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By D. M. Maijer, S. M. Mohseni, A. B. Phillion

The microstructure evolution kinetics of aluminum alloy B206 during artificial aging has been investigated using non-isothermal calorimetry. A combination of differential-scanning calorimetry (DSC) and tensile tests have been utilized to develop an Avrami model to predict the precipitation kinetics as a function of the thermal processing parameters. The Avrami coefficients, found based on a Kissinger analysis, compare well against those reported in the literature for aluminum-copper alloys. The rapid precipitation kinetics predicted by the Avrami model at temperatures higher than 200°C were assessed through a qualitative comparison against hardness measurement results. In contrast to the continuous hardening observed at 150°C, the material softens with continuing heat treatment at 250°C resulting in an overaged state. This can be attributed to the rapid precipitation kinetics at this temperature, leading to the termination of the precipitation-hardening effects at early stages of artificial aging.

Jan 1, 2015

By Diogo de Oliveira Azevedo

No presente trabalho, processos de conformação a frio e recozimento foram aplicados à liga de magnésio ZK60A (Mg-6%Zn-1%Zr) com o objetivo de determinar a cinética dos fenômenos de recuperação e recristalização para permitir o refino de grão. Para tanto, foi desenvolvida uma série de matrizes de conformação para a trefilação incremental de barras circulares da liga ZK60A inicialmente recebida no estado envelhecido (T5), resultando em reduções de 7,8%, 15,4%, 22,6% e 29,4%. Após cada passe de trefilação, as propriedades mecânicas do material foram determinadas. O estudo do recozimento foi realizado em amostras com o máximo encruamento a temperaturas de 400°C, 350°C, 300°C, 250°C, 200°C e 150°C. Pela metodologia aplicada, foi possível avaliar a cinética do processo de recristalização da liga ZK60A e determinar a sua energia de ativação.

Aug 8, 2018

By Peter Swanson, Collin Stewart, Wendell Koontz

A seismic monitoring network has recently been installed in the North Fork Valley coal mining region of western Colorado as part of a NIOSH mine safety technology transfer project with two longwall coal mine operators. Data recorded with this network will be used to characterize mining related and natural seismic activity in the vicinity of the mines and examine potential hazards due to ground shaking near critical structures such as impoundment dams, reservoirs, and steep slopes. Ten triaxial strong-motion accelerometers have been installed on the surface to form the core of a network that covers approximately 250 square kilometers (100 sq. miles) of rugged canyon-mesa terrain. Spread-spectrum radio networks are used to telemeter continuous streams of seismic waveform data to a central location where they are converted to IP data streams and ported to the Internet for processing, archiving, and analysis.

By C. Adcock, R. Farnfield, G. Adderley

The use of explosives to create special effects in the film industry is a well-known past time. A recent production required simulation of a large scale water splash from the effect of a statue falling from a cliff edge and impacting on an open body of water. This was to be achieved through the use of precisely delayed explosions detonated near the surface of the water. A survey of the area revealed a breeding farm for sea bass approximately 250 metres (273 yards) from the intended blast area. It was initially thought that the water pressures produced for the detonation of the explosives may cause harm to the fish. Much work has been carried out over the past few decades on the effect of open water blasting and its effects on aquatic wildlife; this includes water pressure modelling techniques which can be used as predictive tools.

