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By K. G. Markkola

The Minera Candelaria concentrator was commissioned in August 1994, and in October 1997 it doubled its grinding capacity. The concentrator was designed to treat 56,000 metric tonnes of copper ore with a primary crusher, two grinding circuits, pebble crushing, and flotation. The grinding circuit includes two 11.2 m (36 ft) diameter by 4.6 m (15 ft) long semi-autogenous (SAG) mills, each fitted with a 12 MW motor. Throughout the history of Candelaria, different strategies have been developed to maximize the plant's operational time, strategies that include increasing the life of the SAG mill liners and reducing the time involved in changing these elements. This work describes the improvements made in the design of the liners, the change planning, and a new strategy to change the liners with the purpose of increasing their use and throughput.

Jan 1, 2007

Microwave pretreatment can improve grindability by weakening brittle particulate material prior to size reduction. The differential thermal expansion experienced by multiphase materials during rapid heating can also promote damage in the grain-boundary region, which may ultimately translate into enhanced liberation. The effect of microwave pretreatment on the breakage characteristics of different ores has been studied using the Ultrafast Load Cell. The energy accumulated during impact (fracture energy) and the particle stiffness have been measured for untreated and microwaved ore samples. It has been observed that microwave pretreatment can weaken brittle multiphase particulate material, as observed by reductions in fracture energy and increase in damage.

Jan 1, 1996

By James A. Finch, Xiangzhou Ding, Yue Hua Tan

"The Jameson Cell is one of the choices of flotation machine in coal, base metal processing and other specialist applications. This paper determines the effect on vacuum pressure and bubble size of two design variables, orifice size and downcomer length, and the operating variable air-to-water (AWR) ratio. The main findings are: orifice size and downcomer length impact the vacuum but have limited effect on bubble size; AWR < 1 favours high vacuum, conditions are identified where vacuum is maintained at AWR > 1, and water flowrate has slightly greater impact on bubble size than air flowrate.INTRODUCTIONFroth flotation, the most common technique for mineral separation, has been in use for over a century. The process takes advantage of the difference in wettability of mineral surfaces to achieve the separation of valuable minerals from non-valuable minerals, or gangue. Numerous flotation machines have been invented and patented over the years. The Jameson Cell, invented by Professor Graeme Jameson in the late 1980s, is one successful example. First trialed at Mount Isa Mines (Queensland, Australia), Jameson Cells have been installed at operations around the world for the recovery of fine coal (Mohanty and Honakeri, 1999; Cowburn et al., 2006; Hacifazlioglu and Toroglu, 2007; Uçurum 2009), minerals of copper (Farr 1992; Atkinson et al., 1993; Harbort et al., 1997), lead/zinc (Rohner, 1993; Munro, 2003) and gold (Bennett et al., 2012; Lauder et al., 2003), and in water treatment (Yan and Jameson, 2004), solvent extraction de-oiling (Miller and Readett, 1992; Miller et al., 1997; Harbort et al., 2003; Young et al., 2006), oil sands processing (Neiman et al., 2012), and various food industries (Brenneman, 2014). One of the largest units is the 650 cm diameter separation tank with 24 downcomers installed in an Anglo American operation (Osborne and Euston, 2015). Scale up is relatively straightforward: to increase capacity the number of downcomers is increased with corresponding increase in size of separation tank.The Jameson Cell comprises two main parts: a vertical tube (downcomer) which provides self-aspiration and intense bubble-particles contact, and a (separation) tank where particle-bubble aggregates disengage from the pulp. The intense bubble/slurry mixing in the downcomer with air holdups reaching 60% (Marchese et al., 1992) accelerates particle collection enabling the greatly reduced cell volume compared with mechanical flotation cells and columns. The disengagement of the particle-loaded bubbles from the slurry in the separation tank is usually aided by addition of washwater."

