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By Francois E. Heuze

The mined geologic burial of high-level nuclear waste is how the favored option for disposal. The underground repositories must keep the waste away from the biosphere for very long times - several thousands to tens of thousands of years. Also, access must be maintained to the vaults for several tens of years, so that the waste can be retrieved, if necessary. Both the excavation of the underground chambers, and the radiogenic heating will disturb the rock mass. The overall rock mechanics problem is to understand and predict the processes associated with these perturbations, and their impact oh the isolation and containment of the waste (3)**. The specific rock. mechanics issues which have been identified for the three candidate hard rocks (basalt, granite, and tuff), are summarized in Table 1. The table also indicates the level of adequacy of our knowledge in the areas of the various issues. Such an evaluation is consistent with the general consensus of the rock mechanics profession, as explained in several key reports and publications (1 to 11). The main shortcomings of today's rock mechanics for waste repositories can be summarized as: ? lack of resolution for remote mapping of fractures in rock masses ? great difficulty in testing large volumes of rocks to determine their mechanical properties.

Jan 1, 1981

By B. M. Flohr

Railroads are cost competitive with trucks for hauls greater than 500 miles - WRONG. Today I will tell you about many rail movements of less than 100 miles throughout the country. Rail is a short haul transportation alternative you must consider. Transportation today is the largest controllable cost in the total cost of production of goods. In fact it is the one cost area where aggressive management, using new tools, can achieve significant reductions. You can't control the price of metals in the world market, you can't control labor rates since they are tied to industry norms, and the price of raw materials are relatively insensitive to specific price reductions to your firm. Transportation is the one area where major savings are now being realized. Sample Movements First, I will give you several examples of short haul rail moves to make you a believer that they do exist. Then I will show you the reasons why railroads suddenly "like" short hauls.

Jan 1, 1986

By Duane L. Abata

This paper discusses recent technology dealing with the use of computer graphics in the mining industry and presents a newly developed computer software package specifically designed for use in underground mining operations. This software package, developed under a United States Bureau of Mines contract, 1) displays mine ventilation schematics and other representative illustrations for a real time data acquisition system and 2) utilizes the Bureau-owned Minefire and Ventilation Code for display of ventilation and contamination predictions on the microprocessor system. The package utilizes a unique system of display indexing that provides a simple yet efficient method of recalling a series of mine schematics detailing an underground operation and an alarm acknowledgement scheme that provides an effective method of identifying problem areas which may exist in the mine network. The package was written in Fortran for a 64 kilobyte, Z80-based microprocessor-computer.

Jan 1, 1984

By F. Baczek, S. S. Rocks, D. Chaiko, C. Eyzaguirre, S. Asihene, T. Walters

The majority of efforts to improve primary copper sulfide leaching have focused on solution chemistry, temperature, O2 pressure, ultra-fine grinding, the use of catalysts, etc. Historically, very few studies have focused on the solid/solution interface. A new, patent pending approach to catalyzed, copper sulfide leaching has been discovered by FLSmidth that enables manipulation of the 2-D semi-conductor properties of chalcopyrite surfaces to the benefit of higher electrochemical reactivity. Copper dissolution rates are then further accelerated by incorporating a Stirred Media Reactor (SMRt) into the process. By using minute amounts of Cu2+ to "pre-activate" chalcopyrite, leach times have been reduced from >20 hours with incomplete Cu dissolution to <2 hours with 98+% Cu dissolution at 80°C. The pre-activation process takes only minutes to complete at temperatures of 80°C or less. The total atmospheric leaching process, incorporating the pre-activation and Stirred Media Reactor is compatible with existing SX/EW processes. Results of batch leach testing are presented and possible mechanisms are discussed.

