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By O. C. Gaspar

The mineralogical and textural characteristics of the volcanogenic massive sulphide ores from the Aljustrel and Neves-Corvo deposits have been studied by ore microscopy techniques since 1977. Several ore types have been recognized, and the ore paragenesis, ore textures, and behaviours of different ore types during grinding and concentration processes, have been determined. An ore classification was established for use in metallogenetic studies, ore reserve calculations, selectivity during mining, and control of the ore beneficiation processes. In addition, an empirical method was developed for supplying, on time, the qualitative and semi-quantitative information needed for processing the Aljustrel ores and for optimizing the Neves-. Corvo copper and tin concentrators.

Jan 1, 1991

By Christopher Gammons

In developing countries throughout the world, gold ores are being processed by mercury amal-gamation, a technique long banned in the U.S. - unless a retort operation is used for mercury recovery - due to mercury toxicity and its effects on the environment. Amalgamation is a simple process that involves contacting a ground, slurried concentrate or ore with mercury in a slightly agitated vessel, usually for several hours, The amalgamated mercury is separated by gravity and then filtered through a fine cloth to collect the gold amalgam as a sponge, which is then fired to remove the final remnants of mercury and produce high quality gold. However, in Peru and other developing countries in South America and throughout the world, tailings are simply discarded into uncontrolled drainages and ponds and the sponge is fired in the open air. Clearly, in this case, environmental friendly and, to make matters worse, is typically conducted by family members of all ages without proper protection. Furthermore, the technique is inefficient, yielding approximately 50% gold recovery. For the past two years, faculty members from Montana Tech in Butte, MT, USA and the Universidad Nactonal del Altiplano in Puno, Peru have teamed to study the La Rinconada Mine Complex located in southern Peru approximately 100 kilometers north of Lake Titicaca and 25 kilometers west of Bolivia. The mining complex is over 5,000 meters above sea level and exists at the foot of a receding glacier in the Andes Mountains. A suite of soil and water samples collected in 2001 documented extensive Hg contamination in the Rinconada area [1]. The present paper summa¬rizes a follow-up investigation in July-2002, in which water samples were collected at numerous locations along the 200 km length of the Rio Ramis, from the Rinconada mine com¬plex to Lake Titicaca, In addition, we report new results of Hg analyses of fish from Lake Titi¬caca, The results of this study have relevance to safety and health concerns for the miners as well as people in downstream communities.

Jan 1, 2003

By T. Rigg, J. N. Stone

"The process described has been developed to utilize low-grade scrap -turnings, borings, tin cans and other types of ferrons scrap which currently has been of limited or no use in conventional steelmaking processes. If scrap of this type can be converted into high-purity iron by chemical means then there is a potential saving of several million tons of metal annually in North America.The process is chemically quite simple and consists of dissolving ferrons scrap in hydrochloric acid, followed by evaporation and crystallization of the resultant solution to yield ferrons chloride crystal.s. These crystals are dries, briquetted and converted to non sponge by reduction in hot hydrogen. The HCl produced from the reduction step. is absorbed in water and the hydrochloric acid so produced is returned to the dissolver circuit. The hydrogen produced from the initial dissolution of the scrap is used to reduce the ferrons chloride. Purity is maintained by bleeding off impure chloride solutions from the evaporator-crystallizer circuit, and converting these chlorides to oxides and HCI in a high-temperature spray roaster. The HCl produced in the roaster is absorbed in water and the hydrochloric acid returned to the dissolver."

Jan 1, 1970

By Louis R. Bernier

Since 1978, most systematic studies of AMD passive treatment with limestone drains (LD) have dealt with coal mines in the United States. The authors present in this paper the first results of a triennial study initiated in 1999 on the performance of LD installed at the Ni-Cu Lorraine old mine site in Temiscamingue during a remediation plan that involved the installation of a cover with capillary barrier effects (CCBE) over the reactive pyrrhotite-rich tailings. Typically, a LD is a trench enclosed by impervious materials filled with crushed limestone and may be oxic or anoxic. Four LD (one filled with marble and 3 with dolomite) were installed at the Lorraine site. The LD have been in operation since May 1999 and are performing differently. The most contaminated mine effluent flows south and is directed towards 3 LD filled with crushed dolomite, while a 4th LD was filled with crushed marble and installed west. The LD filled with marble has been generating maximum alkalinity since the beginning of the passive treatment. Two of the dolomite drains have been generating alkalinity since mid-summer 1999, but one is not, even if a substantial pH raise was observed. A pH above 5.5 is required usually for the dolomite drains to start generating alkalinity. The installation of LD at the Lorraine site contributes significantly to the reduction of metals and sulphates loading.

