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By Ronel du Plessis, John C. Davidtz, Jan D. Miller

Recent results from electrochemical measurements demonstrate that trithiocarbonate (TTC) collectors are more readily oxidized to their corresponding dithiolates than the dithiocarbonate/xanthate (DTC) collectors. Based on the traditional analysis of collector adsorption, trithiocarbonates might then be expected to be effective for bulk sulfide mineral flotation. Previous bench-scale flotation research had shown that TTC collectors are very effective for the flotation of copper sulfide minerals and PGM (platinum group metal) sulfide minerals. More recently, the TTC collectors were evaluated for auriferous pyrite recovery in benchscale plant scale flotation testing in the United States and in plant tests at Anglogold in South Africa. TTC collectors were also applied in bench-scale testing of a PGM ore. In each case an improved separation efficiency was realized. Fundamental studies at the University of Utah examining the effect of collector structure (functional group, -O-CS2 versus .S-CS2), specifically with respect to auriferous pyrite flotation, are in progress. The effect of collector structure was evaluated with air as well as nitrogen as the flotation gas medium. Experimental techniques utilized included electrochemically controlled contact angle measurements to evaluate mineral hydrophobicity and infrared spectroscopy to explain collector adsorption phenomena at the mineral surface.

Jan 1, 2003

By Dennis A. Hansen

As part of a U.S. Bureau of Mines program to develop a more continuous titanium metal extraction process that uses domestic resources, a study was made to determine the extraction of titanium (Ti) and iron (Fe) from New York rock ilmenite using fluosilicic acid (H2SiF6). The effects of leach temperature, acid concentration, and particle size were investigated for the rate at which Ti and Fe are extracted from the ilmenite. Within the leach time studied, the extraction data fit a shrinking-core model; the rate-controlling step was diffusion of H2SiF6 through an ash layer resulting from a heterogeneous leaching reaction. The rate is linearly dependent on the H2SiF6 concentration and is inversely proportional to the square of the particle diameter. Using 2.6M H2SiF6 at 85°C, 49% of the Ti and 53% of the Fe in 44-to 74-µm New York rock ilmenite were extracted in 3 h.

Jan 1, 2010

By J. J. Rush

Neutron scattering and analysis techniques are extremely powerful, often unique, probes for the characterization of the amount, location, bonding states, and dynamics of hydrogen in all classes of materials. Developments over the past decade at the NIST Center for Neutron Research and elsewhere have greatly increased the sensitivity and dynamic range of neutron methods. In this paper, we provide a flavor of the capabilities of modem neutron instrumentation for the study of hydrogen in a number of technologically interesting systems, including metal hydrides, fuel-cell materials, fullerenes, and disordered carbons.

Jan 1, 2002

By Arkady Senchenko, Andrey Vasiliev, Alexander Aksenov, Metodi Zlatev

"This paper considers the issue of treating argillaceous oxidized ores with low gold grade (around 1.0 g/t). These ores according to their gold recovery level can be treated by heap leaching and agitation cyanide leaching, but low gold grade makes this treatment uneconomic. Heap leaching of argillaceous ores requires high consumption of binding agent for pelletizing to create suitable hydro-physical properties of material, which leads to increasing process cost and makes the material treatment unprofitable. Agitation cyanide leaching of this ore requires grinding processes; these expenses would not be paid back by the amount of gold recovered. Considering the above, poor argillaceous oxidized ores are recommended to be treated according to a combined technology including fractionation of ore, heap leaching of coarse fraction and agitation leaching of argillaceous fraction. Complex approach application allows one to avoid expenses incurred for material grinding and high consumption of binding agent for pelletizing. The success of this technology implementation will firstly depend on the quality of material fractionation, therefore the section of disintegration and division of ore into different components will be the most important part of flowsheet development for gold production. When disintegrating minerals at positive temperatures both standard (mechanical disintegration - scrubbers) and innovative (hydraulic method of disintegration - HydroClean units) equipment is applicable. HydroClean units are characterized by lower energy and water consumption. In a number of cases it is required to treat frozen ores. When treating frozen material standard approaches to disintegration are not reasonable due to their low efficiency. In order to treat frozen material a two stage disintegration flowsheet with screening after each stage is recommended. The first stage is recommended to be performed in a scrubber, the second - in a HydroClean unit. This technological flowsheet will provide high and steady values for ore separation into fractions at low energy consumption for disintegration."

