Search Documents

By R. Barany

The heats of formation at 298.15° K of calcium tungstate, calcium molybdate, and magnesium molybdate were determined by solution calorimetry. For the heats of formation from the elements, the values obtained were calcium tungstate, -402.4 ± 0.5 kcal/mole, calcium molybdate, -369.5 ± 0.3 kcal/mole, -334.8 ± 0.2 kcal/mole. For the heats of formation from the oxides J the values obtained were calcium tungstate, -49.2 ± 0.4 kcal/mole, calcium molybdate, -39.6 ± 0.1 kcal/mole, and magnesium molybdate, -12.9 [ ] 0.1 kcal/mole.

Jan 1, 1962

By R. Nilsson

In the present work the sulphide capacities of Ca0-Mn0-Si0, ternary slags have been measured in the temperature range 1798 - 1873 K by equilibrating the slag with a gas-mixture containing CO, CO,, SO, and Ar. The results are compared with the data reported in literature. A theoretical model has been developed in the present work where the sulphide capacity is expressed as a function of the slag composition and temperature. The model enables the estimation of sulphide capacities of complex slags with a knowledge of the capacities of simpler systems.

Jan 1, 1994

By Hongling Wang, DI WU, Shuai Li, Hui Shu

Isothermal reduction experiments on carbon-bearing pellets of copper slag were investigated by the thermogravimetric method with biomass carbon as a reducing agent. The results indicated that the reduction process of copper slag‑biomass composite pellets was dominated by gas phase diffusion, and the apparent activation energy was 88.44 kJ/mol. In the temperature range from 1000 to 1200 °C, the metallization rate of pellets increased with increasing temperature, and the maximum metallization rate was 78.4%. The optimal reduction temperature of CSBCP (copper slag-biomass composite pellets) was 1200 °C.

Nov 23, 2022

Reaction kinetics for gold dissolution in acid thiourea solutions were investigated using formamidine disulfide as an oxidant. For the conditions studied it appears that a surface reaction limits the rate of gold dissolution. The rate was found to be first order with respect to thiourea concentration and half order with respect to the concentration of formamidine disulfide; the apparent activation energy for the reaction was 10.40 kcal/mol (43.40 kJ/mol); and the reaction rate was independent of pH for the pH range 1.0 to 3.0.

Jan 1, 1999

By D. J. Fitzpatrick

The paper reviews current mining subsidence research at The Department of Mining Engineering, University of Notting- ham. Special attention is being devoted to prediction of ground movements between the mining horizon and the surface using physical and computer-based models. The paper presented discusses linear and non- linear finite element methods and compares results with those from physical models and field observations. Special attention is focussed on the determination of the effect of caved zones on overlying and underlying geological structures. The paper presents data from comparisons with U.K. case histories.

Jan 1, 1986

By T. Nakamura

TiO2 and Ti/TiO2 thin films were deposited on a quartz substrate by laser ablation of TiO2 and Ti targets using Nd:YAG pulsed laser. After sulfurization of the TiO2 film in H2S or CS2 gas at 1273 K for I hour, the surface atomic structure was changed. Furthermore, the Tirri02 film was successfully prepared by the subsequent ablation of Ti and Ti02 targets. The morphology and structure of the films were characterized by XRD, XPS and AFM analyses.

Jan 1, 2003

By LefTvre Y

In May 1991, AZSA commissioned a new conventional Cell House. This paper focuses on the major improvements introduced in the design and the construction of the equipment, machinery and control. An effective control system together with good reporting and routine operation has resulted in quality control of the Cell House at the highest possible level. Consequently the monthly current efficiency consistently averages above 93 per cent with a total energy usage of 3000 AC kWh/t of cathode zinc. The new concept for the year 2000 and beyond is introduced.

Jan 1, 1993

TiO2 and Ti/TiO2 thin films were deposited on a quartz substrate by laser ablation of Ti02 and Ti targets using Nd:YAG pulsed laser. After sulfurization of the Ti02 film in H2S or CS2 gas at 1273 K for 1 hour, the surface atomic structure was changed. Furthermore, the Ti/TiO2 film was successfully prepared by the subsequent ablation of Ti and TiO2 targets. The morphology and structure of the films were characterized by XRD, XPS and AFM analyses.

Jan 1, 2003

By Knasmillner

During blasting body wave interaction with geometrical surfaces induces Rayleigh-waves which propagate along free surfaces, e.g. crack faces or delaminated rock layers. These Rayleigh-waves carry most of their energy within a very shallow surface layer and propagate with very little attenuation in real rock materials. Upon interaction with a crack front a very strong mixed mode stress intensity factor may result and lead to fracture initiation. On the basis of experimental photomechanical results the history of dynamic stress intensity factors Kt and K2 will be studied in Detail.

Jan 1, 1990

By P. Somasundaran, S. Venkatachalam, N. K. Khosla, K. Khosla

Froth flotation of alumina particles was studied by employing and hydrogen gas bubbles. The effect of current density was studied over a range of 0.1 to1.6 kA/m2. Compared to hydrogen, the use of oxygen bubbles at any given gas evolution rate resulted in a higher flotation recovery. The existence of an optimum current density, for each given particle size was indicated. Flotation at higher current densities resulted in better flotation kinetics, while flotation at lower current densities resulted in better Spas utilization.

Jan 1, 1996

The phosphatic overburden of Christmas Island is a lateritic soil and consists dominantly of crandallite and millisite. These minerals are polymorphs of general formula, (Na,K)x Ca2-x (Al, Fe)6 (PO4)4 (OH)10-x (2+x) H2O. Iron occurs only in millisite. Both minerals exhibit similar thermal transformations, dehydroxylating near 600¦C and recrystallizing above 800¦C. Dehydroxylation results in crystal structure collapse but retention of crystal morphology. Ggethite, boehmite and apatite are minor constituents of some-of the phosphatic Soils.