May 1, 2001

By C. H. Elder

A 5-hole pattern was drilled from the surface at a site near Oak Grove, Jefferson County, Ala., to degasify the gassy Mary Lee coal bed in advance of mining. Gas and water production was monitored for 1 year, 4 months to allow gas flow to stabilize fully. A thickened water stimulation treatment was designed and applied in one hole of the pattern to evaluate this degasification technique for the Mary Lee coalbed. A gas production rate of 70,000 fts/day after stimulation treatment indicates that the use of vertical boreholes coupled with hydraulic fracturing in advance of mining the Mary Lee coalbed would provide for more rapid degasification and could provide a possible source of natural gas.

Jan 1, 1974

By Walter Wood, J. T. H. Cannarella, H. F. Yancey, R. E. Zane

More than 50,000,000 tons of bituminous coal and probably about the same quantity of anthracite are cleaned annually in the United States by wet methods. The water, fine coal, and impurities from the water used for washing ordinarily are recovered by moans of various forms of settling tanks. Settling and clarification may be hastened markedly, thereby greatly increasing the capacity of clarification equipment already installed, by the addition of substances to the washery water that cause the fine particles in suspension to agglomerate and thus settle more rapidly. This phenomenon, although well known and applied in other fields, has been used at only a few coal washeries in the United States. It is widely employed, however, as an aid in the recovery or disposal of fine coal or impurities, as a means of preventing, stream pollution, and to enable reuse of washery water at many plants in Europe. Pioneering work in the United States has been done principally by two companies -- the Pittsburgh Coal Co., in Pennsylvania, 6/ and the Pacific Coast Coal Co., in Washington.

Feb 1, 1940

President W. K. Dennison, Jr., called the final session of the Rocky Mountain Coal Mining Institute to order, and introduced H. A. Cornell, Portland Cement Association, Ft. Collins, Colorado. Mr. Cornell explained that the Portland Cement Association was not a sales organization, but is supported by the major manufacturers of portland cement. The research laboratories of the association are constantly endeavoring to improve the quality of cement, as well as promote new markets, new uses, and new ideas. The association works with engineers, contractors and universities, making available to them the results of their research. Mr. Cornell stated that numerous booklets and bulletins were available on request for any phase of construction with concrete. Mr. Cornell presented a film, "How to Make Quality Concrete," to the members of the Institute. D. W. Lyke, General Electric Apparatus Service Shop, Denver, Colorado, was introduced by President Dennison, who presented a film, "A-Hunting He Would Go." Following the film, Mr. Lyke stated that his firm was not confined to electrical equipment, but to all types of equipment, and asked the members to feel free to call for assistance at any time. These two films concluded the Manufacturer's Hour, and President Dennison opened the final business meeting of the session. Robert F. Bowie, of the Auditing Committee, read the Treasurer's Report, and complimented Mr. Whiteside on the commendable state in which the books were found. The Treasurer's Report is as follows:

Jan 1, 1960

THOSE NOT MARKED ARE MEMBERS; MARKED THUS ?ARE ASSOCIATES. HEAVY-FACED TYPE SIGNIFIES HONORARY MEMBERSHIP JUNIOR MEMBERS ARE MARKED ' . THE FIGURES AT THE END OF THE ADDRESS INDICATE THE YEAR OF ELECTION. AARONS, J. BOYD See Honor Roll. '05 ? AARONSON, ALFRED E Pres., Tuloma Oil Co., Unity Bldg., Tulsa, Okla. '18 ABADIE, EMILE R., Min. En r Box 291, Porterville, Tulare Co., Cal. '76 ABBOTT, CLARENCE E., Gen'l Supt., Iron Mines Div., Tenn. Coal, Iron & R. R. Co., 1405 Minnesota Ave., Bessemer, Ala. '04 ABBOTT, Louis BENJAMIN, Chief Engr., Consolidation Coal Co., Elkhorn Div., Jenkins, Ky. '15 ABBOTT, ROBERT R Met. Engr., Peerless Motor Car Co., Cleveland, Ohio. '12 ABE, ASAKA Fujitagumi Taiwan Office, Taipeh, Formosa, Japan. '14 ABBY, HIROSHI Min. & Met. Engr., Mitsubishi Co., Tokyo, Japan. '17 ||ABOUCHAR, S. S., Cia. de Minerales y Metales, S. A., Minas Viejas, Villaldama, N. L., Mexico. '17 ABRAHAMS, A. I 1391 Madison Ave., New York, N. Y. '14 ?ACKER, E. O'C., Met.,128 East Washington Lane, Germantown, Philadelphia, Pa. '86 ? ACKERMAN, ERNEST R., Pres., Lawrence Portland Cement Co., Plainfield, Union Co., N. J. '15 ACOSTA, J. N., Min. Engr., Cons. Engr Hotel Brewster, San Diego, Cal. '15 ADACHI, JINZOO 11 Shiba Park, Shiba-Ku, Tokyo, Japan. '88 ADAMI, CHARLES J., Min. Engr., Gen'l Supt., St. Joseph and Doe Run Lead Companies, Bonne Terre, Mo. '12 ADAMS, ARTHUR K., Min. Geol., Andes Copper Min. Co., Casilla 230, Antofagasta, Chile. '06

Jan 1, 1923

By R. E. Siemens

The Bureau of Mines sought to correlate the variation of structure-sensitive superconducting properties with microstructure in selected Cb-Hf alloys and to compare the experimental results with those predicted by the GLAG theory. Alloys in wire and rod form were evaluated by critical temperature, critical current, magnetization, resistivity measurements, and optical and electron microscopy. In the absence of an external magnetic field, the current carrying capacity of columbium was greatly reduced with addition of up to 85 wt pct Hf, but a large increase in Ic occurred for Cb-90 wt pct Hf. Favorable Ic-H behavior was observed in cold-drawn alloys containing 25 and 57 wt pct Hf. Correspondingly, a maximum in Tc occurred at 10-25 and 90 wt pct Hf. Four- or five-hour heat treatment at 600° C resulted in maximum Ic values and maximum hysteresis in magnetization. Dislocation pileup, polygonization, and fine precipitates, responsible for flux pinning, are listed in order of their effectiveness as pinning sites. Sites having an average separation of 1,500 to 3,000 A and a diameter of 1,000 A or less were most effective in influencing Ic-H and M-H behavior. The resistive critical fields increased smoothly to a maximum of 80 k0e between 60 and 65 wt pct Hf. Highfield, mixed state, reversible paramagnetism was observed in some alloys; however, the GLAG theory was in good agreement with experimental results for the majority of the composition range studied.

Jan 1, 1969

By K. D. Mehta

Copper concentrate containing complex sulphides of Cu-Ni with 14.13% Cu and 10.04% Ni besides impurities such as 0.33% Co and 0.71% Mo, is not acceptable to the copper smelters due to the smelting problems. Selective bioleaching of nickel from the concentrate can be considered an an option to make it suitable for copper smelter. Effect of elemental sulphur and pyrite on the bioleaching of Ni and Co has been investigated using a mixed culture of Acidithiobacillus ferrooxidans (A.f.) and Acidithiobacillus thiooxidans (A.t.). Parameters such as pH, temperature, particles, size etc. were optimised to understand the role of additives in the bioleaching. With 2% S at 308K, 2.0 pH, 5% pulp density and 200µm size particles while shaking at 100 rpm, 79% Ni, 41% Co and 5% Cu were bioleached as compared to the leaching of 81% Ni and 45% Co in presence of 10 wt% pyrite in 60 days; 27% Ni, 24% Co and 4% Cu were recovered in sterile experiment. The selective dissolution of nickel and cobalt as compared to copper may be explained by galvanic interaction between chalcopyrite: pentlandite / pyrrhotite. Bioleaching was facilitated by strong oxidizing conditions due to higher Fe3+/Fe2+ ratio/redox potential (ESCE) as a result of improved interaction of minerals through biooxidation of sulphur and accelerated galvanic interaction by pyrite. The mechanism of selective leaching of Ni and Co was established by XRD phase identification.

