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By G M. Thorpe

This paper discusses mine research at Inco, giving specific examples of research projects which illustrate the approach to mining problems. The first example covers the development of a new mining method, "undercut and fill," which was originated for mining badly broken-up pillars, but which is now rapidly replacing the square set method of pillar recovery. In the new method, ore is extracted in a series of successive horizontal cuts, progressing downward, a cut being completely mined and filled before the cut below is started. In the second example, improvements to the "cut and fill" method of mining are discussed. These improvements are the result of improved techniques and improved equipment, etc., with, in many cases, the former being made possible by the latter. The advances made have permitted the use of the "cut and fill" method at much greater depths than before. The third example is presented to illustrate research undertaken to obtain the earliest maximum advantage of the introduction of a new piece of equipment or material. For this purpose, the development of the "Under-ground use of AN /FO Blasting Agent " has been selected. Work on this project started in May, 1960, at a time when there was very little in-formation regarding the potentialities of AN /FO for underground blasting, either primary or secondary. By the end of 1961, AN /FO made up 64 per cent of the explosives used under-ground at Inco mines.

Jan 1, 1963

By W. E. Halle, G. J. S. Govett

"The Institute of Applied Geology, Manila, Philippines, is jointly sponsored by the University of the Philippines, the Philippines Bureau of Mines and the United Nations Development Programme (Special Fund). It provides, in its fourth year of operation, an interesting example of international cooperation in mineral development. Objectives include: (1) the training of mining engineers in modern techniques of mineral exploration; (2) assisting government and industry in discovering new ore deposits; and (3) providing the basis for the establishment of an economically oriented graduate school of geology at the University, the first of its kind in the country. Training of engineers requires roughly one full year, which is divided between academic study and actual field practice. Lecture and laboratory instruction include courses at university level designed specifically to up-grade those aspects of the geological sciences that are required by mining engineers now qualifying as mineral exploration engineers-economic geology, applied geochemistry, geo-physical exploration, petrology and structural geology. The field training involves direct participation in actual mineral exploration projects arranged with the co-operation of the Bureau of Mines and private interests engaged in mineral development and production. The system works well in practice, and the Institute staff and trainees were responsible for outlining new evidence of economic mineralization. It is also apparent from the application of the exploration methods available to the project -geological mapping, air photo interpretation, magnetic, electric, electromagnetic, self potential and gravity surveying as well as geochemical prospecting -that, under the humid, tropical, mountainous conditions in which the practical program was conducted, air-supported geochemical prospecting with attendant reconnaissance geological mapping affords the most economical and effective approach to mineral exploration for at least some of the deposits characteristic of the region."

Jan 1, 1968

By G. Fuentes, J. Viñals

"The nature and basic kinetics of the hydrothermal reactions of bornite, covellite pyrite and enargite with copper sulfate solutions were investigated, as a previous study on the behavior of the bulk Chilean copper concentrates. The reaction of bornite produced digenite at 160 °C and djurleite above this temperature. Covellite was transformed to digenite at < 200 °C and to chalcocite (Q and M) at > 200 °C. The pyrite reaction was significant at > 200 °C and extensive at 240 °C, enargite reacts only above 240°C and produces digenite. The hydrothermal treatment of Chilean Codelco-type copper concentrates with hydrothermal reactions was similar to those obtained from pure mineral samples.INTRODUCTIONStudies on the hydrothermal enrichment of chalcopyrite concentrates were begun by MacGauley and Roberts (1951), Roberts et al. (1953) and MacGauley and Schaufelberger (1956). In the 1970's these processes were reexamined by McKay et al. (1972), and Johnson and Coltrinari (1976), but it not was until the 1990s when the kinetics, mechanisms and full engineering aspects were studied by Barlett, (1992), Jang and Wadsworth, (1994) and Peterson and Wadsworth (1994). The main objectives were to solve some important problems in the copper pyrometallurgy: The increase of the smelting capacity, the reduction of the iron slag – and associated copper losses – as well as the reduction of sulfur emissions. The present rise in copper demand and price implies the production and subsequent treatment of very impure concentrates. Thus, a significant increase of environmental problems can be expected in the copper pyrometallurgy. The previous purification of concentrates can reduce the processing of wastes containing hazardous heavy metals in the copper refineries and the hydrothermal treatment can be an alternative which combines both enrichment and purification. On the other hand, Chuquicamatatype concentrates (Viñals et al., 2004a) contains digenite (Cu1.8S), pyrite (FeS2), chalcopyrite(CuFeS2), b ornite (Cu5FeS4), covellite (CuS) and sphalerite (ZnS) as the main mineral components, with minor amounts of enargite (Cu3AsS4), galena (PbS) and molybdenite (MoS2)."

