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By K. Biswas

For the pillars, which have been standing long after mining, the stability depends much on the weathering action in the presence of mine moisture. From the field observations, it has been found that this weathering action becomes critical in terms of pillar stability if the coal seam contains partings or binders in it. The weathering action degrades both the partings and coal in terms of their load bearing capacity as the mine moisture penetrates into them. This paper investigates the effect of weathering action on coal and partings in the laboratory. In the field, the strength profile in the coal and the partings and the effect of time (in terms of the pillar age) on them have been studied by using borehole penetrometer. In this paper, an attempt has also been made to establish formulae for time dependent strength of coal and partings.

Jan 1, 1997

By Prashanta K. Chatterjee

The planning of an underground coal mine requires a complex blend of technical expertise, experience and subjective design criteria implemented by the mining engineer. Currently the procedure is largely manual and requires considerable resources to generate a single mine plan. Often three or four people are assigned to work in the development of a single draft layout. Evaluation of the layouts is also tedious as it requires many repetitive calculations. The evaluation of layouts developed manually generally attempts to derive a single economically feasible solution. Operational constraints in underground coal mining such as manpower, time, equipment, etc, do not allow the generations of more than one alternative layout. As a result, the first plan is generally the only one considered. Computer-aided mine planning can automate many of the manual procedures and calculations involved in mine planning thus allowing to evaluate many layouts and mining strategies and to select the optimum plan with confidence. An optimized planning procedure will also provide the capability to evaluate mine performance continuously and critically, thereby helping to maximize return on investment.

Jan 1, 1986

By K. V. Raj, T. Bhowmick

"Computational fluid dynamics (CFD) modeling of an open-pit mine has several challenges. A good quality mesh of the model domain is a pre-requisite for convergence in solution. Good quality tetrahedral meshing and insertion of prism layers in faceted open-pit mine geometry is complicated due to presence of numerous vertices and ridges. Presence of vertices and ridges result in poor quality tetra elements and holes in prism layers, which cause instability in the model. Good quality pit bottom prism mesh elements significantly improve the formation of velocity boundary layer and thermal boundary layer at the pit bottom. This results in an expected temperature dependent micrometeorological buoyancy flow in the pit. Whereas, model geometry without a prism layer, results in abrupt temperature gradient near pit bottom. Buoyancy flow and recirculation have significant effect in lifting mechanism of fugitive dust particles generated near pit bottom. Representative initial and boundary conditions and selection of appropriate turbulence model have significant influences on the simulation results. In this paper, three-dimensional models of open-pit mines are developed using commercial CFD software (CRADLE-CFD). Important constraints and various consequences in modeling complex open-pit geometries are presented. INTRODUCTION Application of Computational fluid dynamics (CFD) to model an open-pit mine to predict fugitive dust and pollutant concentrations in and around a mine is relatively new. In former Soviet republic (USSR), Baklanov [1] and Belousov [2, 3] presented numerical models of pollutant transport in open-pit mines in Arctic regions. In recent years, advances in mathematical and computational fields have enabled better modeling of pollutant dispersion phenomenon around mines using computational fluid dynamics (CFD). Several CFD software packages have been used by various researchers to model the pollutant transport in open-pit mines. Works by Alvarez et al. [4]; Lowndes et al. [5]; Silvester et al. [6]; Torno et al. [7]; Choudhury and Bandopadhyay [8]; Collingwood et al. [9]; Raj et al. [10] and Flores et al. [11]; are examples of application of various commercial and open source CFD packages (COMSOL, ANSYS, OpenFOAM) to model pollutant transport in open-pit mines. These researches provided a strong background for additional research involving CFD modeling of open-pit mines. Due to the limitations of computational times and capacity, 3D modeling and various aspects of fugitive dust dispersion in open-pit mines remained unexplored."

