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By Evan J. Owen, Virginia T. McLemore

Rare earth elements (REE) and critical minerals are increasingly becoming more important in our technological society and are used in many of our electronic devices (such as cell phones, computer monitors, wind turbines, etc.), batteries, and magnets. Measuring REE and critical minerals in ashed coal approximates the REE and critical minerals in the fly or bottom ash remaining after coal is burned at a power plant, where REE and other critical minerals could be leached. In New Mexico, there are 26 coal fields in Late Cretaceous rocks in the San Juan and Raton Basins. These rocks are being characterized as part of the DOE’s CORE-CM (Carbon Ore, Rare Earth, and Critical Minerals) program. Higher concentrations of REE (as much as 2103 ppm total REE) are found locally in ashed coals from the basins. More chemical and mineralogical analyses are required to fully understand the distribution and origin of REE in these deposits. As the demand for REE increases because of increased need and short supplies, the dollar value per ton of ore rises, enhancing deposit economics, perhaps even from coal.

Feb 1, 2025

By E J. Hill, F Huang, A Otto

Geochemical data from drill core samples is used in mineral exploration to enable geologists to understand subsurface geology. However, it is challenging to analyse these data sets rigorously and consistently. Manual data interpretation relies on the knowledge and experience of logging geologists. When multiple geologists are involved, it is possible to introduce inconsistencies in logged lithology type and scale of logging (‘splitters’ versus ‘lumpers’). Machine learning (ML) is a powerful tool for analysing high dimensional data (ie data with many variables) and large data sets (ie data with many samples). However, ML methods applied to drill hole samples do not incorporate spatial information and this can result in high misclassification rates and small-scale ‘noisy’ results. We demonstrate the use of multiscale spatial analysis (wavelet tessellation) as a pre-ML step to analyse spatial information. This step helps reduce misclassification and filter out unwanted small-scale variation in the data. In an experiment, we used wavelet tessellation and supervised ML to predict litho-geochemical rock types from geochemistry data. The data set is from the Valhalla uranium deposit near Mount Isa, northern Queensland. First, geochemical knowledge and statistical analysis was used to select appropriate geochemical elements for litho-geochemical classification. Second, the elements were processed using multiscale spatial analysis. Third, we trained a Random Forest model with the data set and found that the model performs worse in predicting rare rock samples than common ones. We applied over-sampling and down-sampling methods in aim to overcome this issue. As a conclusion, the combination of multiscale spatial analysis (to define rock unit boundaries) and Random Forests (to classify rock units) is a good method for rapid and accurate analysis of drill hole geochemistry.

Mar 22, 2022

By K Ilamparuthi, R. K. Madhumathi

"This paper presents the results of 1g model tests conducted on model piles both single and two pile groups embedded in sand by physically inducing lateral soil movement. From the test results it was found that the pile with higher L/D ratio exhibits higher deflection in case of pile embedded in medium dense sand whereas in loose sand the response is vice versa with higher deflection for the pile of lesser L/D ratio. The induced bending moment in piles is more for longer piles than shorter piles irrespective of the density of sand bed. It is also found that the pile head deflection and the bending moment are found to decrease exponentially with increasing distance between the pile and the wall. For pile group arranged in a row parallel and perpendicular to retaining wall, the deflection of single pile is more than the deflection of two pile group irrespective of the depth of excavation for spacing of piles tested. The influence of soil movement on the lateral response of pile is also analyzed through 3-dimensional finite element analysis. The numerical results thus obtained are validated with the results of experiments. The Mohr-Coulomb material model adopted to represent the soil behaviour predicts the response of pile reasonably and compares well with the experimentally observed response.INTRODUCTIONPile foundations are adopted to support structures such as foundations of high rise buildings, transmission towers, offshore platforms, bridge abutments etc., when good bearing stratum is not present at shallow depth to bear the loads of these structures. In the recent past particularly in the urbanized areas structures are built close to one another and nearby excavation will cause a reduction of lateral earth pressure and soil movement behind the retaining wall (Ong, 2004). The reduction in support stress will induce additional movement to the pile and leading to distress in pile foundations located adjacent to supported excavation. In these situations understanding the response of piles next to supported excavations becomes essential.The behavior of piles subjected to soil movement was studied by Poulos and Chen (1996 and1997) through tests on 1g models and the findings concluded that the maximum bending moment was found to decrease with decreasing pile diameter and decreasing pile spacing . Leung et al. (2000 and 2003) studied the effects of excavation induced soil movement on pile foundations in sand through centrifuge tests and established that the restraints on the pile head would cause additional shear force and/or bending moment at the pile head, although the restraints help to reduce the pile head deflection/rotation. In the theoretical studies of Poulos & Chen (1997), boundary element method (PALLAS) was used for analysing the pile subjected to lateral soil movement and charts were proposed for designing the piles. Pan et al. (2002) and Miao et al. (2006) analysed the passive pile behavior through three dimensional finite element analyses. However research works reported on piles subjected to lateral soil movement are limited."

