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By J. Weertman

The paper of Gifkins and Snowden considers the interesting but difficult problem of determining the stress dependence of secondary (steady-state) creep at low stresses. These authors have concluded that at stresses below 250 psi (2 x 107 dynes per sq cm) the secondary creep rate of lead is proportional to the stress (viscous creep) and is not proportional to the stress raised to about a fifth power. The experimental data considered by them were obtained on tests conducted at room temperature and at 50°C. The lowest stress employed was 50 psi (3.5 X 106 dynes per sq cm). The authors pointed out the main difficulty in determining the stress dependence of creep at low stresses. The creep tests must be run for very long lengths of time. However they made no estimates of when an experimental creep rate determination must be rejected because it does not represent a true steady-state or minimum creep rate. In order to be certain that a creep curve is within the steady-state region, the total creep strain should be of the order of 0.1 to 0.2. For a creep test of a year's duration this requirement implies that a secondary creep rate smaller than about 10-3 per hr cannot be measured reliably. The corresponding creep rate for a 10-year test is 10-6 per hr. The creep rates of the tests that were considered by the authors to prove the existence of viscous creep were of the order of or less than 10-6 per hr. One can conclude reasonably that this data does not prove unambiguously that large strain steady-state creep rate of lead is proportional to the stress in the stress range of 50 to 250 psi (3.5 x 106 to 2 X 107 dynes per sq cm). Another technique can be used to obtain the stress dependence at low stress levels. The creep rate is a very sensitive function of temperature. The creep rate can be increased by very large amounts merely by increasing the temperature. We carried out steady-state creep tests on lead single crystals25 at temperatures up to 320°C. We were able to obtain creep rate data down to stresses as low as 35 psi (2.5 x 10' dynes per sq cm). Our smallest creep rate was 8 x 10-5 per hr. Thus we obtained large strain, steady-state creep rates to even lower stresses than were considered by Gifkins and Snowden. No evidence was seen for viscous creep. The creep rate was proportional to the stress raised to about a 4.5 power down to the lowest stresses. Since there is no reason to believe that changing the temperature should change the stress dependence of steady-state creep, we feel that large strain viscous creep does not occur in the stress range quoted by the authors for lead single crystals or large-grain polycrystalline samples of lead. This conclusion does not imply that viscous creep may nat occur in a lower stress range or in the same stress range for fine grain material or at creep strains very much smaller than 0.1. Support by the U.S. Office of Naval Research is acknowledged. Authors' Reply R. C. Gifkins and K. U. Snowden We thank Dr. Weertman for his discussion and although, as we hope to show, we do not agree with his reservations, we do concur in stressing the importance of ensuring that creep rates are reliably obtained. Dr. Weertman appears to be content to accept n = 1 for low stresses with fine-grained material but not for single crystals. We believe our results show that the former result cannot be accepted without also accepting the latter. We will also show that the probable errors in our minimum creep rates are insufficient to alter our conclusions, that the criterion proposed by Dr. Weertman is arbitrarily restrictive and his alternative experimental approach possibly invalid. 1) A principal result of our Fig. 1(a) is that n = 1 for polycrystalline specimens at room temperature and 50°C for stresses below -250 psi. There was evidence that crystal slip and grain boundary sliding contributed approximately equaily to the overall strain in this low-stress regime. This implies that either a) grain boundary sliding controls slip within the grains or b) both grain boundary sliding and crystal slip independently occur according to mechanisms which give n = 1. Alternative a does not seem acceptable, so we were forced to consider b. This led us to reexamine work on bicrystals by Strutt and Gifkins and plot curves Fig. l(b). Previously Strutt et al. (loc. cit.), had merged these points with others using the Zener-Holloman parameter and thus, we now believe, had been led to overlook the behavior where n = 1. Curves C and D in Fig. l(b) did appear to confirm the hypotheses that n = 1 for crystal slip at these low stresses and the sliding curve F was similarly of the expected form. It was comparatively easy to find a quantitative theory to account for n = 1 for sliding and the similarity of curves C and D to curve F (all obtained from the same set of specimens) led us to feel that the single-crystal curves were valid. 2) We believe the secondary creep rates for both the polycrystalline and single-crystal specimens to be in error by factors c2. In Fig. 6 creep curves for polycrystalline specimens of lead(1) and lead(II) are reproduced as curves a and b, respectively, and curve c is for a single crystal at 100 psi. It is clear that, although the attainment of secondary creep rate takes 2 years for a and 150 days for b, thereafter the curve is linear for periods of 7 and -1 year, respectively. The single crystal has a linear portion commencing after 20 and extending to 90 days. Creep extension was measured directly using a traveling microscope reading to 0.01 mm on gage lengths marked on the specimens; the gage lengths

