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By V. E. Antonov

Hydrides of iron and iron-based alloys are thermodynamically stable only at hydrogen pressures in the gigapascal range and rapidly loose hydrogen under ambient conditions. At low temperatures, however, these hydrides can be retained in a metastable state at atmospheric pressure after being cooled under the high pressure to liquid nitrogen temperature. This review will discuss the current state of studies on phase transformations in the Fe-H and related systems and also on the composition, crystal structure and physical properties of the hydrides, both under high hydrogen pressures and in the "quenched" metastable state at ambient pressure. The studies at ambient pressure include magnetization measurements, X-ray and neutron diffraction, Mossbauer spectroscopy and inelastic neutron scattering. In the sections on Mossbauer and structural investigations of hydrides of Fe-Cr and Ni-Fe alloys new experimental results will be presented.

Jan 1, 2002

By R. T. Johansen

A gradual decrease in injection rates commonly occurs as a water-flooding project becomes older. This decrease can be attributed to changes in reservoir conditions, such as swelling of clay minerals, fillup, or gradual plugging of the sand face. However, a rapid decrease in the rate of injection indicates abnormal behavior and is cause for alarm. Extreme plugging conditions can completely stop injections into a formation. Such behavior in wells was the main concern of the tests described in this report. An accepted method of alleviating this condition is by backflowing input wells - closing the supply lines to the wells and allowing the reservoir pressure to force water back into the wellbore and to the surface. If backflowing is not successful, a string of smaller diameter pipe sometimes is run inside the casing, and the sand face is flushed with a waterspray. More drastic treatment is to inject acid into the wellbore to dissolve extraneous matter, or even part of the reservoir material, in an attempt to restore the permeability of the sand immediately around the wellbore. Any of these procedures can he coordinated with bailing and swabbing of the well for cleanout purposes.

Jan 1, 1957

By J. -C. Sztuke, M. Cao

ABSTRACT Wash water and polyethylene oxide (PEO) were used in the flotation of quartz and coal. Wash water decreased entrainment of –15 µm quartz. The optimum superficial wash water rate was 0.05 cm/s. PEO also lowered entrainment. The combination of wash water and PEO led to a slight further reduction in entrainment. For 1:1 mixtures of –15 µm quartz and –300 µm oxidized coal, the combined use of wash water (0.05 cm/s) and PEO increased the separation efficiency from approximately 30% to > 70%, whereas wash water alone at 0.05 cm/s did not lead to a discernible increase.

Jan 1, 2014

By Hitoshi Iijima, Fumitaka Tsukihashi

"Fine powder of tantalum is used as materials of electric condenser. It is important to control the distribution of particle diameter of tantalum fine powders for the commercial use. In this study, fine powders of tantalum were produced by reducing tantalum chloride vapor with hydrogen gas at 1673 and 1773K. The tantalum chloride vapor was reduced with hydrogen and the produced fine particles of tantalum were collected to observe the distribution of particle diameter. The effects of reaction temperature, partial pressure of hydrogen gas and vaporization temperature of tantalum chloride on the distribution of particle diameter and reaction efficiency of reduction were determined. The mechanism of reduction reaction of tantalum was discussed.IntroductionThe ultra fine powder shows various different physical properties from that of bulk materials. Therefore, the application of ultra fine powder to various fields such as magnetic material, electric material, catalyst, etc is anticipated. The control of shape of powder, size distribution, property of agglomeration, purity is required for the practical use of ultra fine powder. Although the ultra fine powders of ceramics are produced by various methods, the ultra fine powder of metals are produced by the evaporation in gas atmosphere, plasma evaporation process, chemical vapor deposition process, and reduction and precipitation in liquid phase depending on the metal and productivity. The chemical vapor deposition process has features that pure metal powder can be obtained and the control of the distribution of powder size is easy. [1,2,3,4,5]"

