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By B H. Yin, S Mendoza, M Nusheh' C W Bumby, A Zhang

Hydrogen-direct-reduction of iron ore in a vertical shaft furnace is a potential process that could significantly reduce CO2 emissions from the steel industry. This approach requires the pelletisation of iron ore fines, which then undergo high temperature induration to strengthen the pellets before they can be fed into the shaft furnace. Here we report on investigations into the disc-pelletisation behaviour of New Zealand titanomagnetite ironsand, and its subsequent induration and hydrogenreduction behaviour. Initial studies focused on the effect on pellet strength of varying ironsand particle size and induration conditions using bentonite and a commercially sourced carboxymethylcellulose binder. Green pellets formed with ironsand of average particle size of 65 μm exhibited optimal strength. The compressive strength of these pellets after induration at 1200°C for 2 hrs in air was measured to be 976 N. Interparticle bonding within the indurated pellets occurs due to a combination of titanohematite recrystallisation (from oxidation of titanomagnetite), and the formation of a liquid bonding phase due to interdiffusion with the bentonite and subsequent melting. Further investigation with various binders showed that a combination of both organic and inorganic binders was essential to achieve optimal pellet strength. Carboxymethyl-cellulose binders provides green strength, whilst inorganic binders such as bentonite promoted high indurated pellet strength. Hydrogen reduction tests in a thermogravimetric furnace showed that all the pellets could achieve a maximum reduction degree of 97 per cent at 1100°C, indicating that the different pellet preparation procedures had no significant effect on reducibility. Pellet recipes developed in this work are now being used to investigate vertical shaft hydrogen-DRI processing of NZ ironsand in a kg-scale laboratory reactor.

Sep 18, 2023

By J Zhao, C E. Loo

The flame front is a narrow region in the iron ore sintering bed where coke particles combust. The maximum flame front temperature is as high as 1400°C. At high temperatures, the sinter mix components react to form melts, which facilitates material coalescence and the formation of dense sinter particles. It is well-established that flame front speed is an important factor influencing sinter productivity, sinter quality and fuel rate. In this work, the effect of suction, coke addition and mix moisture on flame front speed was studied in a pilot-scale sinter pot and also using the outputs of a recently developed theoretical model, which takes into account most of the significant physicochemical processes in sintering. Airflow through the bed has a large influence on flame front speed. A power law relationship between these two parameters means that increasing sintering airflow rate will lead to increased flame front speed, but the increases become smaller at higher airflow rates. Sinter pot test results showed that increasing coke addition decreased green bed permeability and increased flame front temperature, which resulted in increased flame front resistance and decreased flame front speed. Studies also showed that green bed properties are sensitive to sinter mix moisture level. The changes in green bed properties further influence the flame front speed and temperature.CITATION:Zhao, J and Loo, C E, 2015. Dependence of flame front speed on iron ore sintering conditions, in Proceedings Iron Ore 2015, pp 83–90 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By R A. Pax

Heavy machinery such as AG and SAG mills generate a significant amount of noise due to the processes that are occurring inside them. From an environmental perspective, the level of noise generated is a significant occupational safety hazard. However from a technical perspective the noise presents an opportunity to determine some details of the processes occurring inside the mills. The noise generated is not random and can be attributed to a range of events that occur inside these mills, consequently non-contact acoustic determinations of in-mill behaviour provide powerful insights into the operation of the primary comminution tumbling mills. Traditionally, the use of perfect mixing has been assumed when modelling the operation of AG/SAG mills. If this were true then the acoustic emissions from AG/SAG mills would be uniform along the length of the mill. Experimentally this has been found not to be the case. From another perspective it should not be the case because of the different conditions existing at the feed end compared to the discharge end. This paper presents the results determined by non-contact acoustics and their analysis in terms of understanding of the mechanisms occurring inside a mill.

