characteristics such as elemental sulphur formation, activation and flotation behaviour. Oxidation conditions, which induce floatability on pyrrhotite while causing incremental loss in pentlandite floatability appear to be the root cause of difficulties in the processing of oxidized forms of these ores.

Jan 1, 2006

By R. E. Whitehead

"Abstract - Alkali-alumina and MgO-alumina plots are an effective instrument for displaying chemical and mineralogical compositions of altered and unaltered rhyolites and rhyodacites. They reveal that most supposedly unaltered rhyolites, apart from those of Cenozoic age, have undergone losses in Na2O and gains in K2O. The extreme loss of Na2O from highly altered rhyolites immediately adjacent to VMS deposits is strikingly illustrated by alkali-alumina plots. MgO/Al2O3 vs. K2O/Al2O3 diagrams display a strong negative correlation between MgO and K2O that results from the conversion of sericite to chlorite. A similar negative correlation between MgO and whole-rock d18O is apparent on plots of these two parameters. Alkali-alumina plots underscore problems in selecting appropriate precursor compositions required for mass-balance calculations. Molar ratio plots are a viable alternative to such calculations. Sommaire -Les diagrammes alcali-alumine et MgO-alumine constituent un instrument efficace pour la représentation des compositions chimiques et minéralogiques des rhyolites et rhyodacites altérées et fraîches.Ces diagrammes révèlent qu’à l'exception de celles d’âge Cénozoïque, la plupart des rhyolites qualifiées de fraîches ont subi une perte de Na2O et un gain de K2O. L’intense perte en Na2O que l’on note dans les rhyolites fortement altérées associées aux gîtes de type SMV est particulièrement bien mise en évidence par le diagramme alcali-alumine. Le diagramme MgO/Al2O3 vs. K2O/Al2O3 montre une forte corrélation inverse entre le MgO et le K2O due à la conversion de la séricite en chlorite. Une corrélation inverse analogue entre le MgO et le d18O de la roche totale s’observe sur un graphe comparant ces deux paramètres. L’usage du diagramme alcali-alumine fait ressortir combien il peut être difficile de choisir un précurseur de composition appropriée pour des calculs de balance de masse. Les diagrammes de rapport molaire constituent une alternative à de tels calculs."

Jan 1, 2006

By R. B. Kaunda

One fundamental requirement for surface and underground rock engineering is the ability to characterise the rock mass. An accurate characterisation of the rock mass allows rock engineers to optimize designs safely and economically. A number of classification systems have been developed in the past 50 years to help characterise rock masses such as RMR, Q system, Rmi, and several others. The challenge in developing rock characterisation schemes is often practicality, i.e. creating systems with relatively simple inputs for the everyday practitioner. A second challenge is the degree of subjectivity often inherent in commonly used classification systems. These challenges are especially exacerbated in weak rock or densely jointed rock masses. This paper introduces a new approach to characterise densely jointed rock mass using artificial neural networks and principal component analysis, based on principles commonly used in the geotechnical engineering of rock fills and waste rock dumps. Thirteen input parameters are dimensionally compressed using principal component analysis. Using a global database with more than 100 case histories, an artificial neural network is developed to conduct the rock mass characterisation. The advantage of this approach is less subjectivity as commonly used engineering (quantitative) terms are put to use. A further advantage is that given that the method is site-data dependent, it allows for ‘fine tuning’ of the model for a specific site.

Jan 1, 2015

By W. R. Hopkins, J. A. Davis

"This paper presents a discussion of the mechanisms by which aerosols of the process electrolyte are entrained into the breathing environment of copper, Zinc and nickel eIectrowinning tankhouses. Literature outlining the health effects associated with worker & posure to the acidic and metallic contaminants found in the airbome aerosols is summarized and compared with existing North American regulations.A brief review of the existing technologies for the source reduction of these aerosols is presented. This paper outlines the industry experience with use of covers, balls, beads, shapes, fixtures and chemical surfaetants. Each of these devices is ranked according to its effusiveness in the process in which it is used, and rated according to its operator acceptance.The various forms of existing in-plant ventilation systems are reviewed with a discussion of their relative merits and effectiveness. Actual experience is related, detailing the methods of testing for ambient contaminant levels in a variety of tankhouse environments. Guidelines are provided for the site and process specific criteria which govern the selection and ultimate effectiveness of a particular form of ventilation system.Finally, actual project experience is cited in which hydraulic modelling is used a design tool in tankhouse ventilation design. These projects include the upgrading of existing traditional ventilation designs, and the ''grass roots"" design of a more efficient aerosol source control system to be used in high altitude, cold weather sites."

Jan 1, 1994