Jan 1, 2000

By J. D. Davis

The Bureau of Mines Coal Carbonization Laboratory has been interested for the past 20 years in the quality of coke in connection with the selection of coals for the manufacture of coke. The principal experimental. method of carbonization, whereby 100- to 200-pound charges are carbonized in sheet-steel cylindrical retorts with recovery and determination of the properties of coke, gas, and products, was developed in cooperation with the American Gas Association,4 5 and it is known as the BM-AGA method. Results of the investigations of 90 coals included in the BM-AGA Survey of the Carbonizing Prop¬erties of American Coals have been published; 6 and, in addition to these, about 200 coals have been carbonized over limited temperature ranges. Because coke from cylindrical retorts differs in shape from that made in rectangular ovens, the BM-AGA method has been criticized, although those who developed it have always believed that it served well as a means of measuring the relative strengths of cokes from different coals. It is recognized that no laboratory-method carbonization, even on a large twit, can yield results that exactly duplicate those obtained in commercial ovens and retorts. However, with the completion and satisfactory performance of an experimental vertical slot oven of 500-pound capacity at the University of Illinois Geological Survey Laboratory,' the opportunity to directly compare BM-AGA coke with coke made by two-sided heating became available and the necessary test apparatus was installed. The Bureau of Mines slot oven, which is similar to that designed by the University of Illinois Geological Survey, has been used to carbonize 11 coals (or blends) tested by the BM-AGA method. This report compares the results obtained by the two methods.

Jan 1, 1950

By James C. Fowler

The design and field testing of a seismic miner detection and location system arc described. This work was carried out over a period of three years. The first two and one-half years were sponsored by Continental Oil Company, while the last period of tests were done as the first part of a one-year contract with the U.S. Bureau of Mines. Laboratory and field experimentation in three different nines under simulated emergency conditions have led to three important results: (1) Taps on roof bolts with normally available objects can usually be detected up to horizontal distances of 1,000 ft. (2) The origin of the tans can be located by on-site processing with a small computer. (3) Some predetermination of the approximate location is necessary for a quick and successful rescue. This report also includes preliminary specifications an,d cost guidelines for construction of a transportable field system capable of matching the performance characteristics of the one used during the field tests.

Jan 1, 1973

By D O’Dea, B Godel, T Honeyands, G Evans, T Harvey

The pores within iron ore sinter are important for producing a high quality material that is strong and easily reduced. The complementary methods of mercury intrusion porosimetry (MIP) and X-ray computed tomography (CT) were used to characterise the structure of industrial and pilot scales sinters across a wide range of pore sizes (3 nm to 100 µm for MIP and 50 µm to 5 mm for CT). The inhomogeneous nature of sinter and the variation in the measurements make it difficult to compare samples. The generalised additive modelling (GAM) approach, using the open source statistical software package, R, has been applied to highlight where there are peaks in the concentration of pore sizes. Importantly, the shape of the GAM-fitted function and the heights of the peaks show statistically significant differences between samples. For the samples investigated, the GAM-fitted functions for the MIP volume distribution of pore diameters were found to have a common set of distinctive peaks at 0.005, 0.6 and 20 µm. The GAM approach was also applied to the X-ray CT measured pore wall thickness, highlighting a single peak whose position varies between samples. The cause of these distinctive peaks and their implications for sinter quality are discussed. Correlation was found between the volume in peak 1 (0.005 µm) and the concentration of primary hematite. No correlation was found between the pore wall thickness and the strength of the sinter, suggesting the composition of the pore walls may be more important. Future work will focus on small-scale sinters produced under tightly controlled conditions to study sinters with a wider range of quality values.CITATION:Harvey, T, O’Dea, D, Evans, G, Godel, B and Honeyands, T, 2017. Highlighting key features of the pore structure of iron ore sinter using mercury intrusion porosimetry and X-ray computed tomography, in Proceedings Iron Ore 2017, pp 39–48 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By M I. Pownceby, C M. MacRae, A Torpy