Jan 1, 1968

By José Gutiérrez, Cosme Soto, Octavio Vargas

El presente trabajo detalla las etapas más relevantes del proceso de cambio de la Guía Industrial 7 (IG-7) a la regulación S-K1300 cuya finalidad es reportar Recursos Minerales en la Bolsa de Nueva York. Los autores desean brindar una guía sobre las situaciones y retos más importantes sucedidos durante el proceso de adaptación y auditoria para reportar recursos minerales bajo regulación S-K 1300 en la Cia. de Minas Buenaventura. También, plantear una metodología para ponderar tanto las variables que le dan soporte a la estimación de las leyes, como los ítems que brindan calidad a la información de Geología.

May 10, 2023

By Lee W. Saperstein

In surface mining for coal, common practice for the disposal of preparation plant refuse is to bury it. As with surface refuse piles, these buried wastes can ignite and can also lead to ground and surface water pollution. Steps to ameliorate these problems have been devised over the years. C and K Coal Company, of Clarion, Pa., the largest Pennsylvania surface mining company, has incorporated all of these steps and added of few, of their own in their latest disposal practice. In addition to layering and compacting, C and K practices selective placement and dilution to minimize longterm problems.

Jan 1, 1977

Nearly as impressive as the machines that will be on display at MINExpo are the massive engines and tires that keep the machines moving. As you can imagine, it takes a special tire and special engine to run these machines. The following is a look at some of the exhibitors that will be at MINExpo displaying engines and tires. Cummins Inc. Cummins Inc. will display a lineup engines from 37kW to 2,983 kW (49 hp to 4000 hp) at MINExpo, representing the most extensive ?smallest to largest? range the company has ever put on display.

Jan 1, 2012

By E. G. King

Low-temperature heat capacity determinations of the minerals goethite and pyrophyllite were made in the temperature range from 510 to 298° K. The entropies at 298.15° K were evaluated as 14.43 ±0.15 cal/deg mole for goethite and 56.6 ±0.5 cal/deg mole for pyrophyllite. The entropies of formation from the constituent oxides are -4.4 ±0.2 cal/deg mole for goethite and -12.3 ±0.6 cal/deg mole for pyrophyllite. The standard free energy of formation of goethite from its oxides is ?G°298.15 = 0.16 ±0.20 kcal/mole.

Jan 1, 1970

By Deepak Malhotra

Rosario Dominicana, S.A., operates a gold processing complex at Pueblo Viejo, northwest of Santo Domingo (Dominican Republic). The plant processes approximately 10,000 mtpd of oxide gold-bearing ore with a work index of 11 kWh/mt. The ore hardness has increased to about 17 kWh/mt. Metallurgical auditing of the plant was conducted? to find ways to modify the circuit to process hard ore without sacrificing throughput. In addition, unit operations were optimized to increase recovery and reduce operating cost,. The results of modifications made in the plant are discussed in this paper.

Jan 1, 1989

Changes in mining technology have led to an increase in the number of underground sulfide dust explosions reported in Australian and overseas mines. Samples collected at the Elura mine consisting primarily of pyrite, pyrrhotite, arsenopyrite, sphalerite and galena, were tested in 8 litre explosion chamber. The dusts were found to be capable of producing dangerous dust explosions with maximum explosion pressures of 440 kPa and rates of pressure rise of 5200 kPa/s. The hazards of a sulfide dust explosion are associated with the pressure wave and flame front of the explosion and the toxic gases remaining after the explosion.

Jan 1, 1984

By J. Basi, J. A. Finch

ABSTRACT Testing the effects of bubble size (Db) in a Mo cleaning ?otation column at Highland Valley Copper mine indicated that increasing the proportion of small (< 1 mm) bubbles signi?cantly improved column metallurgical response, compared to typical operation. The results were a three- to four-fold Mo recovery increase and a 1 to 2% Mo (absolute) concentrate grade increase. The improvedcolumn operation produced a 4% Mo plant recovery increase. This study also showed that modelling the ?otation rate constant (k) as an inverse square function of Db was more accurate than considering k to be inversely proportional to Db.

