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By M. Friák, L. G. Wang, M. Šob, V. Vitek

"The paper gives an account of applications of quantum-mechanical (first-principles) electronic structure calculations to the problem of theoretical tensile strength in metals and intermetallics. First, we briefly describe the way of simulating the tensile test and the electronic structure calculational method. Our approach is then illustrated on calculations of theoretical tensile strength in W, NiAl and transition metal disilicides MoSi2 and WSi2 with C11b structure. In Wand NiAl, we consider uniaxial tension along [001] and [111] directions. Although tungsten is elastically nearly isotropic (C44 = C”), theoretical tensile strength exhibits a marked anisotropy (oth/001 = 29 GPa, o'th/111 = 40 GPa). Calculated results compare favorably with experimental value of 24.7±3.6 GPa obtained for tungsten whiskers grown along the [110] direction. Similarly, in NiAl, the 'hard' orientation [001] differs very significantly from the [ill] orientation (oth/001 = 46 GPa, oth/111 = 25 GPa). This anisotropy is explained in terms of higher-symmetry structures present or absent on the calculated deformation paths. In disilicides, the theoretical strength is calculated for [001] loading (oth/001 = 37 GPa and 38 GPa for MoSi2 and WSi2 , respectively). The role of relaxation of internal structure parameter is discussed and changes in bonding conditions during the tensile test are analyzed.IntroductionIn most engineering applications, the strength of materials is limited by the presence of internal defects. If there were no defects, then, for example, the tensile strength could be several orders of magnitude higher and its value would be comparable with that of shear modulus. Therefore, the strength of ideal (defect-free) crystal represents an upper limit of attainable stresses, which is called the ideal strength. While it may not be possible to achieve the ideal strength in practice, it is not possible to exceed it. However, the ideal strength is already approached in situations which are technologically relevant. These include the low-temperature deformation of inherently strong materials, such as diamond, Si, Ge and some of the transition-metal carbonitrides, deformation of whiskers, nanoindentation of materials with low defect densities, hardened thin films and coatings etc. The ideal strength sets the limits of elastic stability of a solid. Its knowledge is useful for estimation of the ideal work of fracture stresses needed for homogeneous nucleation of dislocations and for modelling of crack propagation."

Jan 1, 2001

By T Baumgartl, C Gonzales, A Soliman, M Edraki

A soil cover isolates potentially acid-forming (PAF) mine wastes from atmospheric interaction and thereby mitigates acid mine drainage. As a cover that comprises either a single layer or a composite barrier, it essentially manages percolating rain water from flowing into these PAF materials and minimises air flow as oxygen has low diffusivity in saturated soils. However, the availability of suitable soils as cover materials is limited, especially in arid and semi-arid regions where weathering rates are low.This paper investigates the potential use of mine wastes as cover materials in a water-shedding soil cover in north-west Queensland. Four cover trial plots were built using mine wastes as cover materials. Each 2.3 m cover trial plot consisted of a 1.5 m soil cover made up of waste rocks and fines, a 0.5 m drainage layer that consisted of 0.1 m waste rock aggregates and a base layer made up of blended mine tailings. The hydrologic properties of cover materials were determined by in situ measurements and laboratory experiments, which, in turn, were used as input in a numerical model that described the cover’s transient soil moisture profile. The successful performance of the cover is reliant on the long-term stable geochemical behaviour of the substrate used as cover material. Therefore, investigations were carried out to determine the geochemical properties of the cover materials constructed from benign waste rock using static and kinetic tests, with the objective to increase the level of certainty of the material’s benign characteristics. Consequently, the long-term performance of this water-shedding cover design is described in terms of the physico-chemical characteristics of its outflows.CITATION:Gonzales, C, Baumgartl, T, Edraki, M and Soliman, A, ?2014. Mine wastes as cover materials in a water-shedding soil cover in north-west Queensland, in Proceedings Life-of-Mine 2014 , pp 261–270 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

By Robert F. Conley

Attrition milling, once employed exclusively for the dispersion of pigments, has in recent years found a host of new applications in the area of mineral processing and mineral-pigment production. Broadly categorized, attrition milling is divided into two classes, as defined by the machinery's function, vibratory milling and rotational milling. Each mill type has been defined as a variation on ball milling and the terms, "vibratory ball mill" and stirred ball mill" appear in the literature. The primary design differences between attrition and ball mills are: (1) a stationary canister (or shell) (2) smaller grinding media (3) grinder energy is motor limited rather than gravity limited (4) strong media/feed size dependance.

