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By N. Menad

The formation of the dioxins can be dependent on the quantities of carbon, hydrogen, chlorine and oxygen present in a given system, as well as on parameters such as temperature and pressure. Inadequate supply of combustion air ( incomplete oxidation ), low combustion temperatures ( incomplete combustion ), and insufficient turbulence in the combustion are factors which can favour their formation. Dioxins were produced also calatytically from chlorinated phenol precursors, non-chlorinated compounds that were chemically, and reaction of phenol with inorganic chloride. In this paper different precursors such as combination of C, H, 0, Cl, rapid formation/combustion intermediates and routes to PCDFs are reviewed, and the influence of PVC amount on the formation of these isomers is discussed.

Jan 1, 2000

By Carlos Mariotti

Ante la crisis económica de la industria eléctrica en el Perú, el presente texto revisa los obstáculos y se describe la función del Estado en la dinámica del desarrollo eléctrico.

Jul 1, 1959

By Yosep Han

Mechanically-induced chemical reactions between natural beach ilmenite (FeTiO3) and silicon (Si) have been examined by a combination of X-ray diffraction (XRD) and scanning electronic microscopy (SEM) analyses. The effect of various milling time on the phase transformation, crystallite size, and lattice strain of a beach sand ilmenite with silicon, and on their leaching behavior in hydrochloric acid (HCl) has been investigated. For mechanically activated FeTiO3, the crystallite size decreased and lattice strain increased monotonically with time of milling. However, the mechanochemically synthesized ilmenite with silicon showed a relatively smaller crystallite size and greater lattice strain compared with the mechanically activated ilmenite under the same milling condition. In accordance with the elapse of milling time, the intensity of both pure FeTiO3 and mechanically activated FeTiO3 gradually decreased. However, in case of the mechanochemically synthesized ilmenitereduction of FeTiO3 by silicon resulted in formation of rutile TiO2 at the milling time of 20 h and afterwards. Additional leaching experiments were carried out at an HCl/ilmenite (wt%) ratio of 20:1. The concentration of HCl was 3 M and the reaction temperature ranged from 70 to 90 oC. Mechanical activation was observed to significantly enhance the dissolution rates of both iron (Fe) and titanium (Ti) in HCl. Particularly, effects of both milling time and silicon addition on the dissolution rates of titanium and iron were significant, while those of temperature were relatively minor under the conditions investigated in this study. Keywords: mechanochemical treatment, natural beach ilmenite, silicon, leaching behavior

Sep 1, 2012

By S. H. Amini, A. Noble

"While many classic mineral processing circuit design approaches rely on deterministic methods, numerous studies have shown that the uncertainty inherent to the various input parameters can significantly influence design decisions. In a separation circuit, many of the technical uncertainties can be mathematically represented as statistical distributions for the unit recovery and feed grade. These uncertainties are then propagated by the circuit design and reflected in the circuit performance indicators, such as product grade and global recovery. An effective design strategy entails identifying which units are most influential in this uncertainty propagation and thus merit further consideration. Unfortunately, few analytical tools provide this information, particularly those that rely solely on deterministic methods. However, one promising approach is through the application of Taguchi’s method, in a fashion similar to statistical tolerancing of manufactured products. Since the technical challenges are fundamentally similar, Taguchi’s method shows promise in evaluating the level of compounded uncertainty by various circuit designs while determining the role of each separation stage on the overall selectivity and variability of separation circuits. This paper demonstrates Taguchi’s method in several two and three unit circuit designs. INTRODUCTION AND METHOD DESCRIPTION Uncertainty in Mineral Processing Circuit Design Analysis and estimation of uncertainty propagation in mineral processing separation circuits is an essential and significant aspect of an optimal circuit design procedure. Most of the current circuit design methodologies have been constructed, implemented, and validated using a deterministic modeling approach. However, numerous studies have shown that the inherent uncertainty induced by uncertain design parameters can be a significant factor in many mineral processing applications (e.g. Kraslawski 1989; Xiao and Vien 2003; Ghaffari et al. 2012). Thus, an effective circuit design methodology must be able to quantify uncertainty in separation circuits with limited input data. This paper describes Taguchi’s method, as an experimental design technique, to approximate uncertainty in mineral processing applications, and then the similarity of results between Taguchi’s method and Monte Carlo Simulation is investigated. Monte Carlo Simulation The term “Monte Carlo Simulation” has been used to refer to a variety of stochastic simulation methods spanning a broad array of business, technical, and scientific domains. Most generally, Monte Carlo Simulation refers to numerical analysis which is based on (pseudo) random sampling from a domain of input parameters with a known statistical distribution. This methodology allows one to determine the distribution of expected results from a standard deterministic process model. Execution of a Monte Carlo simulation begins by identifying the domain of input parameters, statistical distributions for each parameter, and a deterministic process model which describes the anticipated result as a function of the inputs. Next, one discrete random sample is taken for each input parameter, considering the input distributions. The process model is then solved for this mix of input parameters, producing a single simulation result. This procedure is then repeated a “large” number of times, utilizing new randomly sampled input parameters for each simulation iteration. Once the desired number of iterations is reached, the results of each independent simulation are aggregated to produce descriptive statistics such as minimum, maximum, mean, standard deviation, kurtosis, and other distribution parameters. Given enough iterations, the Monte Carlo method fully explores potential synergies between the input parameters. The methodology does not require the process model to be differentiable, continuous, or even analytically defined. While the number of required iterations varies in relation to th"

