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By Mehmet F. Taner

"Abstract - "Les Mines Selbaie" is a large, generally low-grade, polymetallic (Zn, Cu, Ag, Au) "giant" volcanic-associated ore deposit in the Harricana-Turgeon belt, which is part of the northern Abitibi Subprovince of Quebec. Economically recoverable mineralization occurred in three zones: the A1 (open pit), A2, and B Zones (underground). The pre-mining resource was 54.9 Mt, including 8 Mt of sub-economic, locally silver-rich massive pyrite. In the Selbaie region, calc-alkaline andesitic volcanics form the "basement." The Brouillan Volcanic Complex formed within an islandarc setting on this regional basement. Evolution of this complex involved the formation of a felsic magma chamber and the development of a large caldera structure over the Brouillan batholith. Second- order linear and sub-parallel faults and rifts developed as a result of back-arc rifting/extension. The edges of these rifts were feeders for linear felsic volcanism (similar to fissural volcanism). During felsic volcanism, the feeder zones acted as conduits for hydrothermal fluids with associated pervasive potassic alteration. The alteration is characterized both vertically and laterally by well-defined quartz, sericite, K-feldspar and/or, locally, biotite halos, to produce a mushroom-shaped morphology. This K-feldspar alteration is not common in most other volcanic-associated ore deposits. Mafic dikes cut all of the geological units and appear to occupy earlier synvolcanic structures. Regional greenschist- assemblage metamorphism and pervasive deformation affect all units. Thrust faults moved part of the Brouillan batholith and basement units over the Mine Sequence. Although there is no relationship between the earlier mineralizing events and these late thrust faults, the thrust faults probably played an important role in location of ore lenses. Three types of mineralization are present: 1) copper-rich veins and hydraulic breccias; 2) disseminated and stringer, low-grade and high volume zinc-copper mineralization; and 3) finely laminated, massive, locally silver-rich pyrite mineralization within structural basins. At the bottom of these basins and at the contact of welded acid tuff (WAT) units, massive pyrite zones are locally enriched in zinc, and contain the possible vestiges of black smoker-like material. The ore metals were probably derived from leached basement andesitic volcanics in a hydrothermal system powered by one or more heat sources within the Brouillan Volcanic Complex. The Selbaie deposits are mainly characterized by: (1) the presence of small volcano-tectonic subsidence basins, which host chemical sediments and volcaniclastic materials; (2) pervasive potassic alteration; (3) locally high-grade silver mineralization (up to 1-2 kg/t Ag); and (4) the presence of random zones of Pb mineralization. The Selbaie deposits can be closely compared with the copper-rich Murgul deposits, which belong to the eastern Pontides metallogenetic province in Turkey. If conventional classification criteria for the volcanogenic massive sulfide deposits (e.g., Noranda, Mattabi types, and recent subsea floor deposits) are taken into account, the Selbaie deposits still exhibit many differences in terms of alteration assemblages, physical volcanology and some styles of mineralization (low-grade and large volume). Consequently, the "Selbaie" deposits belong to a new sub-type of volcanic-associated sulfide deposit, which may be used in future exploration programs."

Jan 1, 2000

By J. E. Ryan

General Description Due to the extreme cold weather experienced in Flin Flon during the winter months, thought and precaution were necessary in the design of the plant buildings. The machine shop, carpenter shop, drill shop, and coal plant buildings are similar in the building materials used in their construction. They are sided with two-inch shiplap, insulated with celotex and asbestos paper, and covered with corrugated iron on all side-walls. Roofing consists of 2 by 4 lumber on edge, laminated, and further covered by celotex and three-ply roofing. These buildings are heated by means of unit heaters. The heaters are primarily steam-heated radiators, through which the air of the buildings is circulated by electrically-driven fans. Our machine shop is located to the east of, but central to, the main operating buildings of the mine and plant, and is so connected by a net work of tracks as to be able to serve all portions of the entire plant conveniently. The building is divided into two bays, the main bay 53 ft. by 340 ft., and the east bay 24 ft. by 340 ft. The shop office and drafting room, a two-story annex 24 ft. by 30 ft., is located on the west side of the shop. The arrangement within the shop is such as to house conveniently the several departments, namely, heavy machine tool section, repair floor section, boiler shop heavy tool and floor section, blacksmith heavy tool and forge section, tool room, electric welding rooms, stock room, tin and copper shop, and electrical parts and armature winding and repair shop (see Figure 1). All the heavy tools, the repair floor section, and railway tracks are so located in the large open bay as to be fully serviced by an electrically operated 15-ton bridge crane, with a span of 50 feet and a travel the full length of the shop. A standard-gauge railway track, branched off the main line, penetrates the full depth of the building. This track lies along the extreme east side of the main bay, allowing easy entrance and movement of rolling stock and heavy machinery, loaded on standard flat-cars, to the repair floors in the main bay. Eight jib cranes, affixed to building columns, further facilitate the heavy repair work throughout the various shop divisions. Our light and heavy machine tools are standard equipment, not unlike tools used in mine, mill, and railway shops.