Jan 1, 2010

By Donald L. Stewart, Ken Overfield, Edward M. Williams

"Recent increases in energy cost have lead to a renewed focus on energy efficiency during aluminum melting operations to reduce fuel usage. The goals of a batch melting operation are to melt the charge using the minimum required energy, to melt the metal to the required temperature within the required timeframe, and to avoid generating unwanted contaminants by overheating the charge.The heat transfer efficiency of a conventional hydrocarbon fired aluminum melting furnace varies over the course of the melt cycle, depending on the conditions in the furnace. The purpose of this work was to develop a method of determining the transient heat transfer efficiency throughout the furnace cycle and to take advantage of this knowledge to optimize the melting process through furnace controls and proper production operations. This furnace survey methodology has been developed and used to evaluate a number of furnaces.Description of a Typical Batch Melting Furnace CycleA typical batch melting furnace cycle will consist of three stages:1. Charging – Solid metal charged through an open roof, solid or molten charged through an open door, and/or molten poured through a furnace blister2. Melting – From the time the door or roof is closed and the burners are turned to high fire until the charge is all liquid and has reached a temperature suitable for alloying (typically ~1350 °F / 730 °C)3. Holding – From the end of the melting stage until transfer or casting is completeIn some cases, further charging can take place after the melting cycle has started. This can happen when the entire solid charge will not fit in the furnace in one load, or if additional molten metal is added while the charge is melting. The bulk of the energy used in the melter is consumed during the melting cycle. The thermodynamic minimum energy requirements for melting pure aluminum are:• Energy required to heat pure aluminum from room temperature to the melting point at 1220°F (660°C) is 288 BTU/lb (670 kJ/kg)• Energy required to change state of pure aluminum from solid to liquid (heat of fusion) is 171 BTU/lb (397 kJ/kg)• Energy required to heat molten from melting point at 1220°F (660°C) to 1350°F (730°C) is 36 BTU/lb (83 kJ/kg)• Total energy required to melt a solid charge from room temperature to 1350°F (730°C ) is 495 BTU/lb (1151 kJ/kg)"

Jan 1, 2009

By C. R. McCann

The Bureau of Mines conducted an experimental study of conditions needed to produce flames of pulverized coal when the heat needed for ignition is sup-plied only from the flame and hot furnace refractory. An electrically heated furnace which burned about 1 pound of coal per hour was designed and fabricated. A sheath of air, surrounding the primary coal and air stream, was used to prevent entry of hot gases from recirculating combustion products. Furnace temperatures needed for ignition ranged from about 1,8300 F for an Illinois coal to 2,250° F for a Beckley seam coal. Apparent flame velocities were about 2 to 5 feet per second, increasing with volatile content of the coal and with distance from the burner mouth to the flame. The time required for ignition, approximately 0.02 to 0.07 sec, was a better measure of flame behavior than was velocity.

Jan 1, 1969

By Qian Li, Haiyan Leng, Kuo-Chih Chou, Haoyuan Xiao, Zhigang Yu

Magnesium borohydride and Magnesium alanate were synthesized by mechanochemical metathesis reaction. The thermal decomposition behaviors of Mg(BH4)2-nMg(AlH4)2(n=0.5,1) systems were investigated as potential hydrogen storage materials. The results showed that the systems started to desorb H2 at 120 ℃ and desorbed 3.9 wt. and 4.9 wt.% H2 below 300 ℃ when n equals 0.5 and 1, respectively, while individual Mg(BH4)2 started to desorb H2 at 250 ℃ and desorbed only 0.82 wt.% H2. Because of the exist of the Mg(AlH4)2, the isothermal desorption kinetics of Mg(BH4)2 in the Mg(BH4)2-0.5Mg(AlH4)2 systems was 50% faster than that of pristine Mg(BH4)2. In addition, the re-hydrogenation rates also increased 49.4% and 37.9%.

Jan 1, 2015

By M. H. Staia

A Venezuelan ilmenite concentrate has been chlorinated at a temperature of 700" C by carbon tetrachloride. In the experimental rig, built at laboratory level, the direct chlorination process yielded a TiCI, recovery of approximately 85% after 280 minutes processing. The partial pressure of carbon tetrachloride was nearly atmospheric (0.94 atm). Product vapors from the reactor were fractionally condensed in a condenser which was maintained at a temperature of 250°C meanwhile TiCl, vapors were condensed in refrigerated coils at a temperature of -20°C. The concentrate used in this investigation was obtained by applying gravitational and magnetic concentration methods to the black sands. The experimental results have shown the need to asses the influence of the weight ratio of ilmenite to carbon tetrachloride on the resultant products. The equilibrium of the heterogeneous system has been calculated taking into account the initial experimental conditions.

Jan 1, 1995

By W. W. Staley

This paper discusses the design of small head frames that will fill the needs of prospectors and small operators whose operations are conducted through shafts. The head frames considered were designed to handle relatively small tonnages. It was assumed that the shafts in which buckets are used would not exceed 300 feet in depth and that not over 60 tons of rock would be hoisted, in, 14 hours. In the design of the larger head frames, a hoisting capacity of about 250 tons per 6 hours from a depth of 300 to 500 feet was assumed. Under these conditions, hoisting speed, rate of acceleration, and weight of rope have a negligible effect on the head frame design and, therefore, have been ignored in the following, discussion. Because timber is relatively cheap and easily obtained in most mining areas, the discussion has been confined to timber construction.

