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By S. Balideh

A good understanding of the behavior of rock helps us to make more informed decisions regarding geo-structures. Engineers need accurate equations to calculate the strength and deformation of rock before and after failure. Previous studies explain the failure of rock to ultimate strength, and laboratory tests adequately determine the ultimate strength and deformation modulus of rock. However, there are few comprehensive equations to determine the post-failure strength and deformation of rock. Previous work shows that the post-failure behavior of rock depends on the behavior of the broken rock particles after failure. The following question is then posed: How can the post-failure behavior of rock be determined by the behavior of broken rock particles? In order to answer the question, this study pursues three objectives: (i) to explain the behavior of broken rock at low confining pressure; (ii) to estimate the behavior of broken rock via the extrapolation of scaled laboratory testing; and to suggest a procedure (iii) to outline the post-failure behavior of a rock mass at low confining pressure commensurate with the behavior of broken rock in a rock mass.

Aug 1, 2013

By Ralph W. Barbaro

This paper presents a cyclic queueing model which evaluates the productivity of a shovel-truck materials haulage system. For a cyclic queueing problem with exponentially distributed service times, a cyclic queueing model provides exact solutions in a fraction of the time that simulation takes to produce an approximate solution. The model is applied to an example problem, and the results are validated with simulation. Simulation is used to show that the assumptions of exponentially distributed service times and steady-state are not serious problems. A cyclic queueing model can be used to quickly obtain an accurate assessment of the productivity of a shovel-truck system.

Jan 1, 1986

By John A. L. Campbell

Surface dependent processes, such as froth flotation and flocculation, are important or potentially important techniques for combating some of the current major problems in coal preparation. In order to correctly apply or imporve a surface dependent process, it is of paramount importance to understand the interfacial phenomenon, especially the double layer properties, exhibited by the solid. The specific objective of this research was to determine the properties of the bituminous coal/liquid interface by an electrokinetic method, streaming potential, and to relate the findings, wherever possible, to the existing unit operations of froth flotation and flocculation. The electrokinetic properties of both the whole coal and its lithotypes were investigated. As part of the total investigation, the role played in the double layer by the reagents commonly employed in the surface dependent process was also established (1). These data will be presented at a latter date.

Jan 1, 1969

By Joan K. Kuenzi

The purpose of this U.S. Bureau of Mines information circular (Ie) is to discuss how job analysis methods taken from different disciplines can be used together to form a more complete picture of jobs in the mining industry. "Job analysis" is a term used by many researchers, but use of the term is far from standardized. Authors of papers on this subject often state that there is confusion in how or why jobs are to be analyzed, what the resulting information is to be used for, and what the "job analysis" actually means. The process of breaking a job into elemental tasks and analyzing them is used to determine what skills and knowledge are needed to perform a given job, to improve efficiency, and to develop safer job procedures. All are valid reasons to analyze jobs, but the methods used to accomplish the analyses may be very different. In order to create a more complete picture of a job, it may be useful to incorporate methods and information from different areas of study rather than choosing one method for analysis.

Jan 1, 1995

By S. Middlemiss

The Indentation Fracture technique is being developed as a tool for use in comminution and mineral liberation analysis. Fracture toughness measurements for a number of mineralogical materials were made and comparisons were drawn between these and properties measured with the Ultrafast Load Cell drop weight apparatus. The technique has also been used as a probe to quantify differences in fracture properties at different areas in the microstructure of a material. In both a Utah limestone and a South African quartzite, material near a grain boundary fractures very differently to that in the bulk. Ongoing work is ultimately aimed at producing a comprehensive fracture model for a multi-mineral system based on its micro-fracture characteristics.

Jan 1, 1994

By Syd S. Peng

The key design parameters of roof bolting using expansion - shell type support for underground coal mine roof support are bolt length, bolt spacing, installed load and anchorage capacity. Depending on the utilization of suspension effect or friction effect, the bolt length is dictated either by the distance between the roof surface and the first overlying strong strata encountered or the desired magnitude of reduction in bending stress at the roof surface, The current prevailing practices about the bolt spacing and installed load are that an initial torque of 125 - 170 ft-lbs is applied and the bolts are spaced at 4- or 5- ft. square grid pattern. This seems to be a rather broad generalization in view of the great geological variances which are expected in underground coal mines. A modest evaluation program to measure the effectiveness of current roof bolting practices is to monitor the load history of roof bolts during a complete mining cycle including the phases of room development and pillar robbing. The load history, when compared with the anchorage capacity of roof bolts determined by in-situ pull tests, will provide information for evaluating the installed load, the bolt spacing as well as the specifications for structural and anchorage characteristics of the bolt assemblies. This paper presents a case history of monitoring the complete load histories of roof bolts in an underground coal mine of Pittsburgh seam.