Jan 1, 2017

By Thomas D. Humbert, Christopher J. Ramsey

Construction of a new underground parking structure in State College, Pennsylvania, is situated on a site constrained by limited ROW and required excavations ranging in depth from 25 ft to 40 ft. Additional complications included busy surface streets, an active intersection, and numerous underground utilities that could not be disrupted by construction activities. To combat these challenges, an innovative approach for earth retention was designed that combined multiple types of retention systems. The overall system included alternating sections of soil nail walls and a hybrid system of soldier pile walls (consisting of micropiles) that were partially restrained by a soil nail wall in the lower portions of the excavation. Further, due to the limited space within the property limits that inhibited the length of the permanent nails, the wall design team collaborated with the project designers to develop a solution such that the completed wall became an integral part of the final design/construction of the underground parking structure. INTRODUCTION HERE at State College is a mixed-use, high-rise building in State College, Pennsylvania. The 12-strory building has up to 3 levels of below-grade parking, with the above-grade levels consisting of residential and commercial/retail space. The existing property was a parking lot bound by the streets Calder Way to the north, Garner Street to the east, East Beaver Avenue to the south, and Heister Street to the west. The overall property sloped approximately 20 ft in elevation from southeast to northwest. Excavation for the below-grade levels extended 21 ft to 36 ft (6.4 m to 11 m) below street level. During design-development phases of the project, it became evident that due to subsurface conditions and right-of- way limitations, conventional construction techniques would not be feasible. The full perimeter of the excavation would require earth retention including the weak shale bedrock along the bottom of the excavation. The project developer (CA Ventures) and general contractor (Brinkmann) coordinated with the specialty contractor and wall design engineer to find a solution. At this time, Coastal Drilling East (specialty contractor) and Wood Environment & Infrastructure Solutions (wall design engineer) became involved. The project developer and general contractor were aware they needed an earth retention system, but given the many variables the project faced, a single, straightforward solution would not work in this application.

Jan 1, 2019

By Joel Darmstadter

The position of the coal industry in America’s fuel and power picture remains one of prime importance. Measured in Btu terms, the industry is the country’s leading energy producer and an important exporter. Foreign coal sales yield annual proceeds of about $4 billion. Coal’s one-fifth share of the nation’s energy consumption is nearly as high as that of natural gas. Coal is the electric utility sector’s principal fuel supplier. It accounts for about55% of the electricity generated at power stations.

Jan 1, 1999

By W. F. Dietrich

1. On St. Thomas and St. Croix, and possibly also on St. John, low-quality red-burning clays probably can be developed to provide the major part of the raw materials for structural clay products and earthenware pottery. 2. The potential sales volume for structural clay products is too small to sustain a plant in the Virgin Islands to manufacture such products in competition with Puerto Rico; however, handmade patio tile might be produced successfully. 3. The market for pottery utility wares in the Virgin Islands is too small to justify a plant devoted solely to the production of such wares; but it may be feasible to evolve a diversified community activity to make jugs, pots, casseroles, bowls, charcoal burners, patio tile, and other items.

