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By Takeshita. Takuo

"In this work, the progress of the HDDR process is discussed mainly on the Nd-Fe-B magnet system. There are three technologies being used for the Nd-Fe-B permanent magnet production; the sintering technique, the rapid quenching annealing and the HDDR process. The HDDR process utilizes· the HDDR phenomenon, in which hydrogen absorbing intermetallic compounds go through as they are heated in hydrogen atmosphere, Hydrogenation - Decomposition Desorption - Recombination. In the HDDR process, these four steps in the HDDR phenomenon are processed by choosing suitable reaction conditions regarding to hydrogen gas pressure, temperature, rate ·of desorption and etc., and we can produce permanent magnet powders of good magnetic properties with microstructures consisting with sub-micron size crystalline grains. In the anisotropic magnet powders, the sub-micron size crystals are being mostly aligned in the crystallographic c-axis direction. Possible applications of the HDDR process to other systems are also discussed.Microstructures of the Nd-Fe-B Permanent MagnetsIt is well known that magnet properties of magnetic materials are very sensitive to their microstructures [l]. This is seen in almost all magnet materials from soft magnetic materials and hard magnetic materials to magnetic memory materials. In this regard, the production technology is very important for the control of microstructures of permanent magnets The Nd-Fe-B magnet is the most powerful permanent magnet as a practical permanent magnet, and its coercivity force is much dependant on the microstructure as is the case for other permanent magnets."

Jan 1, 2000

By W. Z. Yin

It is investigated systemically in this paper that the granularity of the precursor, ZnC2O4?2H2O, is influenced by synthetic conditions. Instantaneously adding of precipitation agent is able to control the mean size of precursor ZnC2O4?2H2O under 300nm, which has great function to obtain well-dispersed ZnO nanoparticles in the next step, pyrolysis. The pyrolysis kinetics model of ZnC2O4?2H2O powder is obtained. Two steps take place during the pyrolysis. The first is dehydration, which the pyrolysis kinetic model is 2(1-a)2/3(chemical reaction), A=8.3×108s-1, E=(75.82±3.00) KJ/mol. The second is formation of ZnO, which the pyrolysis kinetic model is (1-a) (random nucleation and latter growth), A=8.45×1028s-1, E=(360.54±12.00)KJ/mol. ZnO nanoparticles obtained by pyrolysis take on self-growth behavior. It is resulted that for precursor ZnC2O4?2H2O pyrolysis time takes obvious influence on the partilces size under 420?, 500? and 600?. Finally, a new flow sheet for synthesis of ZnO nanoparticles is investigated, in which blendes is used as raw material and hydrometallurgy is introduced into it. The whole flow sheet has no industrial wastes, that is all byproducts can be used in the flow sheet recycled, resulted in the de-crease of productive cost and industrial wastes.