Jan 1, 2010

Ahrenholz, Herman William, Jr., Student, Lehigh Univ Bethlehem, Pa. &apos;35 Allen, Carl A., Student, Colorado School of Mines Golden, Colo. &apos;35 Allen, Paul W., Student, Mass. Inst. of Tech Cambridge, Mass. &apos;35 Allen, R. M., Jr., Student, Virginia Polytechnic Inst., "G" Co Blacasburg, Va. &apos;35 Amberger, K. H., Student, Michigan College of Min. & Tech Houghton, Mich. &apos;35 Andersen, Burton Lee, Student, School of Mines, Univ. of Washington Seattle, Wash. &apos;35 Anderson, Joseph S., Student, Univ. of Texas El Paso, Tex. &apos;35 Anderson, R. C., Student, Univ. of Washington Seattle, Wash. &apos;35 Ansel, Gerhard 627 Clyde St., Pittsburgh, Pa. &apos;34 Anutta, Frederick P., Student, Michigan College of Min. & Tech Houghton, Mich. &apos;35 Apsouri, Constantin N., Graduate Student, Univ. of Arizona Tucson, Ariz. &apos;35 Arakelian, Haig Mark, Student, Mass. Inst. of Tech Cambridge, Mass. &apos;34 Archer, George K 1420 Court Pl., Denver, Colo. &apos;34 Argall, George O., Jr., K. E. House Golden, Colo. &apos;35 Argiielles, Alfredo, Student, Univ. of Texas El Paso, Tex. &apos;35 Atwater, Ralph, Student, South Dakota School of Mines Rapid City, S. D. &apos;35 Austin, Robert B., Miner, Page Mine, Federal Min. & Smelt. CoSpokane, Wash. &apos;34

Jan 1, 1934

By E. Galán

The largest Spanish kaolin deposits formed on granites occur in Galicia (NW Spain) due to a widespread kaolinization of Variscan granitoids. This paper provides insight of the origin of this kaolinization process on the basis of a mineralogical and geochemical study carried out in two kaolin deposits, presently mined to be used in the paper industry. Mineral composition of the deeply kaolinized rocks is dominated by well-ordered kaolinite with minor quartz, K-feldspar, mica (illite/muscovite), locally gibbsite, and traces of resistant accessory phases (rutile, ilmenite, zircon and monazite). The content and structural order of the kaolinite decrease with depth. Kaolinite formed by extensive replacement of feldspars (plagioclase). Differential mobilization of major and trace elements during kaolinization has been inferred by using a mass-balance approach. Significant amounts of Na, Ca and minor Mn, Sr, P and U were removed from incipiently leachable minerals (plagioclase and apatite), and K, Rb, Cs and Ba were released from K-feldspar and mica. On the contrary, Ti, Zr, Th, Hf and the REE are retained in the resistant trace minerals that are concentrated in the fine fractions of the kaolins.

Jan 1, 2010

By K S. Park, J K. Kim, J H. Park, Y Su

The present study investigates the possibility of the direct removal of oxygen from the Ti-30Ni (wt per cent) alloy melt through the thermodynamic equilibrium reactions at 1623 K in the vertical tube furnace. The deoxidation efficiency of Ti-Ni alloy melt by adding different contents of metallic calcium (Ca) as a deoxidant was evaluated with the binary CaF2-MgCl2 flux. The thermodynamic equilibrium experiments showed that the total oxygen content in the alloy decreased from about 650 ppm to 350 ppm when 3.5 wt per cent Ca was added to the Ti-30Ni (wt per cent) alloy. Alternatively, the effect of flux composition in the CaF2-MgCl2 flux on the oxygen content was also investigated at 1623 K. Therefore, the effect of binary flux systems on the deoxidation ability was compared at 1623 K. According to the results, the flux system with 80 per centCaF2– 20 per centMgCl2 exhibited the best deoxidation capability, ie total oxygen content in the alloy reduced from 1450 to 550 ppm.

Aug 21, 2024

By X. -G. Chen, A. M. Nabawy

A novel manufacturing technique for Al-TiB2 nanocomposites has been developed, in which TiB2 nanoparticles were incorporated into liquid aluminum under mechanical stirring and in the presence of a K2ZrF6 flux-wetting agent. The microstructure of the Al-TiB2 nanocomposites was studied using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The microhardness test was conducted to investigate the strengthening effect of TiB2 on the aluminum matrix. The TiB2 nanoparticles were successfully incorporated and dispersed into the aluminum melt in the presence of the K2ZrF6 flux during mechanical stirring. In the as-cast microstructure, most nanoparticles segregated in the interdendritic regions as a result of particle redistribution during solidification. The addition of 2, 5 and 10 wt% TiB2 nanoparticles increased the composite hardness by 60, 90 and 150% respectively when compared to commercial purity aluminum, indicating that the TiB2 nanoparticles imposed a significant strengthening effect on the aluminum matrix. The role of K2ZrF6 flux agent on the incorporation of nanoparticles into aluminum melt was discussed.