Aug 8, 2011

By Wyborn L. A I, Idnurm M, Hinman M. C

Comparison of the Proterozoic Apparent Polar Wander Path (APWP) for Australia with the corresponding geology of northern Australia suggests that a number of discrete interplate tectonic events, manifested on the APWP as bends or inflections, may have controlled sedimentary basin evolution, ore fluid production and the timing of mineralisation. Similar features in the Phanerozoic APWP for the North American plate appear to correlate with major orogenic events, basin deformation, movement and 'entrapment' of hydrocarbons and minerals. Interplate tectonic events cause intraplate deformation which in turn controls the subsidence/uplift and sedimentation histories of the basins. Interplate events are thus responsible for creating, deforming and destroying sedimentary basins and the associated petroleum and mineral systems. The basins of northern Australia show remarkable similarities in the successions of volcanic and sedimentary deposits. Unconforrnities of regional or sometimes only local extent have been mapped between the major sedimentary sequences and it is predicted that interplate tectonic events corresponding to bends or inflections on the APWP directly reflect the processes that have produced these widespread unconformities. These processes are also likely to have controlled the geometry and character of the fluid migration pathways and hence the mineralising events. Palaeomagnetic studies of Proterozoic rocks in sedimentary basins provide a tool for predicting the timing of regional mineralisation events, particularly for low-temperature mineral systems. The techniques, when coupled with systematic regional basin analysis, using petroleum exploration techniques, may identify a number of new mineral 'plays' in northern Australia. Prominent inflections in the APWP occur at approximately 1700, 1670, 1650, 1600, 1540, and 1480 Ma. Each of these may be related to a regional compressional deformation, important mineralising event, or significant change in style and type of sedimentation. Most appear to be associated with magnetic overprints. Some of the inflections between 1400 and 540 Ma may also mark significant events in the evolution of Meso- and Neoproterozoic basins. Further work is required to correlate inflections in the APWP with alteration events in order to understand their regional significance.

Jan 1, 1994

By T Sirinawin, R H. Murfitt, W Shywolup

The Bong Mieu Project lies within the Pre-Palaeozoic Kontum Craton near the southern margin of the regional Phuoc Son û Tam Ky Suture. The Suture and accompanying Truongson Fold Belt of Indosinian age host significant gold and base-metal bearing districts including OlympusÆ other project at Phuoc Son to the west of Bong Mieu and OxianaÆs Sepon project in Laos. The Bong Mieu Project is located some 90 km south of Da Nang and some 30 km south-west of Tam Ky, the provincial capital of Quang Nam province in central Vietnam. The project area is covered by an Investment Licence of some 30 km2 which was granted in 1991 and a mining permit of some 365 ha granted in 1992. Several mesothermal, gold-silver deposits with assigned resources are present on the property. Deposits with assigned resources contain some 615 000 ounces of gold in situ. These are at Ho Gan and Ho Ray which are potentially exploitable by open-pit mining and Nui Kem which is potentially exploitable by underground mining. Newly discovered extensions to the known deposits at Ho Gan, Ho Ray and Nui Kem, and several other new prospects, are currently being investigated by drilling. The Ho Gan mineralisation is of mesothermal, shear and shear breccia quartz vein, as well as intrusive breccia hosted style. Nui Kem mineralisation is of mesothermal, shear and shear breccia quartz vein style. The Ho Ray mineralisation is of skarn (gold-bismuth-tungsten) and lesser quartz vein style. The deposits straddle and flank the east-west trending Bong Mieu Anticline which trends through the central portion of the Investment Licence. In this paper the geology of the deposits, details of resources, results of recent exploration on the Investment Licence and recent engineering and mining studies at Ho Gan are briefly reviewed.

Jan 1, 2004

By A E. C Peres, P R. M Viana

The role of flotation columns in comparison with conventional mechanical flotation cells is discussed under the scenario of Brazilian flotation technology. All iron ore concentrator circuits commissioned since 1990 incorporated column only flotation technology in rougher, cleaner, scavenger configuration. Columns were also added to existing circuits, especially at the cleaner stage. Columns were also incorporated to phosphate ore flotation circuits operating mechanical cells. In two phosphate concentrators, columns substituted for all mechanical cells. Columns perform the cleaning stage in a large sulfide copper concentrator, following rougher flotation in tank cells. Scavenger of the cleaner tailings is performed in tank cells at this plant. Other ores that are concentrated in flotation columns include graphite, talc, lead-zinc sulfide, and a zinc hydrometallurgical residue for silver recovery.