Jan 1, 2015

By M A. Rhamdhani, R Z. Mukhlis

Removing the ledge formation in the Hall-Heroult cell during the electrolysis process may significantly reduce the energy requirement of the aluminium production process. In the absence of the ledge, however, the sidewall-material types become heavily restricted since the cryolite is very corrosive at the electrolysis temperatures. This paper study the corrosion behaviour of sintered nickel ferrite, nickel aluminate, and magnesium aluminate refractories (as possible candidates for sidewall material) in molten aluminium and cryolite melts with various alumina content at 980°C. Immersion tests of refractories with various porosity were conducted to assess the suitability of the refractories in the corrosive environment of the electrolysis cells. Microstructural change of the refractory after immersion were analysed using secondary scanning electron microscopy (SEM). Sampling of the melts were taken at 0, 10 min, 30 min, and each hour up to 6 hrs, and subsequently analysed by Inductively Coupled Plasma (ICP) spectroscopy. Based on the projected concentration of the refractories constituents in the melts, it was predicted that the corrosion rate of NiFe2O4, NiAl2O4 and MgAl2O4 in cryolite with 11 wt per cent Al2O3 were 461 × 103, 1.03 × 103, and 798 × 103 cm/a, respectively. Much lower corrosion rate of 2.3 cm/a for NiFe2O4, 2.6 cm/a for NiAl2O4 and 0.3 cm/a for MgAl2O4 were predicted if the refractories in contact with aluminium melts. Erosion played an important role in the corrosion as the concentration of the refractory constituents in the melts were beyond its solubility limit. It is therefore crucial to increase the densities of the refractory and improve its wetting characteristics.

Aug 21, 2024

By Lana Alagha, Fardis Nakhaei, Jose L. Corchado-Albelo, Noelia Munoz-Garcia, Michèle Heitz

Sulfide tailings from past and present mining activities are important hosts of critical elements and precious metals. This review paper presented a literature survey on the recovery practices of some critical minerals containing Te from sulfide tailings with a special focus on the physical beneficiation and hydrometallurgical separation methods. Finally, a conceptual framework and possible processing flowsheets were proposed. The findings of this review will be useful for the researchers in the field of geochemistry, mineral processing, and metallurgy to evaluate the separation processes for reprocessing of mine tailings for the recovery of critical minerals.

Feb 1, 2024

By K. Dagdelen , S. K. A. Owusu

Uncertainty with regard to estimated grades and tonnages of a mineral deposit demands risk assessment in order to build investor confidence and attract the interest of other stakeholders in the success of a project. Uncertainties associated with Mineral Resource estimates can lead to unreliable production schedules and unpredictable cash flows. However, the techniques used in the mining industry to determine these uncertainties are inconsistent, because the important decisions taken in the process are solely dependent on the responsible Competent Person (CP), without limitations. This leads to disparities between different CPs’ results, using data-sets from the same drill-holes. The various standard codes for public disclosure provide guidelines and recommendations for the classification of Mineral Resources and Reserves but do not provide details on, for example, the amount of geological and geostatistical information needed to qualify for each category of Resources and Reserves. The parameters used to generate the classification categories are subjectively assumed by the responsible CP. In this paper we investigate the impacts of different CPs’ judgements on resource classification, using the same data-sets. The results underpin the need for the mining industry to develop a uniform Mineral Resources and Reserves classification framework that can minimize or avoid significant discrepancies that lead to potential misleading public disclosures.

Aug 8, 2024

By K. Witt, S. Steinlechner

In different nonferrous metal-producing industry sectors, the impurity element iron has to be removed from the process solution. Examples for the arising residues are jarosite or goethite precipitates from nickel or zinc production but also red mud from aluminum production. Regardless of environmental concerns, the material is landfilled in almost any case, although valuables such as indium, silver, nickel, or zinc are present in considerable amounts. Within the presented research, a low carbon dioxide emitting multi-metal recovery from such iron-containing residues by means of a selective chlorination extraction has been fundamentally evaluated by experiments but also by comprehensive thermodynamic calculations. The paper summarizes the thermodynamic fundamental concept exploited to separate the dominating iron matrix from the valuable elements and shows verification experiments in a lab size of several grams. Through thermodynamic calculations and smallscale experiments with pure metal oxides and sulfates, it has been proven that the metal chlorides AlCl3∙ 6H2O, FeCl3∙ 6H2O, and MgCl2∙ 6H2O are viable and effective reactants for chlorination. In trials with actual industrial iron precipitation residues from the zinc industry, especially, the use of MgCl2∙ 6H2O and FeCl3∙ 6H2O leads to high extraction rates for the investigated valuable metals Ag, Au, Bi, Cu, In, Pb, Sn, and Zn.