Jan 1, 2012

By Joanna LaForte

"IntroductionIn respect to The Human Dimension by M. Phyllis Bray, this author&apos;s impression is that research on long distance commuting (LDC) is long overdue. This type of mining is not new to many workers, especially those from areas such as the Maritimes, who have had to look for work away from their families for at least a decade. Perhaps to the industry the over-all set-up is new, but to workers who have faced mine shut-downs in their areas finding a job was the main objective and if the security of long-term employment was evident, then the families might join them later. This was the situation with which the writer&apos; s family was faced.LDC LifestyleBeing the wife of an underground miner, the author has personally experienced this lifestyle for almost 10 years, and has never experienced accommodation in a company town. The first five years of marriage were spent in a small rural municipality within 50 miles of the worksite, but the town had industry separate from mining and was not affected by the mine shut-down.Since her LDC lifestyle began her family has been pretty much city-based, out-of-province commuters with two children and a third to arrive some years later. She therefore lived a fairly normal married life with a husband home daily. The author has experienced life with a husband who worked away for five-day stretches and then drove long distances to be home weekends or the portion of time left over from driving and fatigue. She has done the 3D-days in/l4-days out routine, and for approximately the past four years has been existing on a two-weeks in/two-weeks out ritual .The author does not agree that the ""bottom line is that mining families go where the jobs are"" . The miners go where the jobs are and the families fend for themselves with the assistance of the pay cheque making it home each pay period.Perhaps because there are many personal frustrations with this type of lifestyle, perceptions may be inaccurate. Having only dealt with underground operations, there may be gross differences between the pressures and demands of other forms of mining."

Jan 1, 1991

By CIM Mineral Resource, Mineral Reserve Committee

Industrial minerals are generally considered to include non-metallic minerals, mineral products, or materials that provide raw material inputs for the construction, chemical, and manufacturing industries. They are often relatively low-value and bulky materials that are generally used close to where they are produced; however, some raw materials may be transported hundreds of kilometres to manufacturers and customers (ENDM, 2021). They do not include the metallic minerals, mineral fuels, or gemstones, and are used in industries based on their physical and/or chemical properties (Wikipedia, 2021). In contrast to most metallic minerals, a general distinguishing characteristic of the industrial minerals sector is their general low degree of market elasticity in relation to the market prices and product specifications. The estimation of either a Mineral Resource or a Mineral Reserve (MRMR) for an industrial minerals deposit can be affected to a significant degree by a number of factors that are not typically applicable to metallic mineral deposits. These factors can include such considerations as the particular physical and chemical characteristics of the final product, product quality issues, market size and market access. In some cases, such information may be confidential and proprietary. One of the key challenges of the industrial minerals sector is to define a commonly accepted listing of which types of minerals, materials, or mineral deposits can be considered as industrial minerals (Mining Standards Task Force, 1999). Although definitions for what constitutes an industrial mineral can vary in detail, general descriptions can be found in American Geosciences Institute (2021), Fastmarkets IM (2021), Snowden (2019), SME (2021) and Wikipedia (2021). A brief listing of some of the materials and minerals that are generally considered to be industrial minerals is provided in Table 1. For the purposes of this document, all references to industrial minerals include not only the minerals, materials, and mineral deposits themselves, but also the various commercial products that are derived from these sources.

