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By F. Baczek, S. S. Rocks, D. Chaiko, T. Walters

The atmospheric leaching of chalcopyrite concentrates using acidic ferric sulfate lixiviants is well known to suffer from slow leach kinetics and poor copper recoveries. A number of approaches have been proposed for improving both leach kinetics and recoveries in this system. Many of these, while effective, suffer from high CAPEX and/or OPEX. As many mine sites begin transitioning from heap leaching of copper oxides to processing of primary copper sulfides, cost-efficient leach processes that are compatible with existing SX/EW processes will be needed to maintain existing cathode production. To this end, FLSmidth is exploring process options and reactor technology for the hydrometallurgical processing of primary sulfides. One approach that appears to be highly effective at increasing copper recoveries takes advantage of the enhanced reactivity of transitory, surface-defect structures generated during particle fracture. Significant process efficiencies are gained by matching the rate of grinding to the rate of electrochemical leaching in Mechano-Chemical leach processes. The patent-pending FLSmidth® ROL process uses a Stirred Media Reactor (SMRt reactor) to achieve copper recoveries of 97+% in 6 hours or less. This approach overcomes many of the surface passivation problems that have hindered other atmospheric leach processes. New insights to leach mechanisms are presented.

Jan 1, 2015

By Karl S. Vorres

Coal my not seem like it, but it is a perishable commodity. The basic coal scientist cannot always replicate earlier experiments with a given sample because of changes that have taken place in the sample. This has led to a stated need for stable samples Coal looks like a uniform black solid to many people, but it does vary in its composition from state to state and mine to mine it also can be shown to vary significantly within a mine or seam. These variations have led to a stated need for consistent samples.

Jan 1, 1985

By Jennifer S. Riefenberg

The U.S. Bureau of Mines conducts basic and applied research related to predicting, eliminating, and/or controlling rock bursts in underground hard-rock mines and coal bumps in underground coal mines. An important element in this research is the development of a reliable and efficient microseismic source location technique. This report presents the results of a Bureau study to develop and evaluate a new algorithm to locate microseismic events based on the Simplex method, a powerful linear programming technique. The technique was tested on both field data and simulated data. Microseismic event source locations obtained with this new Simplex-based algorithm were shown to have less error than those locations obtained using a least squares method. It was concluded that the Simplex approach to source location of microseismic events can be used effectively in microseismic monitoring.

Jan 1, 1989

By R. L. Ziegfeld

It has often seemed to me that people are too prone to turn to new and untried materials in an effort to solve their problems, without giving sufficient consideration to the old stand-bys, except as a last resort, It?s a little like middle-aged men who are swept off their feet by the fresh beauty of a young girl without first considering the many advantages that a more mature woman has to offer. Maybe it?s because, like the older woman, the older materials have to make a determined effort to keep themselves looking young and attractive. T at?s just about the situation with which the lead industry is laced. We have to make a determined effort to keep lead looking young and attractive to industry. However, there is one difference and it is important, Lead can not only be kept looking young, but it can, in fact, actually be kept young, This results from two things. First, industry and technology are constantly changing. For example, we have known for years that the density of lead makes it ideal to stop gamma rays, but it is only recently that atomic fission as a source of gamma radiation has become an important tool of industry, That makes old knowledge about lead useful in developing a new market for it.

Jan 1, 1958

By James R. Jones

The tempo of air pollution control regulations has increased dramatically in the past few years. Because coal mining operations are frequently located in remote areas away from urban developments, specific regulations applying to coal mines have received lower priority and are thus only now being promulgated and/or enforced. Therefore, many mine operators are not yet familiar with the regulations and the impact upon their method of operations. Few have been faced with an inspector on the property sighting them for specific violations. Several of the Mid-western states are just now requiring permit applications to be submitted.

