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By Charles W. Huggins

The Bureau of Mines investigated palygorskite, a natural asbestiform material, to accumulate knowledge that might serve as a foundation for future synthesis of a similar material. Unit cell, chemical analysis, DTA, TGA, optical constants, and electron microscopy data were obtained. Selected palygorskite samples of bettor than 97-percent purity were used to obtain this information. Chemical analysis revealed the following formula: (OH2)4 (OH)2 Ca0.01Fe0.02K0 .c3Mg2.10A12.00Si7.93020.3.91 H2O. The optical constants for sodium light are a = 1.522; S = 1.530; ?=1.533; biaxially (-). The following orthorhomibic unit cell constants were determined: ao = 12.690 A, Z = 2, bo = 17.857 A, Dx = 2.327. co = 5.207 A, Identical diffraction patterns resulted from the three palygorskite samples that were studied. X-ray, chemical, DTA, TGA, and optical data were compared with literature values for similar fibrous materials. X-ray diffraction lines were indexed. Several electron micrographs were made to compare the structures of palygorskite and attapulgite with that of chrysotile. The micrographs revealed extremely short laths for attapulgite, very long flexible laths for palygorskite, and tubular structure for chrysotile.

Jan 1, 1962

By P W. Cleary, G K. Robinson, M D. Sinnott

Discrete element modelling (DEM) is a research tool that involves numerically solving the equations of motion of large numbers of particles. It can be very useful for investigating mechanisms that can lead to bias when extracting samples from material as it is carried on a conveyor belt or as it falls from the end of a conveyor belt. DEM is more realistic than conceptual models and mathematical models; but it is not as realistic as physical experimentation. Its primary advantages over physical experimentation are that it is cheaper and that it allows many factors to be varied while keeping other factors unchanged.This paper reviews our investigations of the performance of sampling systems by using DEM. The sampling systems investigated include falling-stream cutters, cross-belt cutters, Vezins and a device called a ætrue-beltÆ cutter, which is being developed. The purpose of the review is to explain what DEM has contributed to the theory and practice of sampling, and to indicate what it is likely to be able to contribute in the future.CITATION:Robinson, G K, Cleary, P W and Sinnott, M D, 2012. How discrete element modelling is influencing the theory and practice of sampling, in Proceedings Sampling 2012 , pp 15-20 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 21, 2012

By J H. Park, M J. Lee

Because the environmental problems are occurred by greenhouse gases such as CO2, the industries have tried to increase electric motor efficiency to reduce CO2 emissions. A core material of electric motor is high-silicon electrical steel. The ferrosilicon (FeSi) alloy, a raw material for the production of electrical steel, affects the electric properties of silicon steel. The main impurities such as Ca, Al and Ti make inclusions or precipitates that causes core loss. The slag treatment has been widely used to remove impurity elements. Thermodynamic principles for the refining of several impurities, specifically Ca and Al, have been investigated, whereas thermodynamic behaviour of Ti has not been fully understood yet. Therefore, in the present study, the titanium distribution ratio () between ferrosilicon and CaO-SiO2-Al2O3 slag system at 1773 K was investigated. The results show that is influenced by both the basicity and stability of titanium ion in the slag. Specifically, exhibits a minimum value at about C/S=0.7 indicating a shift in the titanate structure unit from [TiO5]-square pyramid to [TiO4]-tetrahedron because of lack of Ca2+ ions in a C/S<0.8 region, contributing to an increase in titanate capacity and .