Nov 19, 2023

By Lisa L. Van Loon, Neil R. Banerjee

Canada is a world leader in uranium exploration, but many deposits are located in remote regions making exploration targeting challenging. Novel approaches are needed to detect the presence of large-scale ore-forming systems and to vector toward mineralization. Boron is commonly used as a key pathfinder element associated with sandstone/unconformity-hosted and basement-hosted uranium deposits in the Athabasca Basin, but the genetic relationship remains uncertain. Alteration assemblages containing boron geochemical anomalies are commonly spatially-associated with – and possibly coeval with – uranium mineralization. Boron is commonly found in tourmaline minerals but in some portions of ore deposits the host mineral for the anomalous boron remains cryptic. Boron coordination chemistry within alteration haloes can better constrain boron host mineralogy, provide insight into the nature of the boron-uranium relationship, and thus has the potential to better constrain targets for exploration. Synchrotron-source X-ray absorption near-edge structure (XANES) spectroscopy is a direct, element-specific analysis that identifies boron coordinated in both trigonally- (BO3) and tetrahedrally-coordinated (BO4) forms. This makes XANES uniquely suited for identifying the geochemical hosts for boron that may be related to hydrothermal ore forming processes. XANES spectroscopy was conducted on whole-rock assay powders from uranium deposits across the Athabasca basin containing boron concentrations ranging from <10 ppm to >10,000 ppm. XANES directly identifies the relative amount of trigonally- (BO3) and tetrahedrally-coordinated (BO4) boron in these complex mineralogical mixtures. Our work suggests a link between boron and uranium that is likely related to the unique physiochemical characteristics of ore bearing fluids that may provide a unique vector to mineralization.

Jan 1, 2020

Microseismic (MS) methods offer one of the few ways to monitor a 3D volume of rock and essentially see into the rockmass and the regions of real time rock fracture. This is a critical component when considering workplace safety as well as the economic viability of a mining operation. New Gold Inc. New Afton Mine, an intermediate copper-gold mining company located 350km northeast of Vancouver in the south-central interior of British Columbia, Canada, has recently installed a MS system to help understand the block caving process in space and time. For a block cave mining operation is it important to utilize the MS events to map out the seismogenic zone related to the regions of stress concentration and fracturing mechanisms which lead to caving. The geological setting within the local array is complex, consisting of several distinct lithologies with unique material properties that each affect the microseismic signal differently. The block cave consists of a muck filled void, also affecting the seismic waveform path. This paper compares the use of a single velocity model to a variable velocity model which accounts for the differing lithologies and cave. The variable velocity method determined 3D raypaths for all source to receiver possibilities through five irregular shaped geological domains and the estimated cave. For calibration blast data, the variable velocity model is found to successfully decrease the error for event location from an average of 38m to 20m (47% improvement), and its importance to location accuracy is expected to increase as the cave develops in size.

Aug 1, 2013

By Z. Jun, L. Kerning

Jinlong copper smelter and refinery, originally designed for 100,000tpa primary copper and started up in 1997, has been expanding its capacity on the basis of operational optimization and by modifying its facilities. Currently it is producing 210,000tpa primary copper, and the new phase of expansion project with a target capacity of 350,000tpa primary copper is ongoing. This paper reviews problems and improvements made with operation and equipment in the past years. Recent plant operation is briefly described. The expansion projects completed are summarized and the ongoing expansion project is present.

Jan 1, 2007

By R. H. Sheaphim

THE RECENT and continuing activity in the Boundary district, British Columbia, makes the publication of this paper timely. The following description and discussions are based on two years&apos; experience in the district as Field Manager and Geologist for Attwood Copper Mines, Limited. The Attwood project was organized by Dr. D. F. Kidd to re-examine the Boundary mining camp. Thanks are due to Dr. Kidd, both for his intelligent guidance during the project and for his permission to publish this paper. Much of the data and many of the interpretations presented are credited to the work of, and to discussion with, Dr. W. H. White, Consultant Geologist, who worked for two field seasons on the project. However, the author assumes the responsibility for this presentation. Dr. C. D. A. Dahlstrom worked with the author during the latter stages of the project. His assistance and advice are gratefully acknowledged.