Jan 1, 1983

By Y. Xi

In this paper we present an availability approach for determining the capacity of a major bucket wheel excavator (BWE) system to be used in Yuabaoshan surface coal mine in China. Based on previous time studies on other BWE systems for delay times due to internal and external causes, and a four-level maintenance and repair schedule, we develop a model taking into account all random failures and present a fast and simple solution to this highly complex problem. A procedure employing the Markov renewal theory for determination of the distribution of random failure times and failure rate of the whole system, as well as some other factors useful for calculation of the overall system capacity are discussed in the paper.

Jan 1, 1993

By S. K. Palm

Volatility is a fact of life in the mining industry. Prices of and demand for mineral products are among the most volatile of those for any product. The volatility of these markets wreaks havoc on both corporate management and the personal lives of mining people. Yet, until recently, it has been difficult to assess the impact of volatility on business strategy. This paper discusses how mining firms can profit from market volatility through an operations strategy that stresses operating flexibility. The foundation for our strategy analysis is the observation that a mine is analogous to a stock option. Techniques based on those developed to value stock options have recently been extended to the field of mine valuation. The insights provided by option pricing are very valuable in the development of mine operating strategy.

Jan 1, 1986

By D. Men, R. Q. Honaker, J. C. Hower

"Maceral separation is one possible technique to expand coking coal resources, either by increasing the blending ratio of non- or slightly caking coal or rationally utilizing the coking coal according to the different behaviors of macerals in coking. The success of maceral enrichment for a given coal using flotation is dependent on the differences in flotation kinetic rate among macerals. This paper presents the flotation rates and zeta potentials of the vitrinite-rich and inertiniterich maceral concentrates obtained from six coal samples of different ranks – from high-volatile B bituminous coal with mean random vitrinite reflectance (Rrandom) of 0.64 percent to low-volatile bituminous coal with Rrandom of 1.73 percent – using a float-sink procedure. The flotation results show that vitrinite-rich concentrates can be produced in tap water using froth flotation only with frother for the high-volatile B and A bituminous coal samples, but there was no good performance for the high-volatile C bituminous and medium- to low-volatile bituminous coal samples. The zeta potential results show that froth flotation could probably separate the high-volatile C bituminous coal samples well by adjusting pH, but there was no good performance for the higher-rank coal samples. IntroductionMetallurgical coke is used in blast furnaces for steel production and is produced by the carbonization of coking coal. Because caking coals are rare and expensive, they are often blended with non- or slightly caking coals. Considering the tight supply-demand situation for coking coal in China, it is important and urgent to develop highly efficient technologies for rationally utilizing and expanding coking coal resources (Mochizuki et al., 2013)."

Jan 1, 2015

By Zygmunt Kowalczyk

"A theory permitting the determination of expected surface deformations for planned underground exploitation is proposed and discussed in this paper. The relations between surface subsidence and various methods of mining are analyzed, and allowable horizontal .deformations for protected objects, according to the degree of their significance, are reviewed."

Jan 1, 1966

By Mihaita Matei

An adaptive approach to control the deformation in tube hydroforming process is presented. This requires: the use of an existing non-linear FE software (ABAQUS) that incorporates a user material model (VUMAT), the development and implementation of an adaptive control strategy to coordinate the internal pressure and the axial load so as to prevent fracture and wrinkling failures (knowledge-base controller) and the application of the developed adaptive simulation approach for finding the optimal loading path required to hydroform a defect-free part with as uniform thickness distribution as possible (user's load subroutine (VDLOAD). In order to validate the approach, the case of conical hydroforming and the case of bending followed by hydroforming component is discussed.

