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By A. Farnoud

Thousands of miners, construction workers, and truck drivers are exposed to diesel exhaust particles. Diesel Particulate Matter (DPM) is a probable human carcinogen and stringent occupational and environmental standards have been established or are planned worldwide. Modifications in fuels and diesel engine designs have reduced emissions, but may not be enough to comply with the tightest standards. Post-combustion aftertreatment devices are likely necessary for many engine operators. However, even the most common and well studied aftertreatment devices fail from time to time. The objective of this study was to design, construct, and test an electrostatic aftertreatment device to treat DPM. An electrostatic precipitator (ESP) was designed and constructed to capture DPM from diesel exhaust, and different configurations were tested to optimize its performance. DPM was produced by a 6 kW diesel-powered electric generator and directed to the ESP through a short section of galvanized steel pipe after the muffler. Number and mass removal efficiencies were measured with a condensation particle counter (CPC) and by sampling through a stainless steel cassette and collecting the DPM on Teflon filters. Particle size distributions were measured with and without control using a 6-stage cascade impactor. The experiments were performed with the engine running at idle and also at medium load. The results show that our first generation ESP provides 60 percent mass removal efficiency, and up to 80 percent number removal efficiency. Power consumption was generally low, about 20 to 30 watts, to achieve these levels of performance.

Jan 1, 2009

By David Estrella, Hector M. Lizama, Jhonny Carrión

"Microcel™ sparging systems were installed on one column of the molybdenum cleaner circuit and one column of the copper first cleaner circuit at Antamina. The Microcel™ system is known to generate finer bubbles than jetting-type spargers, and smaller bubbles have been associated with higher recoveries in flotation. Alternating tests were carried out on the molybdenum column, using either jetting-type spargers or the Microcel™ system. Experimental conditions of gas flow rate, wash water rate, and froth depth were tested. Use of Microcel™ decreased the bubble sizes from 2.6-2.9 mm to 1.5-2.0 mm. In addition, Microcel™ improved both unit molybdenum recovery and unit molybdenum concentrate grade. In the copper first cleaner circuit, side by side tests were carried out that compared the Microcel™ column with a parallel columns fitted with jetting-type spargers. Best results were obtained at manifold pressures of 260-290 kPa, where bubble sizes of 1.6-2.6 mm were observed. In either copper or molybdenum flotation, the Microcel™ system required only 50-60% of the gas flow used by jetting-type spargers.INTRODUCTIONAntamina is a copper-zinc mine located in the Peruvian Andes. Compañía Minera Antamina is owned by BHP Billiton (33.75%), Xstrata (33.75%), Teck Cominco (22.5%), and Mitsubishi (10%). The mine was commissioned in 2001 with a capital investment of US$2.3 billion, and has a nominal 100,000 t/d mill capacity. Mining, milling, flotation, and tailings impoundment take place at the mine site, which sits at an altitude of 4,300 m above sea level. The deposit is a polymetallic skarn ore body with intrusive phases of quartz-monzonite porphyry into Cretaceous aged limestone [Evans et al, 2005]. Ore body thickness is 100 to 150 m and has the shape of a flat-lying crescent. Copper is present mainly as chalcopyrite with a minor bornite component. Zinc is present as sphalerite. Molybdenum is present as molybdenite. Some lead, bismuth, and silver are associated with the sulphides. The deposit is currently classified into six main ore types [Dechert, 2006], grouped into two categories: copper and copper-zinc. The mill produces four concentrate types: copper, molybdenum, zinc, and lead-bismuth. Copper, zinc, and lead-bismuth concentrates are transported by pipeline down to the port of Huarmey. Molybdenum concentrates are bagged and trucked to port."

Jan 1, 2008

By A. E. Raddatz

In an attempt to develop technology to use domestic resources in place of imported bauxita, the Bureau of Mines investigated sulfurous acid leaching to extract alumina from kaolin. The process consists of leaching the calcined kaolin with a 30 wt-pct S02 solution at 60° C and 160 psig for 17 hours, fil¬tering the leach slurry, precipitating monobasic aluminum sulfite from the filtrate at 110° C and 60 psig, a& decomposing the sulfite in the spent liq¬uor at 150° C and 55 psig to produce crude alumina. Purification of the crude alumina was accomplished using a modified Bayer process. Results from closed-circuit tests employing the sulfurous acid process showed that overall extraction of alumina from kaolin was 67 pct. Production of 1 ton of alumina would require 3.6 tons of calcined kaolin, 0.7 ton of sul¬fur dioxide, and 8.4 tons of water. After purification by a modified Bayer process, the alumina product contained the following; impurities, expressed in weight-percent: Fa203, 0.009; S, 3.6; Si02, 0.07; Ti02, 0.002; K20, 0.017; and P205, 0.03.