Jan 1, 1973

By Lynn Huntsman

INTRODUCTION The Sunnyside mines of Kaiser Steel Corp. are lo¬cated on the west flank of the Book Cliff Range, a tongue of the Wasatch mountain range in Utah. The mines are 193.12 air km (120 air miles) southeast of Salt Lake City and 40.23 km (25 miles) east of the town of Price. The area has a semiarid climate with an an¬nual rainfall of 304.8 to 381 mm (12 to 15 in.) and a temperature range of -23.3 to 32.2°C (-10 to 90°F). The base of the Book Cliff Range is approximately 1981 m (6500 ft) in elevation with some mountain peaks in excess of 3048 m (10,000 ft) (Fig. 1). The Sunnyside mines were opened in the late 1890s and have been operated continuously since that time. Kaiser Steel leased the No. 2 mine in 1942 and pur¬chased the entire property in 1950. There are three mines adjacent to one another, each with its separate access, ventilation, and haulage. The three mines en¬compass an area extending 12.87 km (8 miles) along the outcrop and dipping northeasterly 2.41 to 3.22 km (11/z to 2 miles) into the Book Cliffs. During 1975, only the No. I and No. 3 mines were operating to sup¬ply 908 184.7 t/a (1,000,000+ stpy) of clean coal to the Kaiser Steel mill at Fontana, CA. Sunnyside coal is blended with coal from the Kaiser Steel mine near Raton, NM, and with purchased coal from noncompany sources to form the mix for the coke ovens. At that time, Sunnyside operated three longwall units and five to seven continuous miner units. Typical production for that time came from one miner unit pillaring an area not conducive to longwall mining; one or two miner units on construction or modernization projects, and the remaining units used to develop future longwall panels. Longwall mining has been a part of the Sunnyside scene since 1961 when the first panel was set up in the lower Sunnyside seam of the No. 3 mine. Through 1975, 27 longwall panels were mined (Fig. 2). Of the more than 47 173 604 t (52,000,000 st) of clean coal that were taken from the property through 1975, 6 350 292.9 t (7,000,000 st) were mined by longwall methods. Coal was brought to the surface in 4.5-t (5-st) mine cars and crushed to -152.4 mm (-6 in.) before entering the preparation plant. Coarse coal is cleaned by Baum jigs and fine coal (-28 mesh) is cleaned in flotation cells. The coal is reduced to 50.8 x 0 mm (2 x 0 in.) and belted to an aboveground storage pile with a ca¬pacity of approximately 113 398.1 t (125,000 st). The coal is gravity fed through two 1.52-m (5-ft) diam culverts directly into railroad cars, which pass beneath the storage pile through an arched excavation. Eighty-four 90.7-t (100-st) cars make up a unit train which makes the round trip to the steel mill in four days. Additional trains are scheduled in as demands dictate. Loading rates in excess of 13 607.8 t/h (15,000 stph) have been attained. Geology The coal seams of this area are of Cretaceous age and are classed as a medium volatile bituminous coal. coal, with a sulfur content less than 1 % and 6 to (20-mile) zone of the Book Cliffs, and this area is owned or under lease by either Kaiser Steel or US Steel. Coal in adjacent areas is noncoking but an excellent steam coal, with a sulfur content of less than 1 % and 6 to 7% ash. Sunnyside coal contains 40% volatile, 53% carbon, less than 1 % sulfur, and 51/2 to 61/2 % ash after washing. There are two minable seams throughout most of the Sunnyside property known locally as the upper and lower Sunnyside. Separation between the seams varies from less than 300 mm (1 ft) near the southern boundary adjacent to the US Steel Columbia mine, to over 12.19 m (40 ft) in areas of the No. 3 mine in the center of the Sunnyside property. The upper seam varies in height from 1.2 to 1.98 m (4 to 61/2 ft) while the lower seam varies in height from 1.52 to 4.28 m (5 to 14 ft) in areas of No. I mine where the two seams apparently come together. The majority of early work was con¬centrated in the upper seam which has a stronger roof and a lower sulfur content. When Kaiser Steel began mining the No. 3 mine in the early 1950s, it mined in the lower seam beneath the old workings with conven¬tional and continuous mining equipment. Numerous bounces and pressure points created by unextracted pillars and barriers in the upper seam made this a low¬production, high-cost mine and brought about the ad¬vent of the first longwall system. The first unit, while small by today's standards, successfully mined panels that had been all but given up and saved the mine from closure. There were areas that could not even be mined by longwall because of the erratic extraction in the upper seam. The system was successful enough to allow operations to gain access to and develop virgin areas of the upper seam. Development of longwall mining in the No. 3 mine has been confined to the upper seam since late 1964. With the almost complete extraction afforded by the longwall system, it is felt the lower seam can be successfully worked in future years (Fig. 3). In most of No. 1 mine, only the lower seam (or lower seam and upper seam combined) is minable, except in the northwest portion where a rock split has again separated the seam into two 1.83 to 2.13-m (6 to 7-ft) thick beds. In this area, the upper seam or upper split is being mined. The separation between seams at the present workings in this area varies from 0.609 to 6.1 m (2 to 20 ft). It is hoped that most of the lower split can be mined using shield supports and/or what¬ever new technology is developed in the coming years. The coal seams in this area dip to the northeast at an average grade of 10%. The dip near the outcrop reaches 22% and gradually decreases downdip. Over¬burden ranges from a few meters at the outcrop to 762 m (2500 ft) over some of the deeper workings. In the next several years, some overburden will be in excess of 914 m (3000 ft) as the lower mine workings extend ever deeper under the Book Cliffs. To cope with the