Jan 1, 2014

By B. K. Cantrell, K. L. Rubow

"The US Bureau of Mines and the University of Minnesota have developed design and performance criteria for a personal diesel exhaust aerosol sampler for underground coal mines. These are based on the premise that size can be used to separate diesel exhaust aerosol, which is mostly submicron in size, from coal dust aerosol, which is mostly greater than a micron in size. The sampler has three stages: a respirable aerosol preclassifier, a 0.8-um aerodynamic diameter inertial impactor to collect mineral dust and a final filter to collect the diesel aerosol. Using a sample flow rate of 2 L/min and gravimetric analysis to within 0.1 mg, the measure sub-0.8 um diesel aerosol has an a-priori limit of detection of 0.3 mg/m3.A miner working in an underground coal mine with diesel equipment is exposed to a wide array of pollutants from the diesel exhaust. These include CO, CO2. NO, NO2, SO2, diesel exhaust aerosol, and a variety of hydrocarbon compounds. A quantitative definition of the health risk resulting from these exposures remains elusive. During the past several years, though, progress has been made in defining the problem.Results from epidemiological studies by Garshick et al. (1988 ), animal inhalation studies by Mauderly eta). (1986), Iwai et al. (1986), and Brightwell et al. (1986) and in vitro studies by Lewtas et al. (1986) have provided sufficient data for the National Institute of Occupational Safety and Health (NOSH) to recommend that ""whole diesel exhaust be regarded as a 'potential occupational carcinogen,' as defined in the Cancer Policy of the Occupational Safety and Health Administration"" (NIOSH, 1988). NIOSH further stated that ""though the excess risk of cancer in diesel-exhaust-exposed workers has not been quantitatively estimated, it is logical to assume that reduction in exposure to diesel exhaust in the workplace would reduce the excess risk.""The Mine Safety and Health Administration (MSHA) has also been directed by an advisory committee to establish a diesel exhaust aerosol standard and to establish regulations to minimize exposure to diesel pollutants in underground coal mines (MSHA,1988). Both reports point out the need for development of measurement techniques for respirable diesel aerosol.In the past four years, the US Bureau of Mines (Cantrell,1987 and Cantrell, et al. 1987), in cooperation with Marple, et al. (1986), at the University of Minnesota's Particle TechnologyLaboratory (PTL), have studied the use of size-selective sampling techniques to measure the mass concentration of diesel aerosol in underground coal mines. Results from these studies have been used to develop design and performance criteria for a personal diesel exhaust aerosol sampler for use in underground coal mines.These criteria are based on the premise that size-selectivesampling techniques,can be used to separate diesel exhaust aerosol, which is predominantly submicron in size, from coal dust aerosol, which is mostly greater than a micron in size. In addition to the performance criteria, this paper discusses the laboratory and field test data used to develop the criteria."

Mar 1, 1992

Proposed by outstanding electrochemist and electrometallurgist Prof. Raphael Agladze (191 1- 1989), process of copper and manganese co-electrowinning was enhanced to the pre- electrowinning stages: low,temperature co-leaching of copper and manganese containing materials, and to high-temperature co-roasting of the same materials with consecutive leaching. The report presents results of experimental investigations of the processes mentioned above, as well as results of thermodynamic investigations of co-roasting processes, and co- leaching processes computer modeling.

Jan 1, 1997

By J. A. Herbst

Professor Klaus Schönert and his students used fundamental physics to develop many of the principles required for the design and scale-up of "Gutt Bett Zerkleinern" devices such as the high pressure grinding roll (HPGR) or the high pressure roll crusher (HPRC). As the equipment evolved so have the tools used for its selection and analysis. In the current paper discrete element modeling (DEM), Metso's proprietary Fast Breakage simulations, and Schönert's packed bed piston test are combined with energy based population balance models (PBM) to yield an alternative to ore characterization and equipment selection by pilot plant testing. The resulting methodology is used to take the next step in understanding these devices with a view toward predicting plant performance. This paper describes a journey beginning with precise modeling of a small HPGR including stud geometry and system hydraulics. A key to predicting performance is the accurate modeling of individual particles, their motion in the machine, the probability of breakage and redistribution of fragments, and the inter-particle breakage events that occur between the rolls at different pressures, speeds and moisture levels. Advanced DEM simulations and particle breakage characterization methods provide the necessary technology. The resulting combined models were validated using a small diameter laboratory scale unit. The validated physics based model was used then used to predict the performance of plant scale units using a specific energy based scale-up method. Scale-up results are analyzed in terms of power draw, throughput, and discharge product size distribution.