Jan 1, 1955

The U.S. Bureau of Mines and the U.S. Mine Safety and Health Administration (MSHA) are participating jointly in a research program to evaluate the strength characteristics and air-leakage resistance of various proposed seal designs for use in underground coal mines. The full-scale seals were constructed in the USBM's experimental mine at the Lake Lynn Laboratory, air-leakage tested, then subjected to pressure pulses of 20 psig or greater. In experiments prior to this study, seven seal designs using solid-concrete blocks were tested. Only the standard-type seal passed the explosion and air-leakage criteria. Tests also were performed on four seals constructed with low-density foam blocks. All four of these seal designs withstood the pressure pulse. In more recent studies, nine cementitious foam seal designs of varying thicknesses and densities were investigated. Six of the nine designs successfully survived the explosion overpressures. Six wood-block convergence seals also have been tested. The typical 3-ft-thick, wood-block seal design currently used in many coal mines did not maintain its integrity, in the absence of convergence forces, following the explosion test. Five modified wood-block seals successfully withstood the 20-psig pressure pulse. Based on these tests, three alternative seal construction materials, cementitious foam, low-density foam block, and wood, have been approved by MSHA for use in underground coal mines.

Jan 1, 2010

By J. E. Dooley

A mass spectral scheme of analysis was devised which can be used to identify individually a single compound from a larger group of similar compounds. Mass spectra for 32 alkyl aryl sulfides are provided for future reference work, and analytical correlations used in producing the analytical scheme are discussed. Some of the correlations show that base peaks are either the same mass as the parent peaks or may be derived from cleavage alpha to the sulfur atom with migration of one hydrogen to the sulfur atom. Other spectral consistencies provide means of separating ortho-, meta-, and paratolyl arrangements in an overall analytical scheme. Determinations of chain lengths and separation of isomeric species are also discussed.

Jan 1, 1972

By Stanley M. Moos

In reviewing available vacuum filtration equipment in this paper, several types of filters have been included which are probably not familiar to operators in the mining industry. However, it was felt that these units might be of interest in the event that an application should arise for the filtration of a product in the future that does not exist today. In addition, exposure of our industry to equipment used in other industries might have a tendency to be thought provoking and perhaps lead to the development of equipment and/or applications in our industry which do not necessarily exist at this time. Most innovations in filtration equipment have been confined to the improvement or design change of components and accessories, particularly reflecting the availability of materials of construction that have been developed. Recent developments in the application of horizontal belt filters have been innovative. The application of this unit as a substitute for or an adjunct to thickeners in a CO circuit can certainly be innovative and perhaps provide a basis for reduction in capital and operating costs in this area. For example, mill tails are generally pumped at the highest possible density that will adequately flow. Tailings ponds and dams with their attendant design requirements are based upon this estimated water volume. Availability of a much dryer, non-flowing filter cake opens up several new options for disposal. Considerable cost savings could result in the design and planning of disposal areas for containing dryer material. . No attempt has been made in this paper to provide a manual for the operation of all of the many types of equipment that are available. Rather, the paper tries to present an overview.

Jan 1, 1978

By M. R. Geer, H. F. Yancey

Four coals were treated in the Humphreys spiral concentrator, and the products were examined by float-and-sink and screen-sizing tests to determine fundamental performance characteristics. The efficiency of the separation between coal and impurity was shown to be influenced greatly by particle size.

Jan 1, 1950

By Esko O. Nermes

Outokumpu flash smelting of copper concentrates was introduced in 1949 and flash smelting of nickel concentrates in 1959, both at Harjavalta in southwest Finland. The first flash smelter outside Finland was started up in 1956 in Ashio, Japan. Between 1956 and the present about 25 flash smelters for copper, and nickel concentrates have been put into operation in different parts of the world. Outokumpu"s research organization has been highly involved in the development of flash smelting. For example, a direct blister flash smelting process was developed in 1975 and introduced in Glogów, Poland, in 1978, and another has been designed for Zaire. This straight metal process is based on low iron content of the concentrate, which reduces the amount of recycling slag copper. Additionally, the concentrates are rather low in impurities.