Jan 1, 2018

By Flávio James Humberto Tommasini Vieira Ramos

O estudo teve como objetivo a produção de corpos de prova de nanocompósitos baseados em uma matriz polimérica de polietileno de ultra alto peso molecular (UHMWPE) com carga de carbeto de boro dispersas, nas proporções de 0,0625%; 0,125%; 0,25%; 0,5%; 1% e 2%, respectivamente. As respectivas misturas entre os materiais, polímero e carga inorgânica, foram moldadas em prensa hidráulica quente à partir do estado fundido da matriz polimérica. A caracterização dos nanocompósitos com as cargas sem tratamento foi realizada pelas análises de difração de raio-x (DRX) e calorimetria diferencial de varredura (DSC), o que possibilitou a identificação dos planos cristalográficos característicos dos materiais, o grau de cristalinidade da matriz orgânica e suas respectivas temperaturas de fusão. As microestruturas dos materiais, morfologia da carga e adesão interfacial foram observadas através da microscopia eletrônica de varredura (FEGSEM). Através desse estudo foi possível o sugerir o comportamento do polímero com cargas de carbeto de boro dispersas em diversas proporções.

Oct 30, 2017

By Lucas Teixeira Costa

Um modelo matemático foi criado para simular a dessulfuração do aço no desgaseificador RH na condição de uma camada de escória sobrenadante adicionada dentro da câmara de vácuo após a subida do aço sob efeito da pressão. Tomou-se como base o modelo físico do LaSiP (Laboratório de Simulação de Processos) em escala 1:5 para a instalação industrial de uma usina brasileira. A validação do modelo foi realizada por meio da taxa de circulação do modelo físico e de sua simulação. A dessulfuração do aço foi realizada pelo modelo matemático para as condições operacionais da indústria e a avaliação de parâmetros como composição química e volume de escória foram investigadas. Ao final, obteve-se resultados compatíveis com os presentes na literatura e um modelo capaz de prever com grande confiabilidade a evolução do teor de enxofre ao longo do processo de dessulfuração. Considera-se, portanto que a prática de remoção de enxofre no RH é viável e tem-se uma rota adicional/alternativa ao forno panela.

Aug 16, 2017

By N. P. Gallagher

The U.S. Bureau of Mines investigated a hydrothermal sulfidation (HTS) and chloride leaching procedure to recover lead and silver from plumbojarosite. The plumbojarosite, generated during pressure-oxidative leaching of zinc concentrate in a commercial operation, contained, in percent, 25.4 Pb, 18.8 Fe, 1.4 Zn, 29.5 sulfate (S042.), 3.2 elemental sulfur (SO), 13.4 total S, and 7.4 tr oz/st Ag. The HTS was conducted in an autoclave and converted the plumbojarosite into amorphous iron oxide and liberated the Pb and Ag as sulfides (S2) The best operating conditions were 50 g of plumbojarosite and 7 pct So (2.04 g So added) in 500 mL of 2.0-mol/L NH3 at 150° C for 1 h. The sulfidation product contained, in percent, 37 Pb, 28 Fe, 2 S042., 7 total S, and 11.2 tr oz/st Ag. Flotation of the sulfidation product was conducted at pH 3 with 15-pct pulp density and 2.4lb/st of isopropyl xanthate as collector. The flotation concentrate contained 43 pct Pb, 25 pct Fe, and 13 tr oz/st Ag. FeCl3 leaching of the sulfidation product in a resin kettle extracted 98 pct Pb and 97 pct Ag from the sulfidation product, and HCI-Oz leaching in a shaker glass bottle extracted 99 pct Pb and 98 pct Ag. Both leach residues met the Environmental Protection Agency&apos;s Toxicity Characteristic Leaching Procedure (EPA-TCLP) standards for nonhazardous wastes. The HTS and chloride leaching procedure is a potentially effective method for detoxification of plumbojarosite-bearing residue from the zinc pressure-leaching circuit.