Jan 1, 2012

By B. Erik Ydstie, Dimitrios I. Gerogiorgis, Sridhar S. Seetharaman

"Carbothermic production of aluminium is an important alternative to electrolytic processes and has in fact been identified several decades ago as a potentially feasible and profitable process. The cornerstone principle is to take advantage of the endothermic reduction reaction between carbon and alumina instead of resorting to extreme amounts of electric energy to ionize and reduce aluminium oxide to aluminium. Electric energy is necessary only for heating purposes.The present study focuses on constructing and solving a steady-state electrothermic model for obtaining the spatial distributions for electric potential, electric field intensity and temperature. The complex issues of reaction kinetics and multiphase flow are handled by an approximation and are not addressed at the present stage, due to the lack of complete validated models. Because of its inherent complexity, the reaction slag is considered a pseudohomogeneous layer.An electrothermic simulation encompasses important research challenges, due to the limited knowledge of thermophysical properties for high-temperature multi component molten slags. Therefore, thermophysical property modeling and a systematic compilation of published data is a necessary and major first step towards enhancing understanding of the process fundamentals. Models are obtained by analyzing measurement data from numerous literature references for the density, viscosity, thermal and electrical conductivity and specific heat capacity of the slag.The electric potential, field intensity and temperature distributions obtained reveal interesting maxima which indicate localized superheating and lead to important engineering conclusions. The temperature profile calculated will serve as the foundation for the flow problem solution. This computational study will form a basis for future research towards combining the scopes of microscale CFD modeling and mesoscale process modeling into a unified modeling approach."

Jan 1, 2001

By Anita Marks

In 2007 Copper Mountain Mining determined that there were sufficient resources to consider reopening the Similco Mine near Princeton, BC. The mill facility that had been built by Newmont Mining in 1972 was closed in 1996 and all of the process equipment removed. The mill had been built on the west side of the Similkameen River to facilitate mining of the Ingerbelle Deposit. In 1980 construction was completed on a primary crusher and cable belt to deliver ore across the Similkameen River from the Copper Mountain deposit to the Ingerbelle mill. With the decision to restart mining of the Copper Mountain deposit, the decision was made to design and build a 35,000 tpd grinding and flotation mill near the mining operations. This paper discusses the application of historical operating data for the selection of the mills for the new grinding circuit and provides an overview of the grinding circuit design.

Jan 1, 2012

By A. J. Makoka, B. C. Qi

Reliable monitoring of corrosion is vitally important in the combat against corrosion and over the last two decades the interpretation of electrochemical noise has received considerable attention as a means to discriminate between different types of corrosion. To this end, many different analytical methods have been proposed, such as power spectral density analysis and analysis via various other stochastic criteria. However, although many corrosion systems are nonlinear and therefore not readily interpretable by the abovementioned analytical approaches, few studies in the analysis of electrochemical noise to date have exploited advances made in the analysis of nonlinear systems. In this paper, the use of phase space methods to analyze and detect change in corrosion systems via electrochemical noise is considered. In particular, the electrochemical noise data are used to reconstruct trajectories in the so-called phase space of the system and changes in the topology of these trajectories or attractors as represented by correlation dimension curves are consequently interpreted as an indication of change in the dynamics of the system.

Jan 1, 2005

By V. A. Luganav

The behavior of arsenopyrite under heating has been studied by many scientists. It has been already established that under heating at more than 650°c and without air access the arsenopyrite dissociates with the formation of one atom arsenic. Under vacuum the dissociation process begins at 5500C with the formation of elemental arsenic. The residue of dissociation process contains pyrrhotite and throilite. In the presence of pyrite, arsenopyrite dissociates under lower temperature and with a higher velocity than without it. The industrial realization of fool scale processing of arsenic bearing raw materials is possible only by the use of standard equipment and oxygen containing blast. In this view the paper presents the results of the study on the effect of oxygen in the gaseous phase and its addition into the charge of pyrite in the process of arsenopyrite decomposition. Thermodynamic analyses showed that under thermal processing of arsenopyrite in the presence of pyrite and limited quantities of oxygen in the gaseous phase the formation of arsenic sulfides is possible according to the following reactions:

Jan 1, 2003

Palabora Mining Company (PMC) processes a multi-component ore body using a circuit consisting of two AG mills in parallel, closed with vibrating double deck screens and hydrocyclones. The bottom screen undersize feeds the hydrocyclones, but the screen oversize products can be treated in a variety of ways. The top deck screen pebbles can be crushed and then combined with the bottom deck oversize and recycled to the AG mill. Alternatively both the top and bottom deck screen oversize can by-pass the recycle crusher and be recycled directly to the mill. A full tap-off is a configuration when both the top and bottom deck screen oversize streams are stockpiled. The other configuration is when the bottom deck screen oversize is recycled to the mill while the top deck screen oversize is stockpiled - termed partial tap-off. This article reports the findings from the surveys performed to evaluate the performance of the PMC auto mill circuit when operated under the four different configurations discussed. Ore characterisation tests were performed to assess the deportment of the key ore components for the different configuration.