Jan 1, 1982

By C. J. Wilhelm, John M. Devine, Ludwig Schmidt

"Steel tanks often corrode rapidly in oil fields where the Gas produced with crude contains an appreciable quantity of hydrogen sulphide. In many instances working tanks have been discarded after only six months of service because of failure induced by corrosion.Aluminum has been used for some time in the fabrication of certain equipment incidental to the handling of oils containing hydrogen sulphide gas in solution, and has exhibited no carious corrosive action. These uses indicated that aluminum tanks,be equally effective in counter- acting hydrogen sulphide corrosion. Consequently, in the spring of 1920, an all-aluminum stock tank of 500 barrels capacity and a ""composite"" tank of equal capacity, having a steel bottom and bottom ring and an aluminum top and top ring, were placed in service on the State-Lassiter lease of the Gulf Production Co, in Crane County, Tex. These tanks were under observation for one year, the toot being sponsored by the Gulf Production Co., the Aluminum Co. of America, and the Parkersburg Rig and Reel Co. The results of this preliminary test sustained the belief that aluminum is highly resistance to hydrogen sulphide gas and likewise indicated the type or grade of aluminum which could be most economically used for lease tankage. However, in this preliminary test the tanks were not subjected to contact with the quantities o highly concentrated brines such as often are associated and produced with crude oil. Therefore, it was suggested by representatives of the aluminum Co. that additional tests be made to include production conditions in large quantities of brine would be handled, for pact experience had shown that aluminum often is susceptible to the corrosive action of brines."

Apr 1, 1931

By John Nagy, Henry G. Dorsett, Murray Jacobson

Laboratory studies show that ignition of a dispersed combustible dust in an open vessel may be prevented by adequate inerting . Factors affecting the inerting requirements are -- dust concentration , spark energy , ignition temperature , composition of the substances used for inerting , fineness of dust and type of combustible . The oxygen concentration of the atmosphere and in some instances the proportion of admixed inert powder and moisture required to prevent ignition are given for 367 dust samples . Variations in inerting requirements with strength of igniting source are discussed .

Jan 1, 1964

By Spencee L. Willett

In 1986, at the request of the Bureau of Land Management, the U.S. Bureau of Mines studied a 51, 160-acre portion of the 107,920-acre Diablo Mountain Wilderness Study Area (OR-001-058) in order to evaluate its mineral resources. The study area is located 1n Lake County, OR, about 45 miles northwest from Lakeview. The study area is located near the northwest corner of the Basin and Range physiographic province. Tertiary Picture Rock basalt with tuff interbeds underlies the area (Travis, 1983). No mineral resources were identified; no mines, prospects, claims, or mineralized areas exist in or adjacent to the Diablo Mountain study area.

Jan 1, 1987

By K. G. Markkola

Since 2005, Compafifa Contractual Minera Candelaria (CCMC) has defined various strategies which aim to optimize the usage of the available energy in each of the SAG grinding circuit modules (SABC-A configuration). For this purpose, the use of larger size balls along with operating with an optimum balls/load ratio has been implemented. Additionally, in the ball mills, the amount of balls in relation to the equipment's usable diameter has been optimized. In the pebble crushing circuit, the percentage of material passing 12 mm (112 in) product has been increased by 15% by: (1) modifying the crusher mantle profile, (2) implementing a strategy for maximizing the power in each crusher, (3) using continuous improvement tools (Lean - Six Sigma), (4) redesigning SAG mills discharge grates, and (5) changing discharge grates in order to control the crusher feed size distribution profile. All these activities have improved plant throughput by 1,000 t/d with no significant capital investment. As part of the energy consumption optimization study, we have considered determining the optimum operational rate of each SAG mill, in relation to the mill liner life and also the improving the control strategy in conventional grinding.

Jan 1, 2007

By Alan Jorgansen, Dave Hummer, Scott Scovira

Kennecott Energy's Colowyo Coal Mine is the largest open pit coal mine in Colorado and produces 5.5 MM tons per year. Colowyo uses the terrace mining method to recover up to seven seams of rolling coal ranging in thickness from 5 to 20 feet. Draglines are used to strip overburden ranging from 60 to 120 feet thick off two coal seams. These two seams are characterized by soft and fold fractured coal and in past practice cast blasting caused excessive coal damage. As a result, to ensure minimal coal damage and high coal recoveries, the overburden was excavated in two passes. The first pass removed the upper overburden to within 10 to 20 feet of the coal seam. The second pass removed the remaining overburden above the coal. Two-pass mining was effective in controlling coal damage, but also carried significant additional costs.