Jan 1, 1982

By Victor Freire de Oliveira

A exaustão das reservas mundiais de minérios de ferro de qualidade, bem como o progressivo avanço das legislações ambientais, são tendências que têm motivado pesquisas acerca do uso de resíduos ricos em ferro e carbono para a fabricação de sínter metalúrgico para uso em alto-forno. Para tal, é necessário que se verifique o comportamento desses materiais nas condições termodinâmicas e cinéticas do processo de sinterização, bem como o seu efeito sobre a qualidade do sínter e sobre os parâmetros de processo da sinterização. Com esse objetivo, em uma primeira etapa do presente projeto de pesquisa, misturas representativas da prática operacional das usinas brasileiras, bem como misturas visando à maximização da reciclagem de resíduos foram testadas em laboratório em condições próximas às da sinterização. Os resultados de análises químicas e mineralógicas obtidos experimentalmente foram comparados com predições termodinâmicas de um modelo de equilíbrio multicomponente, havendo concordância satisfatória.

Oct 30, 2017

By J. O. Winget

Phosphonic acid and iminodiacetic acid chelating resins were investigated to assess their potential as selective ion exchangers for separating lanthanide elements and yttrium . The affinity of phosphonic acid resin for lanthanides increases with increasing atomic number , and that of iminodiacetic acid resin for lanthanides increases with atomic number to a maximum for element 62 and then declines with atomic number throughout the remainder of the series . Elution sequences of the elements with mineral acid eluants corresponded favorably with equilibrium data , whereas the elution sequence obtained with chelating eluants was proportional to the relative values of the stability constants of the chelating agents with the lanthanides . Separation of lanthanide mixtures into groups of light and heavy elements with iminodiacetic acid resin appears feasible .

Jan 1, 1964

By Willy Contreras, Omar Barrios, Ned Vásquez

Entre los diferentes tipos de riesgos asociados con la minería subterránea, uno de los más críticos son las vibraciones generadas por efecto de las voladuras. En este contexto, las vibraciones por voladura son un riesgo inherentemente ligado con los eventos sísmicos. Por tal motivo, es de suma importancia realizar un estricto control de vibraciones para minimizar el daño al macizo rocoso que a su vez nos permitirá: reducir la sobreexcavación, optimizar los recursos para el sostenimiento de labores, mitigar los riesgos subsecuentes por subsidencia o estallido de rocas y sobre todo la continuidad de la operación minera cuando está cerca a comunidades sensibles a su área de influencia.

Sep 29, 2023

By S. M. H. Ahmadi, K. Barani, F. Moradpouri, R. Ghaedrahmati

As exploration is time-consuming, costly, and risky, determination of the erosion surface of a metalliferous deposit before geophysical surveying and exploration drilling might be very helpful. Geochemical haloes can be used to determine whether the erosion surface is supra-ore or sub-ore and thus reduce the risk of exploration operations. The aim of this investigation is to determine the erosion surface of the North ROK porphyry deposit (NRPD) in northwestern British Columbia in Canada using linear productivity (LP), which is the content of an element defining the halo multiplied by the width of the halo. A total of 2045 soil samples from the B horizon were analysed using ICP-MS for 36 elements, including Cu, Mo, Pb, Zn, Au, As, Ag, Ni, Co, Fe, and Mn. The data-set was snalysed to obtain the statistical parameters and the elements Cu, Mo, Pb, and Zn were chosen to calculate the linear productivity and the total linear productivity. These four elements were modelled using probability plots to identify and separate subpopulations in terms of anomalous haloes and background, including the threshold values of each subpopulation. The results of the probability plot modelling and thresholds values were then used to map the distribution of each element in a GIS to calculate the linear productivity. The total linear productivity indicated that the erosion surface is supra-ore. Finally, a 3D orebody model of the Cu, Mo, Pb, and Zn distributions was constructed using borehole data and used to validate the results.