Jun 19, 2024

By P. Zhu

The leaching behavior of copper powders recovered from waste printed circuit boards (WPCBs) was investigated using electrogenerated chlorine and aeration in a sulfuric acid solution with added NaCl and CuSO4. Various parameters were studied to understand the mechanism of the copper leaching. When the current density increased from 0 to 0.1 A/cm2, the temperature from 30 to 60° C, agitation speed from 100 to 400 rpm, and the size ranged from below 75 to 150 µm, the leaching ratios of copper powders increased. The leaching kinetics were analyzed using a shrinking core model: 1-(1-X)1/3 = kt, and the leaching process was chemically controlled with an activation energy of 14.7 kJ/mol due to Cl- ion catalysis. The ratios of [Cu+]/[Cu2+] at various temperatures (30, 40, 50, 60 and 70° C) showed a periodic variation with the increasing of the leaching time. The redox potentials of the leaching solution and copper leaching ratios in different conditions were measured. The result indicates that dissolved oxygen achieved the dissolution of coppers and electrogenerated chlorine can promote the dissolution of copper powders and improve the reaction rate of kinetics in the presence of oxygen.

By Mitsuru Tanahashi

In order to develop an effective process for the production of from metallurgical-grade one (MG-Si), the oxidation removal of boron from molten MG-Si was investigated at a solar-grade silicon (SOG-Si) 1773K by the following two CaO-saturated CaO-CaF2 flux treatment processes. I) Boron removal by flux addition onto the molten M6-8 followed by oxygen gas injection into the melt (Two-stage connecting process). II) Boron removal by simultaneous injection of flux powders and oxygen gas into the molten MG-Si (Simultaneous injection process). These processes can establish the special condition of both high basicity of the flux and the high oxygen partial pressure at the boron removal reaction sites. Through these processes, especially by the simultaneous injection Process using a flux powder injection equipment, the boron content in MG-Si can be efficiently reduced. The obtained results clarified that both processes should be conducted for a time period as short as possible by using as much flux as possible. By repeating the simultaneous injection process for 60 s three times under the optimum operating conditions determined in the present study, the boron content in MG-Si can be reduced from 14 to 4.7 mass ppm.

Jan 1, 2003

By S. Street

The Environment process, invented by Prof. H.K.Womer and developed at the University of Wollongong, simultaneously treats ferruginous and organic wastes via bath smelting. Conceived in the late 1980&apos;s, the patented process was originally developed using steelworks dust to settle solids from sewage, producing a composite material suitable for smelt reduction. Work began on the process in 1990 with the Australian patent having a priority date of February 1990. Early research focussed on settling of solids from sewage, while pyrometallurgical investigations examined smelting in small induction furnaces. By 1992 smelting trials had been undertaken in pneumatic and electric arc furnaces, the process being successfully demonstrated up to on 8 tonne scale. The success of this particular trial, and other smaller trials, resulted in construction of a 100kg DC arc furnace which was commissioned in 1993. By 1994 the main project focus was on development of the smelting technology. Over 3 years of trials on the DC arc furnace have identified and clarified many of the pyrometallurgical reactions. optimum operating parameters, as well as demonstrating the versatility of the process for treating a wide range of wastes. Currently the Illawarra Technology Corporation (lTC), the commercial arm of the University of Wollongong, is pursuing commercialisation of the process.

Jan 1, 1996

By Konstantin G. Ashkinadze

The paper considers performance of piles supporting transient pipe anchors in heavy industrial pipelines. Events such as pump trips or opening and closing of large valves produce short-term dynamic pulses in the pipeline with variable spectral characteristics. Their magnitude is large enough to cause major damage to the pipeline and its anchors, which face horizontal impact loads amounting to hundreds of kN. Design of pile foundations supporting these anchors is often governed by limitation of deflection of the support to prevent overstressing pipeline connections and equipment nozzles. The maximum deflection does not always correspond to the largest load because the stiffness of the soil surrounding the piles heavily depends on the rate of loading. Faster actions encounter stiffer soil response while loads of smaller magnitude applied slowly may be more critical for the deflection time history of the anchor. A typical transient action has both high- and low-frequency harmonics, which makes the response complex. Using load rate-dependent p-y curves published in literature, the paper develops methods of analysis of pile foundations for transient anchors. Pile displacement amplitude – input frequency – natural frequency correlations and time histories of pile response are constructed for typical profiles of transient actions, considering nonlinear soil response to large horizontal loads.