Jan 1, 1935

By Getu F. Biftu

There is general agreement among scientists that global surface temperatures have been increasing during the past decades. The increase in temperature is postulated to be the result of either an increase in greenhouse gases emission or climate variability (i.e., due to variations in sun or volcanic activity or El Nino and La Nina events) during past decades and may continue to increase. The effects of a predicted rise in the Earth?s surface temperature include an increase in average global evaporation and increase or decrease in precipitation (Bloomfield, 1992; Mann et al., 1991; Vinnikov et al., 1990; Gan 1995; Zhang et al., 2000a). The general circulation models (GCMs) project a global warming due to greenhouse effects of 1.5-4.5°C by the mid 2050s, with the most pronounced changes taking place in northern latitudes (Nicholls et al., 1996). However, similar predictions at a watershed scale or even a regional scale using GCMs are mot possible yet (Arnell et. al., 1996; Georgievskii et. al., 1996; Zhang et al., 2000a). Detection of historic trends, changes and variability in climatic variables is another indirect means of understanding potential future changes or variability at regional and local scales. The main objective of this paper is to review studies related to climatic change or variability and associated hydrologic changes at a regional scale and local scale, particularly those studies applicable to the Oil Sands Region (OSR) of Alberta. This paper identifies gaps in our current understanding of the hydrologic processes that may be affected by climate change; it discusses potential implications to developments in the OSR; and it explores mitigation opportunities including several that have already been implemented.

May 1, 2004

By James H. Bechtold

The yield strength of annealed tungsten was found to have a strain rate exponent 12 times as great as that of low carbon steel. The effects of temperature and strain rate could be correlated through the Zener-Hollomon parameter with a heat of activation associated with yielding of 32,000 cal per g-atom. This heat of activation is independent of strain although both the temperature and strain rate dependence of the yield strength vary with strain. MOST metals have mechanical properties that are relatively insensitive to strain rate, especially at temperatures below that at which creep is important. In iron and molybdenum," however, relatively large strain rate effects are observed in the temperature range where the rapid increase in yield strength occurs which leads to the ductile to brittle transition. In this temperature range Zener and Hollomon' have suggested that the effects of strain rate and temperature T on the yield strength could be correlated through a single parameter, P, in the following manner where Q is a heat of activation characteristic of the metal and associated with some unspecified relaxation process. They also observed that if the temperature is restricted to a relatively narrow range— below room temperature for steel—that the logarithm of the yield strength could be expressed as a linear function of the logarithm of P. From this relation the logarithm of stress should be a linear function of the logarithm of the strain rate at constant temperature: where r will be referred to herein as the strain rate exponent. At a constant strain rate the logarithm of stress should be a linear function of l/T, ay(e = C) ~ eT [4] where q = Qr [5] and is referred to herein as the temperature exponent. These equations have been found to relate the effects of temperature and strain rate on the yield strength of molybdenum in the temperature range wherein the ductile to brittle transition occurs, —75° to +150°C.2 Bechtold and Shewmon3 have shown recently that the ductile to brittle transition in annealed tungsten occurs in the temperature range +150° to +350°C. In this temperature range the yield strength in-