Feb 6, 2023

By L. C. de Kooker, K. Esmaeili, I. Musonda, M. Ferentinou

A numerical investigation of the effect of pore pressure regime on the safety factor and the critical failure mechanism is presented for fly ash storage facility. Pore pressures’ measurements from standpipe piezometers and pore pressure estimated from seepage analysis are used to compare the factor of safety for a fly ash slope. This was applied for considering static and seismic scenarios. A probabilistic approach was applied to account for the uncertainties resulting from the limited data available and support a qualitative risk assessment evaluation. Slope stability analysis is conducted in two and three dimensions, adopting the limit equilibrium analysis approach, and also a finite element seepage analysis, to assess the stability of the slope. The two-dimensional cross-sections were extruded to three-dimensional models to estimate the factor of safety and associated shear failure. The results from the performed analysis suggest an increase in safety factor values of 5%.

Mar 27, 2024

VOLUME I Volume I of this three-volume report is the result of development of a comprehensive, coordinated approach to site data-acquisition activities to produce key plans and reports during the evaluation and development of a surface coal mine. A logic diagram illustrates activities in the planning and decision-making process from exploration through post-mining monitoring. The report briefly discusses major elements, other than the site environment, which influence development of mining and reclamation plans and refers to other readily available literature for details outside the scope of this study. The essence of the rationale is shown to be the 1 employment of necessary skills at the proper time to evaluate specific data ' requirements and integrate them into a cost-effective program to produce initial and major feasibility reports, mining, and reclamation plans, and the environmental impact assessment.

Jan 1, 1976

By M. Shriwas, F. Calizaya

"Controlled recirculation may be considered as a beneficial means in mines of cold climate, where heating of air is required, and in deep or extensive mines, where cooling of air is required. Controlled recirculation can be designed by proper sizing of the booster fans with respect to main fan. Intuitively, it seems that the buildup of methane at the face will cease when a steady state condition is attained, and also that, at that same time, the maximum concentration at the face will remain same as in the return air. This supposition is proved by mathematical analysis that considers uniform mixing of methane in air in successive cycles of recirculation. This study includes two scenarios to show the effect of controlled recirculation on methane concentration in a sample network. Firstly, when recirculation crosscut exists near the working face; secondly, when recirculation crosscut exists away from the working face. The later scenario shows lesser buildup of methane concentration than the former one. INTRODUCTION The controlled recirculation is designed purposefully to allow a partial fraction of used air that increases the air velocity due to increased quantity of air and consequently allows effective dilution of contaminants to improve local ventilation condition at the working face. It can be designed by proper sizing of booster fan with respect to main fan in a ventilation network. Controlled recirculation may be categorized as crosscut, in-line or combined system based upon the configuration of the booster fan locations in a district ventilation network. Research on controlled recirculation has shown numerous benefits of controlled recirculation especially in deep or extensive underground mines, where further heating or cooling is required (Calizaya 1990; McPherson 1993 and Jones, 1987). However, fear of buildup of concentration has misled the mining communities to view the controlled recirculation as a hazard and deprived the mining industry to derive benefits from recirculation. Intuitively, it seems that the buildup of methane at the face will cease when a steady state condition is attained, and also that, at that same time, the maximum concentration at the face will remain same as in the return air. This supposition is proved by mathematical analysis that considers uniform mixing of methane in air in successive cycles of recirculation. This study includes two scenarios to show the effect of controlled recirculation on methane concentration in a sample network. Firstly, when recirculation crosscut exists near the working face; secondly, when recirculation crosscut exists away from the working face. The later scenario result shows the less buildup of methane concentration than former scenario result."