Jan 1, 2016

[Abbott, Jay Union Supply Co., 7458 So. Jackson Street, Littleton, CO 80122 Achziger, Ronald H Midwest Rubber & Supply Co., 6404 E. 39th Ave., Denver, CO 80207 Acre, Leland H Dorchester Coal Co., 2795 Skyline Ct., Grand Junction, CO 81501 Adams, Dell H Consolidation Coal Co., Consol Plaza, 1800 Washington Rd., Pittsburgh, PA 15241 Adams, Robert W Energy Fuels Corp., 3 Park Central, Suite 900, Denver, CO 80202 Adams, Douglas K General Electric Co., P.O. Box 2331, Denver, CO 80201 Adams, William R ATW, Inc., 760 Three Fins, Dr. #106, Murray, UT 84107 Adsero, Richard Falkirk Mining Co., Box 1024, Washburn, NO 58577 Afflect, Robert S Anderson Mavor (U.S.A.), Ltd., 303 Progress Street, Zelienople, PA 16063 Agee, Pete Driltech, Inc., P.O. Box 338, Alachua, FL 32615 Ahlborg, William Joy Mfg. Co., 26 Sedgwick Dr., Englewood, CO 80110 Ainscough, Harlen R D. H. Emling Co., 5500 S. Syracuse Cr. #118, Englewood, CO 80111 Aitken, Don Goodyear Tire & Rubber Co., Box 15256 Trontwood, Spokane, WA 99215 Alexander, Doug A C. W. Silver Co., Inc., 761 So. 7th, Grand Junction, CO 81501 Alison, David R Amoco Minerals Co., 6900 S. Yosemite St., Suite 150, Englewood, CO 80112 Alke, R. J Westinghouse Elec. Corp., 55 West 5th Ave., Denver, CO 80204]

Jan 1, 1981

By Y Chung, B Choi, H Lee

Numerous studies have explored refractory corrosion in the presence of slag and/or metal, utilising the Finger Rotating Test (FRT). Recent experimental results revealed that corrosion initially increased with rising rotation velocity but was then suppressed above a critical rotating speed, under conditions involving a two-liquid solution of slag and molten steel. This phenomenon indicated that the liquid/liquid interface movement occurred during spindle rotor. However, understanding of the phenomenon, known as the rod climbing effect, remains inadequate in the case involving slag, molten steel and refractories. To gain deeper insights, a simulation experiment was conducted on the phenomenon using silicon oil/water and the phenomenon was analysed using computerised simulation software (Ansys Fluent). Experimental modelling demonstrated that interfacial movement occurs even at low rotation velocity, as low as 200 rev/min, when the viscosity of silicone oil is at 100 cP. Computational analysis utilising the Volume of Fluid (VOF) method and a realisable k-ε turbulence model elucidated that interface elevation during rotor rotation arises due to viscosity disparities between the two fluids. Furthermore, this movement is more pronounced when the viscosity difference is lower. Additionally, the study findings suggest that higher density differences between two liquids suppress the phenomenon of interface movement.

Jun 19, 2024

By Mitsuru Tanahashi

In order to develop an effective process for the production of a solar-grade silicon (SOG-Si) from metallurgical-grade one (MG-Si), the oxidation removal of boron from molten MG-Si was investigated at 1773 K by the following two CaO-saturated CaO-CaF2 flux treatment processes. I) Boron removal by flux addition onto the molten MG-Si followed by oxygen gas injection into the melt (Two-stage connecting process). II) II) Boron removal by simultaneous injection of flux powders and oxygen gas into the molten MG-Si (Simultaneous injection process). These processes can establish the special condition of both high basicity of the flux and the high oxygen partial pressure at the boron removal reaction sites. Through these processes, especially by the simultaneous injection process using a flux powder injection equipment, the boron content in MG-Si can be efficiently reduced. The obtained results clarified that both processes should be conducted for a time period as short as possible by using as much flux as possible. By repeating the simultaneous injection process for 60 s three times under the optimum operating conditions determined in the present study, the boron content in MG-Si can be reduced from 14 to 4.7 mass ppm.