Jan 1, 1956

By Zhiqiang Wang

This paper mainly focuses on the method of ?three-zone? definition (a caving zone, a fissure zone and a curve subsidence zone) for full height cutting in a thick seam. Based on criteria of a caving zone and a water conducting zone, as well as existing research achievements, it is believed that there exists great error for calculation of height of the ?three-zone? area using cutting height and the coefficient of bulk increase. Dynamic factors should be considered, so, based on the theory of key rock strata and combining this with several other factors, such as mining area, this paper presents a new method to determine the overburden ?three-zone? definition. The results are as follows: (1) geometric models of a working face and key stratum are established through the rock displacement angle, with consideration of the influence of mining on the key stratum (the range of key stratum influenced by mining is enlarged as the mining area increases); (2) because there is always a cavity below the key stratum of the thick coal seam with full seam cutting, and the key stratum gradually fracture with face advancing, based on the geometric dimension of strata, the maximum fracturing interval expression has been presented, including the working face advancing range. This can theoretically lead to the location of the key stratum influenced by mining, and its stability before mining, helps to confirm which zone the key stratum and following-up strata belong to, using the criteria of sliding instability or deformation instability; (3) the new method of ?three-zone? definition which is based on the theory of key rock strata is first proposed for full height cutting in thick seam. Finally, combined with practical engineering, and comparing with field data, it is believed that the proposed method is more objective than existing methods.

Aug 1, 2013

By Grant Small, Jessica Kinal, Christopher J. Greet

"The conversion from an electrochemically reactive grinding media (forged steel) to a more electrochemically inert alloy (high chrome white iron) not only reduces the wear rate of the grinding media, but also has an impact on the grinding chemistry. Typically the grinding chemistry becomes more oxidising, with less reducing Eh values and more dissolved oxygen in the pulp. There is also a decrease in the EDTA extractable iron, which is an indication of the change in the media corrosion. These changes are indicative of alterations in the surface chemistry of the minerals that the operator is trying to separate. For porphyry copper ores the changes in the pulp and surface chemistry not only affect the copper sulphide minerals, but also impact the iron sulphides (i.e. pyrite and pyrrhotite). Generally, with more oxidising pulp chemical conditions during grinding there is an increase in the oxidation of the iron sulphides which renders their surfaces hydrophilic, thereby depressing flotation. This leads to improved selectivity for copper sulphides against iron sulphides.INTRODUCTIONPorphyry copper deposits are the dominant source of copper that is mined today to satisfy global demand. These style of deposits typically contain one percent copper mostly as chalcopyrite, but may contain other copper bearing minerals (for example, bornite, chalcocite, azurite, malachite), small quantities of pyrite and quartz. Porphyry copper deposits also contain economically significant quantities of gold, silver and molybdenum. Interestingly, the majority of the world’s porphyry copper deposits are concentrated along tectonic plate boundaries (Figure 1)."

Jan 1, 2016

By George C. Coupland

"THE PRELIMINARY EVALUATION of the orebodies was computerized for tonnages and grades on a 20- by 20-ft grid. The evaluation was based on drill-core intersections over 40-ft vertical projections coinciding with the proposed bench intervals, taking the deviations of the drill holes into account. The computer print-outs gave an ore distribution and evaluation bench by bench and indicated the areas of varying mineralization. The two orebodies have a combined length of 2,200 ft. and a maximum width of 600 ft. They strike almost due north, dip about 85 degrees east and rake to the north. The computer print-outs were used to design an open pit with an over-all waste to ore ratio of 2.58:1. At the outset, the waste to ore ratio was 4:1. The pit is tear-drop shaped, with the narrow end to the south, and at the surface is 2,600 ft long by 1,800 ft wide. Ramps are 100 ft wide, with a 10% grade. The south ramp is left-handed, starts at the southeast and will continue to the bottom of the pit. A second ramp on the west and north walls runs from surface to join the south ramp at 7 bench. This ramp will handle the total pit production when part of the south ramp, from 4 bench to surface, is lost due to the underground operation. Over-all wall slopes are 53 degrees, and are laid out to avoid prominent protuberances which could relax and become unstable and potentially dangerous (Fig. 1) ."