Jan 1, 2012

By Mahmoud Sepehrmanesh, Verya Nasri, Maziar Partovi

"This paper presents an assessment of the impact of tunneling and its associated risks on pile foundations located in the influence zone of tunneling operation. Tunneling in proximity of pile foundations introduces deformations in piles and in turn induces additional axial and bending forces. In modern mechanized tunneling, ground convergence is controlled through balancing the earth pressure at the tunnel face as well as applying pressurized bentonite through the shield. Reducing ground deformation can consequently lower the additional deformations and forces developed in the pile foundation and lessen the associated construction risk. In this paper, comprehensive detailed finite element modeling was performed to quantify the effect of the different parameters on induced forces in piles. Finite element models took into account the nonlinear behavior of soil and pile-soil interface. The modeling results are of practical importance in risk evaluation of tunneling in vicinity of pile foundations. INTRODUCTION Tunneling operation in congested urban areas becomes more frequent as demand for further utilizing underground spaces grows. In urban settings, it is not uncommon for tunnel designers to plan a tunnel route in close proximity to other structures to satisfy other competing objectives like raising the alignment to reduce excavation volume. Setting the alignment close to existing structures increases the risk involved in the project. It is the responsibility of the designer to thoroughly identify, assess, and mitigate all design risks involved. In this paper, we focus on the aspects involved in tunnel construction in proximity to existing pile foundations. Tunnel operations introduce deformation in the soil mass. Consequently, a pile located within deformation zone experiences extra forces as a result of the imposed deformation. The developed forces and bending moments can be in orders comparable with the pile capacity depending on the relative horizontal proximity of the tunnel and the relative depth of tunnel with respect to the pile length."

Jan 1, 2016

By N. S. Dalal, Xianglin Shi

"Electron spin resonance (ESR) spin trapping experiments have been carried out to investigate the mechanism of sulfite oxidation em¬ploying 5,5-dimethyl-l-pyrroline-1-oxide (DMPO) as a spin trap. The results show that sulfite autoxidation, catalyzed by Mn(II), involves not only the SO-3 radicals but also the •OH radicals. An addition of H2 02 to the sulfite aqueous medium significantly increases the •OH radical formation. This result provides new clues to the chemical mechanism of the sulfite oxidation and the sulfite toxicity.INTRODUCTIONStudies of the oxidation of the sulfite (SO 2-/3) ions under various conditions are of high current interest because excessive exposure to sulfite is toxic and the origin of this toxicity seems to involve sulfite oxidative pathways [1]. An important fact is that human exposure to sulfite is on the increase [1,2]. Some of the increase in the sulfite exposure is linked to the fact that SO2 is a major air pollutant [2] and in aqueous media SO2 exists in equilibrium with SO2-/3. In addition, beverages and foods are common sources of sulfite intake. For example, sulfite is used extensively in the wine industry as an inhibitor of yeasts and bacteria and is present in finished wines in concentrations up to 6 mM [1]. Sulfite is also often added to dehydrated fruits, vegetables and soups, as well as fruit juices and beer [1,3,4]. Because of these, the mean daily intake of sulfite from diet (in the United States) has been estimated to be between 0.0014 and 0.14 mM/kg body weight [1]. At such high levels, sulfite exposure can have toxic effects, such as the induction of an acute asthmatic state [5,6]. Sulfite also appears to have adverse genetic effects [7] and can act as a mutagen or comutagen [8] and a cocarcinogen [5,7-9]."