Jan 1, 1989

By J. R. Goode

There are at least a dozen methods of selectively removing cerium from a mixture of the rare earth elements (REE) including separation techniques based on the oxidation of cerium to the quadrivalent state. Several of the oxidation processes have been operated on a commercial scale, others have been tested and in some cases are part of proposed flowsheets. In this paper, we describe and compare the various methods. We also present preliminary estimates of the costs of early Ce removal and discuss recovery and purity aspects of the options.

By R. K. Filip

"Steel bearing piles have long been used to carry high compressive, tensile and lateral loads. Such piles are most commonly tubular or ""H"" profile and are typically installed using percussive techniques. The noise and vibration associated with such installation techniques tends to preclude the use of steel bearing piles in urban and other sensitive areas.This paper describes the design and construction of an innovative new road bridge in Milton Keynes, UK. The steel bearing piles were required to continue out of the ground to form the bridge columns and abutments and then be cast directly into the soffit of the reinforced concrete bridge deck. This project was to be the first time in the UK, that this form of bridge design had been used.The paper shows how new installation techniques allowed the designers to use these high capacity steel elements in a sensitive urban environment without the use of percussive or vibratory installation techniques. Finally the paper shows how these quiet and vibration-less installation techniques can be extended to other applications.A UNIQUE BRIDGE SUPPORTED ON ""BOXED SHEET PILES""CONCEPT HISTORYThere are over 700 bridges in Milton Keynes. Concrete is the dominant construction material, most are single span with massive parallel wing wall retaining abutments. All have a certain uniformity of aesthetic design. Pell Frischmann Consultants Ltd (PFC) proposed to the client, English Partnerships (EP), that an ""integral bridge"" with a slender open appearance would be an appropriate aesthetic form for a new highways bridge, within the district of Westcroft (figure 1). The concept required that the bearing piles be continued up out of the ground to form the bridge columns and abutments. Four rows with four piles in each row were suggested. Each would then be cast directly into the reinforced concrete bridge deck forming a moment connection (figure 2). This concept meant that a single continuous steel structural member would replace traditional reinforced concrete bored piles, pile caps and piers. This member would carry vertical and lateral loads. The conceptual design was intended to meet the following client requirements:"

Jan 1, 2005

By Swaminathan Srinivasan, Aaron J. Muck

"When an opportunity arises to combine state-of-the-art concepts with advanced modeling tools, engineers need to take what they know and apply forward thinking to geotechnical solutions to promote the state-ofpractice. Such an opportunity was seized during the design and construction of the Great American Tower in Cincinnati, Ohio. The forty-one story Great American Tower at Queen City Square – currently the tallest building in Cincinnati – has not only changed the downtown skyline, it is also contributing to the advancement of the state-of-the-art use of auger cast-in-place (ACIP) piles as settlement reducers. Predicted settlements of a traditional mat foundation were excessive, and the costs and construction time associated with traditional ACIP piles extending to bedrock were not preferred. A mat supported on a limited number of ACIP piles, with the piles primarily acting as settlement reducers, was evaluated as the preferred foundation type.Promoting the unique soil-structure interaction of the foundation system with confidence required the use of sophisticated numerical modeling tools. Traditional standard penetration test boring data (SPT) was initially used to develop a numerical analysis of the soil-structure interaction using FLAC 3D software. The model was further modified with cone penetration (CPT) and pressuremeter testing (PMT), along with actual load test results on several ACIP pile elements of varying lengths, but all tipping above bedrock. Through a combined design team effort, and detailed numerical modeling analysis, ACIP piles were recommended for reducing mat foundation settlement. Instrumentation during and post-construction confirmed design assumptions and predictions. Integrating sound geotechnical concepts, and using advanced geotechnical analysis and design methods, traditional mat and ACIP pile foundations were successfully integrated into a unique foundation support system.INTRODUCTIONThe Great American Tower at Queen City Square in Cincinnati, Ohio is located within a region dissected by historical geologic deviances associated with the meander of the Ohio River and glacial progression/recession. Combining a challenging geology, with the development of a high-rise office building afforded the design team an opportunity to combine state-of-the-art soil-structure interaction concepts and method with traditional geotechnical engineering concepts. Such a combination required a variety of field tests, collaboration with the design team and owner, and geotechnical-structural modeling during the design phase. During construction, in addition to materials testing and observation, a variety of instrumentation systems were employed. Together, the data was used to corroborate the design model and make adjustments during construction and further substantiate design assumptions following construction."