Jan 1, 2005

Upgrading of MgO in Dolomite Ore by Froth Flotation

Sep 13, 2010

By R Yong, A McEwan, D G. Miljak, D Milinkovic, A Curtain, P J. Coghill, R Stefulj, B Lovric, G Roberts

The CSIRO has pioneered the development and use of certain classes of magnetic resonance (MR) for mining applications. The MR technique is a radio frequency-based spectroscopy that provides highly quantitative measurement of selected ore minerals. MR has many inherent advantages for bulk sensing in mining applications, including deep sensing penetration into most bulk ores with the use of non-contact sensors that are robust and tolerant of demanding mine conditions. The highly discriminating nature of the technique also provides the very desirable attribute of robust and simple calibration, that can often be performed prior to sensor installation. Rapid sensing (within seconds) at very low grade (few hundred ppm Cu) has been demonstrated, as well as sensing at high tonnage rate. Besides sorting applications, MR may also be applied to preconcentration applications involving very large volume sensing including: (i) haul truck sensing using portal arrangements, where truck destination assignment may be dynamically determined based on the truck grade, (ii) in-pit gantries used for loading trucks that may similarly be equipped with sensors for truck assignment and (iii) deep mine bench sensing, recently progressed through a CRC ORE project, where local bench grade is determined at the few-metre lateral scale and at depth prior to blasting, to aid selective blasting and ore extraction. MR sensor prototypes have been developed for each of these applications and have been tested in laboratory or limited field conditions. To inform the value proposition for truck or bench sensing, initial analysis of truck assignment improvement based on an analysis of in-situ mine bench grade has been performed for a porphyry style deposit. The prototype sensors, preliminary results and future technology development and objectives will be described.

Nov 10, 2020

By Y-B Kang, J H. Park, J Park

In order to understand the effect of oxygen injection into the molten metal on the valuable metals (VM) recovery and interfacial phenomena, several high-temperature experiments were conducted using a high-frequency induction furnace with a quartz tube as the reaction chamber at 1673 K. Copper-based waste printed circuit board (PCB) that contains some impurities was selected as the end-of-life resource. CaO-SiO2 based pre-fused slag and oxygen gas were used in present works. The composition change and microstructure of the samples were analysed. As oxygen was injected into the system, impurities were rapidly removed. After the removal of impurities, continuously injected oxygen lowered interfacial tension between liquid slag and liquid metal. Lowered interfacial tension induced Cu loss into the slag.

Aug 21, 2024

By O Aydan, R Ulusay

Blasting is the most commonly used excavation technique in mining and civil engineering applications. Blasting induces strong ground motions and fracturing of rock mass in rock excavations. Particularly, high ground motions may also induce some instability problems of rock mass and structures nearby. Furthermore, it may cause some environmental problems due to noise as well as vibrations of structures near the populated areas. Furthermore, flyrocks is another major issue for the safety of people and damage to machinery and equipments when blasting is employed. In this study, the authors explore the ways how to estimate the ground motions as a function of distance, amount of explosive, number of holes. The ground motions were measured by stand-alone accelerometers developed by the first author and some empirical relations are developed. The effect of ground motions on the instability issues of benches such as sliding, toppling and rockfalls were investigated. Furthermore, the flyrock issue is investigated and some empirical relations to estimate the maximum distance of flyrocks from the blasting relations are compared and discussed. CITATION:Aydan, O and Ulusay, R, 2018. The ground motions induced by blasting in open pit lignite mines and its environmental effects, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 142–151 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

By S H. Li, H Z. Gu, A Huang

High aluminium steel is a promising advanced steel known for its exception properties and holds significant economic and strategic importance. However, the CaO-Al2O3-SiO2 based slag with high alumina content reacts vigorously with alumina refractories during the smelting process at high temperature, seriously affecting the safe and efficient production of furnaces and resulting in the formation of Al2O3-MgO non-metallic inclusions within the molten steel. This is a bottleneck problem for high-quality steel refining, and the key reaction path during the corrosion remains unclear. The dissolution reaction mechanism of alumina refractories in high alumina CaO-Al2O3-SiO2 slags under a weak static magnetic field was investigated in this work, using high temperature laser confocal microscopy and in situ radiation spectroscopy techniques. The results indicate that the interaction between the high alumina slags and the alumina refractories is governed by free radical reactions. The dissolution of alumina forms AlO and AlO2 radicals. The reaction rate increases with the C/S ratio of the slag due to its low polymerisation. The reaction between non-bridging oxygen and AlO2 free radicals accelerates the generation of AlO and O2ꞏ- radicals. The reaction layer composed of calcium aluminate is formed through the recombination of AlO, Caꞏ+ and O2ꞏ- radicals. The weak static magnetic field induces the Zeeman splitting of free radical pairs and intersystem crossing occurs, promoting the formation of triplet free radical pairs through the hyper-fine coupling effect. The reaction can be significantly inhibited as the triplet free radical pair does not meet Pauli’s incompatibility principle. This discovery perfects the structure theory of molten slags with radicals and provides supplement to the design of the highly slag-resistant refractories, and provides the theoretical basis for the development of external field protection technologies for high-quality steel refining.