Electron probe microanalysis (EPMA) and quantitative X-ray diffraction (QXRD) techniques are capable of providing high-quality quantitative information regarding the phase mineralogy and distribution of alumina within iron ore samples. The techniques, however, use different methodologies in determining the mineralogical information (ie structural versus chemical), which introduces some limitations. In this study, EPMA was used to identify and quantify the deportment of alumina within mineral phases in iron ore samples (-1 mm crushed) sourced from different suppliers. Results were directly compared with quantitative mineralogical data derived from QXRD to provide an evaluation of the relative merits of both techniques. The four ores studied contained alumina either in the form of gibbsite, aluminosilicates (eg kaolinite), or associated with goethite.For minor phases, gibbsite and kaolinite, the abundance trends measured via QXRD were generally reflected in the EPMA data. Agreement was less satisfactory for the more abundant goethite phase (both low- and high-Al forms). The discrepancy may be the result of sampling issues arising from textural features such as grain size, and also a systematic overestimate in the amount of Al-rich goethite when hematite and Al-bearing phases are finely intermixed and the EPMA step size is coarse. A second difference in the EPMA results compared to the QXRD data was in regard to quantification of low-Al and high-Al goethite phases. The sensitivity of the chemical-based EPMA was better for distinguishing between high- and low-Al goethite although the results remain overprinted by potential errors introduced via sampling.Care should be taken when directly comparing results from each method, although in general the data should be considered complementary, as each approach provides slightly different results and interpretations regarding the overall mineralogy.CITATION:Pownceby, M I, MacRae, C M and Torpy, A, 2017. A comparison of X-ray and electron-based analysis techniques for characterising the mineralogy and alumina distribution in iron ores, in Proceedings Iron Ore 2017, pp 593–598 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By Anil K. Ray

This paper discusses in situ studies conducted at an Illinois Basin room-and-pillar coal mine to evaluate the performances of three different types of bolts under similar geologic conditions. The bolt types considered were the fully grouted passive rebar (FGPR), the resin-assisted mechanical anchor (RMAB), and the fully grouted tension rebar (FGTR). During the evaluations, the three types of bolts were installed in a single entry covering a span of three contiguous pillars with almost identical geologic conditions. The performances of the three types of bolts were investigated by instrumentting the bolts prior to installation as primary supports on cycle. Additional data on roof behavior was collected with extensometers and shear meters placed near the instrumented bolts. Excluding some time lapse right after installation, the performance evaluation of the three bolt systems was based on the data collected for over a year. Based on this study, it was found that the axial loads measured in the different bolt types did not show any identifiable patterns under the prevailing geological conditions at the mine. Therefore, the assumption that active bolts must be superior to passive ones is not always valid. Even though the studied mine did not have any thinly laminated, weak rocks in the immediate roof, the passive bolts performed as well as the active systems.

Jan 1, 2012

Electrochemistry Measurement, Using Chena Analyser, to Investigate Selective Separation of Pentlandite and Pyrrhotite

Sep 13, 2010

By C. C. Anderson, H. H. Hinson, H. J. Snhroeder

"INTRODUCTION The Eunice field is one of a group in southeastern New Mexico producing oil and gas from so-called limestone-type reservoirs in which the productive strata are dolomite or dolomitic limestone ordinarily, wells in reservoirs of this type show wide differences in their productive characteristics, indicating erratic variations in porosity and permeability. Often there is a large difference in total footage of actual ""pay"" penetrated in neighboring wells and the vertical distribution of the ""pay"" within the productive strata varies. In the Eunice field there are few easily recognizable geologic markers to indicate true structural conditions of the oil-productive section, due to horizontal and vertical gradation in chemical compositions and lithologic characteristics of the strata. Geologic markers are found some distance above the oil-producing zones in this field and consequently they indicate only the general structure. Furthermore, no direct relation has been found between the general structure and the accumulation of oil within the reservoir.Many problems in well-completion and production practice have been met in the Eunice field because of erratic variations in porosity, permeability, in vertical distribution of ""pays,"" and the apparent departure from ordinarily accepted relations of oil accumulation to structure. A detailed study of the position and characteristics of the oil- and gas-producing zones aids production procedure. The methods employed in studying the Eunice field, discussed in this paper, may be applicable to other limestone-type reservoirs."

