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By C V. Putnis, T Geisler, A Putnis

In nature, ilmenite (FeTiO3) undergoes weathering through oxidation and removal of Fe to form an apparently continuous series of compositions from ilmenite to pseudorutile (ideally Fe2Ti3O9), and with further weathering, to leucoxene. To determine the mechanism of acid-leaching of ilmenite to ultimately form rutile, we have carried out an experimental study of ilmenite alteration in autoclaves at 150¦C in HCl solutions. Resulting products were studied by X-ray diffraction, scanning electron microscopy, electron microprobe and Raman spectroscopy. In some experiments the solution was initially enriched in 18O and the distribution of the isotope in the alteration products mapped from the peak shift in the Raman spectra. The results indicate that the alteration may proceed in two stages, each with a sharp interface between the parent phase and the product. The alteration begins at the original ilmenite crystal surface and along cracks through which the fluid can migrate. The first alteration product is pseudorutile û no phases intermediate between ilmenite and pseudorutile were detected. The textural relationship between ilmenite and pseudorutile suggests a coupled dissolution-reprecipitation mechanism rather than a solid state continuous oxidation and Fe diffusion mechanism. The second stage involves a further dissolution-reprecipitation step to form rutile. Raman spectroscopy shows that the 18O is incorporated in the rutile during the recrystallisation. Throughout the alteration process the original morphology of the ilmenite is preserved although the product is highly porous. The rutile inherits crystallographic information from the parent ilmenite, resulting in a triply-twinned rutile microstructure.

Jan 1, 2008

By W. J. Guo

Overburden movement as a result of longwall mining can be classified into, in ascending order, caving zone, fractured zone, and bending zone. Operation experience and laboratory research have demonstrated that there are bed separations in the bending zone due to differential movement and rock mechanics properties between adjacent strata. In china several coal mines have injected flyash into bed separations to prevent strata movement and control surface subsidence. This method is very effective because it can reduce surface subsidence by 35-55%. Combining the field survey results and laboratory simulation research, the author has investigated bed separation and its mechanisms and effect of backfilling the bed separation and its mechanisms. Finally backfilling application in three mines are introduced, including grout flow chart, grouting pressure, and radius.

Jan 1, 1994

By K. C. Li

TITANIUM, because of its high strength, weight ratio, and high melting point, became the metal of the jet age. Zirconium, because of its low neutron cross section and high corrosion resistance to hot water, became an integral part of the nuclear era. Since both metals are very similar chemically, more or less the same process is used for their production. The sudden rise of this new industry of titanium and zirconium seems to have caused some uncertainty as to the future development of processes for making these metals. Although zirconium was discovered in 1789 and titanium in 1790, it was not until 1945, six years after W. J. Kroll patented his process, that F, S. Wartman of the U. S. Bureau of Mines perfected the technique of producing ductile titanium, and it was not until 1946 that Kroll perfected the technique of producing ductile zirconium in commercial quantities. Since then the Government and private industry have spent millions of dollars each year constantly searching for new methods, with the hope that some day titanium can be produced as economically as aluminum and magnesium or as cheaply as stainless steel.

Jan 11, 1957

By Mauk JL, McOnie A, Simmons SF

Three cross sections, 200 m apart, display the distribution of indicator hydrothermal minerals across the Empire zone of the Golden Cross epithermal Au-Ag deposit, Waihi, New Zealand. These minerals are used to interpret the temperature and composition of hydrothermal fluids. The distribution of interstratified illite-montmorillonite and illite indicate that temperatures ranged from 140 to >220¦C, with temperatures above 220¦C predominating. The mineral assemblage of quartz-adularia-chlorite-illite-calcite-pyrite envelops the Empire vein system and stockwork, and reflects formation from an alkali chloride water, whereas the mineral assemblage of replacement calcite-interstratified illite - montmorillonite- kaolinite forms a carapace and reflects formation from a C02-rich steam-heated water. Alkali chloride waters appear responsible for the epithermal Au-Ag mineralisation.

Jan 1, 1995

By Benito Perez

Newmont Akyem mine in Ghana is committed with continuous improving results. A new environment where the price varies rapidly requires of better understanding of the deposits and the gold contained in the ore. This better understanding allows the mine planners to quick adjust and fast response to economic changes for gold price. Newmont Akyem Mine has approximately 9.4 million tons of ore in the stockpiles. Mine planers are still using average grade in all stockpiles to do a mine plan. The re-handled material is blended with the prime material coming from the mine.