Nov 14, 2023

By Honglei Zhang, Wuguo Xiang, Xinhao Huang, Guotao Xu, Xilai Chen

"The service behavior of refractories used in hot air pipeline for hot air stoves in a 3200 M3 blast furnace of WISCO was analyzed. The damage factors can be concluded as the poor quality of and alusite based bricks, the severe thermal shock damage, the more porosity in structures, loose bonding capability, and the unreasonable choice of materials and design of bricks. By analysis, the service life of hot air stoves can be enhanced by the measurements such as the reasonable choice of materials and their match, the use of light-weight refractories, the improvement of brick type, etc. Thereafter, the normal production operation of hot air stoves is guaranteed.IntroductionThe No.7 blast furnace of WISCO has been used for about 5 years and it was mid-repaired in March, 2012. The top phenomena of worn hot air pipelines are brick drop, breakage, severely local wear and deformation, existing hidden danger, so the worn hot air pipelines were renewed. Investigations have been done on the stove damage and design [1,2]. In order to clarify the wear mechanism, the used refractories for hot air pipelines were sampled and analyzed, the properties and structures of worn materials and reused materials are relatively studied."

Jan 1, 2013

By Bond. F. C.

Introduction Although autogenous grinding applications date back to the early years of mineral processing when tumbling-type mills were first used, there has been a renewed interest in this type of grinding over the past few decades. A review of the historical aspects of autogenous grinding is provided which follows the development of the various types of mills and processes. Wet and dry grinding operations using either autogenous or semiautogenous mills, including the Aerofall mill, are described. Em¬phasis has been placed on the test work required to evaluate the feasibility of using autogenous or semiautogenous grinding for a spe¬cific application. The factors which must be considered to establish the appropriate design criteria for these types of grinding circuits are discussed in detail. Successful application of these grinding circuits results from a thorough test program, a careful analysis of the test results, and a practical engineering approach to the design of the process flowsheet and milling equipment. Certain pebble milling applications, where the pebbles consist of the ore or rock itself, can be classified as autogenous pebble mill grinding, or better known as ore-pebble mill grinding. In the generic sense, pebble milling includes those grinding operations using a tum¬bling mill in which the grinding media consists of various types of pebbles, either ore or other pebbles, instead of metal balls. Conse¬quently, this subject is covered separately in Chapter 5, Pebble Mills. Operating data from many of the installations located throughout the world are included in this chapter. Our appreciation is extended to those companies who contributed this important information. History of Autogenous Grinding F. C. BOND Autogenous grinding, the grinding of ore by itself rather than by special metallic or nonmetallic grinding bodies distinct from the ore, has an old and honorable place in the art of mineral processing. It antedates the use of the rod mill and is only a few years younger than the development of the continuously fed rotating tumbling mill in which it is accomplished. Its history71, 72 is inextricably bound up with that of gold mining. Every important early development of autogenous grinding took place on ores of gold, except in one case of silver ore. In common with many other features of modern mineral processing, autogenous grinding would have been greatly retarded if the winning of gold had been so small a part of mining in the past as it is today. Gold unlocked the secrets of rock-on-rock grinding. In years past gold ores were crushed in stamp batteries and then flowed over copper plates covered with mercury which amalgamated the gold. The McArthur Forrest cyanide process for the dissolution of gold in a dilute alkaline cyanide solution appeared in 1890. With finer grinding it recovered more gold than could be won by amalgama¬tion alone. The first response was to stamp in cyanide solution and finer mesh screens guarding the stamp discharge. However, the fine screens greatly restricted the tonnage stamped, and they wore out rapidly. Rotating tumbling mills70, 73 were the obvious choice to grind the coarse product from stamps. Many of these were Gates tube mills; more than 1,000 of these were sold between 1907 and 1913. They were made in 6, 51h, and 5 ft diam, with lengths of 20 and 22 ft. The 5 x 22-ft size was the most popular. The term tube mill did not refer to the mill shape, but included all tumbling mills using grinding pebbles. The flint or chert rocks found along the coasts of Denmark and Normandy are probably the most durable and