Jan 1, 1957

By F. Weinberg

The distribution of solute during the progressive solidification of dilute Sn-Ag alloys was determined in both solid and liquid as a jbnction of growth rate, rod diameter, temperature gradient, and solute concentration, using radioactive tracer techniques. The results indicated that partial mixing occurs in the liquid during freezing for most of the conditions investigated, approaching complete mixing for larger rod diameters (>2mm) and slow growth rates. Measured solute distributions were fitted to distribution functions based on diffusion controlled solute transport in the liquid state, by treating the normal solute diffusion constant and distribution coefficient as variable solute transport and segregation parameters. Values of these parameters were determined for the growth conditions investigated. Observations were made to determine whether mixing in the liquid was primarily due to volume changes in freezing or to differences in density between solute and solvent. The former effect was investigated using a selected Sn-Bi alloy as a solvent with zero volume change on fusion, and the density effect was studied using vertical solidifications of Sn-In and Sn-Ag alloys, systems having, respectively, very small and large differences in density between solute and solvent. The result indicate that mixing in the liquid cannot be primarily attributed to either volume changes or density differences. THE solute distribution in progressively solidified rods of dilute alloys, in which there is complete mixing in the liquid, is given by the expression1 where C, is the solute concentration in the solid at the point where the fraction g of the material has solidified, C, is the initial solute concentration and k is the equilibrium distribution coefficient. If it is assumed that there is no significant con-vective mixing in the liquid, then the solute distribution in the initial portion of a semi-infinite rod has been calculated to be2 where t is the time from the start of freezing and x1 is the distance in the liquid ahead of the solid-liquid interface at time t. Expressions [1] and [2] describe the limiting cases of solute distribution in the liquid, i.e., complete mixing, or no convective mixing; in practice it might be expected that the solute distribution would be somewhere between these two cases. pfann3 has suggested that Eq. [I] is applicable for partial mixing, as well as complete mixing, if an effective distribution coefficient k1 is used instead satisfactorily describes solute distributions in rods of magnesium, n-g, and b-sb6 alloys that were progressively solidified from the melt without mechanical mixing. The values of kl were observed to depend on the growth rate4-6 and the temperature gradient.6 The purpose of the present investigation was to measure solute distributions in both the solidified rods and the melt as a function of the solidification variables, and to determine to what extent the observed solute distributions could be described by the above theoretical expressions, keeping in mind that expressions [2] and [3] have been derived solely for the case of diffusion controlled solute transport in the liquid and are not theoretically applicable to

Jan 1, 1963

By Galen H. Clevenger

Although there are exceptions, oxidized silver ores containing the higher oxides of manganese are generally refractory to hydrometallurgical methods of treatment. When these ores are of high enough grade they can be smelted; indeed, some rather low-grade ores of this type have been smelted at a profit because of their fluxing value. In the past, when these ores could not be smelted, they either were not treated or were treated at low efficiency, generally by cyanidation. The need for thorough investigation of the problem was therefore evident for some time before the writers began their research. The problem of treating manganese-silver ores seems to have been recognized first about 35 years ago by C. W. Goodale in applying pan amalgamation at Tombstone, Ariz. He attributed the low extraction of silver to the fouling of the mercury by manganese rather than to the presence of a refractory compound of manganese and silver. Although definite knowledge as to the cause of the poor extraction of silver was lacking, a more or less effective preliminary treatment, that is, a chloridizing roast, was applied.

Jan 1, 1925

1. Book reviews Mill Operators' Conference. Parkville (Australia), Australasian Institute of Mining and Metallurgy, 1982. 425 pp. Reviewer: B. K. Loveday Off highway truck haulage. Newman Combined Group, the Australian Institute of Mining and Metallurgy and the Institute of Engineers in Australia. Sep. 1982. Reviewer: B. J. Vorster Environmental engineering in South African mines.Johannesburg, Mine Ventilation Society of South Africa, 1982. 974 pp. Reviewer: A. N. Brown Underground Operators Conference. West Coast Tasmania Branch. Australasian Institute of Mining and Metallurgy. Reviewer: D. R. Aspeling 2. New publications Electric steelimaking in the eighties: challenges and opportunities. Rotterdam, Balkema, 1982. 362 pp. $50.00 or £33. Tungsten: a review, by P. M. Harris and D. S. C. Humphreys. London, Institution of Mining and Metallurgy (Occasional Paper 2), 1983. Members: £3, nonmembers £6. The platinum industry - prospects in recovery. London, Shearson{American Express Ltd (St. Alphage House, Fore Street, London EC2Y 5DA), 1983. £75. The best of E&MJ mining and processing idea book' New York, Engineering and Mining Journal, 1983. 128 pp. Free with subscription to Engineering and Mining Journal. Mining 1983. Harlow (U.K.), Longman Group Limited, 1983. 500 pp. £39.50. Ooncise guide to world coalfields. London, World Coal Resources and Reserves Data Bank Service (14/15 Lower Grosvenor Place, London SW1W OEX), 1983. 380 pp. £45. 3. Canadian publications Asbestos, by G. O. Vagt, 9 pp. Ooal and Coke, by J. A. Aylsworth, 16 pp. Orude oil and natural gas, by R. L. Thomas, 12 pp. Phosphate, by G. S. Barry, 8 pp. Rhenium, by S. A. Hamilton, 3 pp. 4. Mintek reports Report 2102D The recovery of magnesite from dump fines from the Strathmore Mine. (First issued Feb. 1981.) Report 2106D The evaluation of drill cores and a bulk sample from a deposit of andalusite near Thabazimbi. (First issued Mar., 1981.) Report 2108D Evaluation of a grinding aid in batch grinding, classification, and gravity concentration. (First issued Jul. 1981.) Report 2109D The evaluation of an andalusite deposit from Kleinfontein, Groot Marico. (First issued Apr. 1981.) Report M7D The beneficiation of chromite ore from the Ma-l seam near Marikana. (First issued Nov. 1981.) Report M62 A preliminary investigation into the extraction of zinc by direct oxidative leaching of high-manganese sphalerite. Report M76 A mineralogical investigation of a refractory gold ore, and of a sulphide concentrate and calcined tailing from that ore. Report M85 List of unrestricted Mintek publications issued from 1966 to 1982. Report M97 Reduction in metal consumption by the use of alternating lines of higher and lower lifter bars in a rod mill. Report M98 Multivariable control and optimization of the operation of a milling circuit at East Driefontein Gold Mine. Report M101 The potentiality of heat-treated balls in the grinding of gold ores. X-ray diffraction The Southern Transvaal Section of the South Mrican Chemical Institute is to present a mini-course on 'X-ray Diffraction: Theory and Application' in Johannesburg on 18th and 19th October, 1983.