Jan 1, 1971

By B. C. Darst

Intensive efforts to develop potash use in agricultural production were begun in the US 50 years ago. Early growth was rapid and continued well into the 1960s. Many soils were inherently low in K, so crop responses to fertilization were often dramatic. Deficiency symptoms were common. Per-acre use has continued to increase in recent years, but annual growth rates have slowed. Soil buildup has occurred in some areas. Poor economics in the 1980s have been difficult to overcome. Efforts are now well under way to develop potential markets around the world.

Jan 1, 1987

By M. Rosales

Using the k-e turbulence model, a mathematical fluid dynamics simulation of the flow characteristics in a Teniente converter has been conducted. Two cases were studied: - Transversal sections in the smelting-converting zone; and - A three-dimensional simulation that includes the walls of the reactor The calculations give the velocities field, the gravity waves amplitude, the splashing behaviour, the phase distribution and the shear stress distribution. The latter helps to explain the pattern of refractory lining wear. The calculation includes the approximate shape and dimensions, and the eventual coalescence of bubbles.

Jan 1, 1999

CHEMICAL PRECIPITATION U.S. 4,067,789 - Removal of soluble manganous ions from a zinc sulfate solution formed by leaching roasted zinc sulfide ore with spent electrolyte. An excess of ammonium persulfate or like oxidant is added to the leach solution to convert manganese to insoluble, filterable gamma-manganese dioxide, and the precipitate separated from the solution by filtration. L. Harris and A. K. Hanson, Jr., assigned to Newmont Exploration Ltd. Jan. 10, 1978. 11 pp. (204-119). Filed: 5-3-76 (682.442). (Drawing on page 67.)

Jan 1, 1979

By Hsin H. Huang

Equilibrium calculational software programs can be effectively utilized to model the importance of activity or concentration, solubility, temperature, solution pH, solution potential, and ligand complexation on extraction and recovery processes. Illustrative examples using the calculational program ST ABCAL for the creation of diagrams such as EwpH, activity or concentration-pH, and activity or concentration-EH are presented to demonstrate the fundamental characteristics of real hydrometallurgical mercury dissolution and recovery processes. An industrial application will include leaching of mercury from K 106 mercury sulfide waste and solution purification by iron cementation.

Jan 1, 2003

UNITED ENGINEERING TRUSTEES, INC. James L Head, '55 E C Meagher, '52 Gail F Moulton, '53 Advisory Committee to Real Estate Committee Cleveland Dodge Herbert Hoover J Paul D Merica THE ENGINEERING FOUNDATION E. R Kaiser, '54 W. M Peirce, '52 E C Meagher, ex officio as President, UET Research Procedure Committee E. R Kaiser ENGINEERING SOCIETIES LIBRARY BOARD James L Head, Chairman Frank T Sisco, '54 E M Wise AMERICAN STANDARDS ASSOCIATION Mining Standardization Correlating Committee Otto Herres, '53 J K. Richardson, '53 H H Otto, '53 E W Bullard, '53 - Alternate

Jan 1, 1952

J. K. EVELETH, Anaconda, Montana (Communication to the Secretary): Partly for the reasons which Mr. Jones enumerates, and partly because of the presence of copper in greater or less quantities in so large a proportion of the ores throughout this region, I have also found Marguerite's method the most convenient and satisfactory for the determination of iron. In order to avoid the previous precipitation of the copper with H2S on the separation of the iron by means of ammonia, with the consequent necessity for re-precipitation

Jan 1, 1889

By J. D. Miller

Reaction kinetics for gold dissolution in acid thiourea solutions were investigated using formamidine disulfide as an oxidant. For the conditions studied it appears that a surface reaction limits the rate of gold dissolution. The rate was found to be first order with respect to thiourea concentration and half order with respect to the concentration of formamidine disulfide; the apparent activation energy for the reaction was 10.40 kcal/mol (43.40 kJ/mol); and the reaction rate was independent of pH for the pH range 1.0 to 3.0.

Jan 1, 1999

The paper describes the progress made in the last decade with the introduction of comprehensive monitoring of the mine atmosphere into U.K. collieries. Brief descriptions are given of the various portable and fixed point instruments which have been developed for this purpose and the methods available for transmission of information to the surface are also discussed. The paper also outlines some of the research work being carried out both in the laboratory and underground on the development of alternative methods of fire detection. Some of the results from this work are illustrated and discussed.

Jan 1, 1981

EXECUTIVE COMMITTEES OF LOCAL SECTIONS New York LOUIS D. HUNTOON, Chairman. ARTHUR S. DWIGHT, Vice-Chairman. THOMAS T. READ, Secretary, Woolworth Bldg., New York, N. Y. E. MALTBY SHIPP. Treasurer. GEORGE F. KUNZ, W. De L. BENEDICT. Boston ROBERT H. RICHARDS, Chairman. ALBERT SAUVEUR, Vice-Chairman. AUGUSTUS H. EUSTIS, Secretary-Treasurer, 131 State St., Boston, Mass. TIMOTHY W. SPRAGUE. HENRY A. WENTWORTH. Columbia F. A. THOMSON, Chairman. GEORGE W. RODDEWIG, Vice-Chairman. LYNDON K. ARMSTRONG, Secretary-Treasurer. P. O. Drawer 2154, Spokane, Wash. R. S. McCAFFERY. S. H. RICHARDSON.

Jan 5, 1914