resistant to abrasive and tumbling wear of any on earth. They were much used in the early tube mills. The early linings were all silex or Danish flint blocks, cemented into place with portland cement. Local hard stones or cast iron blocks were also used later. The cast iron liners carried lifters and were not bolted to the shell, but were held in a tight circle against it by steel wedges hammered home between them. The first ribbed metal liners designed to hold grinding pebbles pounded into them by the mill action were developed at El Oro, Mexico, about 1905. These and the Forbes, Komata, and Tonopah types, as well as the Osborne type developed in South Africa within about five years, were very successful in reducing liner wear. They sometimes lasted two years or more, and equalled or exceeded the life of silex lining at a lower cost. Some of the types were patented. The pioneer name recorded in the history of autogenous grinding is that of Kenneth L. Graham. In 1907 at the Geldenhuis Deep Ltd. mine near Johannesburg, he ran a comparative test on two tube mills. One mill used pieces of the common gold ore, or banket, and the other used the customary imported Danish pebbles as grinding media. He published the first account of autogenous grinding.&apos;&apos; In a test lasting 81 days the ore pebbles showed a definite saving over the Danish pebbles. Graham&apos;s historic paper also describes the invention of B. Chew of the Crown Deep Mines of the first trammel to be attached to a grinding mill discharge. The first known account of autogenous grind¬ing printed outside of South Africa was the description of the Graham test in Mining and Scientific Press&apos;s The use of grate- vs. overflow¬discharge was also described at this time." The news of this successful test appears to have had immediate effect, for by the end of 1908 the number of tube mills on the Rand had increased from 72 to 120.76 Presumably, most of these mills were now using autogenous grinding. The ore was principally a hard conglomerate of quartz peb¬bles cemented by silica, and was eminently suitable for use as a grind¬ing media. It is unfortunate that in South Africa the new autogenous process continued to be called by its old name of pebble milling, since the name does not distinguish between grinding with ore and grinding with extraneous pebbles. For increased clarity the former is called rock pebble milling. The first historical stage in the development was what is now designated as secondary autogenous grinding, or rock pebble milling. It consists of grinding a feed all passing &apos;A in. or finer with ore pebbles about 2 to 4 in. in diameter. The next stage to develop was that now called intermediate autogenous grinding, where larger amounts of larger pebbles about 5 in. in size were used to grind ore which had been crushed to about rod mill feed size or somewhat finer. It was developed on the Rand and in other places where coarse stamp screens were used to increase mill tonnage. In many cases the early secondary and intermediate autogenous mills have now been replaced by conventional ball mills and rod mill-ball mill circuits, with the object of further increasing grinding capacity. The third stage to develop is designated as wet primary autogenous grinding, in which run-of-mine ore or a primary crusher product is all fed to the autogenous mill together. It developed many years later indepen¬dently in the United States and in South Africa. The fourth and most recent stage is that of dry primary autogenous grinding, which developed in the United States and Canada. All four stages originated in gold mining. The first use of commercial autogenous grinding outside of the Rand apparently took place five years later in 1912 at the Santa Gertrudis gold mine at Pachuca, 55 miles northeast of Mexico City. This was followed closely by an installation at Goldfields, Nevada, in 1914-1915. The first name associated with autogenous grinding

Jan 1, 1985

By Y S. M Tabatabaei, R Hosseini Tabata

Application of Acidithiobacillus ferrooxidans bacteria to flotation of Sarcheshmeh low-grade copper sulfide ore was studied. Sarcheshmeh low-grade ore contains pyrite, which causes some problems in the flotation of copper minerals. In this study, A ferrooxidans was used to change the surface chemistry of pyrite and copper sulfide ores and consequently, their flotation behaviour. In the presence of A ferrooxidans and xanthate as a collector, pyrite was depressed whereas chalcopyrite and other sulfide minerals were unaffected. In addition, the pulp pH remained unchanged. It was shown that the surface chemical properties of the bacteria could be manipulated successfully to achieve the desired effects in a flotation process. The results showed that the recovery of pyrite in the presence of the bio-depressant is 50 per cent lower than when no bacteria were present. At the same time the recovery of chalcopyrite remained unchanged.