Jun 19, 2024

China has been producing gold for more than 4000 years with gold production increasing substantially since the 1980s, from about 25 tonnes in 1980 to some 160 tonnes in 1998. More than 80 per cent of the gold production is from East China. However, complete information on eastern China gold has been rarely reported internationally. This is a general overview on the tectonics and metallogeny of gold deposits in East China. The geology of these gold deposits is compiled mainly from data and information reported in China, and is also based on the authorÆs work in China from 1974 to 1986 and a recent visit to China.

Jan 1, 1999

By T Raynlyn, A Edenton, M Adam, R J. Holmes, J R. Manuel, N Ware, R Smyth

Due to ongoing demand and increasing depletion of high-grade iron ore resources from large deposits, Australian iron ore producers are developing smaller size deposits to maintain current export levels. The iron grade, mineralogy, chemical and physical characteristics of iron ore fines being mined from different deposits vary considerably. It is therefore imperative to develop long-term strategies to maintain the quality and consistency of iron ore fines while moving to a larger diversity of smaller deposits. Blending is a common practice in sinter plants as it is almost impossible to produce a high performance sinter mixture displaying the required characteristics from one single ore. Blending is also one of the most effective options being used by iron ore producers to ensure the long-term stability of their products while increasing production. When designing a blend, the blend components are selected to support each other to achieve the required overall balanced metallurgical performance of the final product at a relatively low cost. To do so, a fundamental understanding of the key characteristics of iron ore fines and their potential impacts on the iron ore sintering process and sinter quality are required. In this paper, the sintering process and sinter structure have been analysed and the key factors affecting the sintering performance of iron ore fines, including productivity and quality, identified. Under fixed sintering conditions, the granulation efficiency, nuclei stability and the volume and properties of the primary sinter melt are believed to have important impacts on both sintering productivity and sinter quality. Discussion is then focused on the effects of ore chemical, physical and mineralogical characteristics on the key factors identified and in turn the consequences for sintering productivity and sinter quality.

Jan 1, 2009

By V Ser, I Smit, C Robertson

Anglo American has been researching the potential benefits of inter-particle comminution techniques for several years. Inter-particle comminution has additional benefits in terms of milling circuit performance such as energy consumption and stability. This paper focuses on the flotation benefits. Inter-particle comminution leads to selective breakage, mineralogical analysis has shown that this leads to improved liberation of the valuable minerals. In addition to selective breakage, the relatively short residence time experienced in typical inter-particle comminution machines allows more efficient classification which contributes to a æsharperÆ product size distribution. The effect of particle size in flotation has been well documented in literature. In general, it is has been shown that there is an optimal particle size range for flotation, and that both above and below this range, flotation recovery is adversely affected. Results show that the narrow size distribution which results from inter-particle comminution improves flotation recovery. Furthermore, the absence of excessive fine gangue material which typically results from conventional fine (-75 ¦m) milling of talcaceous ores, can lead to 100 per cent savings in depressant consumption when such ores are subjected to inter-particle comminution. To-date, this technology has been evaluated on more than ten ores. This paper will focus on one set of results which demonstrates a number of common differences that exist between material that has been milled conventionally and using inter-particle comminution technologies, with emphasis on what the impact of these differences is on flotation performance. A pilot scale (200 kg/h) vertical roller mill (VRM) was used to produce the material, and the results shown will describe conventional laboratory batch, locked cycle and pilot plant flotation testwork.