Jan 1, 1976

By R. N. Gow

EH-pH diagrams are useful tools in understanding how mineral surfaces react in solution and particularly how aqueous conditions can be changed to enhance mineral leaching processes. However, successful application of these diagrams requires several things be kept in mind to prevent what others have termed ?gross errors? in their calculation and use. The aqueous Cu-S system is used as the basis for explaining the mass-balanced method of calculating EH-pH diagrams with the thermodynamic equilibrium software, STABCAL. This includes a breakdown of the Gibbs? Phase Rule and how it is employed in STABCAL to modify the diagrams. This methodology was then applied to the aqueous Cu-As-S system and resulting diagrams are compared against examples of those generated using the predominant-ion method. The resulting mass-balanced diagram for enargite (Cu3AsS4) is noted to compare well with spectroelectrochemical measurements using Raman spectroscopy and cyclic voltammetry.

Feb 23, 2014

By D. Pawelus, J. Butra, R. Debkowski, M. Szpak

Impact of horizontal stresses on stability of underground workings in mines is a very important issue in underground mining. Identification of the initial state of stress in the rock-mass should be one of the main actions taken into account while designing and carrying out the mining activity in underground mines. The paper presents the tests on three dimensional stress pattern in Polish copper mines, owned by KGHM Polska Miedz S.A. Group, carried out in 2012. The research program covered 7 measuring stands in two mines; their average depth was about 1000 m. The main aim was to identify the values and directions of horizontal stresses in order to optimize the extraction and to improve the safety. The overcoring method with the use of CSIRO HI type probe was applied. The paper also describes the measuring technique which was developed for the purpose of specific mining and geological conditions of KGHM mines, taking into consideration the natural hazards encountered there as well as technical and operational capabilities with regard to drilling equipment. The experience gained during the underground measurements and the issue of making such measurements in underground copper mines in Poland are presented in the paper. The stress patterns obtained during the underground measurements are of application importance for the process of designing the spacing of mine workings and improving their stability and mine support selection.

Jan 1, 2015

By Keith A. Heasley, Christopher R. Newman

"Originally developed in 1993, LaModel has aided mining engineers and researchers alike in improving the design and safety of underground single- and multiple-seam mining operations (Heasley, 1998). Through the years (Heasley, 2011), the use and capabilities of the LaModel program have grown immensely while adapting to ground control concerns and problems within the mining industry. Presently, MSHA specifically mentions the use of LaModel for the analysis of, “complex non-typical roof control plans,” defined as either room-and-pillar retreat mining greater than 1000 feet, bump- or bounce-prone mines, or other criteria considered unusual by the District Manager (Stricklin, 2013).With an ever increasing number of users and an increase in available solution options and complex analyses, there is now a significant demand for better education and training in the practical application and detailed analysis using LaModel. This paper presents the development of an electronic user’s manual and comprehensive online training course created in an open online learning environment in order to better inform and train industry professionals as well as engineering students and new users. The development of both the user’s manual and online training course will ultimately increase the ground control design effectiveness of mining engineers, leading to safer and more productive mine designs.INTRODUCTIONOver the past 20 years, mining engineers and researchers have used the LaModel program for improving the design and safety of single- and multiple-seam mining operations. LaModel uses a laminated, displacement-discontinuity, boundary-element method which simplifies the overburden into a stack of frictionless homogeneous laminations and limits the detailed analysis to the seam itself. This approach is fundamentally simpler than either finite-element, finite-difference, or discrete-element approaches; and, therefore, the program provides a significant reduction in computational time and efficiently calculates the displacements, stresses, pillar safety factors, multiple-seam interactions, subsidence, etc. for thin-bedded deposits such as coal, salt, potash, limestone, etc. (Heasley and Salamon, 1996; Heasley and Agioutantis, 2001). The laminated overburden model in LaModel is different than previous homogeneous elastic formulations and more realistically represents the natural flexibilities of the stratified sedimentary overburden typically associated with coal seams (Heasley, 2008)."