Jan 1, 2015

By G. Mucsi, F. Kristály, R. Szabó

Kaolin is one of the most important ingredients in porcelain manufacturing. Its main phase is clay mineral containing aluminum hydrosilicate, namely kaolinite. Beside kaolinite it also contains quartz, illite and feldspars, which impair its applicability. Kaolin is a non-reactive material, but metakaolin can be produced by heat treatment (calcination) of kaolin, which is also used by the cement and concrete industry due to its latent hydraulic (pozzolanic) properties. Beside thermal activation, reactive materials can also be produced by mechanochemical activation in general. This paper deals with the mechanochemical activation of kaolin. The raw material was classified into various size fractions, then ground in a batch stirred media mill under varying circumstances (residence time, circumferential velocity). After grinding, the structural changes of the products were investigated by X-ray diffractometry (XRD) and Fourier Transform Infrared Spectroscopy (FTIR). In addition, the particle size distribution of the ground material was determined by laser scattering. As a result of the grinding experiments and analytical measurements of the products, it can be clearly seen that reactivity of kaolin can be improved significantly by mechanical activation in a stirred media mill, but due to its high energy density the circumstances were optimised carefully to avoid aggregation. Keywords: Kaolin, grinding, stirred media mill, mechanical activation, material structure

Jan 1, 2020

By A. E. Lewis, J. Du Plessis, J. Chivavava

Current metallurgical processes lack selective and efficient REE recovery from aqueous leach liquors. Antisolvent crystallisation is used to selectively recover pure inorganic salts from aqueous solutions without excessive chemical use in ambient conditions. Yttrium sulfate octahydrate (Y2(SO4)3.8H2O) was used as a representative rare earth salt to investigate the effect of antisolvent selection on the crystal morphology and size distribution of the final crystalline product produced through antisolvent crystallisation. The antisolvents of choice were short length alcohols that are water miscible i.e. methanol, ethanol, 2-propanol and t-butanol. All experimental parameters except the type of antisolvent were kept constant under isothermal conditions. The large reduction in solubility of the salt by the antisolvent creates high supersaturations. This leads to high product yields as observed in this study at > 91%. In general, a variety of morphologies were successfully formed in each individual alcohol including; rods, plates, prismatic cubes and starburst clusters. The powder X-ray diffraction (XRD) analysis indicated that Y2(SO4)3.8H2O was the only species present for all final products. There was a change observed from the starburst and rod structures for the shorter alcohols towards prismatic cubes for the longer alcohols due to different strengths in the solute-antisolvent interaction at the crystal growth faces. The crystal sizes increased with an increase in the alcohol chain length because of the lower supersaturation conditions due to a limit in the mass transfer induced by the bulkier alcohol structure. In conclusion, it has been shown that the particle morphology and size can be greatly affected by the selection of antisolvent even under high supersaturation conditions, contributing to understanding the effect of different antisolvents on the final particle characteristics. The engineering of favoured product characteristics can therefore be achieved by antisolvent crystallisation, presenting a viable alternative process for the recovery of REE. Keywords: Antisolvent crystallisation, rare earth elements, morphology, particle size

Jan 1, 2020

By N. C. Steenkamp

Clay minerals are present in ores and their colloidal behaviour in slurries impacts on the full metallurgical process from comminution to the tailings storage facility. Geotechnical classification of tailings has been based on parameters such as grain size. This paper proposes that this parameter does not consider rheology and plasticity, and, while. Atterberg limits are useful, they do not consider other aspects such as active clay and chemical porewater.