Jan 1, 1981

By S. F. Fu

The Charkhan Salt Lake area of the Chaidamu Basin in West China is characterized by soft super-saline soils with very high contents of soluble salts. From the engineering point of view, these saline soils are saturated, liquid-plastic and moderately to highly compressible lean silty clay and clayey silt. In the natural state, their allowable bearing capacity is only 60-80 kPa. As to the saturated lean silty clay, liquifaction in case of an earthquake of intensity 7 on the Modified Mercalli scale is considered likely. In order to improve the geotechnicai properties of the saline soils, stone colomn stabilization by means of vibroflotation was performed. As the geotechnicai properties of the soils are closely linked with the amount and composition of the soluble salt content, saline water with chemical content similar to that of the saline soils was used as flush fluid in the course of hole-making and column-forming, with a view to keeping unaltered the amount and composition of the salts in the soils and thereby precluding reduction in or loss of their strength. Systematic monitoring on the behavior of the foundation soils before and after the treatment and comparison of the numerical data thus acquired have shown good technical results, testifying to the effectiveness of stabilization of soft superealine soils by vibroflotation. As a result of the treatment, the allowable bearing capacity was increased one to two fold, accompanied by elimination of the liquefaction potential.

Jan 1, 2010

By K. K. Kelley

Thermodynamics data for silicates have applications in the fields of extractive metallurgy, ceramics, and geochemistry. To facilitate these applications, up-to-date tables of heats and free energies of formation are needed. It is the purpose of this report to supply such tables for anhydrous silicates. During the last 15 years the heats of formation of a substantial number of anhydrous silicates have been reliably determined at or near room temperature. This resulted from the development (first by the Bureau of Mines and later by the Geophysical Laboratory of the Carnegie Institution of Washington, by the Institute of Geology of the University of Helsinki, Finland, and by the Department of Geology of the University of Chicago) of accurate solution calorimeters, employing hydrofluoric acid as the reaction medium. Specific references to work of these laboratories will be made in the next section of this report. Also, entropy data at 298.150 K. and high-temperature heat-content values are available for many of these silicates, mainly owing to work of the Bureau of Mines. Most of these entropy and heat-content data have been compiled in Bureau of Mines Bulletins (13, 15).3

Jan 1, 1962

By H. R. Shell

Fluorphlogopite mica was synthesized from inexpensive and abundant olivine, clay, feldspar, and sand (plus K2SiF6). The raw materials were melted in crucibles and in an internal resistance electric furnace. The melts yielded >95 percent mica. The major difficulty encountered was incomplete settling of the highly dispersed ferroalloy. This problem was not completely solved. Reducing agents tried in melts of 300 to 400 pounds were carbon, silicon, and silicon carbide. Carbon slowly reduced the iron of the raw materials, with much fuming. Silicon apparently was oxidized ahead of the melting and was ineffective under the conditions obtained. By far the best reducing agent was silicon carbide. With silicon carbide, fuming did not occur and ionic iron content of the mica flake approached 0 percent. However, even with SiC, the highly dispersed globular iron did not completely separate from the mica portion. The fluorphlogopite made during this investigation should be suitable for metallurgical use. A byproduct ferroalloy containing about 5 percent nickel, 3 to 5 percent chromium, and some cobalt was obtained. Because of the highly dispersed metallic ferroalloy, the mica was not deemed suitable for electrical or electronic uses.