Jan 1, 1990

By Kim Chan, Bryn Thomas, Ben Dening

"Increased rail capacity is required into Kooragang Coal Terminal near Newcastle, NSW, Australia to relieve rail traffic congestion and improve management of train arrivals. An additional arrivals track is proposed on new embankment within a heavily constrained site located between existing railway tracks, a high pressure gas pipeline located 7m beyond the toe of the embankment and an environmentally sensitive wetland area. Ground conditions at the site consist of deep soft estuarine clays, a soil profile which is consistently encountered throughout this part of the east coast of Australia. Upon determining that a ground improvement solution was required to ensure global embankment stability, various solutions were considered including a piled viaduct, retaining walls, dry deep soil mix (DSM) columns and concrete injected columns (CICs). DSM columns were adopted as the design solution, a decision which was driven by the presence of sensitive infrastructure and a confined site. DSM offered further advantages including reduced impacts on temporary working platform design, where the use of a thinner platform could be justified owing to the lower track loads of a DSM rig relative to other ground improvement techniques.INTRODUCTIONThis paper presents a case study of the design of DSM ground improvement works to provide support for and enable safe construction of a new railway embankment over deep soft soils with a number of nearby infrastructure and other constraints. The project site is approximately 1km long and is constrained by existing railway tracks, a high pressure gas pipeline and a wetland area of ecological significance. Due to the site constraints and ground conditions, a number of ground improvement techniques were considered during the design process, with DSM columns eventually adopted. This paper discusses the design development and the particular suitability of the technique for use in this application.SITE DESCRIPTIONLandformThe site is located along the northern boundary of the Kooragang Coal Terminal (KCT) at Kooragang Island (KI), a collection of former islands located near the mouth of the Hunter River, north of Newcastle, NSW. The topography of the original area was generally flat with mudflats, swamps and mangroves existing along tidal water courses. Subsequent dredged fill reclamation and development has amalgamated the previous islands into the current KI. The site area extends over numerous channel infills including the buried former course of the Moschetto Channel (paleochannel).Figure 1 shows the proposed 1km long new rail corridor construction area in relation to the various natural and man-made site constraints including existing tracks, the high pressure gas pipeline, the wetland area and the existing reclaimed area."

Jan 1, 2015

By Cezar Henrique Gonzalez

Processos de conformação plástica têm sido aplicados nas ligas com memória de forma (LMF) para melhorar suas propriedades mecânicas. No entanto, estes processos provocam alterações das suas propriedades termoelásticas (temperaturas e entalpias de transformação, cargas críticas de indução da martensita, deformação termoelástica reversível e outras). Para aplicações tecnológicas destas ligas, por exemplo como atuadores termomecânicos, elas devem manter suas características constantes ao longo de sua utilização (propriedades termoelásticas). Neste trabalho são analisadas estas propriedades das ligas de Ni-Ti com memória de forma que foram conformadas termomecanicamente pelos processos de laminação convencional e de extrusão angular (Equal Channel Angular Extrusion - ECAE). As analises foram realizadas por calorimetria diferencial de varredura, microscopia eletrônica de varredura e teste de tração sob carga constante (simulação do efeito memória de forma para determinar a propriedades termoelásticas). Os resultados mostraram que os processos de conformação alteram drasticamente as propriedades, principalmente para aquelas amostras submetidas ao ECAE que chegam a bloquear a transformação martensítica. Tratamentos térmicos foram aplicados com o objetivo de melhorar ou restabelecer as propriedades do efeito memória de forma. Resultados das difrações de raios-X e das micrografias indicam que cada tipo de processo de conformação plástica e a formação de precipitados influenciam de forma preponderante nos comportamentos das propriedades termoelásticas. Estas análises são relevantes para aplicações tecnológicas destas ligas, pois requerem boa resistência mecânica combinada com as propriedades funcionais dos fenômenos de memória de forma.

Aug 16, 2017

By R. H. King

Underground coal mining machinery utilizes portable electric sables, "trailing cables." to obtain power from load centers or distribution boxes. Cables are frequently damaged since mobile equipment, poor lighting, and restricted space are inherent to coal mining operations. Normally, the damage is repaired by splicing--the joining of one or more severed conductors and replacing insulation and jacket. Figure 1 illustrates a typical single conductor splice. Although the repair seems simple, difficulty of the splicing process is exemplified by the many safety hazards and frequent production delays that result from defective splices. Forty-two cable splice related injuries were reported to the U.S. Bureau of Mines in 1972 and 1973. Additionally, 17 splices related fires were reported in the three year period prior to December 1972. Assuming the damaged area is quickly located, an average splice time for a two conductor cable is twenty minutes. Some operators estimate this delay is incurred once per day per operating section. If one ton per minute is averaged throughout the shift, each unit could loose 4800 tons per year from splice delays. An estimated cost for materials and labor to make a splice is $20. The expenditure could result in a $4800 annual cost per section. The estimated expense does not include wages of other personnel waiting for the repair to be completed. Nevertheless, labor and materials cost is minor compared to the income lost from decreased production.