Jan 1, 1983

By R. A. Swalin, B. W. Roberts

ONSIDERABLE controversy has centered about the existence of an order-disorder transformation in alloys in the composition vicinity of 75 atomic pct Ni and 25 atomic pct Cr. All the evidence to date for such a transformation is of a rather indirect nature, since direct X-ray confirmation is difficult to obtain as a result of the small difference in X-ray scattering factors between nickel and chromium. As a result, superlattice lines would be very faint if present. Several investigators1-5 have observed anomalies in the electrical resistivity vs temperature curves of alloys in the vicinity of 25 atomic pct Cr. The observed change is characterized by a rather broad resistivity peak at about 540°C. A discontinuous drop in resistivity is normally associated with ordering. However, Taylor and Hin-ton4 have rationalized that the discrepancy could conceivably be caused by changes in the Brillouin zones upon ordering. The same investigators measured the specific heat as a function of temperature and have also observed anomalies in the vicinity of 540°C. Nordheim and Grant5 have proposed, because of the absence of superlattice lines and the absence of a discontinuity in the resistivity vs temperature curve, that long-range order is improbable and that the results could be better explained by short-range ordering. To date, however, the question has not been resolved satisfactorily. Neutron diffraction techniques provide a method for partially resolving the question since nickel and chromium have considerably different atomic scattering factors in the case of neutrons and, therefore, superlattice peaks, if ordering occurs, should be readily discernable. The results of a neutron diffraction investigation* coupled with a dilatometric in- vestigation are reported here. An alloy containing 28.0 atomic pct Cr was prepared from carbonyl nickel and electrolytic chromium in the form of a 1-in. diam x 10-in. ingot. Melting was done in an alumina crucible and casting in a graphite mold. The ingot was homogenized at 1250°C for seven days, after which a 5-in. long piece was cut into shavings in order to obtain a suitable neutron diffraction sample. Hardness samples and samples suitable for dilatometric analysis (% in. diam x 2 in.) were prepared from the remainlng piece. The neutron diffraction sample, along with a hardness sample, was annealed at 501°C for seven days, at which time the temperature was lowered to 479°C and held at this temperature for twenty-four more days. The hardness was observed to increase from 133 to 147 Vhn during the course of the annealing treatment, in qualitative agreement with Nordheim and Grant." Neutron diffraction traces taken at room temperature and at 42 °K are shown in Fig. 1. The insert shows the trace taken at room temperature with short counting times and thus only fair statistical accuracy. No evidence for superstructure reflections of Cu3Au-type ordering is observed. The statistical accuracy of the 4.2°K trace was improved by using longer counting periods. Several weak intensities are observed at small angles, including an aluminum reflection from the cryostat assembly and a very