Jan 1, 2015

By C. van Buuren, R. F. Sandenbergh, P. J. Pieterse

Gold extraction from double refractory ores using conventional cyanidation has proved challenging due to the presence of carbon within the ore. Carbon particles may adsorb leached gold resulting in gold losses to tailings, i.e. preg-robbing the gold. Some of the preg-robbed gold may be recovered by the application of the HiTeCC process on CIL tailings. The process developed by Metso Outotec involves caustic conditioning of the tailings followed by high temperature desorption and simultaneous adsorption onto virgin activated carbon of the aurodicyanide. The aim of this paper was to develop a model for the HiTeCC process which could be used to support design and optimisation of the process, based on the adsorption characteristics of the preg-robbing and activated carbons. It was found that accurate experimental isotherms can be used to predict the behaviour of preg-robbing adsorbents. Comparing the sorption isotherms for preg-robbing ores and activated carbon indicated similar dependencies on temperature and ionic composition. Applying boundary layer diffusion models coupled with experimentally determined isotherms for preg-robbing ore and activated carbon, the HiTeCC process was successfully simulated at experimental and plant scale. Gold recovery of the HiTeCC process is most sensitive to the temperature of desorption and gold loading of the activated carbon, with increased temperature improving recovery. The gold loading of the activated carbon in the process should always be maintained lower than that of the normalised pregrobbing carbon gold loading to ensure favourable conditions for adsorption onto the activated carbon. Caustic conditioning stabilises adsorption and is therefore not necessary during the desorption stages of the process, but potentially improves recovery during adsorption. Keywords: Preg-robbing, refractory gold ores, HiTeCC, aurodicyanide

Jan 1, 2020

By I. WILKOMIRSKY, J. BECKER, F. Parada

Purification of molybdenite concentrate from copper concentrates was performed by sulfation. The sulfation of molybdenite concentrates was carried out with pure sulfuric acid (> 96%) at 160–190 °C to study the influence of the reaction temperature and reaction time on the residual copper in the molybdenite concentrates. A purified concentrate with less than 0.1 wt% copper and low levels of other metals were obtained. For up to 7.1 wt% copper, the conditions required are a temperature of 190 °C, a reaction time of 14 h, and a moly/acid weight ratio of 1/1. Furthermore, several designs of sulfation reactors were evaluated in order to obtain the desired level of copper in the product and to analyze the influence of the operational and design parameters on the reactor dispersion number (Le). The basic design for an 80-t/day plant fed with 4 wt% copper molybdenite concentrate requires five backmixed reactors in series, each measuring 8 m3, operating at 190 °C and with a reaction time of 10 h. The reactor must be protected against severe corrosion by the hot sulfuric acid with either Teflon, glass or ceramic.

Jun 14, 2022

By D. Harrington

As no cure is known for silicocis after it has developed, prevention is the only effective remedy. There are two main lines of approach to the problem of dust-disease prevention in industry - the engineering, through control of dust production, and the medical, through selection of workers by examination; success probably depends upon a combination of the two. Hatch (146) considers the following measures essential to a complete, well-balanced program of control of the dust hazard in industry: 1. Selection of workers by means of physical examinations in order especially to eliminate those with tuberculosis and other disorders of the respiratory system. 2. Reduction of the duct concentration below the standard of permissible dustiness through adequate moans of dust control and good housekeeping. 3. Limiting the frequency and duration of employment in the dusty occupations, thus reducing the rate of deposition of dust in the lungs. 4. Routine measurement of the effectiveness of the dust-control program by means of periodic medical examinations and duct surveys.