Sep 1, 2012

By B. Hosseini

Considering the subtractive trend of the sulfide and high-grade zinc ores in worldwide and also in Iran, Nowadays special attentions have been drawn to the extraction of zinc from its other resources such as low-grade oxide ores and secondary resources. Oxide ore of the eastern part of Mehdi-abad lead and zinc mine is silicate and has an average grade of 7% (with cut off grade of 4%). Main mineral of the Mehdi-abad ore is Hemimorphite and this mineral is associated with Goethite, Hematite, Ferrous Dolomite, and Manganese oxide mineral so that oxides of Iron, manganese and silica include almost 50% of the total ore. In this paper, the results obtained from the leaching kinetic study of the low-grade zinc oxide ore using Sulfuric acid are presented. The effects of particle size, reaction temperature, acid concentration, and solid percent on the dissolution rate have been investigated. The results obtained from the Taghochi approach showed that the zinc recovery is about 78% under the following optimized conditions: particle size: 106µm, leaching time: one hour, temperature: 45°C, acid concentration: 15% and solid percent: 15%. Kinetics study was revealed that zinc minerals leaching controlled by diffusion rate through the product layer during leaching time with the activation energy of 5 KJ/mol and compliance with the 1- (2/3. x) ? (1- x) 2/3 = k. t model. Keywords: leaching kinetics, kinetics models, sulfuric acid leaching, taguchi methods, low grade zinc ore, mehdi-abad mine

Sep 1, 2012

By Masayuki Kudoh, Kiyotaka Matsuura

"Molten aluminum and nickel cast onto a steel block exothermically react and produce molten nickel monoaluminide, NiAI, which is simultaneously joined to the steel. The heat of the exothermic reaction is transferred to the steel block, and steel near the surface of the block is melted. The depth of the melted steel increases with both the initial temperature of the steel block and the thickness of the produced NiAI. Iron from the melted steel dissolves in the molten NiAI, and an intermetallic compound of NiAI-Fe pseudo-binary system is produced. During solidification of the intermetallic compound, it is strongly joined to the steel. The Ni.Al-Fe intermetallic compound has an excellent resistance to oxidation and corrosion.IntroductionAn intermetallic compound of nickel monoaluminide, NiAl, offers many advantages over conventional superalloys, such as higher melting temperature, lower density, greater specific modulus and higher thermal conductivity [1]. NiAl also exhibits excellent high-temperature oxidation resistance when doped with zirconium or hafnium, and excellent high-temperature corrosion resistance when doped with chromium or yttrium, that are superior to existing high temperature alloys or coating materials [1-4]. On the other hand, NiAI is significantly brittle at temperatures below 600 K [5-7], which is the most sigriificant disadvantage of NiAI. A possible way to overcome the disadvantage and to utilize NiAl as an environmental-resisting high-temperature structural material may be joining of NiAl to a ductile material."

Jan 1, 2000

By R. B. Nourse, R. Hundermark, B. Masters, H. Joubert

The new 30 MVA slag cleaning furnace at Waterval Smelter, Rustenburg Platinum, South Africa, has been in operation since 10 March 2003. The furnace design and operation face a number of challenges including a wide variety of feed materials and resulting bath conditions. Furnace feed varies in combinations of granulated Waterval Ausmelt Converter Slag (WACS), hot fed Peirce-Smith converter slag, concentrate and reverts. Coke is added as reductant. The resulting slag composition varies considerably and regularly. For the case feeding WACS an almost pure fayalitic slag (60%+ FeO, 30%+ SiO2) with a very low viscosity results. Due to the widely varying slag conditions, including a superheated fayalitic slag with high fluidity, a robust sidewall design is required adjacent to the slag bath. For this reason the furnace sidewall is equipped with Pyromet's MAXICOOL® high intensity copper cooling system. The design and installation of the copper coolers as well as tap holes are discussed. To cope with the variation in bath conditions and high slag superheat (350°C when tapped at 1650°C), the copper coolers are capable of removing peak sidewall heat fluxes above 500 kW/m2. Feedback is included on the performance of the Pyromet MAXICOO® copper cooling system for the first two years of operation. The paper further includes an overview on the design and performance of the tap holes, furnace shell, furnace roof and copper slag spouts.