Jan 1, 1958

By H. C. Gatos, J. T. A. Pollock, V. Sadagopan

PREVIOUS investigations on the effect of neutron irradiation on the superconducting properties of bulk transition metals indicated that little or no change occurred in poly crystalline disordered materials, particularly if cold-worked prior to irradiation. Only the superconducting properties of ordered intermetal-lic A15 compounds were found to be sensitive to irradiation, and the observed reduction in Tc and increased magnetic hysteresis or critical current densities were attributed to the introduction of flux pinning vacancy clusters and disorder in the lattice. Since the former would also be expected to be present after irradiation in disordered alloys, the general conclusion was that the disordering effect of the irradiation was the primary reason for the changes observed. The present note reports some unusual effects of neutron irradiation on cold worked Nb(Cb)-Ti-V alloys. Specimens with nominal composition as given in Table I were prepared by repeated arc melting, taking the usual precautions, and homogenized at 1000°C for 24 hr prior to a reduction of 15:l by cold rolling. Samples of size 1 by 1 by 25 mm were sliced from the rolled strips. The sarmples chosen for irradiating were sealed in a cadmium tube (wall thickness 1 mm) prior to exposure in a fast neutron flux of 3.7 x 1019 neutrons per sq cm in the swimming pool reactor of Union Carbide Corporation&apos;s Sterling Forest Reactor. During irradiation the temperature of the samples was maintained below 70°C. The irradiated samples were stored at room temperature for approximately 1 year allowing the radiation levels to reach a safe handling value. Tc measurements were made employing a self-inductance coil technique. Jc data at 4.2"Kwere obtained using a four lead resistivity method. The latter measurements were made at the Francis Bitter National Magnet Laboratory by setting the perpendicularly applied field and increasing the direct current through the sample until a potential of about 10-6 v was detected. Tc values for the nonirradiated samples are listed in Table I together with the change in Tc after irradiation. A decrease in Tc of 0.25 or 0.3"K was measured for three of the four samples, the exception being the Nb-30 at. pct V-20 at. pct Ti alloy which showed a decrease of 0.5K. Jc vs applied field data are plotted in Fig. 1 for the Nb-20 at. pct V-30 at. pct Ti alloy. These curves are typical of the four alloys and surprisingly indicate that a degradation occurred in all the samples after irradiation. Hc2 values, obtained by extrapolation to zero current, are 8 to 15 pct lower than those measured for the nonirradiated specimens. The reasons for the degradation of Tc and jc ob-served in the alloys on exposure to neutron irradiation are not immediately apparent. The temperature at which the samples were maintained during bombardment (<70°C) and stored (20°C) make it highly unlikely that any significant change in the dislocation density of the materials through thermally activated migration and annihilation would occur. The explanation must lie in the type of damage produced by the bombardment. McEvoy et a1. reported no change in superconduct-

Jan 1, 1970

By Rex E. Cheek, Donald E. Menzie

The fluid mapper, a model relatively new to the petroleum industry, was used to study the effect of various mobility ratios on the areal sweepout efficiency for two typical spacing patterns. The experiments indicated the areal sweepout for the five-spot pattern varied from 51.8 per cent at a mobility ratio of 0.093 to 89.1 per cent for a ratio of 24.4. In the direct line-drive pattern, the areal sweepout varied from 58.7 per cent at a mobility ratio of 0.089 to 92.0 per cent at a ratio of 24.8. The fluid mapper may prove useful to determine quickly the effective areal sweepout for any well spacing. INTRODUCTION The effect of the mobility ratio on the areal sweepout efficiency during primary depletion of a water drive reservoir and during secondary recovery operations has recently become more widely recognized The mobility ratio, M, is defined as: _ kjp (displaced fluid) k/u (displacing fluid) where k = effective permeability u = viscosity When the displacing fluid is miscible with the displaced fluid, the permeabilities are equal and the mobility ratio may be expressed as a ratio of viscosities: u (displacing fluid) u (displaced fluid) The mathematical analysis for calculating the areal sweepout efficiency with mobility ratio other than unity is quite tedious.5,11 An experimental method by using a potentiometric model2 in a step-wise manner and in using an X-ray shadowgraph model3,12 with continuous fluid flow has been published. Several types of models have been used to study oil and gas reservoir performance. These models may be classified as physical, electrolytic, potentiometric, X-ray shadowgraph, and fluid mapper. The X-ray shadowgraph and fluid mapper are models relatively new to petroleum engineering and have not been used extensively for specific applications. The theory of the fluid mapper indicates it may be adapted to a study of areal sweepout efficiencies for various mobility ratios as well as other complex problems in petroleum engineering. The use of the model and results obtained when using displacing and displaced fluids of equal densities but different viscosities are discussed. FLUID MAPPER DEVELOPMENT H. S. Hele-ShawV eveloped a fluid mapper model based on the hydrodynamic theory. This theory is that in the steady flow of a viscous fluid between horizontal parallel plates spaced a very small distance apart, the effect of viscous shear is of such magnitude in the vertical plane that the motion in the horizontal plane is practically undisbrted streamline flow. Techniques developed by Hele-Shaw were not expanded and no additional developments in fluid mapper models were forthcoming until A. D. Moore, University of Michigan, published a series of papers starting in 1949, which describe the construction of a flexible and inexpensive model&apos;h nd the fluid mapper technique for the solution of certain problems.&apos; The essential components of the fluid mapper as developed by Moore are::.ln 1. A base slab. made of dental stone (calcium sulphate and water). which is shaped to represent the prototype. 2. Plate glass slightly larger than the slab and spaced