Jan 1, 2015

By Y. M. Jubeli

"Gamma-ray spectrometry, an effective tool in geological mapping, was used to de?ne boundaries between various lithological formations in three adjacent areas of Central Syria, namely, the Syrian Desert, Ar Rassafeh Badiayat and the Northern Palmyrides mountains.This paper describes the role of an airborne gamma spectrometric survey which was originally undertaken to assist uranium exploration. Interpretation of the total count data obtained through the survey has led to signi?cant modi?cations and corrections to the previously published distribution map of the palaeogene phosphate rocks.Another important result of the survey is the discovery of four previously unknown phosphorite horizons in the Rasm Al-Aawabed area of the Northern Palmyrides. In addition, previously unknown phosphatic horizons are outlined in the other study areas. The importance of this technique as an effective prospecting method, not only for U but also for exploring for the economically important phosphorite formations in Syria, is emphasized. Furthermore, its role in geological mapping is stressed, especially in areas that lack suf?cient geological data."

Jan 1, 1997

By I T. Cameron

The commercial production of copper metal involves a sequence of purification stages. One step of this process eliminates bulk quantities of iron and sulphur from matte Cu2S(FeS to produce blister containing 95.5 per cent copper. This task is traditionally performed in the Pierce-Smith converter, a cylindrical vessel in widespread use throughout the copper industry. Typically, multiple Pierce-Smith converters are arranged along an aisle, simplifying material transfer from vessel to vessel. Materials are moved through the aisle in pots and boats, using overhead cranes. In terms of the overall process, the converter aisle represents a critical processing unitùit contributes significantly to the value added nature of the metal. The aisle is subject to significant process disturbances. Thus, improvements in the operationÆs modes and conditions have a direct impact on process profitability. As with any commercial operation, improvements are always sought to increase process performance. The general approach involves process modelling, followed by an application of control and optimisation theory to this model. The results of such a study are then applied to the real process, leading to improved performance.

Jan 1, 1998

By Harvey P. Knudsen

This paper illustrates the application of geostatistics to a roll front type uranium deposit located in Wyoming. The steps involved in calculation of experimental variograms, variogram modeling and verification of the resulting models are described in detail. The resulting spherical variogram models for grade thickness and thickness show strong geometrical anisotropies. The major axis of anisotropy for both variables is approximately parallel to the axis of the roll front and the minor axis perpendicular to the roll. This model confirms the technique of drilling "fences" across the roll front, where the drilling is much closer together than the fences along the roll.

Jan 1, 1978

By S. Ozbilen, B. Erdogan, M. Erdogan

To study by thermal analyses the response of precipitation hardenable alloys of Al-Cu-Mg and Al-Li-Cu-Mg system to natural and artificial ageing, a series of ternary and quaternary Al-alloys with nominal compositions of Al-l.13wt%Cu-0:65wt%Mg (alloy-I), Al-1.15wt%Cu-0.57wt%Mg-0.07wt%Li (alloy-2), Al-l.19wt%Cu-0.56wt%Mg-0.75wt%Li (alloy-3), Al-2.0lwt%Cu-0.89wt%Mg (alloy-4), Al-2.14wt%Cu"0.56wt%Mg-0.07wt%Li (alloy-5) were used in the present investigation. Samples in the form of rolled sheets are subjected to water quenching at 25EC after solution treatment at 530EC for 20 min. Alloys were aged naturally at room temperature (25EC) up to 2 months and artificially at 190EC up to 2 days. By using differential scanning calorimetry (DSC) in the temperature range of25-300EC, differential thermal analysis (DTA) in the temperature range of25-600EC together with Vicker's hardness measurements, the response to natural and artificial ageing of the alloys used in the present study were investigated. It was observed that in these alloys, GPB(Cu, Mg) zones [Guinier-Preston zones with Cu and Mg] do form during water quenching at 20EC following solutionizing heat treatment. Natural ageing of the same alloys causes formation of more GPB(Cu, Mg) zones, which results in hardening in the alloys. Artificial ageing at 190EC up to l day results in GPB zone dissolution causing preliminary decrease in hardness values while two days of artificial ageing in the alloys cause S' (Al2CuMg) precipitation confirmed by DSC/DTA analyses resulting in an increase in hardness values. Li addition up to 0.75wt% helps T1 (Al2CuLi) and T 2 (Al6CuLi3) phase formation together with S' precipitation as DSC/DTA analyses show after the same heat treatment.