Jan 1, 2014

By A. R. Taylor

Using solution calorimetry, the following heats of reaction were determined: (1) NaCN(c) + 1/Cu20(c) + 129H20(l) ? CuCN(c) + NaOH?128.5H2O ?H = -13.44±0.10 kcal/mole, (2) HCN(2) + NaOH?128.5H20 ? NaCN(c) + 129.5H20(l) ? = -2.52±0.02 kcal/mole. From these reactions, the heats of formation for CuCN(c) and HCN(2) were calculated to be 22.7±0.4 kcal/mole and 24.9±0.4 kcal/mole, respectively. Reaction 2 was made to check the consistency of literature values for heats of formation of HCN and NaCN. Adiabatic calorimetric measurements between 10° and 400° K showed the entropy and heat capacity of CuCN(c) to be 21.51±0.06 eu and 14.58±0.04 cal/mole deg, respectively, at 298° K. A broad anomaly in the heat capacity was found in the temperature range 285°-320° K. The heat of transition associated with this anomaly was less than 1 cal/mole, the sensitivity of the measurements.

Jan 1, 1971

By R. K. Koch

The vapor pressures of liquid columbium and liquid hafnium were deter-mined by the Langmuir free evaporation method as a part of the Bureau of Mines program on the study of transition metals. An electron-beam furnace with a water-cooled copper crucible was used for melting. Temperature was measured with a two-color ratio pyrometer. Least-squares analyses of the vapor pres-sure data gave the following equations: [Logp (atm) = 5 .429 -31,310 T] for liquid columbium in the range 2,740° - 3,140° K, and [Log p (atm) = 5,690 28 T] for liquid zirconium in the range 2,500° -2,810° K. Third-law evaluations of each data set gave mean heats of sublimation (298.15° K) of 175.1±3.2 kcal/mole and 148.3±1.2 kcal/mole for columbium and hafnium, respectively. Second-law standard heats of sublimation determined from sigma plots and from sigma-prime plots agreed fairly well with the third-law values. The sigma-prime plots gave standard entropies of sublimation of 30.96±0.84 eu and 33.S6±0.44 eu for columbium and hafnium, respectively.

Jan 1, 1968

By J. W. Walkiewicz

One of the objectives of the Bureau of Mines is to develop substitution technology for scarce materials. In accordance with this goal, alloys containing lanthanum, cobalt, copper, and magnesium were investigated for fabrication of rare-earth-cobalt (RE-Co) permanent magnets. A complete substitution of lanthanum for samarium and a partial substitution of copper for cobalt was accomplished. Magnets of La-Co and La-Co-Cu-Mg alloys were fabricated by powder metallurgy techniques and evaluated. A maximum intrinsic coercivity of 23.2 kOe was obtained with a La-Co-Cu-Mg alloy. In comparison, maximum values of 9.3 kOe and 11.6 kOe were obtained with La-Co and La-Co-Cu alloys, respectively. The substitution of copper and magnesium for part of the cobalt resulted in a large increase of intrinsic coercivity, similar to the results of Bureau research with mischmetal-Co-Cu-Mg alloys. Unlike the mischmetal-Co-Cu-Mg magnets, the La-Co-Cu-Mg magnets showed signs of physical deterioration on exposure to air. The effects of fabrication parameters on the magnetic properties of the La-Co-Cu-Mg alloys were also determined.

Jan 1, 1982

By Alcy Dias Rodrigues

O Centro de Operações do Sistema Elétrico da Aperam South América possui um sistema de automação chamado SAE (Sistema de Automação de Energia) para realizar a distribuição e operacionalização da Energia Elétrica na planta em Timóteo, sistema este com mais de 20 anos de implantação. Devido ao alto grau de obsolescência do sistema SAE, a dificuldade de se atualizar todos os componentes do sistema e a complexidade e dificuldade do acesso aos dados, verificou-se a necessidade de encontrar uma forma de disponibilizar os mesmos para os demais sistemas da empresa. Com base nestas necessidades, foi desenvolvido e implantado um GATEWAY capaz de realizar a comunicação com todas UTR’s CORTEX (remotas do sistema), através do protocolo CONITEL 2020, disponibilizando estas informações coletadas em uma camada OPC SERVER para que o sistema PIMS (Sistema de Gerenciamento de Informação da Planta) realize a coleta e armazenamento destas informações, permitindo assim um melhor gerenciamento de energia pelo VIRIDIS (Sistema de Gestão da Eficiência Energética utilizado na APERAM), além de permitir que toda a planta tenha acesso em tempo real às informações de tensão e corrente de todo setor de 13,8 kV, 69 kV e 230 kV.