Jan 1, 2011

By B. McFadzean, P. E. Ngoepe, P. P. Mkhonto, J. Taguta

The adsorption of heterocyclic collectors such 2-mercaptobenzothiazole (MBT), 2-mercaptobenzoxazole (MBO), 2-mercaptobenzimidazole (MBI) and their derivatives on pyrite form a basis in understanding the flotation reactivity that may be applicable in a wide range of sulphide minerals. This study uses a computational and experimental approach to determine the heat of adsorption of MBT, MBO, MBI and modified MBT collectors onto pyrite surfaces. Computational calculations found that the adsorption energies were in the order: MBO > MBI > MBT. The heterocyclic collectors were adsorbed in their thiolate form on the surface. In the case of the pyrite (100) surface, the MBT adsorbed through the exocyclic sulphur atom, while MBO and MBI adsorbed through the exocyclic sulphur and N atoms onto the 5-coordinated Fe atom. The (111) surface was found to be more reactive and different adsorption mechanisms were predicted, where the MBT exocyclic sulphur atom bridged on the 5- coordinated Fe and surface 2-coordinated sulphur atoms, while the N atom adsorbed on the 5-coordinated Fe atom. In the case of MBO and MBI, dissociation of the exocyclic sulphur atom from the collector occurred with subsequent interaction with the surface 5-cordinated Fe and 2-coordinated S atoms. This resulted in the collector carbon atom adsorbing on the surface 2-coordinated S atom, while the N atom adsorbed on the 5-coordinated Fe atom. The adsorption of the modified MBT was found to be more exothermic than the MBT, which showed that introduction of a –CS2 group on the exocyclic sulphur atom improved the affinity of MBT on the surface, and was thus a better flotation collector. The computational results were supported by experimental enthalpy of adsorption measurements and microflotation tests. The chemistry of the heterocyclic thioamides is complicated by the fact that they can exist in a number of tautomeric and ionic forms at different pH’s. This is discussed in relation to the flotation and calorimetric data.

Jan 1, 2018

By Carl F. Austin

The subject of strata control in mining can be approached from both static or loading concepts or from dynamic or impulsive loading concepts. The fracture process itself appears to be primarily a dynamic process as is the gross creation of fractures through the use of impact, stress wave passage or in more general terms, the use of explosives. This paper presents experimental results which indicate that the understanding of the fracture behavior of rock that has been, established in the open literature is not always appropriate. In particular, the results of this experimental program have shown very interesting differences between the formation of fractures in rock and the formation of fractures in other materials such as metals and plastics which are often used as models for rock behavior studies Fracture patterns and causes of dynamic fracturing in various rock and artificial materials are presented.

Jan 1, 1965

By Layton C. Binon

Exploration budgets are commonly determined by "rules of thumb" such as a percentage of earnings or other fiscal measure. An appropriate exploration budget is the amount needed to achieve the goals of the company. It can be determined by discounting the income expected from achieved goals. Budgets for individual projects are determined in a similar manner except that risk of failure is included in the computation.

Jan 1, 1981

By L. M. Oshinowo

The incorporation of advanced analysis tools, such as CFD, into the process plant design process has become possible through advances in commercially available computational fluid dynamics software and faster computers. Multiphase modeling is now typically employed in the design phase of process plant design at Hatch. The multiphase models include Lagrange-Euler and Euler-Euler treatment of the multiple phases. Additionally, mixture models with interface-sharpening algorithms are applied to the prediction of free-surface flows in complex geometry. CFD is applied to applications where traditional design rules are not applicable. The additional rigor of CFD modeling in 2D and 3D allows process engineers to come closer to realizing true virtual plant design. The objective of this paper is to outline the benefits and pitfalls in the application of multiphase modeling for rigorous design. Several application examples in the hydrometallurgical field will be presented.

Jan 1, 2005

By K. Darcovich

The wettabilities of agglomerates made from coals of several different ranks were measured by the adhesion technique. Oil levels from 0 to 10% by weight were used. As was expected, it was found that higher-rank coals are more easily oil-wetted and that the surface properties of the agglomerates correlate with agglomeration recovery and ash removal data.

Jan 1, 1992

By A. Kurkov

Flotation process is based on the formation of primary collector-based supramolecular associates at the mineral surface and within the pulp. Supra molecular chemistry allows studying within a common framework, all kinds of molecular associates, from dimers to large assemblies, resulting from spontaneous association of a large number of interacting components of the flotation system, where the collective action of non covalent bonds can have an important role. Self-organization of supra molecular assemblies in the flotation process can be controlled by modifying the chemical structure of the collector, the nature and arrangement of functional group in it, by introducing secondary agents (SA) into the process, to adjust the interaction between the collector and the surface and to control the hydrophobicity of the adsorption bed. This offers broad opportunities to build supramolecular assemblies to improve the efficiency of flotation. Besides, the more complex is the system, the weaker are the interactions, that determine its behavior. This powerful factor still is not employed deliberately to control the flotation process. Organophosphorus compounds (OPC) - dialkyl phosphoric acids whose radicals contain ethoxylated groups ? are considered as nanocompounds, that can be used in building supramolecular assemblies. The presence in an OPC molecule of functional groups (P=O, P (O) O-, P (O) OH), ethoxylated groups, and aromatic rings is the basis for the formation of stable supramolecular associates. Gross formula: C54H94KO16P. Molecular weight is 1069.39. Phosphoryl anion has a regular tetrahedral structure with the angle of 109.5°. Lengths of -P-O- bonds in a PN molecule are 1.7345Å; length of the hydrocarbonic radical C42-C72 = 33.942Å. In an alkaline environment, PN is in the form of the anion, in an acidic environment ? in the form of the polycation due to protonation of the oxygen in the EO group. Chem Office software suite was used to generate three-dimensional images of an OPC molecule in acidic and alkaline environments, to reveal the OPC geometry (bond lengths, valence angles, aliphatic radical length), to identify the collector's binding sites with the mineral surface, to find the most stable and energy-efficient molecular conformations of an OPC molecule and its complexes with minerals under various conditions. Mechanisms of interaction between OPCs and the mineral surfaces are different. In ores whose minerals are dominated by ionic bonds (fluorite), the interaction mainly involves the anionic form of the collector; in ores, whose minerals are dominated by covalent bonds - the oxygen of the phosphoryl group (donor-acceptor interaction) and the oxygen of the ethoxylated groups. This difference is responsible for the formation of spatial associates with different surface layer structures. Introduction of supramolecular chemistry concepts into the analysis of flotation phenomena and mechanisms can become an effective tool for better understanding the flotation process and offers new means of consistently improving its effectiveness.