Apr 8, 2026

By Andrew Palangio, Blessing Taiwo

Understanding rock mass structural features is essential for optimizing blast design, highwall control, and evaluating post-blast performance in both surface and underground mining operations. This paper presents a comprehensive methodology utilizing image-based structural mapping to accurately characterize geological discontinuities including joints, faults, and lineations captured from both terrestrial and aerial imagery at varying scales. Key structural parameters such as joint orientation, spacing, and apparent in-situ block size are extracted to understand rock mass classification and enhance blast design inputs with greater geotechnical precision. The study introduces a significant enhancement to the existing discontinuity assessment algorithm by integrating a deep learning-assisted detection process. This improvement enables more accurate, quantitative and consistent identification of pre-existing cracks and surface features across complex bench free faces. The enhanced system facilitates better evaluation of how structural features influence blast fragmentation, energy distribution, and slope stability. A case study from a limestone quarry illustrates the use of a derived comminution factor based on the relationship between joint-controlled pre-blast block sizes and post-blast fragmentation to evaluate blast performance and optimize future design strategies. The results highlight the value of structural analysis in reducing overbreak, minimizing underbreak, and improving fragmentation predictability. This paper emphasizes the importance of integrating structural assessments into the blasting workflow to enable a more data-driven, geotechnically informed, and performance-optimized approach to modern blast design and evaluation.

Jan 26, 2026

By F. S. McNicholas

Various methods of block caving and draw practice are classified and the advantages, disadvantages, rock, treatment, size of orebody, costs, and profit comparisons, and other factors which determine the selection of the proper method are outlined.

Jan 1, 1951

Executive SIDNEY J. JENNINGS, Chairman GEORGE D. BARRON J. E. JOHNSON, JR. EDWIN LUDLOW ROBERT M. RAYMOND Membership KARL FILERS, Chairman LEWIS W. FRANCIS J. E. JOHNSON, JR. LOUIS D. HUNTOON ARTHUR L. WALKER Finance GEORGE D. BARRON, Chairman CHARLES F. RAND BENJAMIN B. THAYER Library E. GYBBON SPILSBURY,1 Chairman ALEX C. HUMPHREYS3 GEORGE C. STONE 2 J. H. JANEWAY4 BRADLEY STOUGHTON

Jan 5, 1918

By P Albert

A wedge-shaped underwater rock plug has to be blasted in order to tap the reservoir and furnish water to a new underground powerhouse at Manicouagan-5. The paper deals with the design and engineering aspects of drilling and blasting of this plug where the topographical configuration is extremely difficult. In this study small diameter vertical holes are considered with the OD-method and a fixed platform is recommended for drilling and loading operations.

Jan 1, 1984

Executive SIDNEY J. JENNINGS, Chairman GEORGE D. BARRON J. E. JOHNSON, JR. EDWIN LUDLOW ROBERT M. RAYMOND Membership KARL EILERS, Chairman LEWIS W. FRANCIS J. E. JOHNSON, JR. LOUIS D. HUNTOON ARTHUR L. WALKER Finance GEORGE D. BARRON, Chairman CHARLES-F. R AND BENJAMIN B. THAYER Library E. GYBBON SPILSBURY,1 Chairman ALEX C. HUMPHREYS8 GEORGE C. STONE2 J. H. JANE WAY' BRADLEY STOUGHTON Papers and Publications BRADLEY STOUGHTON, Chairman

Jan 4, 1918

By James K. Grunig

As the real price of uranium increases, deposits of lower and lower grade will be treated. The various occurrences of uranium ore are described and the chemical aspects of extraction are detailed.

Jan 1, 1981

By K. Aoki, N. Kameda, T. Esaki

The shortage of adequate construction sites and their difficult location has compelled many engineering structures to be planned in old mining areas in Japan. This paper shows, first, the characteristics of the excavated underground environment and next, the necessary preventive measures during construction of surface structures. Where the depth of a mined out area is relatively shallow, there is a tendency of cave-in consequent to surface loadings. The effect of surface loadings is inversely proportional to the depth of goals. Finally, a power plant project is studied as an example.

Jan 1, 1984

By H. Chaouki

The aim of this work is to simulate the forming process of a green anode. For this purpose, a nonlinear compressible viscoelastic constitutive law is presented. The concept of natural reference configuration is considered. Within an isothermal thermodynamic framework, a Helmholtz free energy is proposed to take into account the nonlinear compressible deformation process occurring between natural reference configuration and current configuration. A dissipation potential is introduced in order to characterize the irreversible aspect of compaction process. Thus, the constitutive law is formulated through two equations: 1) an expression of Cauchy stress tensor and 2) a differential equation characterizing the evolution of the natural reference configuration. Material parameters are assumed to be a function of the bulk density. This allows capturing the micro-mechanical phenomena within the chosen macroscopic approach. An experimental study based on compaction tests is carried out in order to characterize the mechanical behaviour of the anode paste. A user's material VUMAT subroutine for finite element dynamic explicit analysis has been developed and implemented in the ABAQUS commercial software. To evaluate the model predictive capability, numerical simulations of the compaction forming process of anode paste were performed. Simulation results show that the constitutive law predicts the experimental trends and gives interesting physical responses. This constitutes a first step toward making a benchmark with experimental results on the forming process of anode paste.