Jan 1, 1998

By W. A. Zingg

Impervious zones in copper waste heaps create a problem in contacting the rock with leaching solutions. These zones are normally associated with compacted layers .formed on the surface of each lift by dump truck traffic and by disintegration of the rock exposed to atmospheric conditions. These layers are usually only a few feet in depth--but, nevertheless, act as barriers to vertical flow causing the leach solution to perch in the heap, Consequently, much of the rock remains untouched and the leach solution breaks out the side of the heap instead of continuing downward to bedrock. One solution to this problem is breaking the hard pans with explosive charges. However, to use explosives means adopting new explosive materials and methods. To use this process successfully requires finding answers to operating conditions inherent to waste heaps. Foremost among these are: (1) type and size of casing that can be used because of limitations brought about by drilling problems, caving and, corrosive conditions; (2) perforating the casing at required levels; (3) an explosive capable of being pumped; (4) obtaining detonation of the, main charges through, the wail of the casing; (5) an explosive with the ability to propagate through the voids of the rubble and one which is not affected by water, acidic solutions, or back pressure conditions from hydrostatic heads; (6) to heave and rupture the compacted zones without chambering or recompressing the waste material.

Jan 1, 1970

By T. Fekete, D. L. Flocks, R. T. Hart

The plugging effect of bacteria was investigated by injecting various concentrations of dead bacteria cells though sandstone cores. Pressure profiles along the cores were recorded periodically during the injection cycles. The plugging effect was analyzed using a plot of the ratio of reduced permeabilities to the initial permeability versus input volume. Results indicated that Tock permeability has little effect on plugging, but that the concentration of bacteria in the injection water has a significant effect on plugging characteristics. The pressure profile curves showed that bacteria penetrated several inches through the core but that the greater portion of the bacteria accumulated at the in-put end of the core.

Jan 1, 1960

By J J. L du Plessis, S Viviers, G Ratner

Escalating electricity costs are one of the biggest operational cost drivers in mining. The trend to use high-powered auxiliary fans delivering increased airflow to meet the dilution requirements of diesel equipment, together with the reliance on ducted systems rather than traditional flow-through systems to ventilate areas, increases the overall energy requirements of ventilation systems. To manage and reduce electricity costs energy management systems can be implemented, inefficient operating units can be replaced and the operation of energy-consuming components of ventilation systems can be optimised.This paper describes the process followed to design and develop an energy-efficient axial flow auxiliary fan. The fan-targeted design was based on static pressure and volume flow rate requirements incorporating higher overall fan efficiencies. A brief overview of the results is given, including the aerodynamic design procedure using computational fluid dynamic (CFD) analysis. The mechanical design criteria used, including stress analysis on the rotor and designs to improve the vibration levels of the fan, are also presented. Through this study it was demonstrated that the aerodynamically designed rotors using profiled and twisted blades improve the total fan efficiency considerably when compared with some of the older-generation fans using cambered plates. The latter were typical in the mining sector in South Africa at the time of the study where average overall fan efficiencies of standard cambered fans less than 63 per cent and some of the older-generation cast aluminium blades have peak overall fan efficiencies of about 65 per cent. Peak overall fan efficiency of more than 80 per cent was achieved by using the described design and development process. Additional benefits are that the fans are quieter due to the better aerodynamic design and have a longer operating life due to reduced vibration levels.In conclusion, the use of CFD to develop fans to deliver the required volume flow at the required pressure allows quicker design turnaround time. It furthermore allows the ventilation engineer the option to specify a specific fan and is not limited to an off-the-shelf catalogue fan. It thus allows engineers to purchase a fit-for-purpose energy-efficient fan. The introduction of reliable fan control systems may, however, still result in the biggest cost benefit for underground mines.CITATION:du Plessis, J J L, Ratner, G and Viviers, S, 2015. Design and development of energy-efficient secondary axial flow fans, in Proceedings The Australian Mine Ventilation Conference, pp 337–344 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By Y. Champoux, N. Atalla, R. Oddo, C. Lesage