Sep 1, 2012

By H. Lachmund, R. Bruckhaus

At Dillinger Hüttenwerke/Germany steel production of grades for linepipe applications especially for sour service has a long tradition. The BOF process after replacement of the vessels is optimized by a newly developed lime addition model and variations in lance tip geometry. Equipped with three state-of-the-art VOD tank degassers metallurgical requirements of lowest contents of e. g. sulphur, nitrogen and hydrogen can be achieved. Three continuous casting machines of vertical bending type with solid core even improve already high levels of cleanliness. The vertical part corresponds to the metallurgical length of 12 to 15 m and therefore assures a maximum of cleanliness after solidification before bending. Slab thickness up to 400 mm can be produced with model controlled dynamic soft reduction. The accurate alignments of the casters assure minimized segregation and microporosity. Surface and internal cracks can be avoided by special cooling, bending and straightening strategies.

Jan 1, 2005

By C V. Deutsch

"Geometallurgical variables often cause problems to conventional geostatistical workflows. There are many variables; some are compositional and some are non-additive. They often show: complex multivariate relationships undersampling relative to conventional grade variables unequal sampling; that is, all variables are not available at all data locations.A variety of approaches have been developed over the years, but geostatisticians remain mostly focused on modelling rock types and a few grade variables with an abundance of data. The problems are reviewed and a chained workflow is presented where appropriate techniques are employed in sequence to permit reliable spatial prediction of geometallurgical variables. The spatial models may be used to assess the value of additional data, for prediction of process performance, for improved mine planning and other optimisation tasks. The chained workflow will include data transformations such as ratios and normal scores that make the variables amenable to geostatistical modelling. Data imputation techniques to account for missing values are considered with special consideration to spatial correlation with the available data. Decorrelation techniques such as the principal components, min/max autocorrelation factors and projection pursuit multivariate transformation are employed to manage massively multivariate modelling. Full distribution modelling must be considered to avoid biases in the prediction of non-additive variables. The post-processing of geometallurgical models must be streamlined for robustness and efficiency. The precise workflow varies according to the specific purpose of the study. Guidelines and thoughts on best practice are presented.CITATION:Deutsch, C V, 2013. Geostatistical modelling of geometallurgical variables - problems and solutions, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013, pp 7-16 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 29, 2013

By L. W. Kelly

The purpose of this paper is to indicate some of the benefits that have been derived in the Zeigler No. 3 mine by using roof bolts under extremely adverse roof conditions J with the thought that much better results could be obtained in other mines with more normal roof conditions by applying some of the practices that were developed in this mine. Some of the benefits that have been obtained in this mine, which will be shown in this paper, are: 1. Increased tonnage per man-shift at the face when roof bolts are used, as compared to the tonnage under similar conditions when conventional timbering methods were used. 2. Increased efficiency of roof bolting by giving the foremen a definite plan to follow. 3. Reduction in delays caused by failures of the trailing cables of loading, mining, and drilling machines. 4. Reduction in the number of accidents after roof bolting was adopted. Inasmuch as the success that followed roof bolting in this mine was obtained under one of the most treacherous roofs in the Middle West, it is reasonable to suppose that correspondingly better results could be obtained under more favorable roof conditions by using the same procedure.