Jan 1, 2003

By D. Das, B. K. Nandi

The present study focuses on utilising the electrocoagulation (EC) process for the treatment of process water generated in an iron ore beneficiation plant for safe discharge and reuse. Removal of heavy metals like Fe, Cr, Cu, Zn, Mn and Pb which was found in higher concentration along with some other impurities exceeding the permissible and discharge limit were attempted. The influence of different electrode material, current density, inter-electrode distance, and solution conductivity was explored for effective removal of the metal ions. Experimental results infer that almost 99.95% Fe, 97.77% Cr, 73.44% Cu, 99.34% Pb and 88.69% Mn was removed using aluminum electrodes at monopolar mode at a current density of 68.50 A/m2, inter-electrode distance of 1 cm and solution conductivity of 1.033mS after 60 min of EC. In addition, removal of other toxins like TDS, turbidity, salinity and conductivity etc. was also assessed during the process. Removal of such heavy metal ions by EC was found to follow 1st order kinetics with electric energy consumption of 3.93 kWh/m3, electrode consumption of 0.1191 kg/m3 and operating cost of 0.6115 US$/m3 respectively. Keywords: Fe removal, electrocoagulation, Al electrode, turbidity

Jan 1, 2020

By Bastiawarman Rifki, Nugraha Nico, Priatna Anton

The Deep Mill Level Zone (DMLZ) is one of the underground mines operated by PT Freeport Indonesia (PTFI). DMLZ is located approximately 1,500 m below ground level, where dominant rock types are skarn and diorite. The DMLZ mine and layout was designed based on the previous mine located above ground, the Deep Ore Zone (DOZ). The DOZ mine, located approximately 1,000 m below ground level, was a proven success, with a maximum capacity of 80K tonnes per day. During the production ramp up, which started in 2015, the DMLZ experienced several seismic events. The most significant event occurred in January 2018 with a recorded magnitude of more than 2.0 Mw, which resulted in a 14-month delay of the undercutting until March 2019. The significant event in January 2018 required the DMLZ to apply several adjustments related to the mining plan to help ensure it could continue development and achieve production target safely. This paper will describe the changes in the DMLZ mine plan as a response to the seismic activity at the mine, the reason behind the decisions being made to change the mine plan and strategy, as well as strengths and weaknesses between the previous plan compared with the new plan.

Apr 26, 2022

By M. C. Ruiz

The conventional pyrometallurgical methods to treat copper sulfide concentrates include generally, one or more oxidizing steps where the formation of SO2 gas can not be prevented. From the economical point of view and the nature of some of the processes in which SO2 is produced, its complete capture is not feasible; therefore an important fraction is released to the atmosphere as fugitive emissions. In this research, the reduction of chalcocite was studied in the presence of lime as an alternative method, which overcomes the pollution problems related to SO2 emissions. The effect of temperature, time, concentration of carbon and CaO on the reduction rate were studied. Among these variables, temperature affects most the reduction rate. Conversions over 95 % can be obtained in less that 20 minutes at temperatures over 1000 ° C. The measured partial pressures of the gaseous components indicated that the chalcocite reduction proceeded through the gaseous intermediate species CO, C02, and the overall kinetics was controlled by the Boudouard reaction. The kinetic model In(1-X)= kt fits well the experimental data. Apparent activation energy of 3 14 kJ/mol was calculated for the temperature range of 900 0C-1050 °C.