"Percussion drills are the source of the most serious noise problems in mining activities, due to their extremely high noise levels(114-122 dB(A)) and widespread use(Bartholomae and Stein, 1988). Percussion drills will continue to be widely used to drill small diameter holes in hard rock because no other method seems to be economically avail-able to replace them (Boillat et al., 1993).Many studies (Danière, 1991; Hawkes etal., 1977a; Jensen and Visnapuu, 1972;Leblond et al., 1976; Milette, 1989) were con-ducted to determine the major noise sources of percussion drills. The exhaust air of pneumatic drills, the hammer, the bit in contact with the rock and the drill rod have been identified as the major noise sources. A muffer can be used to reduce the exhaust noise and the hammer can be enclosed. The bit noise is considered to be of concern only at the beginning of holes. When all the available methods are used to reduce the noise of a percussion drill, the drill rod vibrations become the dominant noise source (Hawkes and Burks, 1979). However, the noise levels generated by this source remain high and future efforts should concentrate on reducing its radiation.Works by Hawkes and Burks (1979) and Hawkes et al. (1977b) for the U.S. Bureau of Mines provide the most complete description on the noise and vibration of percussion drill rods.The longitudinal and bending waves are the two most important types of elastic waves generated in drill rods. Among these, only the longitudinal waves contribute to the drilling rate. The bending waves are caused by non-centralized impacts, drill rod curvature and non-uniform bit/rock interface. Drill rod noise is generated by Poisson’s ratio expansions and contractions of the rod as the longitudinal waves travel up and down it and by transverse rod motions induced by bending waves. The radiation efficiency is much higher for bending waves than for longitudinal waves. Most of the impact energy is transformed into longitudinal waves, as expected for axial impacts. The evaluation of the relative contribution of longitudinal and bending waves to noise generation poses a very difficult problem for experimental, analytical and numerical approaches. It is, however, an important issue because the relative contribution of these two waves will guide future noise reduction efforts. It seems that very little can be done to reduce the noise radiation of the axial waves without affecting the drilling rate. The main difficulty that analytical and numerical approach-es face, in the evaluation of the relative contribution of the two waves, is that there is no adequate theory for predicting the bending vibrations from the factors that cause them. The experimental approach has, thus, been limited to test fixtures that do not adequately represent the boundary conditions, as well as by measurements obtained under real operating conditions from which it is difficult to establish the relative contribution of the two types of waves. For example, Hawkes and Burks (1979) and Hawkes et al. (1977b) used a test fixture with free-free boundary conditions and made no clear link with measurement under real operating conditions. Rather, they have based their discussion on a simple model. Many authors assume that fexural waves are the main noise source on drill rods. However, measurements have been somewhat contradictory and researchers are still unable to state with certainty that this is indeed the case (Lednik et al., 1988)."

Jan 1, 1997

By P Hatherly, H Gurgenci

With the depletion of the mineral reserves that can be mined by surface mining, demand for highly productive and safe underground mines will increase. Underground drill and blast techniques continue to be refined but true æmass productionÆ is difficult to achieve. As is evidenced by the longwall mining of coal, alternative mining methods based on mechanised mining can meet the expectations but the issues of how to effectively cut strong rocks, how to define the orebody and how the mechanised miners can be automated and maintained all need to be addressed. CMTE is working in all of these areas. We believe that the oscillating disc cutter may provide the long sought-after breakthrough in mechanised rock cutting. Disc cutters are one of the most robust designs of cutting tool and the cutters attack the rock in a manner which effects direct tensile breakage. The internal cutter drive and the inertial damping mean that the already low cutter forces are not all transmitted back to the machine, making it possible to design lightweight, flexible mining systems. For orebody delineation drill monitoring, drillhole logging and geophysical imaging are key procedures being developed at CMTE. To automate mining machines, work is progressing well in the development of systems for autonomous vehicle navigation and mining robotics. A strategic contribution to maintenance issues is being made through the development of procedures for automatic analysis of used oils, monitoring the strength of mechanical structures, and operating point optimisation.