Jan 1, 1937

By Bernard Porter

The solubility of UO2 was determined at 1,250° C. in ternary melts of UF4 and BaF2 with CaF2, LiF, and SrF2. The solubility of Ce02 was measured at 800° and 850° C. in a solution of CeF3, BaF2, and LiF. The amount of La203 which dissolves at 950° C. in a binary mixture of LiF and LaF3 and a ternary of LiF, LaF3, and BaF2 was also measured. In each case, the amount of soluble oxide was mound to be less than 5 weight-percent. A procedure was developed for filtering fused, oxide-saturated fluoride melts in order to obtain a representative sample for chemical analysis. The oxide content of the samples was determined by an inert-gas fusion procedure.

Jan 1, 1961

By G. E. Veins

This paper summarizes an investigation in which beneficiated ilmenite ore was smelted in a continuous, three-phase, 250 kv.a., open-top electric furnace. Minus %. inch ore was smelted, using the standard method. Fine ore, in the order of minus 14 mesh, was smelted in the briquetted form by the open bath method, and in the unagglomerated form by the cold dry-top method. The latter was shown to be superior. The data obtained .are discussed at some length. During the investigation, slag aver-aging 82.5 per cent Ti02 was produced over a period of 87 hours, the maximum being 85 per cent. Such slag should .be particularly attractive for the production of titanium tetrachloride, from which titaniurn metal is produced. The advantages of using paper-mill bark for producing a furnace charge of low bulk density, as required in cold dry-top smelting, were emphasized.

Jan 1, 1957

By Yoshisada Michiura, Junko Umeda, Katsuyoshi Kondoh

Rice husks or straws, one of the main agricultural wastes in South-east Asia, have a large possibility to be employed as usefully renewable resources to produce energy and high-purity silica (SiO2), because they consist of about 70% organics such as cellulose or hemi-cellulose, and 20% amorphous SiO2. The former is utilized as bio-mass energy; for example, thermal or electric energy, and bio-mass ethanol. High-purity silica can be used as raw materials in the industrial uses. It would be possible to extract silica elements from rice husks and straws by burning them in air because their main contents are organics. In the previous studies, a strong acid leaching treatment on rice husks before burning was carried out by using H2SO4, HCl and HNO3 to prepare high-purity silica materials. This was available to accelerate the hydrolysis of celluloses and hemicelluloses contained in rice husks, and remove the above metallic impurities. A strong acid leaching treatment, however, is significantly hazardous to environment and human life, and causes an increase of the process cost. In this study, the environmentally benign, harmless to human and economically effective process to produce high-purity amorphous SiO2 materials from rice husks has been established without using strong acids. From a viewpoint of the harmless influence on human body, the carboxylic acids were used in the leaching treatment on rice husks. TG-DTA measurement and GCMS analysis indicated that the leaching was effective for the hydrolysis of celluloses and hemicelluloses contained in rice husks at 473K~873K, which produced the same results in using the conventional sulfuric acid. The metallic impurities could be also removed from the husks via a chelate reaction between carboxyl groups (-COOH) and the metal elements. In particular, it was clarified that cadmium (Cd) were completely removed from rice straws by this reaction. Concerning the burning conditions of rice husks after the acid leaching, it was necessary to supply a suitable amount of air to completely combust organics; for example it required air supplement of 50 ml/min. or more. The burning temperature should be less than 1273K to obtain amorphous structured silica. High-purity amorphous silica materials with 99% or more were prepared from rich husks by applying the citric acid leaching treatment and burning process at 1073K in air.

Jan 1, 2008

By Lynton Gormely

Oxygen transfer in a stirred tank bioreactor has been modelled mathematically to determine the trends in transfer efficiency (kg transferred per kWh) with transfer rate, tank depth, superficial velocity, and mixer power.