Jan 1, 2016

By S. W. White

Plasma arc technology is increasingly being used to process a number of waste materials. In present research, plasma technology is being investigated to treat waste magnesium baghouse dust, which is a waste material from the Magnetherm process. This dust contains mostly MgO, but also contains NazO, CaO, and KzO. Plasma energy is to be used along with a reducing agent to produce pure gaseous magnesium while keeping the other materials in a slag. The magnesium will then be collected by rapid quenching. A non-transferred arc plasma torch is ideal for this reaction because of its high enthalpy and improved energy efficiency over conventional methods. Another advantage of plasma is that it allows for the pre-heating or pre-reacting of fine particles before contact with the melt. Thermodynamic calculations using the Gibb energy minimization method were used to determine the most stable compositions of the materials at various temperatures. Energy balances have also been calculated. These results conclude that we can recover approximately 98% of the magnesium with a proper quenching technique. The calculated results are compared with the experimental data, and good agreement between them was observed.

Jan 1, 1999

By Yasuhiko Ito

"This talk is concentrated on the topics of compound film formation on the substrate electrode by interdiffusion of substrate element and electrochemically deposited species and/or by direct electrochemical implantation of the component element of the film into the substrate. As a typical example, electrochemical implantation of nitrogen atom into Ti metal to form TiN surface film is described. Another example is the formation of various kinds of intermetallic compound films including Ni2Y, Ni2Dy and Pd3 Y by the electrochemical implantation of lanthanoid elements into transition metal electrodes. By combining these two methods, Sm-Fe-N ternary material film also could be formed. The principle and application of the ""electrochemical implantation"" are discussed in detail.IntroductionGenerally speaking, surface film formation by molten salt electrochemical process can be divided into the following three categories:(i) single element film formation on the electrode by electrodeposition,(ii) compound film formation on the electrode by electrocodepostion of more than two elements, and(iii) compound film formation on the substrate electrode by interdiffusion of substrate element and electrochemically deposited species and/or by direct electrochemical implantation of the component element of the film into the substrate.This talk is .concentrated on the topics of category (iii), especially on the electrochemical implantation. Typical example can be seen in the electrochemical implantation of nitrogen atom into Ti metal to form TiN surface film. Another example is the formation of various kinds of intermetallic compound films including Ni2 Y, Ni2Dy and Pd3 Y by the electrochemical implantation of lanthanoid elements into transition metal electrodes. By combining these two methods, Sm-Fe-N ternary material film also could be formed. The principle and application of the ""electrochemical implantation"" are discussed in detail with examples above as well as other experimental results also obtained very recently in the author's laboratory."

Jan 1, 2000

By Arpad E. Torma

The identification and characterization of lithographic iron and sulfur oxidizing bacteria in the 1940' s. opened up new possibilities and challenges for the mining and metallurgical industries. These were exploited during the 1950's and' 1960's, when it was demonstrated' that mining wastes and complex unused mineral resources could be economically treated by bacterially assisted heap and dump leaching processes?. During the 1970's this technology grew into a more structured discipline called "biohydrometallurgy". In the l980's efforts were devoted to the identification of a variety of organisms involved in naturally occurring leaching processes. Further efforts dealt with the elucidation, of leaching mechanisms; the leach ability of nickel, coban, zinc, and precious metals; the desulfurization of coal; and diverse biosorpion phenomena. The application of genetic engineering techniques for the improvement of microbial performance was also initiated?. Current trends in biohydrometallurgy include improvement of many of the techniques noted above, as well as application of leaching. technolog.ies to. environmental remediation scenarios. These activities afford considerable opportunities for research in the 1990's. For example, bioremectiation of abandoned mining and processing sites requires development of new and economically viable technologies capable of removing low concentrations of toxic metals from high volumes of solid and/or liquid wastes.

Jan 1, 1991

By H. Sano

Most of the dust generated from the copper smelting process in Chile has been stored after the stabilization by hydrometallurgical process because it contains high concentrations of arsenic. However, in recent years, the dust generation has increased because of degrading the quality of concentrate. In addition, the environmental regulations become stricter. On the other hand, valuable metals such as copper and zinc are contained in the dust at high concentrations and it is desirable to recover them. In this study, the effect of dust recirculation to the smelting process was examined in order not only to decrease the amount of dust but also to recover copper. Dust generation and the distribution of arsenic, lead, zinc etc. among the matte, slag and gas phases were evaluated as a function of the amount of recirculated dust, partial pressure of oxygen and temperature. It was found that the direct dust return to the smelting process was quite effective for the recovery of copper and the reduction of dust generation, but the acceptable dust amount was limited by the produced matte quality.