Jan 1, 1998

By J. Kemeny, R. Fuentealba, C. Rodriguez, F. Fernandez, M. Rocha, T. BoBo

"Mathematical modeling in conjunction with mineral characterization is widely used as a method for design and optimization of comminution circuits, to simulate the processes of crushing, grinding and classification. An important input parameter to the simulation models is the Run-of-Mine Particle Size Distribution (ROM PSD). The run-of-mine size distributions due to blasting have a great influence on the performance of a semi-autogenous grinding (SAG) mill. In this paper, a mine case study was conducted where there are four primary geologic units and the material properties between the four units vary considerably. Also, the mixture of the four unit that will be mined at any given time also vary considerably. This presents a challenge in terms of optimizing the blasting for mill production throughout the mine life. As part of the case study, field rock mass characterization, laboratory rock mechanics tests, and laboratory breakage tests were conducted. The field characterization and rock mechanics tests provide material properties used to simulate the effect of different blast designs on run of mine particle size distributions (ROM PSD). The JKSimBlast software was used for these simulations. The rock breakage tests provide material properties used to simulate crushing and grinding performance. The JKSimMet software was used for these simulations. The goal of the mine is a mill throughput of 95,000 tonnes (104,720 tons) per day (TPD). Based on this goal, run-of-mine fragmentation analysis was conducted for four blasting designs resulting in powder factors of 0.44, 0.54, 0.64, and 0.94 kg/t. The powder factor of 0.44 represents a standard blasting design, while the 0.54 and 0.64 kg/t designs are high-energy blasts specifically to assist with mill production. The 0.94 kg/t design was investigated for the one geologic unit with very high strength. The results of the run-of-mine fragmentation analysis was then input into a crushing and grinding simulation model to predict the mill throughput for the time periods of 1-5 years and 6-10 years. The results indicate that certain blast designs are able to achieve the 95,000 tonnes TPD (104,720 tons TPD) goal, while other blast designs were not. A standard blast design with a 0.44 kg/t powder factor, for example, was not able to achieve the throughput goal, while a design with a 0.64 kg/t powder factor was able to achieve the goal in both the 1-5 and 5-10 year time periods. INTRODUCTION In recent years, mathematical modeling in conjunction with mineral characterization has been widely used as a method for the design and optimization of comminution circuits. The Run-of-Mine Particle Size Distribution (ROM PSD) is a function of rock properties and design parameters of the blast and has a significant impact on the crushing and grinding treatment circuit. Traditionally, design of the grinding treatment is estimated using only the F80 value instead of the full distribution of sizes in the feed, but the finer sizes have great influence on the treatment of a grinder, particularly in the SAG mill."

Jan 1, 2015

By Varadarajan Seshadri

The performance of mould fluxes in satisfying its quality requirements can have a significant effect on the efficiency of the continuous casting process and on the surface quality of the products. This performance is affected by various parameters including the characteristics of the mould fluxes, the quality of the steel being cast and the operational conditions of the caster. The extremely complex relationships involving the parameters mentioned above make it very difficult to have simple criteria for selecting mould fluxes for casting a certain grade of steel in a continuous casting machine. These difficulties led steelmakers and mould flux suppliers to select mould fluxes based mainly on plant trials. In the present work, a software to help in the analysis and development of mould fluxes for continuous casting was developed_ This software includes several models for prediction of mould flux viscosity and consumption. A mathematical model was also used to predict the heat flux through the mould flux. The proposed methodology was applied to continuous casting of crack sensitive steels_ Some of the results given by this software are presented, discussed and compared to plant data.

Jan 1, 2003

By Knox Van Dyke, Vincent Castranova, Lixin Wu, Mark J. Reasor, James M. Antonini