Jan 1, 2015

By M. Ghiani

Biohydrometallurgy originated, some forty years ago, from an environmental problem, namely the serious pollution of the Ohio river by acid drainage water coming from neighboring subbituminous coal mines. Studies aimed at elucidating the cause of the intensive oxidation of the iron sulfide (pyrite) inclusions of those coals, led to the discovery of a bacterium, Thiobacillus ferrooxidans (Temple and Colmer, 1951), capable of acting as a catalyzer, accelerating the otherwise very slow chemical oxidation of iron sulfide to rates many orders of magnitude higher. However, it is now recognized that the biotechnology of microbial mining dates back to 1963, when the ability of this bacterium to solubilize copper from sulfide ores was ascertained (Razzell and Trussell, 1963). Much research has been carried out on biohydrometallurgy over these last 25 years and is still being actively conducted all over the world. The interdisciplinary nature of this young branch of science and technology is reflected by the variety of experts involved: microbiologists, mining engineers, hydrometallurgists, physico-chemists, mineralogists, solid-state physicists and biochemists. This intensive research effort has provided a solid background on the fundamentals of this technology, although many important issues have still to be solved, amongst which the enzymatic mechanisms controlling biocatalysis of mineral sulfides dissolution, the influence of bulk- and surface solid-state physics of metal sulfides on dissolution mechanisms, the interaction of the various strains composing natural microbial floras. Their elucidation should permit the rationalization of biohydrometallurgical techniques and the optimization of commercial processes. Biohydrometallurgy has already achieved satisfactory results: copper recovery from submarginal copper sulfide run-of-mine ores (i.e. assaying less than 0.3% Cu) by in-situ, dump and/or heap leaching is successfully practised in many countries and uranium recovery through bioleaching is competitive with other leaching processes.

Jan 1, 1987

By G. Guiglionda, A. Deschamps, F. De Geuser, M. Langille, B. J. Diak

"Increased demand for light-weighting in passenger vehicles has created a need for strong, light, ductile materials to be used in body-in-white applications. The AA6xxx-series of aluminum alloys are suitable candidates meeting most requirements but can fall short of the formability demands of designers, necessitating an understanding of what controls the formability in this alloy series. This work examines the effect of copper alloying in AA6xxx on the pre-ageing and natural ageing responses of the microstructure and mechanical properties. The changes in microstructure observed by differential scanning calorimetry and hardness testing are related to the work-hardening and strain-rate sensitivity parameters for these alloys measured by tensile testing. An observed asymmetry in the measured strain-rate sensitivity associated with increasing versus decreasing strain rate changes suggests that a different mechanism operates for the two conditions. It is postulated how this asymmetry in strain-rate sensitivity will impact the necking and ductility behaviour of these alloys.INTRODUCTION The widespread use of AA6xxx series alloys in the form of sheets has provided the need for a more thorough understanding of the complex interactions between composition, processing, resulting microstructure and ultimately, the mechanical properties of the alloys. Conventional industrial practices involve the production of rolled AA6xxx sheet (typically 1 mm thick) to be used for body-in-white (BIW) applications for auto body panels (Hirsch, 2004, 2014). The final metallurgical step prior to the shipment of these panels to manufacturers involves a solution heat treatment (SHT) reverting the ageing products of the alloys into solid solution and the product is then shipped to the customer. During this shipping time and while sheets are waiting to be used, the natural ageing (NA) process occurs whereby the strength of the alloys increases resulting in reduced formability. This can result in a product that is unable to meet the formability demands of the automotive manufacturer. As a result, industry has moved towards performing pre-ageing (PA) treatments to prolong the “shelf-life” of the material prior to it having insufficient formability. Once formed into BIW panels, the parts are then painted and subsequently undergo the paint curing heat treatment which consists of a short period of time at medium temperature, typically 20 minutes at 170–190°C. This short artificial ageing (AA) treatment, known as the paint bake (PB), provides additional strength and improved dent resistance for the material, but reduced formability. The PB result is strongly dependent on the PA treatment performed prior to the forming operation. Furthermore, the addition of copper (Cu) to a base Al-Mg-Si composition is known to increase the alloy’s strength. The goal of this work is to study the effect of Cu on strength, strain hardening, and strain-rate sensitivity (SRS) of these alloys, to understand the strength-formability compromise, for two separate heat treatment schedules; one including and one excluding the PA treatment, both followed by NA."