Jan 1, 1962

By Reda M. Bakeer

"An approach slab is the roadway segment that immediately follows a bridge intended to provide a smooth transition between the two elements. Some approach slabs have developed rough rideability with time due to differential settlement between the roadway embankment and the bridge. Soils in south Louisiana are generally poor and highly compressible and, therefore, pile-supported approach slabs were occasionally used. Timber piles of variable lengths are driven into the soft soils where no appreciable toe support exists. This resulted in the soils both supporting loads through shaft resistance and yet experiencing long-term consolidation settlement. Field testing and review of the records of over 120 approach slabs constructed in south Louisiana yielded the conclusion that their performance is primarily governed by negative skin friction (downdrag) imposed on the relatively short timber piles. A software (TU-DRAG) was developed to evaluate the deflection profile of a pile-supported approach slab based on its geometry and conditions of the underlying soils. It evaluates the effect of dragload considering the number and spacing of the piles at each transverse row and their variable lengths along the approach slab. TU-DRAG was utilized in the design of two transportation related projects which have been in service for more than 10 years.INTRODUCTIONThe problem of differential settlement at bridge approaches or “the bump at the bridge” has been recognized for many years. Research studies (1986, 1989, 1997, 2009 and 2013) by the Transportation Research Board (TRB) and the Federal Highway Administration (FHWA) provided comprehensive evaluations of the performance of bridge approach slabs by assessing their field conditions and construction and maintenance records. Various states have also performed their own studies to investigate the performance of bridge approach slabs. The studies considered various types of structures including soil- and pile-supported approach slabs, integral bridge abutments and open-end abutments. Recommendations were provided for the design of new structures and for maintaining and repairing existing structures. Guidelines were offered regarding tolerable movements of bridges and their foundations based on measurements of vertical and horizontal movements of 580 bridges Moulton (1986). Vertical and horizontal movements greater than 102 mm (4 inches) and 51 mm (2 inches), respectively, were considered intolerable. Tolerable limits for angular distortion (differential settlement to span length) were suggested to be 1/250 and 1/200 for continuous and simple spans, respectively. It was reported that a differential settlement greater than 13 mm (0.5 inch) at the bridge interface would be sufficient to constitute a “bump” requiring mitigation."

Jan 1, 2017

By C. A. Komar

The Bureau of Mines conducted oil-displacement tests in the laboratory with three water-in-oil and five oil-in-water emulsions that were created with ultrasonic energy at a frequency of 20 kHz and an acoustic intensity of approximately 100 watts per cm2. Emulsions of either crude oil or kerosine, brine, and 112 to 2 percent emulsifier were formed during 30 seconds of acoustic irradiation. Results indicate that ultrasonic energy induces greater and more uniform dispersion of one liquid in another in the presence of small amounts of chemi¬cal emulsifiers. When the emulsions were injected as a buffer slug before waterflooding, recovery of the oil-in-place was 8 to 22 percent greater than with conventional waterflooding in the test specimens, regardless of the con¬tinuous phase (oil or brine). The emulsions do not appear to be applicable to the Appalachian area; however, because the oilfields are too "tight," the clays in the formation remove the emulsifier from the displacing fluid, and not enough additional oil is produced, compared with recovery using conventional waterflooding, to warrant the increased operating costs.

Jan 1, 1969

By J. D. T. Capocchi, M. B. Mourao

The rate of reaction between iron oxides and carbonaceous materials, agglomerated as pellets, was studied experimentally by measuring the weight loss as a function of time. The effects of temperature, carbon type, inert gas flow rate, pellet size and additions (sodium. carbonate and Portland cement) were determined. It was shown that the value of the apparent activation energy can display large deviations under different experimental conditions; in the present work it was found to be 226.6 kJ/mol. The reaction with coke is slower than with charcoal, and the rate increases as the flow of inert gas in the reaction vessel decreases. Comparison of the rates for pellets of different sizes has shown that for small pellets the initial rate is faster but that it slows down at high conversions owing to the penetration of inert gas into the pellet. Additions of sodium carbonate and Portland cement increase the rate; sodium. carbonate promotes the catalysis of the Boudouard reaction, which is the slowest of the partial reactions. The increase in the rate with Portland cement is attributed to the release of water vapour