Jan 1, 2005

By M, C A. RosiFre, R C. Figueiredo e Silva

Jaspilites and underlying basalt contacts of the Archaean volcano- sedimentary Grpo Parß Group, Carajßs, host giant iron mineralisation in the ~100-km long, E-W trending Carajßs fold. Preliminary, unpublished geochronological data point to a Palaeoproterozoic mineralisation event. Geochemically, jaspilites are typical volcanogenic banded iron formations. Basalts exhibit evidence of spilitic seawater interaction. Iron-associated hydrothermal alteration of mafic rocks was induced by fluid infiltration in amygdales, with development of chlorite- and hematite-dominated zones. In the case of jaspilites, iron mineralisation encompasses: partial replacement of jaspilitic microcrystalline hematite by blasts of martitic magnetite; jasper recrystallisation, producing fine-grained, hematite-free granoblastic quartz; martite recrystallisation, forming lobate¦subhedral hematite; pervasive porosity development by quartz-chert leaching; incipient cavity filling by microlamellar hematite; and advanced filling by coarser, euhedral and comb-textured, tabular- shaped hematite.Peak hydrothermal ore textures indicate typical epithermal-crust conditions, supported by preliminary fluid-inclusion calculations at 160 - 200¦C. Such temperatures and extreme fluid-to-rock ratios during alteration must have exceeded the ambient metamorphic conditions, with the infiltrating fluid relatively hot and capable of leaching SiO2. Therefore, mineralisation developed over exhumed, Archaean, brittly deformed rocks, with mineral associations representative of very low- to low-grade metamorphism. Considering that chlorite (¦talc) abounds in mafic rocks; hydrothermal albite is developed; dolomite fills veins and vugs; the typical rare-earth-element (REE) pattern of jaspilites is significantly modified in higher-grade hard hematite ores (higher LREE); pyrite, copper sulfide minerals and rare gold occur in association with carbonate-quartz-rich alteration zones, it is suggested that an alkaline, H2O-Fe-CO2 mineralising fluid dominated, also containing species like S¦Cu¦Au. Peak-mineralising conditions are likely to have resulted from a single, evolving fluid, via incipient- through advanced-stage alteration phases. The porous, high-grade soft hematite-type ore (SH), rich in microlamellar and anhedral hematite, must have derived from interaction with this relatively hot SiO2-leaching fluid, whereas the high-grade massive hard hematite-type ore (MH) developed due to closer fluid-rock temperature equilibrium conditions, attained by mineral reactions, with relative increase in the Fe/Σcations ratios allowing the precipitation of subhedral-tabular hematite that partially cements the soft-hematite ore. SH and MH hematite ore types must thus reflect intermediate and high fluid:rock ratios, respectively. Since the N5 deposit is to date understood to contain the largest amount of the MH ore, its units are interpreted as the loci of the highest fluid:rock ratios in the district. Preliminary mineralogical information regarding the S11 deposit of the Serra Sul (south range) implies higher-temperature conditions. The near-equant grain size and the granoblastic intergrain relationship, coupled with the presence of riebeckite, augitic pyroxene and garnet, suggest hornfels textures. The data collected, though still relatively sparse, permit the speculation that the immense driving force for the Carajßs world-class iron deposits was a relatively shallow, igneous-related hydrothermal system. If such a model is correct, then the Carajßs Palaeoproterozoic iron deposits could represent an end-member of the iron oxide-copper-gold hydrothermal system in the province.

Jan 1, 2005

Low-grade, porphyry copper type mineralization at the Moonmera prospect is related to the intrusion of a granodiorite porphyry mass into the Upper Permian "Gracemere granodiorite". Significant copper mineraliza- tion appears to be associated with the alteration assemblage quartz-sericite- kaolinite. The ore shell is surrounded by a zone where montmorillonite and kaolinite are in greater abundance and this assemblage is over- lapped, mainly at depth, by potassium feldspar alteration. Secondary biotite is abundant throughout the mineralized zone. Preliminary sulphur isotope results on the sulphide mineralization are compatible with a magmatic origin for the sulphur.

Jan 1, 1974

By G Ryan, Yu Nazimova

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. This paper aims to highlight the global exploration opportunities that exist in connection with Ural-Alaskan (UA)-type intrusions. The key economic importance of UA intrusions is the existence of metallic platinum (mainly iron-platinum alloys) associated generally with chromite mineralisation and located within a dunite core, especially its coarse-grained part. Being very dense and resistant to erosion, platinum can form rich placers as the intrusion erodes. Big multimillion ounce placer platinum deposits of this type have historically been successfully mined for many years (eg Russia, Colombia and Alaska).However, large-scale exploration and mining of platinum placers currently occurs only in the Russian Far East. Outside of Russia, there is now little or no understanding of this type of deposit and its economic importance. Using successful operations in Russia as examples, it is demonstrated that there are many opportunities for similar discoveries all around the world, especially around the Pacific Rim, where such intrusions tend to be concentrated. Examples of highly prospective areas in eastern Australia and New Zealand are given. There is also excellent potential in British Columbia (BC) Canada, South-East Asia (Philippines, Indonesia, Papua New Guinea and New Caledonia) and South America (Colombia and Ecuador).CITATION:Nazimova, Y and Ryan, G, 2015. Platinum potential of the pacific rim of Ural-Alaskan-type intrusions, in Proceedings PACRIM 2015 Congress, pp 665–670 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By B J. Monaghan, P Zulli, X F. Dong