Jan 1, 1999

By C. A. Heiland

THE investigations described were made on a portion of Clear Creek basin near Golden, Colo. (A portion of the area under survey is shown in Fig. 1. The photograph was taken in the vicinity of station No. 2 of Line II.) Three principal purposes were in the minds of the investigators: 1. To repeat with modern, more sensitive and more reliable instruments magnetometric placer investigations previously made. 2. To disprove the recently advanced theory that deposits of the glacial period have no pronounced magnetic effects. 3. To develop in detail the theory of the magnetic effects produced by placer deposits. Six years ago, the first magnetic observations were published, which proved that it is possible to locate gold-bearing channels with relatively crude instruments.1 Two years ago, K. C. Laylander published results obtained with similar instruments.2 The measurements of the latter were discussed by the senior author of this paper.3 At that time, however, the material available for such a discussion was somewhat scarce and not made with the most modern magnetic instruments, although very brilliant results were obtained. Therefore, the senior author felt that magnetic investigations should be made on very clear geologic conditions with the most modern instruments.

Jan 1, 1928

By D Preedy, J K. Claflin, S R. J La Brooy

This paper summarises the lessons learned during a recent carbon reactivation kiln upgrade project at the Sukari Gold Mine in Egypt. The kiln is being replaced to ensure that the plant achieves full value from the current throughput expansion from 5 to 10 Mt/a.The suitability of the original engineering design criteria for kiln selection and the adequacy of the original kiln are reviewed in the light of the carbon chemistry, operating experience and a site inspection of the kiln. Particular aspects of the reactivation facility are discussed including: predrying, preheating, feeding, gas seals, kiln heat transfer, steam injection, counter-current sweep gas flow, carbon cooling, fines minimisation and removal.Design criteria for a carbon predryer, reactivation kiln and cooler combination for carbon heavily fouled by high molecular weight frothers and collectors are discussed and the abridged Ausenco datasheet for the combination is presented.Responses to a request for a budget price sent to most of the worldÆs suppliers of carbon regeneration kilns are summarised.CITATION:Claflin, J K, La Brooy, S R J and Preedy, D, 2013. Ausenco carbon reactivation design criteria, in Proceedings World Gold 2013 , pp 401-410 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By N Kojola, A Vickerfält, J Huss

The possibility of using an acidic autogenous hydrogen direct reduced iron (H-DRI) slag as a basis for vanadium extraction is investigated. For a raw material to be suitable for producing high-quality FeV, the vanadium oxide content should be sufficiently high and the phosphorus oxide content in a tolerable range. Therefore, the feasibility for vanadium extraction relies on fulfilling two demands: the predominate partitioning of phosphorus to the metal and vanadium to the slag. Correspondingly, the behaviours of phosphorus and vanadium in the Al2O3-SiO2-FeOx-VyOz-P2O5-Fe system were studied experimentally. Slag, 10 g, was put in contact with liquid iron, 30 g, for different durations (2–24 hrs) in closed alumina crucibles at 1873 K. The slag composition was varied between 33.1– 49.3 wt per cent Al2O3, 27.1–46.7 wt per cent SiO2, 16.6–30.1 wt per cent FeOx, and 2.5– 8.8 wt per cent V2O3. The equilibrium phosphorus distribution was 0.42, while the vanadium distribution ranged from 7.6 to 43.4, increasing with the Al2O3- and the FeOx-content.

Jun 19, 2024

By Robson Gambeta

A CLE Brasil possui uma subestação de 230kV que apresentou sérios problemas de trincas e rachaduras nas estruturas de concreto após alguns anos. Em alguns pontos a ameaça de queda era real. Foi iniciado um estudo de patologia das estruturas de concreto, com uma empresa especializada em recuperação estrutural para conhecer as causas e recomendar a melhor terapia estrutural a ser realizada. Após o estudo, definiu-se a terapia adequada das estruturas. Esta atividade foi classificada como de grande risco e teve foco na segurança da equipe e operação do sistema, de modo que todo o serviço fosse executado sem quaisquer incidentes as pessoas, ao meio ambiente e ou interrupções de energia elétrica. Havia desafios como realizar manutenção nas proximidades da linha viva, serviços em altura com utilização de andaimes, período de chuvas e ventos, trocas de equipes e anomalias. As estruturas tratadas foram Pórticos com 17 metros de altura, postes e suportes para isoladores, TPs, TCs, Seccionadoras e Transformadores. A atividade durou 04 meses e contabilizou 5.752 horas de trabalho. Os resultados foram significativos e dentro do esperado, sem ocorrência de incidentes, prolongamento da vida útil e aumento considerável da segurança da equipe e do sistema de distribuição.