Jan 1, 1990

By Paul Cherin

ThE angle of intersection, 0, between h2k2l2 planes and the (loo), (110), (101), and (111) planes was calculated on an IBM 7040 using the well-known relationship

Jan 1, 1968

COUNCIL OF SECTION DELEGATES Jack A. Criehton. Chairman Allen T. Cole. Vice Chairman M I. Signer, Secretary EXECUTIVE COMMITTEE W. C. Leonard, North Pacific W. K. Beck, Cleveland W. W. Leonard, Southwest Texas

Jan 1, 1952

By Yves Picot

Construction of new installations was recently completed in the Port of Tubarao, Brazil, With this expansion the port, operated by Companhia Vale do Rio Doce (CVRD), has become the largest iron ore port in the world, with an annual throughput capacity of 60 million long tons. GROWTH OR IRON ORE EXPORTS Since its formation CVRD has steadily increased the shipment of iron ore to overseas markets. Starting with less than 100,000 tons in 1942, the yearly export volume grew to 1,500,000 tons in 1951, 5,000,000 tons in 1961 and 25,000,000 tons in 1971. The number of different grades of ore also increased during this period. Production of high grade pellets, starting in 1970, further increased the number of ore products to be shipped. In the same period the size of ore carriers increased twenty-fold to over 250,000 DWT.

Jan 1, 1974

By Larry J. Nicks

The Bureau of Mines is investigating the catalytic activity of rare-earth compounds to develop a catalyst for the cathode reaction of a hydrogen-oxygen fuel cell. This report presents the results of studies of the catalytic activities of lanthanide oxides for the oxidation of hydrogen at 150° to 250° C. Preliminary activity tests were made with approximately stoichiometric mixtures of hydrogen and oxygen diluted with helium. A series of tests was also run under oxygen-rich conditions in which specific rate constants and activation energies were determined. Variations in rate constants up to 2,000 times were observed for the various lanthanide oxides. The three most active catalysts were oxides of Ce, Pr, and Eu, having specific activities of 6.93 X 10-7, 4.88 X 10-7, and 4.06 X 10-7 moles H2.sec-1.m-2, respectively, at 200° C.

Jan 1, 1973

By Fazakerley VW

The Murrin Murrin deposit is located about 210 km NNE of Kalgoorlie and 50 km E of Leonora in the North Eastern Goldfields region of Western Australia at latitude 28¦ 50'S. longitude 121¦ 54'E on the Laverton (SH 51-2) 1:250 000 map sheet. The tenements are held by Anaconda Nickel NL. Geological investigations between 1994 and 1996 resulted in resource calculations being completed for the ten lateritic nickel cobalt deposits shown in Figure 1. At a 0.8 per cent nickel cut-off the resources at May 1996 for the nine deposits are 116.8 Mt at 1.10 per cent nickel and 0.082 per cent cobalt. The nickel-cobalt mineralisation is contained in a laterite profile developed over Archaean serpentinised peridotites. A bankable feasibility study has been completed and the project is scheduled to be in production by the beginning of 1998.

Jan 1, 1996

By David P. Lindroth

The heat content above 25.0° C up to 1,000° C was measured for six rock types: St. Cloud Gray Granodiorite, Holston Limestone, Sioux Quartzite, Rockville Quartz Monzonite, Salem Limestone, and the basalt at Dresser, Wis. The calorimetric data were obtained with an isothermal jacket-copper block calorimeter. The experimental heat content data for each rock type are presented, along with specific heat data obtained from the temperature derivative of the heat content. For the six rock types the maximum deviations of the specific heats at a given temperature were within 10 percent below 575° C and within 34 percent above 5750°C. The increase in the values of specific heat range from a minimum of 13 percent for the basalt at Dresser, Wis. (temperature range, 100° to 1,000° C) to a maximum of 46 percent for Holston Limestone (temperature range, 100° to 870° C).

Jan 1, 1971

By Nickelsen J, Theisen KG, Hansen PH

The use of stationary calciners in the processing of aluminium hydroxide has emphas- ized the importance of Bayer hydrate properties with respect to particle breakdown during calcination and subsequent treatment. Test results from calcination of several Bayer hydrates to sandy alumina in the FLS Gas Suspension Calciner (GSC) were obtained in a 250 kg/h pilot plant unit. Particle breakdown during calcination was influenced by content of solid sodium oxalate, trapped in the hydrate particles and operating gas velocities. Owing to the design and operational principles of the GSC it is possible to reduce particle breakdown to at least the same as what is found in long rotary kilns. Other major advantages reviewed are obtained through simplifications in plant design and operation, pointing to low specific power and heat consumption, and generally low production costs, thereby providing an attractive alternative to fluid-bed calciners.

Jan 1, 1981