Jan 1, 1935

By Charles F. Coleman

Kinetics studies and other rate measurements are reviewed in the amine extraction of uranium and of some other related and associated metal ions. Equilibration&apos; is relatively fast in the uranium sulfate systems most important to uranium-hydrometallurgy. Significantly slow; equilibration-has &apos; been encountered&apos; in some other systems. Most of the recorded rate information, both qualitative and quantitative; has come from exploratory and, process-development development work, while some kinetics studies have been directed specifically toward elucidation of, extraction mechanisms. In contrast to some other extraction systems, relatively little attention has been given to the kinetics of uranium extraction by amines. This is because investigators have not been troubled by slow extractions. Instead, when rate limitations have been of concern in amine extraction (Amex) process developments, they have been mainly from slow phase disengagement rather than from slow equilibration. Nevertheless, taking uranium together with several other elements that are closely related to it or associated with it in typical processes, a considerable body of rate information has been recorded.

Jan 1, 1979

By Charles M. Keenan

THIS PUELICATION lists and provides brief accounts of the major disasters not classified as explosions of gas or dust that have occurred in the cod mines of the United States from the earliest times to the present. Together with an earlier publication of the Bureau2 it provides information on all the known major coal-he disasters (disasters causing five or more deaths) in this Nation&apos;s history. Sources of each account are given individually. In each account the actual words of the original publication are used unchanged, but sentences or paragraphs referring to details that are not significant have been omitted. In those few cases where conflicting data were reported in different publications the selected version is the one that appears most logical and which in general is in agreement with most of the other accounts.

Jan 1, 1963

By R. Degel

Keywords: Pyrometallurgy, DC furnaces, electric smelter, FeCr, FeNi, FeMn, Si metal, ferro-alloys, platinum production, circular furnace, energy recovery system In 1906, the first submerged-arc furnace was supplied by SMS Siemag. Since then, the division has become established in various industries such as ferro-alloys and non-ferrous metals, and in numerous other special applications. During the evolution of this technology, more efficient units with longer lifetimes were developed. Today, especially the potential of DC-based smelters, raises worldwide attention, with some projects having already started to implement this kind of technology. This paper evaluates SMS Siemag?s general viewpoint regarding the potential application of DC smelter technology and possible options for the ferro-alloy and non-ferrous industry. SMS Siemag is currently executing a FeCr project in Kazakhstan, where four of the world?s largest closed-type DC smelting furnaces, with a power input of 72 MW, will be installed. These furnaces include the latest technological features of modern DC smelters, which are described in this paper. SMS Siemag has started a long-term research and development project allowing a direct comparison of AC versus DC technology on a large scale, using a recently installed 1 MVA test furnace at the IME at the University of Aachen, in Germany. For open-type ferro-alloy and Si-metal furnaces, SMS Siemag has developed an energy recovery system, which is presented in this paper.