Jan 1, 2005

By Sheng-ping He, Ya-bing Zhang, Qian Wang, Kun-peng Xu

A mass of Al2O3 tends to form during the continuous casting process of high manganese high aluminum steel, and the properties of mould flux and the quality of slab are seriously affected. The dissolution rate of Al2O3 into the CaO–SiO2–MgO–Al2O3–F−−Na2O−Li2O−BaO−B2O3 slag system has been investigated at 1573 K by employing rotating cylinder method. This paper focuses on the effect of Na2O, Li2O, B2O3, F−, Al2O3 contents and (CaO+BaO)/(Al2O3+SiO2) ratio on the dissolution rate. Experimental results show that the dissolution rate increases with increasing Na2O, Li2O, B2O3 contents and decreasing Al2O3 content, among which Li2O has the greatest effect on increasing dissolution rate; the dissolution rate increases with increasing F− content in slag A-1, but decreases with that in slag A-2; the dissolution rate increases with (CaO+BaO)/(Al2O3+SiO2) ratio within the range from 0.91 to 1.31. The dissolution rate of Al2O3 into molten flux is mainly affected by the viscosity of the molten flux and the thermodynamic driving force.

Mar 1, 2018

By R. S. Dean

"It has long been recognized that the properties of polycrystalline substances are not the same as those of single crystals. These differences are especially marked in metels and metallic minerals, and are of greatest practical importance in metal working and ore treatment. The property changes encountered in passing from a metal single crystal to a poly-crystalline aggregate are the same as are produced by cold-working a metal or by the precipitation of a disperse phase. Hence, we may logically assume that the property changes are all due directly or indirectly to the formation of interfacial area or internal surface. Our problem, then, is to ascertain the physicochemical state of the metal atoms at such internal surface and show how this physicochemical condition accounts for the pronounced changes of mechanical, magnetic, and electrical properties that accompany increased internal surface.GENERAL CONCEPT OF INTERNAL SURFACEIn 1678, Huyghens attempted to explain the double refraction of calcite by postulating that crystals were built from a regular arrangement of ellipsoidal particles. Over 100 years later, Abbé Hauy concluded from his studies of cleavage that crystals might be built from small units, but the units were of the same shape as the entire crystal. This idea, which was prevalent in mineralogical thought before the advent of X-ray spectrometry, was discarded when the great success of Bragg made it appear that the chemical atoms were in reality the elements of structure. In the further development of X-ray technique, however, C. G. Darwin, in England, and P. P. Ewald, in Germany, found it necessary to postulate crystal units con¬taining many atoms. The latter gave the name of mosaic crystals to those so constituted. The individual units are supposed to Possess the ideal atomic arrangements revealed by the X-ray but are not oriented with respect to one another."

May 1, 1938

By P Jonsén, S Larsson, M Parian, B I. Pålsson

The question of effective energy utilisation in grinding mills is not new. There are several conflicting arguments about tumbling mills, whether the efficiency is around 1 per cent or maybe 10 per cent, or even much lower. The energy not used is assumed to be lost as heating of the pulp, the grinding mill body, the charge, generation of shock waves and vibrations, etc. Stirred media mills on the other hand are generally considered to have better energy utilisation, but their energy efficiency is still not that clear. To shed some light on this a pilot-scale, wet stirred media mill was investigated over a range of operating conditions. The wet stirred media mill is a Drais PMH 5 TEX pearl mill fitted with an electric motor at 11 kW. It has been investigated over a range of operating conditions to try to balance the dissemination of the input energy in forms of the net grinding energy, mechanical energy losses, and the heating transferred to the pulp, the mill, the charge, and the cooling water. It is found that approximately 20–40 per cent of the input energy accounts for the grinding process. Also, that the difference between gross and net input electrical energy is mainly disseminated as heating of the pulp and cooling water. Mechanical energy losses appear to be much smaller than the heating effects. The use of a dispersant seems to mainly influence the heating effect.

Aug 24, 2022

By T. M. Bhatti

The main purpose of present study was to characterize the dissolution of uranium from low-grade black shale with indigenous isolated strain of Acidithiobacillus ferrooxidans (BSAF-01). The nature of shale is quartzite-schistose and contains uranium content of 0.005% U3O8 (50 ppm U3O8). Uranium is present in the tetravalent oxidation state (U4+) in the shale matrix. The main minerals identified are graphite, quartz, pyrite, mica minerals (phlogopite, biotite, sericite, and chlorite), microcline, K-feldspar and kerogen (hydrocarbon-compounds). Bacterial oxidation of pyrite was an acid-generating system and produced sulfuric acid and ferric sulfate during this biological phenomenon. A series of bioleaching experiments were conducted in shake flasks for leaching of uranium from black shale. The leaching experiments were performed at 50% pulp density using indigenous Fe- and S-oxidizing bacterium (Acidithiobacillus ferrooxidans). Bioleaching data revealed that about 90% ~ 95% U3O8 was leached out from black shale ore. Uranium dissolution from shale depends on pH (pH 1.5~1.9), redox potential (=500 mev) and the concentration of Fe2+ and Fe3+ ions in the leaching environment. The oxidative leaching of U4+ involves a redox reaction with Fe3+ as an oxidant and bacterial re-oxidation of Fe2+ in acidic leaching environment. Uranium leaching efficiency was attributed to the sulfuric acid and ferric sulfate production during bacterial oxidation of pyrite.