Jan 1, 2004

By DING TANG, JINGHE CHEN, Shuiping Zhong, CHEN KUANG

The Zijinshan gold-copper mine, located in Shanghang County, China, is a porphyry-type, low-grade ore deposit with a geological profile of upper gold and lower copper. Despite its low-grade nature, it has become one of the largest in production scale and most profitable nonferrous metal mines in China, which can be attributed to the successful application of hydrometallurgy as well as proper engineering design. A large-scale, open-air cyanide heap leach has been successfully implemented to recover gold under the humid and rainy weather conditions of southern China. Furthermore, according to the gold ore characteristics, a combination of gravity separation, carbon-in-leach and heap leaching processes was developed to improve gold recovery. In terms of copper extraction, copper ore of a grade higher than 0.25 percent is fed to the flotation plants to produce copper concentrate (gold is also enriched here), while copper ore of a grade lower than 0.25 percent undergoes heap bioleaching followed by solvent extraction and electrowinning to produce cathode copper. Additionally, a unique bioleaching system has been established at the Zijinshan Mine: low operating pH (0.8~1.0), high concentration of total soluble iron (~50 g/L), high temperatures (45~60 °C) and low activity of microorganism (~104/mL) in the pregnant leach solution (PLS). This review paper summarizes the practical experience acquired in developing the Zijinshan gold-copper mine and could be of use in other gold and/or copper plants.

By S. L. Windes

This report presents a tabulation of the physical and petrographic properties of Over 100 rock types from operating mines or mineral-investigation projects. The physical properties include the following: Apparent specific gravity Apparent porosity Compressive strength Flexural strength, (modulus of, rupture) Impact toughness Abrasive hardness Scleroscope hardness Modulus of elasticity (Young&apos;s modulus) Modulus of rigidity Specific damping capacity Longitudinal bar velocity

Jan 1, 1949

By Matthias Schnitzler, Herbert Pfeifer, Ralf Bolling

"To transform metals high temperatures are usually needed. A fast and efficient heating can reduce the C02 emitted. The fastest way to heat metals is called direct flame impingement (DFI). The flame impinges upon the item being heated. For this method it is important to know the shape and length of the flame. Laser-induced fluorescence (LIF) technology allows measurements of a two-dimensional field without influencing the reaction or the flow. Commonly used is the measurement of OH-radicals, an indicator of the reaction zone.In the presented study measurements of a turbulent diffusion flame are shown. The position of the reaction zone and the influence of the distance between the item being heated and the burner are investigated. Conventional measurements and LIP-measurements are compared and the potential of DFI to increase the efficiency of heating metals is discussed.IntroductionDuring industrial heating processes a fast and efficient heating technology is required. Two important aspects are the NOx emission and the energy efficiency. The direct flame impingement (DFI) technology has the highest heat transfer rate possible with a gas/air flame. The turbulent high velocity flame jet impinges upon the item being is heated [ 1]. Due to the high heat transfer rate furnace and exhaust gas temperatures are lower. Therefore the energy efficiency is increased and the amount of NOx emitted is reduced.Hydroxyl- (OH-) radicals are an intermediate product that is generated during the combustion of hydrocarbons [2]. They are commonly considered as an indicator for the reaction zone and position of heat release. Figure 1 shows the hydroxyl-mole fraction in dependence of the distance along the gas flow. The figure clearly shows how fast the OH-concentration increases in the reaction zone. Figure 1 also shows that OH-radicals are present in the post combustion region, however in smaller concentration [3].The laser-induced fluorescence technology serves to measure the spatial distribution of OH-radicals in a two dimensional cross-section area of the flame. Therefore the flame dimensions and location can be determined with high spatial resolution without influencing the flow or the reaction [ 4,5]."