Oct 30, 2017

Edward K. Landis, Philadelphia, Pa.: In studying Mr. Thackray&apos;s paper it seemed that a critical comparison of the results from different methods therein reported would he of interest. For this purpose Table I. was constructed by grouping all determinations made by the same method, and the probable errors were calculated. In this table all chemists titrating with permanganate (A1, E, F, G and 0 of Mr. Thackray&apos;s paper) are classed under "Emmerton;" those titrating with nitric acid (C, J, S and Y) under " Handy; " those re Probable error of result: a, ±0.0008996; b, ±0.000694; c, ±0.00107; d, ±0.00115; e, ±0.000674; f, ±0.000473; g, ±0.003675; h, ±20.0007959; i,0.000.5098; k, ±0.0008303. Probable error of single determination: a, ±0.001989; b, ±0.001547; c, ±0.00214; d, ±0.0023;e, ±0.00116;f, ±0.000818;g, ±0.0019;h, ±0.00224; i, 40.00143; k, ±0.00234. The formula for calculating the probable error is 0.6745, where N (N— 1)&apos; S is the sum of the squares of the differences from the mean and N is the number of determinations.

Jan 1, 1897

By K. N. Han, H. Lee, M. C. Fuerstenau

An investigation of the recovery of finely-divided cassiterite and silica particles less than 1 µm (1200 mesh) in size has been carried out using packed and fluidized beds. The bed particles used included cassiterite and silica particles ranging from 44 to 210 µm (325 to 70 mesh). Effects of various system parameters on the recovery and selectivity of cassiterite fines were investigated. System parameters included pH of the slurry solution, superficial velocity, slurry concentration, and bed particle sizes. High recoveries of cassiterite fines were obtained at pH 4.0 and slow slurry flow rates. In a packed bed system, recovery of cassiterite fines was greater than 95%, while that of silica fines under the same conditions was about 35%. Although the total recovery per pass is not as good as the packed bed, the fluidized bed system exhibits good recovery in general and an excellent selectivity of cassiterite fines. There is an optimum superficial velocity, vo, for the rate of fine particle uptake and the apparent rate constant has the form of Kvo1/2- K&apos;vo, where K and K&apos; are system constants.

Jan 1, 1985

By Ahmet Geveci

[Generally accepted formula related to sulfur slag-metal distribution ratio is given by the following equation: [ ] According to the above equation it can be deduced that sulfur distribution between slag and metal is governed mainly by metal composition (?s term), slag composition (slag basicity and in turn sulfide capacity), oxygen potential of the system (ao¬¬ term) and temperature(related to equilibrium constant, K). In this study, the results of ladle furnace operations conducted in Erdemir-Iron and Steel Works Co. (Turkey) in relation to sulfur removal, have been given. Typical ladle furnace slag analyses of 4937K quality steel have been presented. Activity coefficient of FetO,?FetO, have been calculated with the relation obtained fromthe literature. Activity calculations have been performed with the program written in Mathcad. The changes in activity of aFetO in the slag phase,, have also been studied in relation to the sulfur removal: The relation between % Decrease aFetO and %DeS (measured)have been investigated for 4937K runs and someother types of steel produced in the Erdemir Plant. Related to ladle operations %desulfurization defined as [(%Sinitial-%Sfinal)/S%initial]*100 values have been presented for different steel qualities.]

Jan 1, 2006

By E U. Petersen, D R. Cooke

Hydrogen and oxygen isotopic constraints on hydrothermal fluid composition from the Pliocene Boyongan and Bayugo porphyry copper-gold deposits (southern Philippines ) reveal mixing of magmatic and sea water reservoirs as the hydrothermal system evolved. Magmatic-equilibrated fluids (d18O: +8.3ë to +9.1ë; dD: -61ë to -51ë) are represented by hypersaline brines implicated in copper-gold transport and deposition. These dominate the fluid inclusion assemblage in early comb-quartz (unidirectional solidification textures), miarolitic quartz, and in K-silicate-stage quartz-K-feldspar ¦ biotite veins. Fluids responsible for post-K-silicate alteration assemblages of pyrite-clay (illite, pyrophyllite and kaolinite), alunite and smectite are represented by low-moderate salinity two-phase inclusions in co-existing quartz. These are interpreted as mixtures of evolved magmatic fluids (d18O dD: -42ë to -20ë) with evolved Pliocene sea water (d18O: + 4.0ë; dD: +4ë). The isotopic evidence for sea water involvement in the hydrothermal system suggests that porphyry emplacement and associated diatreme formation could have occurred in a submarine setting. An&nbsp;EXTENDED ABSTRACT&nbsp;is available for download. A full-length paper was not&nbsp;prepared for this presentation.

Jan 1, 2008