Jan 1, 1956

By D. B. Jugle, J. B. Darby

The equilibrium solubility limits of the transition elements Ti, V, Cr, Fe, and Co in liquid tin were determined in the temperature range from 827" to 1211°K. Since the equilibrium concentration of Ti, V, or Cr in liquid tin is moderately dilute in the temperature range investigated, the solubility data were employed to estimate the partial molar enthalpy and the partial molar excess entropy of solution for the three solutes in liquid tin. The reference state s for titanium or vanadium were selected relative to the solute in an intermetallic compound. The thermodynamic quantities for chromium were calculated relative to pure chromium. RECENT experiments1 have shown that the rate of solution of several transition elements in liquid aluminum can be qualitatively predicted from a knowledge of the temperature dependence of the solvent-rich liquidus. In order to extend the analysis to binary tin systems,&apos; it was necessary to know the equilibrium solubility of several of the first-long-period transition elements in liquid tin. Since solubility data for the tin-rich portion of binary systems are meager, the present investigation was undertaken to determine the equilibrium solubility limit of Ti, V, Cr, Fe, and Co in liquid tin in the temperature range from 850" to 1200°K. EXPERIMENTAL PROCEDURE A useful technique3 to determine the equilibrium solubility of a solute in a liquid-metal solvent consists essentially of placing a pure solute in contact with a pure solvent and allowing sufficient time for equilibrium to be attained at the temperature of interest. Subsequently, the solvent is removed and the equilibrium solute concentration in the solvent is determined by an appropriate analytical procedure. The technique can be applied very successfully to relatively simple systems such as the copper-germanium system.3 However, in many binary systems of transition elements with tin, several intermediate phases are known to exist and precipitation of the phases from solution, in solubility experiments, can lead to an erroneously large solubility. The difficulty was avoided in the present work by equilibration of the most solvent-rich intermediate phase with the pure solvent over a range of temperatures. The compounds employed in this investigation, and the temperature range over which each compound is in equilibrium with liquid tin are listed in Table I. No stable intermediate phases are reported in the chromium-tin system4 and, therefore, pure chromium was utilized as the solute. The stoichiometric compounds were prepared by arc-melting on a water-cooled copper hearth in a helium-argon atmosphere. The elemental tin employed in.this investigation was 99.998 pct pure, and typical lot analyses of the transition elements were reported elsewhere.&apos; A sample of an appropriate solute, in the form of a button and in sufficient quantity to exceed the equilibrium solubility, and the pure tin solvent were placed in a high-purity recrystallized-alumina crucible. The crucible and contents were placed in a horizontal furnace under a high vacuum (10-6 torr) and held at temperature for periods varying between 24 and 72 hr. A water-cooled quench tank, partially filled with diffusion-pump oil, was attached close to one end of the

Jan 1, 1970

By M. G. Benz, J. F. Elliott

A new type of solution calorimeter has been constructed to measure heats of mixing, enthalpy increments, and heats of fusion, formation, and reaction at temperatures above 1000°C. With it, measurements hove been made of the partial molar heats of mixing joy tin in the Cu-Sn system from 0 to 13 at. pet Sn at 1127°C and fir nickel in the Cu-Ni system from 0 to 9 at, pet Ni at 1200°C. The integral molar heat of mixing for the Cu-Sn system is strongly negative with a calculated minimum value corresponding to the composition Cu3Sn. The integrnl molar heat of mixing for the Czi-Ni system is slightly positive at these temperatures. These integral molar values have been measured with a probable error less than 30 cal per g-atom at an atom fraction of nickel or tin equal to 0.1. The estimated probable error for the Cu-Sn system is approximately 450 cal for a measured heat of solution of approximately 9000 cal. For the Cu-Ni system it is approximately 700 cal for a measured heat of&apos; solution of approximately 60 cal. A new type of heat of solution calorimeter was designed and constructed to provide a more accurate experimental method for determining heat effects at high temperatures, (T > 1000°C). With it, partial molar heats of mixing, enthalpy increments, heats of fusion, and heats of formation and reaction for metal systems can be measured directly. Previously it has been necessary to rely upon the use of the dropping calorimeter or the van&apos;t Hoff equation applied to equilibrium data for this information. For the most part equilibrium data are scarce and difficult to obtain in many cases, and it has been necessary to rely upon the "method of mixtures" for the desired enthalpy measurements. An earlier study1 provides a prototype for this work. The "method of mixtures" as outlined by K. K. kelley,2 "consists of dropping the substance under investigation from a furnace, with controlled and measured temperature, into a calorimeter operating at or near room temperature.&apos;&apos; In this manner the change in the total heat content (enthalpy) of the substance between the temperature of the furnace and that of the calorimeter is determined. In order to determine high-temperature heats of mixing, enthalpy increments, and heats of fusion, formation, and reaction, it is necessary to take the difference between two such measurements, one before and one after the occurrence of the enthalpy change being studied. The desired enthalpy change is then the small difference between two large numbers. Small errors in the large numbers are included as large errors in this small difference. It is this difficulty that must be avoided for accurate measurement of the desired functions. The procedure with the new solution calorimeter consists of dropping the substance under investigation from a furnace, with controlled and measured temperature, into a solution calorimeter operating in the temperature range of 1000o to 1200°C. Measurements in the range of 1200" to 1600°C are planned for the future. By selection of the composition and