Jul 31, 2018

By Steve Davidow, Scott Tunison

As the demand for electric power grows and generation facilities are constructed in more remote areas, the industry faces an increasing number of foundation construction challenges. The importance of quality geotechnical information prior to construction is accentuated by the linear nature of the projects and the potential for drastic changes from one end to the other, but is often difficult or unfeasible to obtain. Alignments are crossing remote, rugged and/or environmentally protected terrain, and completing a comprehensive geotechnical program is made challenging from an access or economic standpoint, or both. In these situations, the industry needs a flexible foundation alternative. This paper will present micropiles as that alternative and demonstrate how the implementation of micropile foundations mitigated these challenges on the Koolau-Wailupe 46 kV Circuits in Oahu, Hawaii, which involved rugged, steep slopes and helicopter construction methods. It will detail the selection of micropiles over other foundation options, micropile and steel pile cap design methodologies, foundation construction, and quality control. Special attention will be given to the unique geology in the area, and why precise identification of saprolite and basalt layers was integral to the successful performance of the foundations. The intention is to communicate the benefits of a flexible solution based on continuous collaboration between design and construction.

By Michael S. Wieland

The work-principle from thermodynamics was used to formulate a model for predicting toxic fumes from mining explosives in underground chamber tests, where rapid turbulent combustion within the surrounding air noticeably changes the resulting concentrations. Two model constants were required to help characterize the reaction zone undergoing rapid chemical transformations in conjunction with heat transfer and work output: a stoichiometry mixing fraction and a reaction-quenching temperature. Rudimentary theory with an unsteady uniform concentration gradient was taken to characterize the combustion zone, yielding 75% for the mixing fraction. Four quenching temperature trends were resolved and compared to test results of ammonium nitrate compositions with different fuel-oil percentages (ANFO). The quenching temperature 2345 K was the optimum choice for fitting the two major components of fume toxicity: carbon monoxide (CO) and total nitrogen oxides (NOx). The resulting two-constant model was used to generate comparisons for test results of ANFO compositions with additives. Though respectable fits were usually found, charge formulations which reacted weakly could not be resolved numerically. The work-principle model yields toxic concentrations for a range of charge formulations, making it a useful tool for investigating the potential hazard of released fumes and reducing the risk of unwanted incidents. Keywords: Toxicity; Fumes; Explosives

By J. C. Nigro

Hematite-to-magnetite reduction kinetics were investigated mainly in CO-CO2 atmospheres at temperatures ranging from 500° to 1,000° C. Reduction rates were measured with a thermobalance, which recorded the weight loss as the specimen was reduced. Reduction data on both synthetic and natural hematite spheres showed good linearity of ro [1-(1-R)1/3] with time, t, up to over 85 pct conversion to magnetite; the rate coefficient (k[L], cm/min) obtained from the linear portion of the plot was used to characterize the penetration rate of the hematite-magnetite interface. Gas composition, porosity, and silica content were major factors affecting the rate. Temperature dependency of the reaction rate was small, yielding a mean activation energy of about 3 kcal/mole. Silica additions increased the reaction rate, probably through an increase in the effective surface area and diffusion; however, above 900° C, silica can react to form fayalite. Experimental data showed that the linear thickening rate of the magnetite layer, normally evidence of a chemically controlled reaction, can also be indicative of a reaction controlled by both mass transfer and diffusion. Evidence from this study indicates that the dominant rate-controlling factor in the reduction of hematite to magnetite at high temperatures is transport in the gas phase.

Jan 1, 1973