Jan 1, 1975

By George Gazetas, Sissy Nikolaou, Fani Gelagoti, Irene Georgiou, Rallis Kourkoulis

"The need to shift geotechnical design from a “factor of safety” to a “performance based” design (PBD) approach has increased rapidly in the past years following examples from structural engineering. PBD supports sustainable engineered systems that target project-specific geotechnical behavior objectives and results in more rational and, in most cases, less conservative solutions. Resiliency, efficiency, risk optimization, and cost-effectiveness are key components of this approach. For design of retaining walls, the concept of mechanically stabilized earth (MSE) systems combines these attributes, while being environmentally friendly and adaptive to variable construction conditions. Natural hazards, such as earthquakes, may drive the design of MSE systems whose reliability depends on their performance under extreme events. In this paper, the authors compare the seismic response of an MSE steel-reinforced vs. concrete-reinforced retaining wall. The MSE system is composed of a grid of longitudinal and transverse ribs which internally enhances the capacity of the soil backfill. Results of fully non-linear twodimensional (2-D) numerical finite element analyses using two commercial programs with emphasis on the interface conditions are presented. The pull-out resistance of the grid used in the numerical simulation was evaluated from actual pull-out experiments. The results demonstrate a superior performance of the MSE system as compared to the concrete one, especially when subjected to strong seismic excitations.INTRODUCTIONThe idea of performance-based geotechnical engineering is not new, and has been evolving as our perception for ‘good’ performance has also evolved (Kramer, 2008). In early practice, the only criterion for achieving good performance was to avoid failure; designers had only to ensure that the available capacity of the geotechnical system is sufficiently higher than the expected demand (i.e. Load and Resistance Factor Methodologies). Yet, even when the key design requirements against collapse are satisfied, the system may still be placed into a condition in which the deformation constraints are not met (Bolton, 2012). To address these issues, geotechnical design has been developing into a predominantly performance-based approach that correlates deformation considerations to the severity of the experienced loading. As such, in earthquake-related problems, the definition of good performance of a geotechnical system is no more unique; for a low intensity earthquake the system should remain serviceable (i.e., the developed deformations should remain low), whilst for the design earthquake the maintenance of lifesafety is the single performance criterion."

Jan 1, 2016

By Nicolás Lugo

The electric steel industry has reached a level of maturity in its relative participation in the world’s steel production. As the industry has grown and matured, EAF steel producers have participated in an ever more competitive market. This competition has led to a continuous search for lower cost alternatives for energy and input materials. Over the years, the Electric Steel Furnace community of operators has developed a variety of technological improvements geared to increasing EAF productivity. Operators have emphasized lowering operating costs and improving the quality of steels produced. Depending on market conditions, the EAF operators may run with different goals and priorities. In times of low demand, the goal may be to operate with an emphasis on cost and the goal of maximizing cost effective use of resources. When the market demand is high the goal may be to maximize EAF throughput. The objective of this work is to list some of the EAF operating best practices observed by our team in the electric arc furnace operations around the world. EAF operators can consider and possibly implement these practices depending on the specifics of each EAF operating reality.

Jul 29, 2018

By W. Pawlos

"The paper will present the methods of visual observation and recording of movement paths of coal grains of different physical properties in the paramagnetic liquid. The paths were recorded with a video camera in the working chamber by means of a specially constructed device, acting as a periscope, which were then transformed into digital images.Experimental movement paths were confronted to the paths obtained in a theoretical way by means of solving differential equations of movement. The outlet level of a grain of the same physical properties from the separator is a random variable with normal distribution which modal value is equal to the outlet level of a spherical grain, calculated from the solution of grain movement equations. At these assumptions it is possible to calculate the height of the passage from the separator working chamber to separate a given product with a given separation accuracy, measured by a probable error and to determine separation conditions."