Jan 1, 1974

By C. Moreland

Fluidized low-temperature carbonization of coal, a recent development, offers a possibility of reducing fuel costs of coal-burning electric ?generating plants. The Research Council of Alberta have built a pilot plant and are conducting a programme to -develop a carbomzation plant for Alberta sub-bituminous coals which will produce char suitable for use as a .boiler fuel, and tar of a potentially high value as a ?chemical raw material. The economies of the process as a whole, and the value of the tar, have yet to be assessed.

Jan 1, 1958

By G. H. K. Pearse, R. P. Taylor

The Big Whopper, one of only four giant economic rare metal pegmatites worldwide, is set to become a producer of the highly valued lithium mineral petalite (LiAlSi4O10) used in glass, ceramics and the specialty glass-ceramics familiar as Corningware® and the new ceramic stovetops. The deposit has a strike length of 1.5 km, a width of up to 80 m and a resource, open in all directions, of 11.6 Mt, grading 25% petalite. It is amenable to open pit mining and Avalon Ventures Ltd. holds a patent on a flotation process that produces an exceptional quality petalite product. The project will also produce: superb quality Na-feldspar which, too, finds use in glass and ceramics; the unusual Rb- K-feldspar for high voltage porcelain insulators; tantalum, in high demand for electronics; lepidolite, an ore of rubidium; and mica and tin. A positive prefeasibility study has been completed and it remains only to undertake bulk sampling and a full feasibility study.

Jan 1, 2001

By F. Chiesa

Forty aluminium A356 castings were poured on a Low Pressure Permanent Mould industrial machine, 500x700mm in platen size. The 152mm wide casting comprised three steps, 25mm, 13mm, 6mm in thickness and a 2.5mm overflow which allowed to assess the thin wall capability of the process. The casting campaign, which produced 40 parts, allowed to test the influence of various production parameters including the time of application of the pressure in the crucible, artificial cooling of the mould and casting rate. The thermal history in the mould was recorded over the 40 cycles, which allowed to construct a reliable thermal model of the mould/casting assembly. The metallurgical quality of castings representative of the various conditions was assessed in the 25mm, 13mm and 6mm plates. This included measuring the level of microporosity, the dendrite fineness (DAS), along with the tensile properties in the T6 condition. The radiographic quality per ASTM E155 was also determined. Modelling filling and solidification allowed to verify the validity of the predictions based on available relationships relating microporosity, secondary dendrite arm spacing (DAS) and local tensile properties (Quality Index, Q) to the local thermal solidification parameters.

Jan 1, 2007

The extractive industry has the potential to impact the health and well-being of workers, families and surrounding communities. In the current environment of social performance, project planning considers that activities should be conducted in the best environmentally, socially and economically acceptable way across the development cycle (i.e. from exploration ? post-closure). In this context, health impacts of mining can be mapped and extend over the Life of the Community and can encompass worker injury and disease, exposure to communicable and non-communicable diseases, and health outcomes specific to family and community health and well-being outside the fence. To contribute to an emerging field focused on Health and the Extractive Industry, this paper reviews and compares health activities extracted from social and environmental reports published by selected major mining, oil and gas companies with operations in Australia and Canada. The objective of this review is to map corporate approaches to public health management across our previously developed Life-of-Mine within Life-of-Community (LOMLOC) framework in order to identify and compare trends and behaviour in corporate health investments across the project cycle, as well as identify the level of prevention targeted by this investment activity (i.e. primary, secondary and tertiary prevention of detrimental health impact). With the extractive industry facing ongoing rapid growth worldwide, this paper provides preliminary comparative information about corporate health spending by some companies in Australia and Canada. This information serves as a resource for minerals industry managers, civil society and regulators regarding current health management approaches in this sector.