Jan 1, 2011

By L Snyman, S Webster and J Samosir

Northparkes is located 27 km north of the township of Parkes in central New South Wales, Australia. The operations consist of underground block cave mines and an ore processing plant, which produces high-grade copper and gold concentrate. Production is currently sourced from the E48 Lift 1 block cave mine and open cut stockpiles. Mining commenced at Northparkes in 1994 as an open cut operation. Underground block cave mining began in 1997. Northparkes was the first mine in Australia to use the highly efficient block cave mining method, which relies on gravity and natural rock stresses to fragment and recover the ore.The E48 extraction level is located approximately 581 m below surface and consists of ten extraction drives and 214 drawpoints. Several stress measurements carried out at various levels in both E26 and E48 indicated a low underground regional stress environment and a low to moderate stress state in the E48 orebody. The E48 block used a post undercut strategy that was initiated in 2009, with production commencing in September 2010 and cave-through to the surface occurring approximately four months later in January 2011. Changes to the cut-off grade and fixed prices meant that Northparkes was able to develop an additional two drives to the north of the existing cave and one additional drive to the south. Modelling of the cavability of the additional drives indicated that the cave would not readily propagate to sufficient height of draw to mobilise the ore and tended to arch over to the existing cave shape. Based on modelling and a desire to reduce the risk of the project, preconditioning was adopted. Along with the requirement of safely hydrofracturing an active cave, a measure of the success of the preconditioning was desired. Few block cave operations have developed extension drives adjacent to existing caves.This paper summarises the lessons learnt from the development of this extension project, with a specific focus on ground control and monitoring.CITATION:Snyman, L, Webster, S and Samosir, J, 2016. E48 cave extension at Northparkes, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 111–118 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By T. T. Chen, J. E. Dutrizac

"Grooved cast Pb-Ag anodes are used by some zinc refineries to improve current efficiency. It was found that the manganese oxide scale formed on a grooved Pb-0.75% Ag anode consists mainly of MnO2, which occurs characteristically in rhythmically banded colloform structures and adheres to a layer of ""Pb02+PbS04"" that oxidized from the anode. The relatively homogeneous and nearly fracture-free morphology of the ""Pb02+PbS04"" layer suggests the relatively uniform corrosion of the anode. Deposition of the Mn oxide initially follows the contours of the anode surface, but the grooves eventually become filled with Mn oxide and gypsum. Hydrous Mn oxides and amorphous Mn oxides are believed to be also present in the manganese oxide scale. Tiny particles of PbS04 and SrS04, together with gypsum, other impurities and micro-pores, tend to concentrate in the grooves.IntroductionManganese is a common impurity in hydrometallurgical zinc processing circuits. The manganese originates from sphalerite (Zn,Fe,Mn)S and from the Mn02 added to the leaching circuit to oxidize ferrous ions [1]. Manganese in the sphalerite follows Zn through the roasting, leaching and purification processes, and is present as Mn(II) in the purified ZnS04 solution. The Mn in the added Mn02 is reduced to Mn(II) during the oxidation of the ferrous ions present in the leach solutions. In both cases, MnS04 is generated, and the MnS04 accumulates in the purified solution. In the cellhouse, Zn is plated at the cathodes to produce high quality metal. The Mn(II) is partly oxidized at the anode surface to Mn(IV), and the Mn(IV) precipitates as a scale on the surface of the anode and as a sludge on the bottom of the electrolysis cells. The presence of a thin layer of manganese oxide scale on the surface of the Pb-Ag anode can minimize the corrosion of lead and, accordingly, reduce the contamination of the electrodeposited zinc. However, a heavy manganese scale build-up can cause ""staining"" of the zinc deposits and reduced current efficiencies. Consequently, periodic anode cleaning to remove excess manganese oxide scale is carried out routinely in commercial operations."