Jan 1, 2011

By K. C. Corin, M. S. Manono, R. M. Manenzhe, J. G. Wiese

"Environmental concerns necessitate the recycling of process water within mining operations. Given that recycled water is chemically different from fresh water, and collectors are added such that they adsorb at the liquid-particle interface, changes in the aqueous phase are expected to affect collector adsorption. A Finnish nickel-copper ore was floated in synthetic plant waters of varying ionic strengths and plant waters obtained at Boliden Kevitsa Mine, with aerophine and sodium isopropyl xanthate as collectors. Of the tested waters, the copper thickener overflow was the least conducive to xanthate adsorption and valuable mineral recovery. The nickel thickener overflow, standard process water, and raw water were the most conducive to xanthate adsorption. For the raw water and nickel thickener overflow, increased adsorption correlated with increased valuable mineral recovery. Further, recycling xanthate retained in water affected the selectivity of the collector and hence the concentrate grades.INTRODUCTIONFlotation is a separation process that exploits the differences in the surface properties of the particles being separated. The efficiency of separation is dependent on the degree of hydrophobicity achieved by the particles meant to be floated, which are, in most cases, valuable minerals. The hydrophobicity is in turn dependent on the adsorption of the chosen collector onto the surfaces of the floated particles (Fuerstenau, 1984; Taggart and Hassialis, 1946). Empirical findings suggest that species dissolved in solution strongly influence collector adsorption and overall flotation response (Fuerstenau and Chander, 1986). Due to environmental concerns, it is becoming more pertinent for mining plants to recycle process water and hence limit the usage of potable water. There is an interest to ensure minimal discharge of plant water into the environment, as this water is typically polluted with process reagents that may render it toxic (Levay et al., 2001).Recycled water, however, has been shown to adversely affect flotation. Reagent efficiency can be reduced due to increased suspended solids. A loss of mineral recovery can occur due to competitive adsorption between reagents and other dissolved species, loss of reagents due to precipitation, and unwanted reactions. Further, a reduction in grade can occur due to non-selective coating of reagents on valuable and gangue minerals, and hydrophobic coating of microbiological material on gangue, causing unwanted flotation. Yet despite these drawbacks, water reuse has the advantages of minimal fresh water use and reduced reagent consumption by recovering the unconsumed reagents retained in wastewaters (Bruckard et al., 2011; Levay et al., 2001; Shengo et al., 2016; Slatter et al., 2009)."

Jan 1, 2018

By S. Swaroopa

Copper-chromium mixed oxides are widely used as catalyst for organic chemicals industry, NOx and CO oxidation, solid propellant etc. In the present investigation, one such spent Cu-Cr catalyst has been tested for recovering copper and chromium values through hydrometallurgical route. The spent catalyst used in this study contains about 42% Cu and 36% Cr. Phase analysis through XRD indicates that major phases are copper chromium oxide (CuCrO2) and copper chromate (CuCr2O4) while minor phase is copper oxide (Cu64O). SEM images show that high energy ball milling changes surface morphology significantly ? more regular shaped grains in unmilled samples changed to fine agglomerates. Surface area also changes significantly due to milling. Preliminary leaching experiments with NH3 and H2SO4 media using unmilled samples indicate that both the media are suitable for selective extraction of copper. About 55% copper recovery is achieved in 2 h using 1.2 M NH3 + 0.2M (NH4)2SO4 solution at 100°C. Increasing NH3 concentration or temperature does not improve the recovery significantly. Under the above conditions chromium, dissolution is insignificant (max. 2.24%). XRD analysis of the residue indicates that copper chromate fraction (CuCr2O4), which is a spinel structure, remains mostly intact. In sulphuric acid media at ambient temperature, 47% copper recovery is achieved with 7.5% (v/v) H2SO4 and maximum of 57% with the increase in acid concentration to 20%. However, 67% recovery is achieved by increasing the leaching temperature to 150°C. High energy ball milled samples show improved leaching efficiency. Under the leaching conditions of 7% H2SO4 (v/v), 2% pulp density, 80°C an unmilled sample yields 47% Cu recovery whereas 3h and 5h milled samples yield 65% and 90% Cu recovery respectively in 2h leaching time. Influence of temperature is also more pronounced in milled sample leaching in comparison to unmilled sample. Water leaching of alkali (NaOH) roasted milled sample carried out at 750°C for 2 h with 100% NaOH (w/w) resulted in 80% Cr recovery as compared to 37% Cr recovery using unmilled sample under the same conditions. Keywords: spent catalyst, copper, chromium, leaching, mechanical activation, roasting

Sep 1, 2012

By Robert H. Merrill

A method of determining the strength of a mine roof layer in place is described in this report. The method was tested on a limestone roof layer 50 feet wide, 100 feet long, and 20 inches thick. In place measurements were accomplished by introducing air under pressure into a separation between the layer and the overlying roof, and as pressure was increased, the corresponding strain and deflection of the roof layer were measured until the roof failed. The ultimate strength of the roof agreed with the tensile strength of the roof rock (modulus of rupture) as determined in the laboratory; the modulus of elasticity as measured in place did not agree with the laboratory-determined values; the deflection and tensile strain in the layer in place showed good agreement with the theory of a body-loaded beam clamped at both ends. This procedure for determining the strength of a mine-roof layer is safer and less costly than successively widening a roof to failure. For example, it would have been necessary to mine the room to a width of 114 feet and a length of 228 feet to produce failure in this roof layer. The method is not necessarily limited to limestone; any thinly bedded rock type can be tested by this procedure when there is an open parting over the mined area.