Aug 1, 2013

By R. Aubertin, G. Panneton, P. Donovan

The Detour Lake gold project is located in northeastern Ontario, approximately 300 km northeast of Timmins, within the Abitibi greenstone belt in the northwestern portion of the Archean Superior Province. Historically this greenstone belt has produced approximately 180 million ounces of gold, largely from narrow vein underground mining. The Detour Lake project is a site of extensive past exploration since 1974, as well as underground and limited open pit mining activity from 1983 to 1999. During this period, it produced 1.8 million ounces of gold. Underground mining focused on narrow vein conventional shrinkage and mechanized longhole stoping. After acquiring the property in January 2007, Detour Gold Corporation initiated a comprehensive drill campaign to define the potential for a large, open pitable, low-grade gold deposit. From 2007 to present, Detour Gold has completed over 500,000 metres of diamond drilling. A technical report completed in March 2011 defined an open pit mineral reserve of 14.9 million ounces of gold, which is Canada&apos;s largest undeveloped gold reserve. The Detour Lake project is currently in development and infrastructure construction of the mine facilities started at year-end 2010, after all the necessary Provincial regulatory permits were received. Gold production is expected to commence in early 2013. Gold mineralization at Detour Lake is associated with a large scale deformation zone (Sunday Lake Deformation Zone; "SLDZ") that occurs at the contact between the 2.72 Ga Deloro Group mafic metavolcanics and the 2.69 Ga Porcupine Assemblage metasedimentary and metavolcanic rocks. The bulk of the gold mineralization is found in the hanging wall of the SLDZ, which is associated with a stockwork of auriferous quartz veins that splay from a flexure along the deformation corridor. The mineralization forms a 200-350 metres wide auriferous corridor defined over 3 kilometres along the strike of the mafic metavolcanic assemblage, from surface to at least 1,000 metres depth. The richest gold mineralized zones are commonly associated with quartz veins with a strong biotite alteration and local zones of pyrrhotite-chalcopyrite-pyrite-gold enrichment formed during the deformation of the quartz vein system.

Jan 1, 2011

By Pizhi Zhao, Yingdong Li, Hailong Cao, Yingjuan Feng

"Three types of anodic films (unsealed, hot water sealed and agent sealed) were prepared to study the effects of anodizing pores structure on the adhesive bonding performance of AA5754 automotive sheets. The morphology of the anodic films was examined by using scanning electron microscope (SEM) and the composition was examined by glow discharge optical emission spectroscopy (GDOES). The adhesive bonding strength and durability in corrosive environment were investigated by using single lap shear test and salt spray corrosion test (SST), respectively. The results showed that the pores structure could significantly influence the adhesive bonding performance. The unsealed sample showed porous structure and provided high bonding strength, however, the durability was poor in corrosive environment. The hot water sealed sample showed fine and loose hydrated alumin a structure on the surface and provided high durability in corrosive environment, but the bonding strength was low. In contrast, the agent sealed sample provided both high bonding strength and durability in corrosive environment.INTRODUCTIONAdhesively bonded aluminum joints by using adhesives have been widely used for the realization of lightweight design in industrial applications like automotive and aerospace industry[1, 2]. Durable bonds which are capable of taking structural loads can be created due to a careful consideration of the way in which the joint is formed, the type of adhesive and the appropriate treatment of the adherend surfaces prior to bonding[3-6]. Experiences demonstrate that the surface treatment is the most critical step which could not be disregarded, since it is essential to achieve long-term service capability [7].In structural applications, a bonded assembly is expected to maintain a significant load and may be combined with exposure to harsh environmental conditions in its service life. For this purpose, the pretreatment for structural bonding of aluminum alloy must provide not only strong tensile strength and durability but also good corrosion resistance. Chromic acid anodizing (CAA) process provides an anodized layer which has good corrosion resistance while also exhibiting useful adhesion characteristics as well as lacquer coating retaining characteristics[8].However, the use of Cr (VI) is unadvised from a health and environmental point of view since it is toxic and carcinogenic, and this process is gradually limited even prohibited. Boeing's phosphoric acid anodizing(PAA) process provides a more open pore structure allowing penetration of high molecular primers/adhesives[8]and PAA process is the most widely used pre-surface treatment suitable for adhesive bonding between aluminum alloy components. Rahimi et al. demonstrated that nanostructure can be produced by PAA process and is affected by the time of pretreatment and anodizing parameters [9]. Xu et al.investigated the influence of surface energy and roughness on adhesive bonding through PAAprocess and provided improved adhesion performance under certain anodizing parameter[10]. However, PAA process is normally not recommended for a major concern of deterioration of the mechanical performance of the joints as a result of exposure to a wet and corrosive environment. Sulfuric acid anodizing(SAA)process, recently, has been widely used for corrosion protection and good base coating for the adhesion of lacquers in aerospace manufacturing[11]. The good performance is explained by properties such as the porous morphology and high adsorptive power of the oxide film, the chemical and electrical inertness of the anodized layer. Moreover, modified sulfuric acid could also used for adhesive bonding. Lunder et al. found that anodizing in hot sulfuric acid is promising as a simple, very rapid and environmentally friendly pre-treatment for adhesive bonding[12].Saeedikhani et al. studied the process of phosphoric/boric/sulfuric acids anodizing and found it was is a promising pre-treatment for adhesive bon"