Jun 18, 1905

By J. Brian Anderson

Jointed micropiles were investigated to support bridge foundations where shallow rock was present. In this application, micropiles would have some amount of unsupported length, and would be subject to nominal lateral loads. Five lateral load tests were conducted on micropiles to demonstrate the impact of casing joints and rock socket embedment on lateral behavior. Load tests were simulated with FB-Multipier, a hybrid-finite element program for analysis of deep foundations, for proper design of the loading apparatus and instrumentation. The micropile sections were 2 m (6.56 ft) long, 273 mm (10.75 in) in diameter, 13 mm (0.5 in) thick walled, with a 50-mm (2-in) long threaded joint. Micropiles were made of one to three casing sections and were embedded 0.3, 0.6, 1.5, or 3.0 m (1, 2, 5, or 10 ft) into rock. In each test, two identical micropiles were pulled together using a simple frame until the weaker pile failed. All micropiles were instrumented with inclinometer casings while two contained strain gages at 0.76 m (2.5 ft) intervals. Load and displacement were measured at the pile heads. Tests showed the embedment of 0.6 m, 1.5 m, and 3.0 m (2 ft, 5 ft and 10 ft) sufficiently carried lateral loads over 180 kN (20 tons). The piles embedded 0.3 m (1 ft) were not able to maintain lateral load. In general, all micropiles tested to failure exhibited a brittle failure mode where there is small lateral deflection followed by a sudden failure at the casing joint. This was demonstrated in three of the load tests. In most cases, the micropiles were stiffer and stronger in the load tests than originally predicted numerically. The final test, where piles were not loaded to failure, verified that embedding vibrating wire rebar strain meters in the grout captured the bending moment profile of the micropile. The results showed the maximum moment in this case being carried directly across the threaded joint as predicted by the preliminary models. The results of these tests were used to calibrate the FB-Multipier numerical model. Using a load test that included bending strain measurements for a match, the soil properties were adjusted to produce reasonable matches for all of the load tests.

Jan 1, 2011

By B. E. Burakov, S. D. Lupal, O. A. R. Thalhammer, B. Saini-Eidukat

Electric-pulse disintegration is a mineral separation technique that liberates all mineral grains from any igneous or metamorphic rock irrespective of its lithology or grain-size distribution. The normal mechanical crushing of whole-rock samples is replaced by the rending effect of an explosion, produced by applying an electric current from a high-voltage power source. A voltage greater than the 100 kV necessary for the electrical breakdown of rock samples is achieved by using capacitors charged in parallel, but discharged in series. The sample sits in a water bath and the rapid distribution of electric pulses leads to an explosion which occurs preferentially along grain boundaries of the sample. Individual, undamaged mineral grains can be recovered in their original shape and form regardless of grain size. Examples are given of the liberation and concentration of important accessory minerals from different rock types. The examples show the recovery of diamond from two types of non-kimberlitic host rock in Popigai and Kumdykol in Kazakhstan and platinum group minerals associated with chromitites from the Konjdor intrusion and sulphides from intrusions in the Kola Peninsula in Russia

Apr 1, 1995

By J. Bakken, M. Th. Jonsson, G. Sævarsdottir

A typical three-phase submerged-arc furnace for production of silicon metal and ferrosilicon has arc currents ~100 kA, phase voltages ~100 V and total furnace power ~10 - 60 MW. The arcs burn in gas filled cavities or "craters", where the main atomic components of the plasma mixture are silicon, oxygen and carbon. Two quite different simulation models for high-current AC arcs have been developed: the simple Channel Arc Model (CAM), and the more sophisticated Magneto-Fluid-Dynamic Model (MFD). These models have been described extensively and results reported at INFACON-8 and INFACON-9, respectively. The coupling between the arcs and the AC power source is described by a complete three-phase Electric Circuit Model. Recent numerical modelling studies of industrial AC arcs show that the boundary conditions at the cathode and anode are critical for the simulation results. A novel Cathode/Anode Sub-Model for high-current AC arcs that treats both cathode and anode indicates a completely different cathode behaviour than previously assumed. A cathode spot which serves a high-current electric arc is shown to be dominated by the energy impact from the arc. This leads to lower cathode fall voltage than obtained from previously developed models. The anode fall voltage is negative, as the main function of the potential barrier is to repel plasma electrons. The cathode spot is diffuse in the sense that the arc in fact contracts away from the cathode. Simulation results are compared to measurements on both industrial furnaces and smaller scale pilot furnaces. An important conclusion, supported by our arc studies, is that the arc length in silicon metal and ferrosilicon furnaces does not exceed 15 cm and the arc may burn anywhere on the electrode, not necessarily beneath the electrode tip.