Sep 1, 2017

By K. Reinhardt

THE idea of burning blast-furnace gases directly in gas-engines, instead of under steam-boilers, as had previously been done, was first put into practice barely ten years ago, almost simultaneously in Great Britain, Germany and Belgium. The pioneers of this movement made their first experiments with small engines. After these experiments had given satisfactory results, and it had been shown that the thermal value of the poor blast-furnace gases, in spite of defective scrubbing, could with safety be directly transformed into mechanical work in the gas-engine, there very soon arose a considerable demand for gas-engines of large power, similar to the large steam-engines employed in metallurgical works. In face of these sudden requirements, the gas-engine builders were placed in a difficult position; for up to that time the gas-motor was considered as suitable for small engines only, and it was generally believed that the limit of size bad been attained with 100 to 150 effective h.p. in a single cylinder. Manufacturers of gas-motors, however, did not underrate the advantages offered by this new field for their manufactures, and it so happened that in Germany the Berlin-Anhaltische Maschinenbau-Gesellschaft, of Dessau, was the first to undertake the construction of a 600-h.p. two-cycle gas-engine, with two cyl¬inders of the Oechelhäuser-Junkers type, for the Hoerder Mining & Smelting Company. The engine was started in 1898, and, with a few improvements and alterations, is still working satisfactorily. This engine worked with astonishingly high of efficiency, considering the period. The builders were therefore

Nov 1, 1906

By Mike O’Brien, Rob Croll

The Evolution of AngloGold -Incorporated in 1944 under the name of Vaal Reefs Exploration and Mining Company Limited -Name changed to AngloGold Limited in 1998 as the vehicle consolidating the gold interests of Anglo American Corporation -Diversification (geographic and orebody) through the sale of low-margin, deep level, short-life assets and the acquisition of higher margin, open-pit and shallow underground operations

Jan 1, 2003

By Aurelian Buzaianu, Cristian-Aurelian Popescu, Gabriela Popescu, Petru Moldovan

"A lot of scraps result in processing of composite materials which contain metallic phases that can be recovered and used again in different field. Considering this point of view the aim of the paper was to separate and recover aluminum from aluminum matrix/graphite composites. The separation and recovery of aluminum alloy from aluminum alloy/graphite composites was done by treatment with halide molten salts. As halide salts were used flux tablets that collect the ceramic particles in dross. After dross separation, was used filtration in order to separate the aluminum matrix from the other impurities.Samples from the recovered alloy were analyzed using chemical analysis, optical and electron microscopy, as well as X-ray diffraction. The desired composition of the aluminum alloy obtained from scraps could be reached by some addition of metals to the metallic phase. From optical microscopy it was obvious that the structure of the aluminum alloy obtained after composite reclamation consists large particle of silicon, eutectic, a-Al solid solution and other phases like Fe, Si, Mg and Ni, or some compounds like CuAl2. 1. IntroductionThe research on the recycling and reclamation of metal-matrix composites (MMCs) becomes active to preserve the natural environment, as environmental requirements become stricter, to save energy, and to reduce garbage. In case of recycled aluminum alloy ingot the production energy is about 3 pct of that of the new ingot. This evidence strongly supports the necessity to recycling of aluminum alloys. Among aluminum alloys, metal matrix composites have high strength and elastic modulus, and also good were resistance. These materials have been developed to meet the demand properties which exceeds that of the ordinary materials, and to save energy."

Jan 1, 2008

By James P. Dorian, James M. Otto

The value of exported nonenergy minerals from the less-developed countries has increased substantially between 1970 and 1985, but their market share relative to world exports has remained stagnant. Of the top twenty minerals exporters, only four are developing countries. Production capacity in the developing countries is shown to be less sensitive to demand downturns than capacity in the developed countries. Two approaches to the management of cyclical minerals demand are given using examples from India and Papua New Guinea. The authors conclude that pro¬tective policies implemented by developing nations have, barring a few exceptions, relatively little impact on the chronic nonfuel minerals oversupply problem.

Jan 1, 1989

By Stein A

The general mechanism of recrystallisation for cold worked metal is well established, and need be only briefly summarised with a few references to recent articles which clarify minor points. The types of extension, whether by stretching, drawing, hammering, rolling, etc., do not alter the general principles (1), although quantitative results may differ somewhat, particularly with regard to differences between the surface and interior of samples.These principles can be summarised as follows: The first stage in annealing is a recovery (sometimes known as relaxation) of physical properties such as hardness, elongation, etc., without any appearance of recrystallisation; the second stage involves a further alteration in physical properties, accompanying the formation of new recrystallised grains which replace the original structure; a possible third stage involves an increase in the grain size of the completely recrystallised structure by absorption of smaller grains by larger ones. These three stages will be referred to as recovery, recrystallisation, and grain growth. Depending on conditions, the three stages may be clearly marked or may occur more or less simultaneously.For a given annealing temperature, cold deformations below a certain amount fail to give recrystallisation, and the final structure consists of the original grains which have recovered and possibly become more equiaxed. When a certain deformation, critical for that annealing temperature, is given, recrystallisation can occur, and will give the maximum recrystallised grain size.Increasing deformations beyond this give progressively smaller grain sizes.For each material there is a minimum recrystallisation temperature, below which recrystallisation will not occur whatever the deformation or time of annealing. For a given deformation there is a temperature, critical for that deformation, below which recrystallisation will not occur, and above which it will take place with increasing rapidity.