Jan 1, 2003

By Darren S. Diehm

"Construction for the restoration and expansion of 102-year-old Wrigley Field in Chicago, Illinois began at the conclusion of the 2014 baseball season. This six year project involves structural upgrades to the Stadium, improvements to the facade, infrastructure, restrooms, concourses, suites, press box, and bullpens, as well as the addition of restaurants, patio areas, batting tunnels, video boards, an adjacent Office-retail Tower and a new Hotel. The Bleachers were demolished and replaced, and a new underground Clubhouse was constructed for the Chicago Cubs beneath a new open-air Plaza. The 1060 Project is privately funded, projected at $750 million (US). The work will be completed in phases during consecutive off-seasons, each with a maximum 23-week duration extending through the Chicago winter. Ownership mandated that on-going construction cause no disruption to the Major League Baseball season, have no impact on hosting concerts and other special events, and it should not adversely affect seating capacity, or diminish the fan experience.The 1060 ProjectAfter purchasing the Chicago Cubs baseball team in 2009 from the Tribune Company, the Ricketts family began planning the renovation and improvement of Wrigley Field and its near neighborhood surroundings in Chicago, Illinois. What came to be known as the 1060 Project was officially announced at the annual Cubs Convention in 2013. Construction began on the $750M privately funded project in October 2014 at the conclusion of the Major League Baseball season. In their vision, the Ricketts committed the 1060 Project to three primary goals. First and foremost as a MLB franchise, the work should provide a meaningful contribution toward winning the World Series and ending the championship drought which stretched to the last win in 1908. Second, the project should be focused on preserving and improving Wrigley Field. Finally, the project should be committed to outcomes that enable the team to be a good neighbor and provide economic and social benefit to the local community.Constructed as Weeghman Park in 1914 for an estimated total cost of $250,000, the stadium provided seating for 18,000 fans and a home for the Chi-Feds and Whales of the National Federal League. The Chicago Cubs were enticed to move from the West Side Grounds in 1915. In the next 100 years, the Wrigley Field would be sliced apart and expanded, double its seating capacity with the addition of double deck grandstands, be enclosed by bleachers (and an ivy covered wall), and, in 1988, experience its first nighttime baseball game with the addition of lighting.The 1060 Project has a total budget of $750M, with an expected construction value of $350M. It is projected to add over 2,100 jobs to the economy and be completed before the 2020 baseball season. The work will be completed in phases during consecutive off-seasons, each with a maximum 23-week duration extending through the Chicago winter. Ownership mandated that on-going construction cause no disruption to the Major League Baseball season, have no impact on hosting concerts and other special events, and it should not adversely affect seating capacity, or diminish the fan experience."

Jan 1, 1900

By M. Olper, M. Maccagni

"The crude zinc oxides (CZO) produced in any thennal process dealing with EAF dust also contain lead, cadmium, and a considerable amount of halides (chlorides and fluorides). The high halide contents make these crude zinc oxides less and less attractive, both technically and economically, and a further refining procedure is nece'ssary to meet the zinc and zinc oxide market requirements.Hydrometallurgical techniques commercially used to dehalogenate the crude zinc oxides are not effective enough to upgrade the crude zinc oxides to the required specification for their direct use in the traditional sulphuric electrolysis by primary zinc producers.The EZINEX® PROCESS has solved the problem of the halides contained in the crude zinc oxides. This process is the only proven technology electrowinning zinc from a chloridebased electrolyte in a conventional cell house. This paper discusses the process economics taking the data from feasibility studies of different size commercial plants."

Jan 1, 2000

By Tracy Shimmield, Philip Samar

"Metals have been mined as ores since pre-history but metal production has increased dramatically in modern times driven by expanding Global GDP. Metal ore mining produces large amounts of waste rock and mine tailings. Mine tailings are the wastes produced after extracting the desired metal from the ore. There are several ways of dealing with this waste, and Ritcey (2005) identifies the following possibilities, land-based storage, backfill to the mine, deep lake disposal and marine disposal. In Papua New Guinea (PNG), both Misima and Lihir Mines adopted the marine disposal option, releasing tailings through a submerged pipe onto the sea floor. This special case is referred to as Deep Sea Tailings Placement (DSTP) in which the tailings deposition is sufficiently deep as to be below the euphotic zone. The most important aspect of deep sea tailings placement is that the tailings are deposited at great depth where exchanges between the seabed and the surface layers are small. The first quantitative multidisciplinary study of tailings impact on the deep sea was carried out from 2006 to 2010 in Papua New Guinea. The physical, chemical and biological work carried out has placed PNG at the forefront of research into the assessment and management of deep-sea environmental impacts related to mining in PNG. The study has provided data which has led to a better understanding of the ecological and geochemical processes in deep water that accompany DSTP in PNG and provided baseline data on deep-sea ecosystems in a scientifically poorly known tropical ocean. Additionally, guidelines on best practice for DSTP have been developed Here we present geochemical data obtained from sediment samples from the marine environment surrounding Lihir and Misima Islands."

Jan 1, 2014