Jan 1, 2004

By Donald P. Tuchman, Robert P. Vinson, Steven J. Page, Linda J. McWilliams, Gerald J. Joy, Steven E. Mischler, Jon C. Volkwein

The National Institute for Occupational Safety and Health (NIOSH), through an informal partnership with industry, labor, and the Mine Safety and Health Administration, has developed and tested a new type of instrument known as the personal dust monitor (PDM). The dust monitor is an integral part of the cap lamp that a miner normally carries to work and provides continuous information about the amount of respirable coal mine dust in the breathing zone of that individual. Testing was conducted on 25 prototype instruments in the laboratory to verify the instruments’ accuracy as received from the manufacturer and after a period of underground use. The laboratory testing verified previous work; there is a 95% confidence that the individual PDM measurements were within ±25% of reference measurements. In-mine testing determined the precision, durability, and miner acceptance. Data from the mines showed a field precision of 0.078% relative standard deviation for the PDM and 0.052% for the recognized standard—the coal mine dust personal sampler unit. The PDM had about 90% availability for collecting valid information in over 8,000 hr of underground use. Anecdotal comments by miners indicated that they found the PDM more convenient to wear for sampling than currently used instruments because of the integration of the sampler into the normally worn cap lamp. The means of the instruments’ pre- and postmine accuracy verification test values were statistically equivalent. Additional data were collected to measure the equivalency of the PDM to the U.K. Mining Research Establishment sampler, as required by U.S. law. However, analysis of the data was more complex than originally anticipated because the variance with increasing concentration required use of a more sophisticated statistical model. Explanation of and results from this work will be the subject of a second publication. Under the broad range of test conditions covered in this work, the PDM functioned as well as the current sampler in terms of availability for use, accuracy, precision, and miner acceptance.

Jan 1, 2006

By R. W. Baker

"The development of uppers drilling at Brunswick Mining is reviewed. This paper describes design criteria for drilling patterns and the research required for selection of a suitable drill jumbo. The success of the uppers drilling program based on operating procedures is highlighted. IntroductionBrunswick Mining and Smelting Corporation Ltd., operates a 10 500 tonnes per day lead /zinc/copper I silver underground mine some seventeen miles southwest of Bathurst, New Brunswick .The No. 12 orebody, first discovered in 1952 by a group headed by M.J. Boylen, had extensive development, including two shallow shafts (500 ft), and test work carried out on it by St. Joe Lead between 1953-1957. However due to complex metallurgy and depressed metal prices, the operation was suspended.In 1961, a group comprised of M.J . Boylen, K.C . Irving and Patino acquired the rights of St. Joe Lead to the No. 12 property. A concerted development plan was initiated along with construction of the necessary sur face facilities and by July 1964, the property was in production at 4500 tons per day.In 1967 Noranda Mines Ltd. acquired operating control of Brunswick Mining and Smelting Corporation Ltd."

Jan 1, 1988

The Wamum and Idzan Creeks Prospect, located 79km W of Lae, Morobe Province, Papua New Guinea (PNG) was discovered by the exploration arm of Conzinc Riotinto of Australia Pty Ltd (CRAE). The detailed surface exploration and 11 vertical holes drilled by CRAE, combined with the recent work by Highlands Gold Limited, indicate the occurrence of porphyry copper-gold mineral- isation and associated alteration. The prospect occurs within andesitic volcanics of the Middle Miocene Langimar Beds. It is bounded by NE trending faults to the NW and SE. The alteration and mineral- isation is hosted in the andesitic tuffs adjacent to high level quartz diorite and hornblende diorite stocks. A NW trend to alteration and mineralisation is obvious in Wamum and Idzan Creeks. The main alteration type is propylitic with minor zones of potassic alteration. A late sericite-quartz-kaolinite-pyrite alteration overprinted the earlier alteration and mineralisation. Copper and gold mineralisation is related to a quartz-carbonate-chalcopyr-ite-pyrite (¦ bornite) vein stockwork and biotite ¦ K-feldspar alteration. The mineralisation system at Wamum and Idzan creeks is low in total sulphides. It is considered as a high- level fracture-controlled system with limited low grade Cu-Au mineralisation.

Jan 1, 1991

By W E. Vance, B H. Ashton

The emission of seam gases into underground workings in coal mines is acknowledged as a major hazard, particularly methane due to its possible ignition. Acknowledge of seam gas parameters is important for the prediction of gas emission rates into the ventilating air current. They are also important as the basis for the evaluation of the likely contained gas as a possible energy source.   Gas content determinations for the Kupakupa seam have been made at the Huntly West Mine.  Applying the method of Creedy (1986) to face samples, gas contents of 1.80 and 1.66 have been determined. Using desorbed and residual gas content data a content of 1.92 m3/t has been derived. These are on an ash included basis. Calculations using the adsorption equation of Kim (1977) and coal quality have given a gas content of 2.19 m3 t. Long-hole exploration drilling at Huntly West Mine has provided information on gas pressure. A pressure rise test has given a reading of 500 kPa (absolute); this is low compared with the pressure given for the determined gas content from theoretical adsorption isotherms.