Jan 1, 1947

By S. A. Voltura

The Phelps Dodge Miami smelter has smelted copper concentrate using the ISASMELT technology since 1992. The design throughput rate was 591,000 tonnes/year and after a slow start-up, the production rate has exceeded the design after the seventh year of operation. In 2002, the smelter consumed 719,000 tonnes of copper concentrate and has the potential to hit the permitted rate of 772,000 tonnes/year. Improvements to the smelting vessel and the surrounding support processes have allowed for continuous improvement from start up until now. This presentation will outline the chronological events and the improvements completed to accomplish these improvements

Jan 1, 2004

By Rasik H. Raythatha

Calcium carbonate is perhaps the most widely used mineral in the world. With total consumption of all calcium carbonate exceeding over 25 million tom per year, within this class of filler, a relatively smaller segment of precipitated calcium carbonates (PCC) is often misunderstood as a commodity product and bundled in the same category as ground calcium carbonate. However, each material has a distinctly digerent role and characteristics. Precipitated calcium carbonates are used to influence specific performance in a specific application whereas ground calcium carbonate is used primarily to reduce cost in many applications. In this paper, attempts are made to demonstrate the role of nano-fine-PCC in improving shear-thinning characteristics of common and specialized sealants and automotive underbody coating and how such "nano-particle" cal- cium carbonate properties can be exploited to process PVC plastics while reducing overall cost. We also review the role of precipitated calcium carbonate as "nano" material and why it must be viewed as a specialty additive.

Jan 1, 2003

By Shonhardt JA, Bagster DF

This paper firstly examines the pollu- tion potential of burning colliery wastes. A comparison of two means of estimating the pro- pensity for coal to combust spontaneously is next presented. The use of microwaves, as a new procedure, is discussed in detail, while a comparison of the results is made with a modi- fied adiabatic technique. A number of coals that are known to combust spontaneously was tested, as were some coals that are not consi- dered to have self heating potential.

Jan 1, 1987

By Heyes GW, Orrock GI

The fine grained complex orebody at Elura contains galena, silver and sphalerite in a matrix which is mostly pyrite; sulphides account for about 90% of the orebody. A differential flotation circuit is operated to con- centrate lead and silver in the first section and zinc in the second. The metallurgical performance to date indicates the need for improvement. The lead section has been sampled in detail to comprehensively assess its overall performance and to define problems associated with lead and silver flotation. The substantial amount of pyrite in the feed dominated the perfor- mance of each stage of the separation. It was responsible for extensive dilution of all concentrates and, as a consequence, for very large circulating loads. The rougher concentrate contained 68% pyrite some of which was rejected through the three stages of cleaning to 39% in the final concen- trate. However, this was still sufficient to hold the assay of this product below 45% Pb. Size by size behaviour shows that flotation rates of the valuable minerals, as characterised by their rate coefficients, were low through- out the circuit. There was a significant deterioration in these rates between rougher and cleaner I stages which resulted in large circulating loads between these stages. There was practically no recovery of coarse valu- able minerals to the final concentrate. The dilution of the final concen- trate by non-sulphide gangue was not a major problem. If the recovery of the galena and silver in the +38¦m size range could be raised to that of the - 381Lm size range, galena recovery would rise from 78% to 86% and silver recovery would improve from 46% to 59%. The Pb grade of the final concentrate would remain the same.

Jan 1, 1988

Recent and on-going studies on the leaching of gold, the properties and activity of carbon, developments in the elution of gold from carbon, and methods of recovering gold from solution are reviewed. Emphasis is placed on Australian contributions, and their impact on gold metallurgy. Consideration is given to the future development of selective solvent extractants, ion exchange resins or alternative reagents for cyanide.