Jan 1, 1964

By L O. Filippov, C H. Veloso de Melo, A Correa De Araujo

Froth flotation of iron ores is one of the most widely used methods to upgrade iron ore into high-grade concentrates. In recent years, reverse cationic flotation of iron ores has been specifically the subject of several studies. Since quartz is the most common gangue mineral in iron ores, understanding the behaviour of this mineral was the main target of the majority of such studies. However, with the depletion of mineral deposits considered rich and easy to process, it has become more common to find iron ores with complex gangue minerals, which are composed not only of quartz but by a variety of silicates. The mineralogical composition of the ore is an important factor for determining reagents and mineral processing parameters. The mineralogical suite of an ore also presents a paramount role for operational optimisation of any given flotation process. Some studies were performed with different types of amphiboles and other Fe-bearing silicates, for example, but the influence of the mineralogical nature of these silicates in reverse cationic flotation has not been fully explored and will be discussed here. Changes in the traditionally used reagent scheme for reverse cationic flotation, generally including alkaline pH values, polysaccharides as depressant (mainly starches) and primary ether amines and diamines, are expected when dealing with iron ores with complex silicate gangue composition.CITATION:Veloso de Melo, C H, Correa de Araujo, A and Filippov, L O, 2017. Reverse cationic flotation of iron ores with complex silicate gangue minerals, in Proceedings Iron Ore 2017, pp 241–244 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By C. F. Vos, J. D. Miller, J. C. Davidtz

Small replacements of C12-trithiocarbonate (C12-TTC) for dithiocarbonate (DTC)/dithiophosphate(DTP) in a reagent suite for the flotation of platinum group metals (PGM) have significantly improved the rejection of gangue. Coupled to this is an improvement in kinetics, grade and recovery of PGMs. In a pilot-plant trial, after a 5 mole per cent replacement of the current DTC/DTP collector combination by C12-TTC, large opaque bubbles were replaced by small clear ones. In addition, a similar flotation response was realized with one-third of the current depressant dosage. During a preliminary plant trial on underground UG2 ore, the initial rougher concentrates were characterized by higher PGM concentrate grades and this was in part due to improved chromite rejection. The concentrate produced from the TTC trial also exhibited a much finer particle size distribution. The overall circuit performance, which included secondary regrind and flotation, showed an increase in concentrate grade of approximately 44% while the tailings grade remained unchanged

Jan 1, 2006

By B Hiebl, J Martens, L Petzold

A research team at the Iron and Steelmaking department at Primetals Technologies has established new upgrading measures for improving the efficiency of the beneficiation process in ironmaking plants, relying largely on pre-existing equipment. After the upgrade, the iron content in the final iron ore concentrate was shown to be significantly higher. Remarkably, the costs for employing the respective measures are surprisingly low.This case study is based on a Kazakh iron and steel producer, whose beneficiation process is currently generating a magnetite concentrate with a final iron content of 65.65 per cent. The study shows that the implementation of Primetals Technologies’ intelligent modification measures to the current beneficiation process, the realisation of more effective dewatering, and the utilisation of an innovative binder lead to an increased iron content in the resulting pellets, reaching a concentration of 69.17 per cent (iron ore concentrate) and 66.5 per cent (pellets).The current operation consists of three closed circuit grinding stages, four stages of low intensity magnetic separation, vacuum disc filters and straight-grate pelletising. By dividing the slurry after the second stage of grinding and the third stage of low intensity magnetic separation, it is possible to divert the more iron-rich fines before they would enter the third grinding stage and the fourth stage of magnetic separation. This then reduces the load on the existing third stage ball mill. Afterwards, the ground material is treated in an additional low intensity magnetic separator and mixed with the previously diverted fraction of the fines. An improved filtration procedure, combined with the application of a highly sophisticated binder, further reduces the amount of additives needed, so that a genuine direct reduced (DR)-grade iron concentrate is produced as a result.All laboratory, pilot and pelletising test work was executed at Primetals Technologies’ laboratories in Austria.CITATION:Martens, J, Petzold, L and Hiebl, B, 2017. Enabling iron ore concentrate for the production of direct reduced iron with pre-existing beneficiation lines, in Proceedings Iron Ore 2017, pp 227–232 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By Y Yamaguchi, S Nomura, M Matsumura, C Kamijo