Jan 1, 1952

By Raul A. Deju

A theoretical and experimental study was made of the surface phenomena occurring in a silicate - sulfonate system and a silicate -amine system, Experiments were conducted varying the collector concentration to examine its effect both on the total surface sorption and the rate of sorption. The results were compared to a theoretical model based on a Langmuir-type isotherm, Finally, the flotation behavior of selected silicate minerals was predicted from the sorption results and an explanation for the flotation of silicates postulated on the basis of both the theoretical predictions and experimental data.

Jan 1, 1967

By I. Filippova, L. Filippov

"The by-product potential of light rare-earth elements (LREE, La, Ce, Nd) and rare-metals (W, Nb, Sn) within the St Austell kaolin deposits (UK) is related to the kaolinisation process, which liberates the accessory heavy minerals of the host granite in the clay matrix and allows their separation in the waste streams. As a consequence these minerals are pre-concentrated in the micaceous residue which displays relatively high LREE content (around 170 ppm) hosted by monazite which is mainly distributed (up to 95%) in the -100 µm fraction. A combined gravity/flotation concentration flowsheet, starting with classification of the residue into 3 size fractions (+150 µm, 150-53 µm and -53µm) was developed. This study presents the results of the clay-rich -53 µm size fraction beneficiation by flotation using sodium oleate and hydroxamate as collectors.The effect of dispersant addition during de-sliming operations on flotation efficiency was also investigated. The LREE grade in the floated product obtained with sodium oleate increased from 3370 ppm to 5350 ppm and recovery from 30% to 80% with dispersant which is attributed to clay coating. Comparison of flotation performance and Falcon Ultra-Fine (UF) concentration of monazite to previous results obtained with Falcon Semi-Batch (SB) gravity concentrator on the unscreened raw residue clearly shows that flotation of the fine residue is more efficient than Falcon UF and Falcon SB. Indeed Falcon UF produced high recoveries (87-95%) but with almost no enrichment (1.3-1.4 ratios) whereas Falcon SB concentration of unscreened residue produced higher grades (up to 0.6 % LREE) but with low recoveries (17-22 %). These preliminary results show that LREE can be pre-concentrated suggesting that the micaceous residue stream (and the associated tailings dams) could be considered as a potential resource for these metals."

Jan 1, 2016

By S. K. Kawatra, H. J. Haselhuhn

"Fine-grained hematite ore can be concentrated by the process of selective flocculation and dispersion, which relies on proper reagent selection and control of water chemistry. While many previous studies have been performed analyzing the effects of different reagents on this process in a laboratory environment, this paper focuses on investigating the water chemistry within the process in a pilot-scale continuous deslime thickener.The pH, sodium concentration, calcium concentration and magnesium concentration were varied to determine their effects on the iron concentrate grade and recovery, and the phosphorus concentrate grade and rejection in the pilotscale selective deslime thickener. The ideal pH for the iron grade and recovery of the process using a starch selective flocculant was found to be 10.5. Phosphorus rejection, however, was increased at lower pH values. Minimization of sodium concentration was shown to improve iron grade, iron recovery and phosphorus rejection. Calcium acted as a nonselective flocculant showing higher iron recovery, lower iron grade and lower phosphorus rejection with increasing concentration. Conclusions could not be drawn from the experiments that varied magnesium concentration.The zeta potential of the solid-liquid interface of particles in each sample taken was also analyzed to show relationships between zeta potential and process performance. In all cases, a maximization of the magnitude of zeta potential correlated with increased iron grade and recovery. This supports the hypothesis that a higher level of dispersion enhances the selective flocculation and separation process.IntroductionThe United States produced 53.2 million metric tons out of the 3,000 million metric tons of concentrated iron ore produced worldwide in 2012 (Tuck, 2013). With this in mind, there has been a large increase in iron ore processing research (Bolen, 2014; Carlson and Kawatra, 2008, 2013; Halt and Kawatra, 2014; Halt et al., 2014; Haselhuhn et al., 2012a,b, 2013a,b; Liu et al., 2014; Manouchehri, 2014; Sandvik and Larsen, 2014; Semberg et al., 2014). Of the 53.2 million metric tons produced, roughly 8 million metric tons of hematite (Fe2O3) concentrate were produced using a process known as selective flocculation and dispersion (Cliffs Natural Resources, 2011). This process is the only economically viable method for concentrating low grade (< 40% Fe) fine grain (< 25µm liberation size) hematite ores. It is scarcely used due to difficulty in controlling the surface chemistry of the ore and high reagent costs (Department of Energy, 2001; Haselhuhn et al., 2013a). The process is highly dependent upon both reagent selection and precise control of the water chemistry during separation. This study shows the dependence of the process performance of a pilot-scale deslime thickener on the water chemistry in the feed slurry."

Jan 1, 2015