Jan 1, 2012

Micro-fine disseminated molybdenite was ground in a laboratory stirred mill using steel media and zirconium media respectively. The floatability of ground molybdenite and slurry chemistry was investigated. It was found that the total recovery of ground molybdenite using zirconium media was higher while the pH and Eh of the slurry are lower than that using steel media. When steel media was used, iron oxy-hydroxides had been generated coated on the surface of molybdenite, and decreased the floatability of molybdenite, especially of the -10µm particles. The iron and lead oxy-hydroxides was generated by the reaction between steel media with pyrite and galena associated with molybdenite. It was also found that changing the grinding media to inert can benefit the flotation of molybdenite. Keywords: stirred mill, grinding environment, floatability, micro-fine disseminated molybdenite, fine grinding

Sep 1, 2012

By K. Woo

"With ever-increasing global demand for mineral resources, mining companies are considering developing deeper, more complex and lower grade ore bodies. Recent years have seen the transition from surface to underground mass mining operations to access deeper resources, with mass mining methods such as block and panel caving being favoured due to the tonnages and economics achievable when dealing with lower grade ore. However, the rock engineering interactions involved with such plans are complex and challenging given the significant disturbance caused to the surface environment. If not properly accounted for, the unexpected propagation of a cave breaking through to surface or the differential surface displacements otherwise produced may threaten the safety and integrity of overlying mine and civil infrastructure.This paper reports the findings of a comprehensive research programme focussed on investigating and integrating new developments in remote sensing characterization and monitoring technologies with state-of-the-art numerical modelling to better manage the challenges and geo-risk associated with the transitioning from open pit to underground mass mining. Procedures were developed to integrate discrete fracture networks (DFN) into finite-element/discrete-element analyses to simulate the influence of rock mass fabric on cave propagation and the evolution of caving-induced surface subsidence and step-path failure of large open pit slopes through the progressive failure of rock bridges. The results clearly showed that caving-induced surface deformations tend to be discontinuous and asymmetric due to large movements around the cave controlled by geologic structures, rock mass heterogeneity and topographic effects. Although parallel investigations of empirical design charts used to predict caving-induced deformations were found to be moderately sufficient for assessing the extent of macro deformations directly above the undercut (i.e. caving collapse features), numerical modelling was found to provide the only means to confidently estimate the lateral extent of smaller strain subsidence.These results were further supported by the use of high-resolution synthetic aperture radar (SAR) data to monitor the ground deformations associated with block caving production, and to use these to calibrate and constrain a series of predictive 3-D numerical models focussed on Rio Tinto's Palabora mine in South Africa. The InSAR data was obtained from Canada’s recently launched RADARSAT-2. The close fit achieved between the predictive 3-D numerical model and InSAR monitoring data demonstrates the significant value of InSAR calibrated 3-D numerical models applied to subsidence prediction.Collectively, the results from this research programme have helped to further the characterization, assessment and understanding of mass mining-induced subsidence, and its evolution, by addressing existing limitations in the use of empirical and numerical design methods. The limitations and uncertainty arising from mine site data were detailed, specifically the representation of mine geology, rock mass properties, in-situ stresses and cave propagation, together with means to constrain these inputs and calibrate sophisticated 3-D numerical models through back analysis and integration with high resolution monitoring data."

Jan 1, 2015

Callie underground gold mine is part of the Newmont Tanami Operations, and is now the primary provider of ore to the Granites processing Mill. The Callie underground mine has produced in excess of 7.6 million tonnes (Mtpa) of ore, since production began in 1998, with a current production rate of 1.9 Mtpa. Callie underground uses sublevel open stoping with extraction through a combination of primary and secondary stopes. The primary stope filling strategy utilises cement aggregate fill (CAF) to allow full recovery of secondary stopes. The Callie backfill operation has had a continuous testing program in place during this time, which has resulted in a great deal of information available for post fill analysis. All CAF placement into primary stopes for Callie has been via surface boreholes and this has given Callie mine an understanding of some of the issues related to borehole design, type of linings to use depending on angle, depth and quantity of fill into stopes. Finally backfill barricades at Callie have undergone a number of changes during the time to optimise the design based on whether CAF or sand fill is used. This paper discusses the CAF backfill practices and testing methods used for backfilling operations at Callie.