Jan 1, 2011

Located 350 km west of Sydney and 20 km outside Orange, NSW, lies the Ridgeway Gold Mine û NewcrestÆs flagship Underground Gold Mine. Key to success at Ridgeway has been the fast tracked development of the 3.8 km, 1 in 5.3 conveyor decline which houses the 850 t/hr conveying system feeding the dedicated Ridgeway Concentrator, built adjacent to the existing Cadia Hill Concentrator. Eroc was contracted to develop the steep conveyor decline, drawing on its personnel and experience from past metalliferous, tunnelling and coal mining projects to complete the ambitious schedule within 12 months. This paper deals with the complexities and experiences in safely delivering what is understood to be one of AustraliaÆs steepest declines of any substantial length in a metalliferous mine.

Jan 1, 2002

By R. R. Nothdurft

The internal friction of eight single crystals of magnesium with orienta-tion ranging from 10° to 84° was measured at 33.5 kc and 272° C, and the results were interpreted in terms of the pinned-dislocation model proposed by Granato and Lucke. Results show that the strain-amplitude-dependent decrement varies with orientation in a manner predictable by the G-L model. Different values of strain-amplitude-independent decrement were observed at different orientation angles, but correlation with the theory was not conclusive. Problems and steps for further study are discussed.

Jan 1, 1965

By K. E. Waters, M. Mirnezami, R. Gauvin, A. Jordens, K. W. Malas

"There is currently very little information on the physico-chemical properties of rare earth elementbearing minerals, or on their processing. With the increasing demand for rare earths, this is something that needs to be addressed. This paper introduces some surface chemistry analysis of fergusonite (YNbO4), and the bubble-particle attachment. Zeta potential measurements indicate adsorption of sodium oleate and, to a lesser degree, potassium amyl xanthate onto the surface, and an increase in attachment to an air bubble is observed at pH 4.5 and 6.5. At a pH of 10.5, no attachment is observed, whether in the presence of the reagents or not. This analysis, although initial, will be used to initiate flotation tests, in order to facilitate the selective recovery of fergusonite. INTRODUCTIONRare earth elements (REE) are increasingly in demand, due to their prevalence in both renewable energy devices and high-end electronics. An article in the New Scientist highlighted the importance of a number of REE, many of which most people are be unlikely to have heard mentioned (Crow, 2011). From batteries (lanthanum and cerium) to magnets (dysprosium and neodymium) and lighting (yttrium), the REE are crucial to the advancement of technology and energy saving devices. For example, neodymium is finding most use in the high end magnets that keep the motors turning that power wind turbines and electric cars. In the case of yttrium, the demand outstripped the supply in 2010, emphasising the need to develop deposits containing this and other REE (Crow, 2011). The impact of our dependency on REE has become even more apparent with the reduction in exports by China, which currently controls 97 % of the world’s rare earth production (Pitts, 2011).With the increasing demand for rare earth elements (REE), there is a drive to exploit the known resources around the world. However, the physical beneficiation of the rare earth element bearing minerals is a subject which will require a great deal of investigation to fill the knowledge gaps surrounding these developing rare earth projects. There are numerous articles on REE mineralogy as well as the hydrometallurgical processing of REE concentrates (Alex, Suri, & Gupta, 1998; Peter Gromet & Silver, 1983; Ring et al., 1993; Schnetzler & Philpotts, 1970; Uda, 2000), however a common feature amongst these resources is the lack of detailed descriptions of the physical beneficiation processes required to concentrate REE-bearing minerals. There is work being conducted into reagents and methods for use in recovering some rare earths from their associated ores (Bulatovic, 2010; Ni, Parrent, Cao, & Liu, 2011), but much more in-depth research is required."

Jan 1, 2012

By Y. M. Jubeli

"Abstract - Gamma-ray spectrometry, an effective tool in geological mapping, was used to define boundaries between various lithological formations in three adjacent areas of Central Syria, namely, the Syrian Desert, Ar Rassafeh Badiayat and the Northern Palmyrides mountains. This paper describes the role of an airborne gamma spectrometric survey which was orginally undertaken to assist uranium exploration. Interpretation of the total count data obtained through the survey has led to significant modifications and corrections to the previously published distribution map of the palaeogene phosphate rocks.Another important result of the survey is the discovery of four previously unknown phosphorite horizons in the Rasm Al-Aawabed area of the Northern Palmyrides. In addition, previously unknown phosphatic horizons are outlined in the other study areas. The importance of this technique as an effective prospecting method, not only for U but also for exploring for the economically important phosphorite formations in Syria, is emphasized. Furthermore, its role in geological mapping is stressed, especially in areas that lack sufficient geological data."

Jan 1, 1997