Jan 1, 1958

By Bo-Hyun Kim, Steve Berry, Mark K. Larson

"When coal pillar bursts occur, they involve the sudden expulsion of coal and rock into the mine opening. These events occur when relatively high stresses in a coal pillar, which serve as support in underground workings, exceed the critical capability of the pillar. This causes the pillar to rupture without warning. A cleating is a type of naturally occurring joint system unique to coal seams. However, cleatings are pervasive throughout the coal seam and are much more tightly spaced than joints occurring in other rock types. In this study, researchers from the National Institute for Occupational Safety and Health (NIOSH) investigated 84 coal samples obtained from a Utah coal mine by conducting both unconfined and triaxial compressive tests in order to examine the response to stress as a function of both confinement and orientation between cleat and loading direction. The results of the study show that the confining pressure dictated not only the peak compressive strength but also the brittleness as a function of the major-to-minor principal stress ratio. The spalling limit of the coal estimated by the s-shaped brittle failure criterion appears to be very dependent on the angle between the cleat and the loading direction, particularly at lower confinement.INTRODUCTIONCoal pillar bursts, or bumps, remain a most critical safety concern in underground coal mining, despite significant advancements in engineering controls. As shown in Figure 1, between 1983 and 2014, there were nearly 400 cases of reportable dynamic failure accidents in coal and nonmetal mines, resulting in 20 fatalities, 155 lost-time accidents, and an estimated 48,000 lost man hours (MSHA, 2015). These types of events have been documented for well over 100 years within the American underground coal mining industry. During this time, mining practices and support technologies have evolved considerably, resulting in an overall decrease in the rate of dynamic failure-related injuries and fatalities. Although techniques and practices of mining are highly advanced, coal pillar bursts, or bumps, continue to occur (Mark and Gauna, 2015). If coal is expected to fail in a brittle manner, behavior changes associated with relatively low tensile strength, such as the transition from tensile to shear failure, have to be considered and reflected in the adopted failure criteria. Rock failure in tension takes place at low confinement around excavations due to tensile failure in heterogeneous rocks (Diederichs, 2007). The prospect of tensile-dominant brittle failure diminishes as the confinement increases away from the excavation boundary. Therefore, it is expected that the transition from tensile to shear mode in the failure mechanism occurs as the confinement level changes and conditions for tensile failure are prevented or strongly diminished. In addition, many uncertainties remain because of the highly anisotropic characteristics of coal seams associated with geologic structure and the mining-induced spatial redistribution of stress in coal pillars. Thus, to prevent fatalities in underground coal mining, continuous effort is required to better understand the catastrophic failure mechanisms in coal mines."

Jan 1, 2018

By Kandipati Sreenivasarao

A promising method for removing heavy metal ions from dilute effluents is ion- or precipitate- flotation, in which a suitable collector is added to form hydrophobic metal-collector complexes or compounds that can be collected as foams. We have successfully removed Cu(II), Cd(II), and Pb(ll) from dilute solutions using sodium dodecylsulfate and ethanol as collector and frother respectively. However the process would not be economically viable unless the collector could be recycled, and the heavy metals recovered in a concentrated, preferably marketable, form from the foams. We investigated four different methods to decompose heavy metal-dodecylsulfate complexes, namely precipitation of hydroxides, precipitation of sulfides, chemical stripping, and electrolysis. We compare the performance of these methods. In each case the observed behavior is related to known thermodynamic data, and potential applications are discussed.

Jan 1, 1995