Jan 1, 2007

By Teruo Bitoh, Shogo Izumi

"The effect of B203 flux melting on the structure and the soft magnetic properties of the (Feo.1sBo.20Sio.os)96Nb4 bulk metallic glasses prepared by casting has been investigated. The ringshaped bulk specimens were prepared by the B203 flux melting and copper mold casting. It was confirmed that the flux melting promotes the precipitation of the a-Fe(-Si) and Fe2B phases in the central region of the specimens. The ring-shaped bulk specimens show a flat hysteresis curve, indicating a good linear relationship between the magnetic induction and the applied magnetic field. These results show that it is possible to develop a new soft magnetic material that exhibits constant permeability, which is necessary for producing inductors and choke coils.IntroductionSince the success of forming Fe-based bulk metallic glasses (BMGs) with good soft magnetic properties, great attention has been developed to synthesis and properties of the BMGs [l, 2]. The BMGs have high glass-forming ability (GFA) and, therefore, they can be used to prepare bulk amorphous alloys with a thickness of the order of a few millimeters by casting. The soft magnetic properties of Fe-based BMGs are better than those of ordinary amorphous alloys; therefore, these BMGs have wider applications as soft magnetic materials [3-5]. It is often required for soft magnetic materials that the shape of the hysteresis curve is changed according to the demands of applications. For example, materials with ""flat hysteresis curves,"" which means the magnetic flux density (B) and the applied magnetic field (H) show a linear relationship up to rather high magnetic field, are necessary for producing inductors and choke coils. Flat hysteresis curves can be easily achieved by creating an air gap in the magnetic path. However, magnetic flux leakage generated in the air gap inhibits high-density packing of the electronic components. In order to achieve flat hysteresis curves without creating an air gap, Fe-based ordinary amorphous alloys are subjected to crystallization by annealing and transformed into thin surface layers of a-Fe; the crystallization results in the compression of the remained amorphous phase [6]. Another way to achieve flat hysteresis curves is the formation of secondary phase (such as Fe2B) that act as pinning site of magnetic domain wall displacements [7]."

Jan 1, 2013

By E. Baliktsis

PPC (Public Power Corporation) operates a new power plant at the South-West part of Crete. Recently the extension of the Power Plant started. ATHENA SA the main contractor of the project assigned to EXORIXI SA the implementation of a blast vibration monitoring program and prevention-evaluation of risks caused by construction blastings inside or very close to the operating part of the power station. The blasting parameters and characteristic elements that had been evaluated, the measures that had been taken and materialized, the overall risk management and the results of the whole program are presented in this paper.

Jan 1, 2006

By A. H. PH. D Wilson

Compared to the rocks encountered in, say, metalliferous mining or tunnel drivage in igneous and metamorphic rocks, the strata associated with the coal measures are relatively soft. If excavations are made at depths greater than one or two hundred metres, zones of fractured or yielded rock develop around the openings. The stress which can be taken by yielded rock at the boundary of an opening is low, but because of the friction present between the fragments or particles, the sustainable stress rises rapidly with distance from the opening until sufficient confinement has been developed to prevent failure of the rock in the first place. Thereafter the laws of elasticity will apply and increasing distance will reduce the stress field until conditions consistent with the cover load are reached. For rocks which maintain their elastic condition right to the edge of an opening, finite element analysis and similar techniques have proved successful in determining the distribution of stress around the opening. This approach, however, is not successful when a yield zone is introduced between the elastic zone and the opening. Nevertheless, some estimate is required if help is to be given in the siting of roadways and in the determination of adequate pillar sizes. This matter is of particular importance in the planning of new mines especially if retreat faces are involved, as extensive roadway drivage must be planned and executed before experience of the effects of face extraction is gained. In 1977, the author published [I] a method based on 'stress balance'. The total aggregate downward load over a large area will remain that of the cover load even after part of the coal seam has been removed. Any rise in stress in ribsides and pillars must be offset by an equivalent stress reduction across roadways and other areas of extraction, and vice versa. Knowledge of one can lead to an estimate of the other, provided the general form of the stress distribution can be postulated. It is the object of this paper to revue the method in more detail and to give further examples of its successful application.

Jan 1, 1981