Jan 1, 2014

By Farid Mirahadi

Forecasting productivity of construction operations is a difficult but crucial task in planning construction projects. Over the past decades, many models have been developed to forecast productivity for different construction operations. Models made up of several functional relations and controlled by a specific number of control rules are more in line with human reasoning and logic. Neural-Network-Driven Fuzzy Reasoning (NNDFR) structure as one of these models shows a great performance for modeling datasets among which clear clusters are recognizable. Lack of the compatibility of conventional NNDFR with fuzzy clustering algorithms besides the insufficient attention paid to the optimization of number of clusters in this model, created a potential area for further research. The main contribution of the proposed model is to develop a modified NNDFR system to model construction data. To this end, Fuzzy C-Means (FCM) algorithm is substituted for K-means in NNDFR structure, and its parameters such as the number of clusters and weighting exponent are optimized through genetic algorithm. The proposed model is further verified through simulation of a construction operation in which several qualitative and quantitative factors are considered. Its implementation to the case study shows a considerable improvement of model performance with lower Mean Squared Error (MSE). The developed model assists researchers and practitioners in utilizing historical construction data to forecast productivity of construction operations with a high accuracy that could not be obtained by traditional techniques.

Aug 1, 2013

By J. L. Lytton, J. E. Dorn, L. A. Shepard

Single aluminum crystals were subjected to creep in simple shear on the (111) planes in the slip direction. The activation energies for creep were calculated from the effect of small abrupt changes in temperature on the creep rate just before and immediately following the temperature change. The results definitely establish the fact that creep of single aluminum crystals occurs by-three unique processes, characterized by thethree distinct and isolatable activation energies: The 35,-500-cal-per-mole activation energy obtained at the highest temperatures was ascribed to a dislocativationtion climb process; the 28,000-cal-per-mole activation-energy process, occurring over the intermediate-temperature range was attributed to a cross-slip mechanism; and it was suggested thot the 3400-cal-per-mole process observed below 400°K may be the Peierls energy. THE most pertinent question regarding the phenomenon of creep in crystalline materials is concerned with the identity of the crystallographic mechanisms of deformation that control the creep rate. For many years slight progress was made in uncovering the basic mechanisms for creep. Over the past 10 years, however, two parallel lines of investigations have contributed to a more definitive understanding of the processes involved in creep. The extensive development and maturing of dislocation theories for deformation of crystalline materials' proved to be of paramount importance for this progress. And second in importance was the replacement of the former prosaic methods of creep testing by new techniques'." which were especially

Jan 1, 1959

By J. Lobel, M. Bourassa, J. A. Kozinski, B. Peng

Non-isothermal kinetics studies of the reduction phenomenon of electric arc furnace (EAF) dust generated in stainless steelmaking have been carried out. The dust was mixed with carbon as a reducing agent and dolomite as a binder to form pellets. A Thermo-Gravimetric Analyzer (TGA) was used to determine the weight loss of pellets heated at an average rate of 40 K/min. up to a temperature of 1500°C. The degree of metal reduction was calculated by considering the pellet weight loss, and evaporation of moisture, dust, zinc and lead at high temperature. The reduction process was divided into three different steps. The first covers the 300°C to 760°C temperature range (from 7 to 18 min.), the second step ranges between 760°C and 980°C (18 to 24 min.), and the third covers temperatures above 980°C. Each step is characterized by different chemical reactions. Non-isothermal reduction kinetics equations were set up to describe each step. The kinetics parameters such as apparent activation energies and frequency factors were established. It was found that the first step was chemically controlled, while the second step was diffusion-controlled. Reduction behaviour in the third step was strongly dependent on the initial carbon content in the pellet. Chromium oxide (CrO) could only be reduced in this last step. High temperatures and higher initial carbon content favoured the reduction of CrO.

Jan 1, 2001