Jan 1, 2003

By M S. Manono, K C. Corin

The optimisation and process developments surrounding the beneficiation of Cu-Ni-PGM ores is of fundamental importance when considering the continued rise in global demand for these precious metals. The selective sequential flotation of these ores is accompanied with various processing challenges such as the successful separation of the Cu-Ni-PGMs from non-sulfide naturally floatable gangue and pyrrhotite. Reagents such as sodium iso-butyl xanthate (SIBX) and sodium carboxymethyl cellulose (CMC) have proven to significantly improve the selectivity of the flotation process in their respective roles. The use of recycled water with abnormal inorganic electrolyte concentrations can modify the selectivity of these reagents, as ions may adsorb onto minerals such as pyrrhotite, thereby hindering or promoting the hydrophocity and floatability of pyrrhotite. Process water quality effects on the behaviour of pyrrhotite may have negative or positive influence on the recovery and grades of the wanted Cu-Ni-PGMs as valuable minerals associated with pyrrhotite such as pentlandite may be affected in like manner. Thus, the impact of concentrator process water quality on the behaviour of pyrrhotite needs to be determined. In this study synthetic process water at various ionic strengths was investigated against various CMC dosages to understand the behaviour of pyrrhotite during the flotation of a Cu-Ni-PGM Merensky ore in a batch flotation cell. This study showed that pyrrhotite grades increased with an increase in CMC dosage for fixed ionic strengths whereas the recoveries of pyrrhotite increased with an increase in ionic strength until 3SPW, then a trend of a decrease in recoveries was seen with 5SPW resulting in the lowest pyrrhotite recoveries. Furthermore, this study showed that moderate CMC dosages of 100 g/t resulted in the highest pyrrhotite recovery for all four ionic strengths of synthetic process water tested. It can be said that to maximise value recovery from Cu-Ni-PGM ores, understanding the behaviour of pyrrhotite against degrading water quality and reagent suites could be of paramount importance given the sensitivity of pyrrhotite to oxidising chemical conditions.

Aug 24, 2022

By N. F. LeJeune, Earl C. Lane

This is the third of a series of reports on a survey of petroleum prod- ucts manufactured on the Pacific Coast from California crude oils. California crudes differ in many characteristics from the petroleum produced in the other parts of the United States, and the claim has been made that some of the present Federal Specifications for petroleum products tend to discriminate against Cali- fomia products. The purposes of the present survey are to determine what par- ticular specification requirements Califomia petroleum products characteristical ly fail to meet, how widely the products deviate from these requirements, and if possible to show whether the fault lies with the specifications or the products, or along what lines investigation to determine this question should proceed. The first report of the series gave the physical and chemical properties of the samples of gasoline and mineral spirits. A second report**, gave the physical and chemical properties of samples of lubricating oils. The present report deals entirely with burning and fuel oils. The refin ing companies have continued their very cordial and helpful cooperation. Seven samples of kerosene, four samples of Diesel fuel and eight samples of fuel oil were obtained. The methods of analysis used are those adopted by the Interdepartmental Petroleum Specifications Committee, published by the Bureau of Mines in Technical Paper No. 323. The specifications used for corparison are those officially adopted by the Federal Specifications Board for the use of the various Depart- ments and Independent Establishments of the Government, effective February 3, 1923, and published by the Bureau of Mines in Technical Paper No. 323, Part 1. Specific gravity, degrees A.P.I., viscosity and other special tests al- though not required by the specifications have been given for comparison. All temperatures are recorded in degrees Fahrenheit. Tables have been prepared giving data on physical and chemical propertios of the individual samples. Before each table the classification and specifica- tions for the particular class of oil considered in the table are given. Follow- ing each table, brief notes show wherein samples deviate from specification re- quirements.

Aug 1, 1923