Jan 1, 2018

By Zhiyong Gao, Ruiying Fan

"Crushing and grinding are the prerequisite processes in many industries, such as minerals processing and powder technology. During crushing and grinding, minerals will cleave or fracture along the directions by broken the interlayer bonds (e.g., ionic bonds), generating some commonly exposed surfaces. The broken (or dangling) bonds at the generated surface makes the surface more active and determine the reactivity of the surface. In this work, the population of broken (or dangling) bonds on commonly exposed surfaces of fluorite mineral (a chosen model mineral) was calculated. Based on the calculated broken bonds information, the anisotropic surface reactivity of fluorite such as surface energy, surface relaxation, dissolution, wettability, surface charge and adsorbability, were discussed. The results show that the surface broken bonds density, which is positively related to the surface energy, can be used to predict the cleavage nature, surface relaxation degree and surface stability of fluorite crystal. The distribution characteristic and the number of broken (or unsaturated) bonds of surface active atoms (like Ca for fluorite crystal) can be used to predict and explain the anisotropic wettability, surface charge and adsorption mode and strength of organic molecules on different commonly exposed surfaces. It is easy to conclude that the calculation of surface broken bonds can serve as a fast and accurate way to start the mineral chemistry studies. These findings will be helpful to the mineral/material chemistry research in related interfacial science communities.INTRODUCTIONGrinding for mineral liberation is a prerequisite for a successful flotation separation. Also grinding for size reduction is a prior process for a favorable powder technology. During the grinding process, the minerals / materials will cleave and fracture along certain crystal directions with relatively weak interlayer chemical bonds1 to form a number of common exposed surfaces. Exposed surfaces are the outer boundary of a solid substance. In the mineral / material block, the bonding orbital of the atoms is filled with electrons and the atoms are in a steady state. Atoms on these exposed surfaces appear to show dangling bonds (or broken bonds) by losing chemical bonds to adjacent atoms in the previous block. Therefore, surface broken bonds serves as an initial property of a fresh surface. The lattice arrangement and crystal orientations causes differences in the number of dangling bonds on each exposed surface, i.e., anisotropic surface broken bonds2. The anisotropic dangling bonds enable the exposed surfaces to show varying degrees of surface reactivity (including surface energy, surface charge, surface relaxation, dissolution, wettability and adsorption behavior), known as anisotropic surface reactivity."

Jan 1, 2018

By Yuanfei Chen, Jianfeng Zha

"China is the largest producer and consumer of coal in the world. The mining-induced surface subsidence has bad influences on the surface and structures above the surface. In order to minimize disasters, removal, reinforcement, or maintenance structures are often adopted. In the application of maintenance methods, it is necessary to carry out dynamic surface subsidence prediction to choose maintenance methods, optimize maintenance time, and evaluate the amounts of work. Time series methods and influence function methods are common for dynamic surface subsidence prediction, but the former is difficult to consider with underground mining conditions, and the latter has low prediction precision. Therefore, this paper develops a dynamic subsidence prediction model aided by field-measured data and realizes the model programming. The model could achieve high-precision prediction of dynamic surface deformation through optimizing the parameters in time by using field-measured data of surface subsidence. The research results of engineering cases show that, with the method of dynamic prediction, the standard error can be controlled in the range of 5%, greatly improving the accuracy of dynamic prediction of mining subsidence, which provides strong technical support for the maintenance and management of structures. INTRODUCTION With the rapid economic development and continued industrialization process, the demand for energy is growing in China. Today, China is one of the largest coal, oil, and gas consumers in the world. Coal consumption accounts for 47.7% of the total consumption in the world (Tian, 2016). In order to meet the demand for coal resources in the process of modernization, more and more coal mines carry out coal mining under villages, buildings, highways, and bodies of water. The mining-induced overlying strata and surface subsidence have bad effects on surface and on various structures (such as buildings, railways, highways, high-tension transmission lines) and could even cause various disasters (Williams et al., 1998; Bell et al., 2000; Doyle et al., 2002). Generally, methods, such as removal, reinforcement, or maintenance are taken to eliminate the adverse impacts (Kraatz, 1984; Bell and Genske, 2001; Wang, 1989). When reinforcement or maintenance is selected to remove bad effects, the proper maintenance methods must be chosen. In addition, maintenance time, as well as an evaluation of time it will take to do the work are necessary to predict the surface subsidence with high precision."