Jan 1, 1987

By Naj Aziz

A series of laboratory experiments were conducted on a variety of bolt types to examine the load transfer capacities of different profiled bolts in short encapsulation push testing. A 75 mm section of 150 mm long bolt specimen was anchored in a 75 mm long stainless steel tube using full resin encapsulation. Six types of different profiled bolts and two non - profiled bolts were tested. Bolts with higher profile were in general found to have greater shearing resistance and higher stiffness than low profile bolts. Widely spaced profiles allowed greater displacement at peak shear strength, and bolts with no profiles produced very link load transfer capability. Rough surfaced plain bolts showed a significant load transfer capability in comparison to a factory supplied smooth surface bolt which supports the belief that rusted bolts have higher lnad transfer capability that un-rusted bolt surfaces.

Jan 1, 2003

By J. J. Knoerzer

A full-scale operational test was conducted on the Coaltek preheating and pipeline charging system at the Semet-Solvay Div. of Allied Chemical at Ironton, Ohio, for the purpose of determining whether a high-quality blast furnace coke could be made from blends containing at least 75% Illinois No. 6 Coal and at the same time reduce air pollution during the charging of the ovens. The coke produced had similar physical characteristics as compared to our conventional wet-charged coke, with the exception of smaller size for the preheat coke. Air pollution during charging was con- trolled and there were no serious operating problems. The coking time was reduced 25% from our normal 17 hr for wet charging to 12.8 hr for preheated charges. The blast furnace performance with preheat coke was satisfactory.

Jan 1, 1976

By John T. Norton

In spite of the very general errlployment of nitride hardening, there is still considerable doubt as to the real nature of the mechanism involved. Experience has shown that the addition of small amounts of hardening elements to iron or steel results in a wide variety of desirable properties in a nitrided case. Perhaps the foremost of these elements is aluminum and in this investigation an attempt has been made to study the behavior of aluminum during the hardening process. It is believed that the establishment of a complete atomic picture of the metal at various stages of the process will indicate the relationships between the several kinds of atoms and their individual influences on the physical properties in a clear and direct fashion. A consideration of the problem suggests a surprising similarity between the mechanisms of nitride hardening and of age-hardening. It is now generally understood that age-hardening may take place by one of two distinct processes, the first involving the precipitation of a finely dispersed phase and the other being concerned with the modification of an existing phase. Following much the same line of reasoning, two theories of nitride hardening have been suggested. The first explanation, which has been generally discussed, particularly by Fry,' states in brief that the presence of aluminum causes the precipitation of aluminum nitride during nitriding and that this finely dispersed phase is the primary cause of hardening. The second explanation, which has not been published but which has been freely discussed by those interested in the problem, postulates the substitution of aluminum atoms for certain of the iron atoms in the several iron-nitrogen phases in the same manner that the substitutional iron-alurninurn solid solution is formed. The marked increase in hardness, as compared with the aluminum-free system, is attributed to the severe lattice distortion accompanying this replacement.

Jan 1, 1934

By H. Asgari, A. G. Odeshi, J. A. Szpunar

In the present study, the dynamic response of AZ and AE cast magnesium alloys to shock loading, are compared for strain rates ranging between 900 and 1200 s-1. Texture measurements showed that after shock loading, the (00.2) basal texture component of both alloys was strengthened. However, the strengthening magnitude was higher for AE samples. Also, it was observed that the twinning fraction decreased in both alloys with increase in the amount of alloying elements. In addition, cracks are formed at the interface between matrix and second phase particles in the AZ alloys. However, crack nucleation and fracture in AE alloys occurred at the sites where twins accumulated. Furthermore, analysis of the dynamic mechanical behaviors showed that the ductility of AE grade is higher than that of AZ alloy for all strain rates used in this research. This difference was explained by differences in deformation mechanisms of these alloys.

Jan 1, 2014

By C. Bourgoin

"The limited development and application of new technologies to narrow-vein mining is currently impeding progress in the industry to a point where productivity, working conditions and operating costs have reached a critical stage in many Canadian mines.In an effort to foster the emergence and application of new technologies, Université Laval, together with other organizations, has carried out a R&D project focussed on the need of identifying new development pos5ibilities and of facilitating the transfer of technology in matters related to underground mining methods and machinery.The first phase of the study consisted of an in-depth assessment of current practices and problems in narrow-vein mining. The second phase was a state-of-the-art survey of mining methods and equipment, together with proposed modifications and innovations. The third phase of the project concerns the experimental development as well as the principal application of various proposed technologies.This paper presents an overview of the organizational, technical and strategic considerations which guided the University group and it serves as well to introduce a newly-published brochure, entitled ""Underground Mining Techniques of Vein Deposits"", which summarizes such work to date. More specifically, a perspective of technological developments applicable to narrow-vein mining is presented."

Jan 1, 1994