"One of the proposed mechanisms involved in the pathogenesis of silicosis is that inhaled silica dust activates a ""respiratory burst"" in pulmonary phagocytes, such as macrophages and neutrophils. This increase in oxidative metabolism results in enhanced generation of reactive oxygen species which if produced in excess, would overwhelm natural defense mechanisms and cause damage to the lung parenchyma. This damage would then result in scarring, fibrosis, and decreased gas exchange.Weiss and LoBuglio' have listed several oxygen species produced by phagocytes which may be involved in cellular injury. These oxidants include superoxide anion, hydrogen, peroxide, hydroxyl radical, and hypochlorous acid. Superoxide anion (0;) is generated from molecular oxygen by the plasma membrane bound enzyme NADPH oxidase according to the following reaction:Once generated, superoxide anion can form hydrogen peroxide:In the presence of myeloperoxidase and halide, hydrogen peroxide can form hypochlorous acid:Superoxide and hydrogen peroxide can also form highly reactive hydroxyl radicals. Hydroxyl radicals can be generated slowly by the Haber-Weiss reaction:In addition. hydroxyl radical production can be catalyzed via the Fenton reaction:Hydroxyl radicals can also be generated from the reaction of superoxide and hypochlorous acid as follows:Recent investigations suggest that, in addition to the reactive oxygen species discussed above, nitric oxide may be a potential mediator of silica-induced toxicity.2-4 Nitric oxide (NO') can be generated by the cytosolic enzyme nitric oxide synthase according to the following reaction:NO synthase exists in two forms. i.e.. a constitutive. Ca2+-calmodulin-dependent form and an inducible. Ca2+-calmodulin-independent form. In pulmonary phagocytes. the activity of the constitutive form of NO synthase is low. However. NO synthase can be induced in macrophages and neutrophils by a variety of stimulants such as lipopolysaccharide. interferon y. chemotactic peptide, platelet activating factor, or leukotriene B4.3.5Once generated. nitric oxide can combine with superoxide anion to form peroxynitrite as follows:Peroxynitrite is a potent oxidizing agent. In addition, peroxynitrite can form peroxynitrous acid. which in turn can produce hydroxyl radical and nitrogen dioxide (all of which exhibit strong oxidizing potential) by the following reactions:Oxygen metabolites have been shown to cause lung damage in vivo.6 Such damage includes edema. leakiness of the alveolar endothelial/epithelial barriers, and airway constriction.7 Superoxide and hydrogen peroxide have been associated with membrane damage and cell lysis.8 These oxidants have also been associated with alteration of cytoskeletal structures at cell-cell junctions and elevation of transepithelial conductance in cultured monolayers.9 Macrophages or neutrophils can be stimulated by bacteria or phorbol myristate acetate to produce sufficient oxidant levels to lyse lymphoma cells.10 This cell killing is inhibited by catalase but is unaffected by superoxide dismutase. hydroxyl radical scavengers. or azide. i.e., an inhibitor of peroxidase. This implicates hydrogen peroxide as the active oxidant. Similarly. Weiss et al.11 have reported that hydrogen peroxide is critical in the death of cultured endothelial cells due to neutrophil activation. In addition. hydroxyl radicals generated by monocytes have been associated with cell injury.12 Lastly. peroxynitrite has been shown to oxidize sulfhydryl groups and to inactivate proteinase inhibitor making the lung more susceptible to damage caused by phagocytotic enzymes.' Therefore. a strong case can be made that activated pulmonary macrophages and neutrophils are capable of causing oxidant injury. This chapter presents in vitro and in vivo data indicating that silica is associated with the production of reactive oxygen species from these pulmonary phagocytes."

Jan 1, 1998

By George P. Tateosian

Merchants perform a number of functions in the copper market. As a major distribution arm of the copper industry, they secure scrap and other copper bearing materials for processing into usable refined shapes. These are ultimately sold to fabricators. Merchants ' hedging and arbitrage activities help keep values in proper relationship from product to product or region to region. Through these switching and trading operations, they optimize the flow of copper from mine to consumer. And finally, merchants act as a repository for copper units during times of surplus and a stockpile from which to draw during tines of shortage.

Jan 1, 1979

By J. Seiter

Mining has always been among the most hazardous of occupations, and with the increasing demand for coal and minerals, safety in mines assumes even greater importance. Worldwide, underground miners are being exposed to noise and respirable dust hazards associated with roof bolt drilling. These hazards are now being understood to cause irreparable damage to the health of miners. The objective of this research was to discover if a Polycrystalline Diamond Cutter (PDC) drill bit generates less respirable dust and hazardous noise than a competing Tungsten Carbide (WC) bit, in dry vacuum drilling. In order to control the drill parameters the drilling tests have been conducted in a laboratory setting. The results were met by determining the quantities of dust and noise generated using each drill bit and analyzing those levels by using monitoring devices and software to collect the data. This paper includes information on experiment setup, equipment used, drilling parameters, and data collected. The test results suggest that there are noticeable trends that the PDC bits produce less dust than WC bits but more testing is needed to substantiate these trends.