Jan 1, 2017

By W. G. Pariseau

Face and pillar bursts, bumps and bounces are violent failures that occur in underground coal mines in response to a complicated interplay of face and pillar geometry, seam depth, coal strength and moduli and interactions between roof, seam and floor strata. Additional complications arise from the presence of gas, mainly methane, and associated pressure and flow that vary with time and are further influenced by the rate of face advance. Numerical models provide a means of quantitatively accounting for the various complications of mining geometry, the stratigraphic column, mechanical properties, gas flow properties and associated interactions. A fully coupled hydromechanical finiteelement code, utAH4, serves the purpose well and allows study of the important interaction between stress concentration and gas pressure in determining safety and stability of the face during the advance of a longwall panel in a deep underground coal mine in central Utah. Face advance is relatively fast compared with gas flow and depressurization in coal seams of low gas permeability. Consequently, gas pressure is high at the face. When a longwall is stationary, depressurization occurs at the face, so effective stress and strength increase. thus, when gas flow at the face is high and requires a pause in face advance to bring gas concentration to an acceptable level, a second benefit occurs because of timely depressurization. However, quantitative analysis of a deep coal mine shows that regardless of gas pressure, high stress concentration is more likely to pose a threat to face and pillar wall stability.

Aug 1, 2013

By Mark E. Gershon

Conventional methods of drillhole site selection are reviewed briefly. Two approaches using geostatistics are then discussed, both of which have been shown to yield improved results. Finally, a branch and bound algorithm is described which will select the best locations for drilling from a user specified number of possible drill sites. Two options are discussed. First, the user can specify a maximum drilling investment or a maximum number of drillholes and the program will select the locations yielding the minimum estimation variance. This amounts to getting the most for a given investment. Alternatively, a maximum tolerable estimation variance can be specified and the program will select the number and location of the drillholes to obtain the desired information at a minimum cost. Another benefit of the approach is the quantification of the tradeoffs between investment and information obtained.

Jan 1, 1983

By Robert F. Shurtz

This paper suggests that pre-occupation with the random process model notised by geostatisticians may result in neglect of more promising techniques, especially since the random process model does not appear to be essential to current geostatistical procedures. This point of view is emphasized pictorially. To emphasize the potential of new techniques a simple application of the conventional Brownian function is described. The probabilities estimated in this truly random way are different from those estimated by Kriging

Jan 1, 1980

By D Liu, M Edraki, L Berry

The presence of clay minerals slows down the settling rate and mitigates compact consolidation efficiency in tailings dewatering. The increasing use of saline water in many plants, affects the dewatering performance and presents the mining industry with new concerns. Efficient tailings dewatering is a great challenge due to the complexity character of tailings, especially clay mineralogy, clay content, and water chemistry. In this study, existing studies of the effect of different affecting parameters, such as pH, ionic strength and polymer flocculants, on clay aggregation behaviours are reviewed. The settling behaviours of three types of commonly observed clay minerals in tailings, kaolinite, bentonite, and illite, are also investigated in saline water with different water salinity as a case study. The settling rates of clay minerals are found to be affected by water salinity, clay type, clay content and polymer dosage levels. High salinity water hinders the settling of kaolinite but assists the settling of bentonite and illite through formation of different aggregation structures.The current work has indicated that strategies to promote more rapid dewatering could include adjusting flocculant type or level, water salinity and salt balance, and tailings solid content levels. Implementing dewatering strategies may require a more detailed knowledge of the effect of surface chemistry on the nature and strength of the clay inter-particle forces. This study discusses the research gaps on how to better manage clay-rich tailings in saline water and identifies new research directions. The development of a water management model, supported through in-line monitoring data to predict and manipulate of the surface chemistry of the clay component of the tailings could be a new direction to manage the issues associated with clay minerals in the process of dewatering and tailings management. Mine planning (water use requirements, operating costs) could benefit from more detailed studies on dewatering of clay-rich tailings in saline water. CITATION:Liu, D, Edraki, M and Berry, L, 2018. Improving the dewatering efficiency of clay-rich tailings in saline water, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 476–484 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By M. N. Plis