Jul 1, 1939

By Jan Visman, S. J. Aresco

INTRODUCTION The accurate sampling of coal, as with most minerals, is a difficult task. Coal is a heterogeneous material made up of different types of coal and varying amounts of mineral matter. The product as mined may contain all the layers of coal and impurities found in the seam as well as portions of the stratas above and below the coal seam. The preparation plant is the device to size, crush, and/or remove impurities so the coal may be shipped as a salable product. Sampling may be needed at many stages in the preparation process. Although this chapter is primarily concerned with sampling in connection with preparation processes, the principles apply to all coal sampling. The main reasons for sampling in connection with coal preparation are: 1) To determine the washability characteristics of the raw coal by means of float and sink tests. These may be used for the design of a preparation plant, prediction of results to be obtained, or monitoring raw coal delivered to the plant. 2) To check the performance of various operating units in the plant, either by float. and sink tests or chemical analyses. 3) To determine the analytical characteristics of the products produced, such as moisture, ash, Btu, sulfur, etc. HISTORY The earliest accepted methods of sampling coal in the United States were given in US Bureau of Mines (USBM) publications by J. A. Holmes,l G. S. Pope,2 and A. C. Fieldner.3 The American Society for Testing and Materials (ASTM) more or less adopted the methods proposed by USBM in their Standard D-21-1916 and it remained a standard for many years. Briefly, this standard called for a 500 lb (227 kg) sample for coals less than 94 in. (19 mm) in size and a 1000 lb (454 kg) sample for all coals over 94 in. (19 mm) in size. No mention was made of increments, but there was an instruction that the sample should spread over the coal

Jan 1, 1979

By D. W. Boydell

The response of reclaimed gold tailings to acid leaching was investigated in the laboratory, followed by a pilot-plant program in which the operations of CCD, CIX and SX were tested with plant feed material. These results formed the basis for the design of the extension to the existing uranium plant at Blyvooruitzicht Gold Mine, commissioned in July 1977. This circuit consists of slimes-dam reclamation by bucket-wheel excavator at a rate of 100,000 t solids per month, acid leaching in pachucas, a five-stage CCD washing section, two parallel C1X absorption columns and two elution columns, SX and an ADU precipitation section. Barren solution is recycled to the CCD section as wash and to the repulper at the slimes dam. The performance of the plant during the first year of operation is compared with the predictions on which the plant design was based. Rated capacity was achieved within three weeks of start-up at a nominal dissolved uranium recovery in the ion-exchange section of around 98%. Owing to recycle, the over-all recovery in the ion-exchange and solvent extraction sections is somewhat higher than this figure.

Jan 1, 1979

By Michael P. Amsden

"THE ECSTALL CONCENTRATOR is situated adjacent to Highway 101 and the Ontario Northland Railroad, 15 miles east of Timmins, Ontario. Ore is delivered to the concentrator by rail from the mine, which is 17 miles northwest of the plant. Power and fuel are obtained from the hydro and natural gas lines which pass close to the plant site. Water is obtained from the Frederickhouse River, 6 miles east of the concentrator. The main concentrator building is a large structure 500 by 640 feet by 90 feet high and contains facilities for fine crushing, crushed ore storage, grinding, flotation, tin recovery, concentrate handling and reagent handling. Located in the same building are the machine shop, warehouse, metallurgical laboratory, pilot plant, men's change room, sample preparation area and an assay laboratory. The general concentrator layout is shown in Figure 47. Originally designed to handle 9,000 tons per day, the concentrator now treats 10,000 tons per day. Two different ore types are processed by selective flotation in three individual circuits to recover copper, lead and zinc concentrates. In 1973, another circuit was added to recover pyrite and tin concentrates from the combined zinc tailings of the three main circuits."

Jan 1, 1974

By D. E. Walsh

Over a period of seven years (1989-1996) the Mineral Industry Research Laboratory (MIRL) University of Alaska Fairbanks, has investigated the effects of temperature, residence time, and particle size on the degree of low-rank coal (LRC) upgrading for a non-evaporative, hydrothermal drying process, also known as hot water drying (HWD). Three Alaskan LRCs were used in this study: Usibelli coal (Seam No.4) from the Nenana Coal Field, Little Tonzona coal from near McGrath, and Beluga coal from the Beluga-Yentna field on the west side of Cook Inlet. Replicated, factorial tests were conducted. Experimental results indicate that most of the low-rank coal upgrading via HWD occurs rapidly within the first 10-20 minutes of residence time. Thereafter, the upgrading process slows down and over 100 minutes of additional residence time are required to produce similar percentage increases in coal properties to those achieved in the first 10-20 minutes. The properties of the hot water dried products were very sensitive to process temperature. Calorific value, carbon and oxygen contents, equilibrium moisture levels and Hardgrove grindabilities all appear to change linearly with temperature within the 275" C to 325" C range.