Jan 1, 2005

By Luis Pommier

The requirements of metals by modern society have created big challenges for mining engineers minerals processing engineers, metallurgical engineers and economists to produce these metals economically from mineral deposits which contain, with time, less and less value. The advances of science and technology allow, today, the exploitation of mineral deposits which only few years ago would not have been considered economical. However, there are limitations both on the minimum grade of recoverable values contained in the ore to be fed to a mill or on the concentrate to be smelted, and on the maximum content of "impurities" i.e. chemical elements which are difficult or expensive to refine from the ore, from the concentrate or from the metal. It is also known that the cost of treatment in a mill or in a smelter, for unit of metal contained in the ore or in the concentrate, increases as the grade of the recoverable values contained in them decreases and also if the content of impurities increases. In order to work a mineral deposit economically it is necessary to ensure not only that it has more than a minimum content of values, less than a maximum content of impurities and that there exists a good up-grading or metallurgical process but also to ensure that the opti-

Jan 1, 1971

By Yongzhong Xiao, Tiejun Chun, Jian Pan, Zhen He, Deqing Zhu

"In this paper, the reduction kinetics of low grade hematite ore was calculated. Mineralogy shows that the ROM (run of mine) ore is of low grade hematite ore type, assaying 27.2 wt% Fetotal and with main valuable minerals of hematite. The reduction kinetics shows that the reduction reaction rates of pellets with additive and without additive are all controlled by diffusion through the product layer. The calculated apparent activation energy of pellets with 12 wt% complex additive is 8.55 KJ/mol, dropping 62.23% compared to that of pellets without additive.IntroductionWith the rapid development of iron and steel industry in China, there has been a soaring demand for iron ores in the past decade. The imports of iron ores have increased from 148 million ton in 2003 to 620 million ton in 2010[1]. Therefore, large quantities of low grade iron resources are necessary to utilize in China at the moment. During the past years, extensive research has been carried out on the low grade hematite ores [2-6], such as reverse floatation, gravity separation, high-gradient magnetic separation and direct reduction-magnetic separation. Direct reduction-magnetic separation is an innovation way to treat the low grade hematite [7]. However, the research of reduction kinetics of low grade hematite is few. Some research about the reduction kinetics of reducing iron oxides by CO was studied [8]. The results indicated that the apparent activation energy is 8.0-28 KJ/mol when the reducing reaction is controlled by internal diffusion. The apparent activation energy is 50-75 KJ/mol when the reducing reaction is controlled by chemical reaction. In this paper, the reduction kinetics of pellets was also been studied."

Jan 1, 2012

By B. K. Choi, S. H. Kang, G. E. Kim, K. B. Kim, S. Noh, T. K. Kim, H. J. Jin

Oxide dispersion strengthened (ODS) steel is being considered as an in-core structural material of future nuclear reactor systems because of its excellent creep and irradiation resistance on the basis of uniformly distributed nano-oxide particles with a high density, which is extremely stable at high temperature in a ferritic/martensitic matrix. Up to now, ODS steels have been intensively studied and developed to apply these materials to the in-core structural component of future nuclear systems. The primary activity is to develop high strength advanced ODS steel, fabrication technology for the structural components and key joining technology for the component fabrication. As a result, a Fe-10Cr-1Mo alloy with a superior creep resistance at high temperatures has been developed. An optimized fabrication process of this alloy system has been established through various process conditions in mechanical alloying, hot/cold working, and heat treatment processes. Joining technology for the ODS steel components is also being developed using solid-state welding such as magnetic pulse welding, friction stir welding and diffusion boding. These R&D activities will contribute to the realization of ODS materials for future nuclear reactor system applications.

Jan 1, 2015