In the lower zone of blast furnace (BF), slag trickles down through a packed bed of carbonaceous particles in the form of films, rivulets or droplets. During its downward flow, there are significant interactions occurring between slag and other phases, ie gas and packing particles. In particular, the interaction between gas and slag is closely associated with the key flow phenomena such as loading, flooding or channelling in the lower zone of the BF. With gas introduced laterally through tuyeres and slag flowing downward from the cohesive zone to the hearth, this interaction varies throughout the lower zone and in the cohesive zone:  strong cross-flow of gas relative to the slag occurs in front of the raceway  counter-current flow of gas and slag occurs in the upper parts of the lower zone  both strong cross- and counter-current flow of gas and slag around and within the cohesive zone. These interactions can be linked to furnace irregularities, affecting smooth operation and limiting production. Therefore, understanding the gas-slag interaction and its influencing factors remains critical for BF process control. In the current review, the physical behaviour and key influencing factors of gas and slag flow are initially examined. Numerical models describing gas and slag flows in a packed bed at micro-, mesoand macro-scopic levels, are reviewed. Each simulation approach has its advantages and limitations, as well as unique assumptions when used in BF process modelling. Applications of these approaches to gas-slag flow in key identified functional zones will highlight the differences between approaches and modelling outcomes. As no single approach can fully address all aspects of gasslag interactions, an integration of different approaches is considered an effective and beneficial method in providing a more complete understanding of gas-slag flow in the BF process.

Jun 19, 2024

By M Suzuki

Although several models for the surface tension of molten oxide slag have been proposed, suitably accurate predictions of this property are not yet possible. The surface tension, or surface excess free energy, of molten oxides is largely determined by the ionic coordination induced by surface relaxation. However, the associated mechanism of surface structural relaxation for molten oxide mixtures such as slag is complex and not yet fully understood. To allow a better evaluation of surface relaxation characteristics, the present work analysed the ionic coordination associated with the surface-relaxed states of several oxide mixtures. This work especially focused on calcium aluminate slags because these materials exhibit complex relationships between composition and surface tension. The effects of incorporating low concentrations of SiO2 as a surface active component on the surface ionic coordination were also examined. X-ray absorption techniques were used to assess oxygen and cationic elements in glassy samples after surface relaxation treatments, and molecular dynamics simulations based on a polarisable ion model of molten slag with vacuum/melt interfaces were also performed. The X-ray absorption techniques provided data related to electron yields (which are primarily associated with surface features) and fluorescence yields (which evaluate the bulk material). Thus, the ionic coordination characteristics of both regions were investigated. The results of molecular dynamics calculations allowed statistical analysis of the distributions of Al- or Sicentred polymorphs as well as the bond angles between cations and oxygen anions in the vacuumexposed and bulk regions in the equilibrated melt. The results indicated that bridging oxygen ions were preferentially distributed in the relaxed surface region rather than non-bridging oxygens. These bridging oxygen ions represented vertex connections between AlO4 or SiO4 tetrahedra. In the case of the calcium aluminate slags, the addition of one Ca2+ ion as charge compensation for two Al3+ ions was found to be necessary to form two AlO4 tetrahedra. This specific feature of surface ionic coordination could be responsible for the complex trends observed in surface tension data. The incorporation of low concentrations of SiO2 reduced the proportion of tetrahedrally-coordinated Al ions such that higher coordination states become dominant in the bulk of the material, whereas AlO4 tetrahedra were preferentially distributed in the surface region. SiO4 tetrahedra were the preferred Si-centred polymorph and were likely connected to one another to form bridging oxygen ions at the surface. On the basis of these results, a model to predict slag surface tension was proposed, and the energy of the formation of the ionic clusters resulting from surface relaxation was taken into account.

Aug 21, 2024

Determining the controls of high-grade mineralisation at Vera Nancy requires careful data collection and assessment on a global and specific deposit basis. The techniques developed over 60 years ago to analyse structure, grade and width data are just as applicable today and can be enhanced using modern geological modelling software. High ore grades at Vera Nancy are controlled by both the primary geometry of the mineralised structure and the intersections of the main mineralised veins with subordinate splay veins. The main mineralised structure dilated as a consequence of extensional tectonics while the splays acted as conduits bringing oxidising surficial fluids into mixing zones precipitating high gold grades. Near-mine exploration is focussed on identifying zones of vein flexure and splay interaction to locate the relatively small high-grade shoots. Data modelling in a 3D environment is an essential process for understanding the geometry of the system being explored.

Jan 1, 2000