Feb 23, 2014

By E. Ilgar

"Deposition studies were conducted in acid copper electrolyte to determine the influence of chloride ions on cathode morphology. A statistically designed screening test was carried out in the absence and presence of 20 ppm CI- using a three factor, two level factorial design, in an electrolyte containing 36 gl'! Cu2+ and 150 gl-! H2S04, The independent variables evaluated were agitation; current density and temperature and their influence on surface roughness was determined. The copper deposited at current densities where activation was the primary control mechanism appeared similar in morphology whether stirring was used or not. The addition of 20 ppm CI- to the electrolyte gave rougher deposits under the same conditions. In the mixed control regions, considerably rougher, dendritic deposits were obtained when CI- was present. Agitation was effective in reducing the copper surface roughness both in the apparent activation and mixed control regions in the presence ofCI-. The results of this study showed that 20 ppm Cl- polarized the copper deposition at low overpotentials but caused depolarization at higher overpotentials.IntroductionChloride ion is inherently present in copper electrolyte, either as an additive or from other sources such as make up water. The behavior of the chloride ion is well documented in electrorefining operations, but its role in copper winning is less obvious. However in both cases there is evidence that cathode growth and solution chemistry are strongly influenced by its presence. The mechanism and electrochemical action of the Cl"" have been shown to be very complex, therefore a better understanding of its influence on electrocrystallization is essential for improved cathode deposit growth control. It was proposed that Cl"" polarizes the copper deposition reaction at low concentrations due to CuCI formation but depolarization occurs at higher concentrations due to the formation of a soluble CuCI2"" complex [1,2]. Franklin [3] reviewed the mechanism of additives in the electrodeposition process and proposed that the Cl"" complexed with copper, adsorbed on the cathode as an induced anion leading to an increase in the reduction rate. At cathodic overpotentials less than 100 mY, lppm NaCl had a polarizing effect, i.e. an increase in impedance of the charge transfer step. At higher Cl"" concentrations up to 100 ppm, depolarization occurred as evidenced by a decrease in impedance, which was attributed to soluble cuprous complexes [4]."

Jan 1, 1997

By Bror Nyrnan

Solvent extraction technology and equipment have been developed within Outokumpu since the early seventies. During this period altogether nine solvent extraction processes for molybdenium, zinc, rhenium, cobalt, nickel, calcium and magnesium have been commercially adopted in Outokumpu's metallurgical plants. During last years a new mixer-settler concept based on a "Vertical Smooth Flow" (VSF) principle has been developed. It has also been found to be a good method for copper solvent extraction, decreasing essentially the crud formation and the organic and aqueous entrainments.

Jan 1, 1994

By K. C. Dean

A flotation method was developed by the Bureau of Mines for concentrating pollucite, a cesium-aluminum-silicate mineral that may contain from 20 to 40 percent cesium oxide. Separation of the pollucite from three typical ores was achieved by froth flotation of the associated micas, feldspars, and other gangue minerals, using sulfuric and hydrofluoric acids and a cationic-type collector. A low-tenor, 8 percent cesium ore from Maine was upgraded to 20 percent cesium with recovery of 87 percent of the cesium. Relatively high- grade ores from Canada and Southern Rhodesia were beneficiated at lower ratios of concentration to 28 and 29 percent cesium content respectively with recovery of over 92 percent of the cesium. In addition to concentrating the cesium content of ores, the method also effectively separates cesium from sodium, potassium, and lithium, and in certain ores from rubidium. This is accomplished by selective froth flotation of the alkali metal-bearing gangue minerals such as lepidolite, other micas, and feldspars. Since the alkali metals, especially potassium and rubidium, are difficult to separate chemically or thermally from cesium to prepare high- purity cesium products, separation by physical mans is important.

Jan 1, 1962