Jan 1, 2018

By B. Zeifert, C. Martínez-Morales, A. Romero-Serrano, A. Pineda-Rivera, H. Martínez-Gutiérrez, G. Diaz-Sandi

In this work, the effects of CaO/SiO2 ratio and the FeSO4 and FeS2 contents on the stability of the mineralogical species in chromium-based slags were studied. The chemical stability was evaluated by leaching with an acid solution. The main Cr-compounds in slags with FeSO4 and CaO/SiO2=1 were FeCr2O4 and Ca3Cr2Si3O12, while Cr3S4 predominated in slags with FeS2. The slags with CaO/SiO2=2 mainly contained CaCr2O4. The highest Cr concentration levels in the leaching liquors corresponded to slags with CaO/SiO2= 2, and the lowest Cr concentration corresponded to slags with high FeSO4 or FeS2, owing to the stable binding of chromium in the compounds FeCr2O4, Cr3S4 and FeS•Cr2O3.

Jan 1, 2011

By A. Warczok

Chalcocite concentrate obtained by magnetic separation and flotation of Bessemer matte is processed in the Inca top blowing bottom stirring MK reactor into semi-blister copper. The semi-blister is then converted into blister copper in the multi-purpose vessels (MPV) by oxidation of iron, nickel and sulphur. High melting point NiO and Fe30 4 are formed inside the MPV s, which together with Cu20 and smaller amount of fayalite are the major constituents of the solid mush. The accumulation of solid mush and buildup requires periodic MPV cleaning by adding reductant and copper-nickel matte, a unique process called "washout". Various reductants and their combinations, such as pig-iron, 15%Si Ferro-silicon and 50%Si Ferro-silicon, have been used for the reduction of solid mush and buildup. The possibilities of using calcium carbide as a reductant and slagging flux were examined experimentally at the crucible scale. The rate of reduction of MPV buildup was determined by continuous measurement of CO and C02 contents in the offgas and the flowrate of argon carrier gas. The rate of the buildup reduction with calcium carbide was approximately five times faster than the rate of reduction with coke. Additionally, the formation of CaO results in the melting of reduced buildup and formation of a slag at 1300°C and higher temperatures. It was found that simultaneous silica addition enhanced the melting and slag formation. The results showed the strong dependence of the reduction rate on temperature. Activation energy is approximately 225 kJ/mol. Expected benefits of using calcium carbide are related to cost saving on reductant, significant acceleration of solid mush reduction, and reduced amount iron input from reductant.

Jan 1, 2007