Jan 1, 1991

By V Morand, W R. H Ramsay

Structural, mineralogical, and textural data from the Tarnagulla Goldfield demonstrate that the area has undergone three significant phases of deformation. The first phase of deformation (D1) predates the intrusion of the Tarnagulla pluton, which has been dated using K/Ar as 391 ¦ 5MY. We regard this pre-granite deformational event as the major regional deformation. Gold-bearing quartz veins have been deposited in dilational sites on west-dipping reverse faults. These sites demonstrate a geometry related both to faulting associated with D1 and the plunge of the F1 fold axes. This evidence, together with chronology of unmineralised ? D2 and D3 faults, the absence of quartz veining associated with D3 events, and the deformation of carbonate-quartz-biotite-sulphide aggregates within Sl by later S2, lead us to conclude that the bulk of the mineralisation was essentially syn- or late D1 . d18O values for fluids in equilibrium with vein quartz from Central Victoria have indicated equivocal support for either a magmatic or metamorphic origin. Our evidence supports a pre-magmatic origin for mineralisation at Tarnagulla and hence tends to favour a metamorphic fluid source.

Jan 1, 1995

Overcasts are indispensible ventilation control devices to permit one airway to pass over another without mixing in room and pillar coal mining. The airflow distribution inside the overcast depends on its spe-cific configuration at which the flow enters into it. This study uses 3D numerical simulation to examine the pressure and velocity distributions inside an overcast. The effects of the overcast angle on the flow field are also examined. The flow is assumed to be turbulent and isothermal and the standard k-e model is utilized. Simulated results display flow separation and recirculation regions of different sizes occurring not only upstream and downstream from the overcast but also inside it. The results also show that the size of the recirculation regions in-creased with the increase in the angle before and after the overcast influencing significantly the flow field and pressure losses. The stream-lines are plotted to show the 3D structure of the flow field. The results from the simulation can guide overcast design commonly used in un-derground coal mines. Keywords: 3-D simulation, Overcast, Room and Pillar, Turbulence, Recirculation Region

Feb 27, 2013

By David L. Giles

The Lime Creek* ore body in northwestern British Columbia is one of the few commercial primary stockwork-type molybdenite deposits in North America. Others include the Climax, Urad-Henderson, Questa, and Endako ore bodies. They are mined on a low grade-high tonnage basis, and are open pit operations except for Climax and Urad-Henderson. Much recent geochemical research on both porphyry copper and stockwork MoS2 deposits has been concerned with dating of micas related to the mineralization and associated igneous rocks. The results appear to show that mineralization and the predominant magmatic events of the deposit are indistinguishable in age (1-5), except where dating has been in sufficient detail to resolve the analytical overlap (6). At Lime Creek, geologic information shows that the Main granodiorite, the major intrusive and dominant host rock for MoS2 mineralization, was emplaced and had solidified sometime prior to the introduction of MoS2. The first MoS2 episode is intimately related to localized bodies of kalialaskite which clearly intrude the older stock. K-Ar dating was undertaken to clarify the age relations between Lime Creek plutonism and the apparently younger hydrothermal event that began with kalialaskite.

Jan 1, 1975

By L. A. Jordan, D. van Vuuren

A two-dimensional finite difference model has been developed to describe the reduction of kilogram quantities of dehydrated phosphogypsum. The model’s scope has been limited to focus on the heat transfer and reactions that occur within a mass of material contained in a vessel inside a furnace rather than also including the effects of heat transfer to the vessel. Changes in the heat transfer properties (k, ρ, and Cp) are incorporated as the composition of the mass changes as the chemical reactions progress. The model is validated against experimental data, with samples heated to 1000°C at 3°C min−1 while purging with nitrogen gas. A sensitivity analysis of model predictions to the pre-exponential factor of the reaction rate constant of the main chemical reaction and the thermal conductivity of the powder bed indicated that, at the envisaged process conditions, the behaviour of the system depends much more on the rate of heat transfer than on the rate of the chemical reaction. The model demonstrated a significant increase in accuracy when the thermal conductivity was modelled to increase linearly with temperature compared to assuming a constant value.

Oct 1, 2022