Jan 1, 1997

By Erik Westman

Few studies have been conducted regarding the location, movement, and relative magnitude of the rear abutment of a longwall coal mine. The rear abutment, or the abutment pressure arch in the gob area, is controlled primarily by the quality of pack of the gob; the more compacted the gob is, the larger the stress would be theoretically. While there is no definitive location for the rear abutment, early studies showed that it could be located as far back in the gob as 300 m (1,000 ft). Like the location of the rear abutment, there has been little research conducted and very few answers as to the exact magnitude of the rear abutment load. Due to the fact that the rear abutment has been studied considerably less than the front or side abutment, the need for further studies is evident. From a ground control standpoint, the location and magnitude of a rear abutment could reveal information on the caving process associated with longwall mining, such as when the initial cave could be expected to occur in future panels. Besides the possible importance of the rear abutment from a ground control perspective, evidence related to the longwall rear abutment could be vital from a ventilation standpoint. The peak rear abutment location could serve as an area for harmful gases, such as methane, to accumulate because forcing air through repacked rock is more difficult than through loose rock. The objective of this study is to determine whether passive seismic tomography could image the location, movement, and relative magnitude of the rear abutment as the longwall face retreated, in addition to the forward abutment and gob. The results of a passive seismic imaging study at a western US longwall show evidence for the location, movement, and relative magnitude of a rear abutment. A clear zone of highlystressed strata is shown where the forward abutment is expected and a low-velocity, damaged zone is shown behind the face where the gob is located. These two zones retreat with the face over a three-week period. In addition, the images show a return to stress levels behind the gob that are slightly higher than overburden stress levels, which is presumably the rear abutment. This occurs at a distance behind the face that is approximately the same as the face width for this mine. We can conclude that passive seismic imaging can be used to identify the location, movement, and relative magnitude of the rear abutment of a longwall mine. This conclusion is dependent on the use of appropriate data collection and processing methods. The information provided can benefit the both ground control and ventilation engineers as they strive to improve the safety and efficiency of longwall mines. The knowledge associated with the rear abutment of a longwall could not only help increase production through proper initial planning and reduce down time, but it could also make positive strides in improving the overall safety surrounding a longwall mining operation.

Jan 1, 2012

Recovery of Precious Metals from Chloride Solution by Magnetite The development of environmental-friendly lixiviants as alternatives to cyanide and the increasing recycling activities to recover precious metals from waste materials have prompted researchers to find efficient methods and alternative sorbents to recover precious metals, such as Au and Pt, from aqueous solutions. This study explored the use of magnetite (Fe3O4) as a sorbent to recover Au and Pt from chloride solutions. Magnetite is a semiconductor and has the capability of transferring electrons both within the solid state and across the solid-liquid interface and has the ability to reduce metal species on its surface. The sorption of AuCl4- and PtCl62- from NaCl solution on commercial grade magnetite powder was investigated by batch-sorption experiments. The effects of pH, contact time, NaCl concentration and precious metal concentration on the recovery were studied. Sorption experiments revealed that magnetite exhibited selectivity towards other metals with the strongest affinity for Au. Both Au and Pt recoveries showed similar pH dependence curves, with peaks at pH 6 - 7. At this pH range, a maximum of 4.4 ¦mol Au/g Fe3O4 and 3.0 ¦mol Pt/g Fe3O4 were recovered after 24 h at an initial metal concentration of 0.05 mol/m3. Increasing the initial precious metal concentration increased the Au and Pt uptake amount by magnetite. It was also observed that the recovery decreased with high NaCl concentrations. The SEM images of the magnetite particles after the treatment showed that gold, which was confirmed by the EDX analysis, agglomerated and were deposited on Fe3O4 surface.