This report describes the initial results of long-range research on bit life conducted by the Bureau of Mines. Three commercial bit designs -a round-nose radial, 60° conical, and 90° conical with tungsten carbide (WC) inserts -and five experimental bits were tested. Four of the experimental bits were radial designs using polycrystalline diamond compact (PDC) inserts. The fifth was a 90° conical with an oversize WC insert. Bits were worn on a high-silica sandstone typical of coal mine roofs. The bits were mounted on a 34-in-diam drum section that provided a bit speed of 565 ft/min. Cutting forces were measured on a modified vertical slotter using a three-axis force dynamometer and recorded on an FM magnetic tape recorder. Changes in cutting forces, bit weight, and airborne dust due to gradual abrasive wear and catastrophic insert failure are presented. Tabulated and graphed data, photographs of the progression of bit wear, and selected qualitative visual and auditory observations of the bits taken throughout the experiment are found in the appendixes. The results show that bit life ranged from approximately 16,000 ft for the WC round-nose radial bit to over 125,000 ft for a PDC round-nose radial. Performance, in terms of bit life, cutting forces, wear rate, frictional sparking, machine vibration, and noise was in general best with the PDC bits, followed by the rotating WC bits, with the nonrotating WC bits (round-nose radial and locked 60° conical) being the worst. The results show variations in the included tip angles of new conical bits have an insignificant influence on bit performance when the effects are averaged over the life of the bit. In addition, new bits were generally found to entrain more primary respirable dust for a given cutting distance than worn-out bits. It is hypothesized that this is due to the difference in frictional behavior between new and worn bits. The results from these tests are being used in the Bureau's cutting system model (CSM).

Jan 1, 1988

By R. Fukuzawa

"The objective of this research is to evaluate the magnitude of carbon prices required to drive process development and innovation for the global nickel industry in a direction that tackles the multifaceted sustainability challenges that the industry faces, including air pollution reduction and greenhouse gas abatement. The results suggest that the currently considered carbon prices are not sufficient to drive innovations in processing methods or upstream pollution prevention. The co-benefits of climate change mitigation and pollution prevention cannot be readily realized under climate change policy alone. Increased coordination between climate change policy and performance-based environmental legislation is necessary. INTRODUCTIONNickel is an important metal in our modern society as it is used in stainless steel, alloys, electroplating and rechargeable batteries, all of which are integral to our economic growth and development (Eckelman, 2010).However, nickel production is energy intensive and therefore susceptible to emerging climate change policies, which may lead to production curtailment and/or increased unit costs of production unless changes in efficiency or energy sources are made (Mudd, 2010). The industry is faced with multi-faceted constraints: future technology must not only deal with metallurgical, financial and environmental constraints but also promote low energy and low carbon practices. This presents a challenge for this industry where technology innovation, development and commercialization are often lengthy, risky and costly processes (Imrie, 2006).Climate change is one of the many challenges faced by our society. Others include other pollution to air, water and land, resources shortage and economic development. From a policy perspective, it is important to balance multiple and often competing needs in an integrated manner. It would require some levels of trade-off in order to maximize the overall effectiveness but also to ensure that one policy does not undermine other policy objectives.The aims of this study are to evaluate how developments in climate change policy would affect the nickel industry in the context of existing environmental regulations and how the industry could respond under these constraints."

Jan 1, 2012

By F. Dinter, S. A. C. Hockaday, Q. G. Reynolds

The thermal decomposition of carbonate minerals as pre-treatment before smelting reduces the energy requirement for smelting. It can also make the combustion of fossil fuels for heating unnecassary. Thermal decomposition may become important in reducing greenhouse gas emissions when producing ferromanganese alloys while simultaneously reducing electrical energy demand during smelting. A kinetic reaction rate model for the thermal decomposition of manganese ores is presented, based on published reaction rate kinetics for the decomposition of manganese oxides and calcium carbonate. The model was validated against thermogravimetric data for two carbonaceous manganese ore samples and one ferruginous manganese ore sample. The reaction rate model shows that carbonate minerals in the manganese ores are decomposed at temperatures above 900 °C while pyrolusite is decomposed at temperatures from 450 °C to 500 °C. Mn2O3 decomposes rapidly at 550 °C. Braunite decomposition at temperatures below 1000 °C was negligible. The presence of organic carbon in the samples led to further reduction of the samples during thermal treatment.

Aug 3, 2023