In order to increase productivity and decrease reducing agent rate (RAR) of blast furnaces, slag content of sinter ore must be decreased. However, gangue content in iron ore tends to increase because of resource depletion. Therefore, amount of high-grade concentrate in sinter ore feeds should be increased, but this situation causes a decrease in permeability of the sintering bed so that the productivity of sinter process decreases. In order to increase the amount of concentrate, NSSMS has developed the P-type separate granulation method, RF-MEBIOS and SPEx II technologies. These technologies have been introduced to actual sintering machines. In this report, a new technology using microparticles of iron ore is proposed to increase the amount of concentrate in sinter blends. Basic experiments simulating the sinter making process using microparticles of iron ore were undertaken. Crushed pisolite, containing &gt;60 wt per cent -10 µm was prepared for binder. The pisolite microparticle binder was mixed with another Australian sinter feed ore in a high-speed agitating mixer. They were mixed for about one minute, and then granulated using a pan pelletiser. After that, they were added to another raw material mixed by a drum mixer, and then charged in a pot for a sinter pot test. As a result, when the amount of concentrate increased from 13 wt per cent to 20 wt per cent, productivity was almost kept constant using pisolite microparticle binder.CITATION:Kamijo, C, Yamaguchi, Y, Matsumura, M, Kawaguchi, T and Nomura, S, 2017. Development of an iron ore microparticle binder for increasing the concentrate content of sinter blends, in Proceedings Iron Ore 2017, pp 69–74 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By W Valery, A Jankovic

The ball mill in closed circuit with hydrocyclones is an industry standard, and well known methodologies exist for equipment sizing, selection and design. However, the potential to improve the capacity of ball mill circuits by replacing cyclones with screens has been recognised for many years and recently has been successfully realised, thanks to developments in fine screening technology. Proper methodology for equipment sizing and selection is required to capitalise on this opportunity, but there is currently insufficient information and few guidelines available on how to design such a circuit. This paper discusses the differences between ball mill circuits closed with cyclones and with screens. A methodology is described for equipment sizing and selection for a circuit closed with screens, and the laboratory testing requirements are described for low grade base metal ores and magnetite ores. An economic evaluation is also presented for a case study demonstrating the potential benefits of closing a ball mill circuit with screens.CITATION:Jankovic, A and Valery, W, 2013. Energy efficient ball mill circuit - Equipment sizing considerations, in Proceedings MetPlant 2013 , pp 285-295 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013

By L. J. Froisland

Water classification and heavy-media sink-float methods were investigated for concentrating metallic junk automobile shredder rejects initially upgraded to about 75-percent metal content in an air elutriation system. An 8-inch-diameter water elutriation column with a feed capacity of 2.7 tons per hour was constructed and operated. The results obtained were compared with those produced by sink-float methods. Tests made on duplicate samples of an intermediate-grade metal product were successful in upgrading the metal con-tent from 75 percent to 98.7 and 99.1 percent with respective recoveries of 95.5 and 98.9 percent for the water classification and sink-float procedures. Tentative flowsheets for treating junk auto shredder rejects are outlined.

Jan 1, 1972

By Chappell B

Backfill in the form of mine waste tailings has inherent problems associated with attaining adequate strengths upon placement. Fines are usually removed to ensure adequate drainage, which lowers the cohesive strength of the fill, leaving the fines to he placed in a tailings darn. Electro-drainage and electro-chemical grouting is examined to investigate its effects on densification and shear strength within a silty clay tailing having low permeability and shear strength. Two separate grouting mechanisms are observed for the iron and silica grouts used. Electro- osmosis is associated with iron grout that deposits within the tailing matrix under a converging pH gradient, and increases the permeability of the tailing. This process initiates cation exchange and causes cementing of the granular contact points between the clays. Electro-phoresis causes sodium silicate solution to deposit silica grout in the voids of the tailings. The resultant effect of these mechanisms results in an increase in cohesion, leaving the void ratio of the iron grouted tailings as it was but significantly reducing the void ratio of the silica grouted tailings.

Jan 1, 1998

By Ke Yang

In Chinese coal mines, extraction of deep, highly gassy soft coal seams sandwiched between soft floor and soft roof in complicated geology is commonly encountered. How to safely and efficiently excavate such seams is a very significant and important problem. It has been a focused research area in recent years. By combining the characteristics of fully mechanized longwall mining methods such as large cutting height and mining along the dip, an integrated method and technologies for the Zhangji Coal Mine were developed. This technology includes the design of a complicated geological exploration system, optimization of mining method and working face parameters, control of rock pressure and high levels of gas, reliability model of the production system, and selection and compatibility of equipment. Engineering practice shows that the integrated technology was successful in mining these complicated seams. This study not only enriches the mining method, but also improves the coal mining practice, especially ensuring both safety and productivity under complicated geological conditions.

Jan 1, 2009