Sep 13, 2010

By F. Parada Torres

Xstrata Tintaya S.A. opera el yacimiento a tajo abierto y procesa el mineral en dos plantas: Planta Concentradora de Sulfuros y Planta de Lixiviación de Óxidos, donde anteriormente consideraba al mineral mixto complejo como intratable en la planta concentradora, por lo que se le destinó a ser tratado como óxido marginal en la planta de lixiviación. En este sentido, el presente texto describe el nuevo tratamiento al mineral complejo en la planta concentradora. De forma que se busca definir las variables geometalúrgicas del mineral de Chabuca Norte, optimizar los procesos metalúrgicos del mineral mixto mediante la investigación geometalúrgica, así como correlacionar el entendimiento de la geología y alteraciones del yacimiento con los procesos metalúrgicos y crear valor mediante la optimización de la tasa de tonelaje de tratamiento y el incremento del porcentaje de recuperación de cobre en el proceso.

Sep 12, 2011

"Geoscan is used for multi-elemental analysis of conveyed bulk materials in the minerals industry with proven performance and demonstrated paybacks of weeks or months in iron ore, manganese, copper, zinc-lead and phosphate industries. Geoscan-M measures continuously through the full bed depth and is unaffected by belt speed, particle size, layering, mineralogy and dust levels. Increments of typically two minutes are accurately measured and provide the plant operators with tonnage weighted results of contained elements. Measurement of the composition in real time enables prompt feedback to the mining operators and also feed forward to the process operators. Crushed ore increments can be diverted based on composition, such as diverting waste for disposal or marginal material to a stockpile for separate processing. Bulk sorting allows material to be placed into relevant stockpiles for subsequent blending to achieve consistency for process feed. Parameters used for decisions may be primary metal content, deleterious component content, other process parameter, or a combination of these. Process parameter may be the elemental ratio between critical components, e.g. Cu:S ratio, basicity, or the content of an “indicator” element (such as Si indicating material hardness). Benefits will be discussed based on case studies in copper and iron ore.IntroductionAs operators of process plants strive to remain competitive as capital and operating costs increase and commodity prices fluctuate, more focus has been directed at incremental performance improvements at incremental cost rather than major expansions to increase output. The philosophy of working smarter allows plants to adopt technologies proven in other industry sectors to minimise risk. This paper discusses one such technology that the minerals sector is adopting and has found to be safe, reliable and accurate with paybacks of weeks in most applications. New applications continue to be found and major benefits realised at various stages in the processing and handling of ores and products."

Jan 1, 2016

By Philip J. Guerney, S. O’ Leary, André R. Laplante

"Concentration of dense mineral phases (s.g. greater than 7) for characterisation of individual particles and mineral grains by electron microscopy is a well established technique for the detection and characterisation of valuable mineral phases. This presentation describes the type of data that can be generated when both the concentration and characterisation steps are carried to higher levels than typical. The concentration step is the gravity recoverable gold (GRG) protocol that has been used for over 100 ore samples. This protocol yields three concentrates that represent three progressive degrees of grinding and liberation. Three ore samples were subjected to the GRG protocol and three size classes of each concentrate were characterised using the mineral liberation analyser (MLA), an automated, EDX-based tool. This presentation briefly presents GRG and MLA technology, and then focuses on the results obtained: photos, images and databank, the latter used to evaluate the extent of particle liberation and particle shape.INTRODUCTIONThe practice of gravity concentration prior to characterization of mineral samples using electron beam microscopy is solidly established. Typically, a dense liquid such as tetrabromoethane (density: 2.97 g/cm3) is used to reject the light phase, typically carbonates and silicates. The heavy phase, mostly sulphides, oxides and precious metals, is then mounted in a polymer matrix and examined using beam microscopy.Both the pre-concentration and the sample preparation/examination steps have seen significant advances over the past ten years, but are not without problems. A major issue of preconcentration is that most dense liquids used are toxic, tetrabromoethane being a prime example. More recently, a dense liquid with little or no toxicity (sodium polytungstate, distributed by Sometu Inc.) has become commercially available, but its use is limited to relatively low s.g. splits around 3 g/cm3. Dense liquids are viscous, and their use is limited to particles coarser than 37 µm, although centrifuge separation can probably lower this limit to around 10 µm. Magnetogravimetric separators can achieve much higher specific density cuts, but upgrading below 100 µm or in the presence of magnetic minerals remains a problem. The use of centrifuge separators such as the 3-in Knelson Concentrator (KC MD3) or the Falcon 4-in SB (SB4) is particularly attractive since these units can easily process large masses (by laboratory standards) and achieve a cut density well above those of dense liquids."

Jan 1, 2003