Jan 1, 2014

By A. Block-Bolten

Copper concentrates from northern Peru contain large amounts of arsenic and antimony in the form of sulfosalts like enargite, tennantite and tetrahedrite. These impurities affect up to 30% of Peruvian copper production. Under the sponsorship of the Instituto Geologico Minero y Metalurgico in Lima a project to separate copper from arsenic without pollution of the environment is being carried out at the National University of Trujillo in Peru. The U.N.T. process is unique in the respect of using .low melting salts as solvents, and sulfides of metals with high cation potential as destructors of the complex sulfosalt molecules. Laboratory scale experiments have given encouraging results but interesting and difficult problems developed on scale-up. The process is pyro-hydrometal-lurgical and under certain circumstances its economics are promising.

Jan 1, 1981

By Mikio Kobayashi

Extraction of valuable metals from sulfide ores continues to be a very important, process and so the strict control of discharge of harmful metals in effluents from refineries becomes more important in the future. The recovery methods for heavy metals have been developed. Some metals such as Se and As are still difficult to be removed to very low concentration, although the techniques for recovery and removal for many kinds of heavy metals have already been developed. Especially, in case of Se the recovery system from water with low concentration has not be developed yet, although the WHO decided Se to be harmful for human beings and then the discharge control is under obligation now. In general Se exists as selenite ion and/or selenate ion in aqueous phase and selenite ion is able to be recovered by coprecipitation with ferric hydroxide or by reduction to solid selenium by general reductants. Selenate ion, however, has a strong resistance to conventional treatments. Therefore the new technique for the recovery of Se from water including selenate ion has to be developed. In this presentation the new approach for removal of selenate ion using the reaction in which ferrous ion is oxidized to ferric ion is presented. Selenate ion is reduced to selenite ion during the reaction and then to solid selenium, while ferrous ion is oxidized to ferric ion. The coexistence of activated carbon is very useful to increase the reaction rate. The use of iron powder is also effective and very useful for reducing gel-like precipitates mainly consisted of ferric hydroxide. The concentration of the residual selenate ion is probably under 0.1 ppm after recovering Se by the mentioned-above approach. In addition to the mechanisms of these reactions, the effects of pH, coexistent positive and negative ions, and reaction temperature are also presented. Furthermore the investigation of the behavior of selenosulfate is presented.

Jan 1, 1998

By Chris P. Pistorius

Over the past few decades the carbon intensity of ironmaking and steelmaking has been reduced considerably through improved efficiency in blast furnace ironmaking, partial replacement of coke with less carbon-intensive fuels, and increased use of scrap and direct-reduced iron in steelmaking. To evaluate possible further reductions in carbon intensity accurate process information is needed. A preliminary test of the fidelity of publicly reported data as a source of process information is reported here. The sources are industry roundups of electric furnace furnace steelmaking and blast furnace ironmaking (published by the Association for Iron and Steelmaking Technology), and data recorded by the Environmental Protection Agency under the US Greenhouse Gas Reporting Program. From a comparison for an integrated steelmaking plant and an electric furnace furnace plant, it appears that the values from the two data sources are consistent. The comparison does rely on process details such as the quantitative relationship between injected oxygen and carbon emissions in electric furnace steelmaking.

By T. J. Chen

Vanadium-beard bone coal is one of important vanadium resources in China.To extract vanadium tailings from Stone coal is produced after extracted vanadium from stone coal through the roasting, leaching and other processes. About 120-150 tons of tailings will be produced in extracting 1 ton of vanadium pentoxide. A lot of tailings that are willfully piled up have caused serious environmental pollution and wasting of resources; it is therefore necessary to realize its resource utilization. This study increases the activity of vanadium tailings by means of alkali fusion, and then uses different alkali activators to react with vanadium tailings so that geopolymer with high value added is produced. Sample of geopolymer is acquired from a mixture containing vanadium tailings, alkali activators, water and a little sodium aluminate through compression-molding process under 20MPa pressure. After cured in room temperature for three days, the maximum compressive strength of the sample can reach 36.2MPa. XRD analysis indicates quartz, the major crystal phase in vanadium tailings is decomposed,and the activity of vanadium tailings is heightened. FTIR and SEM analyses show: structural change having an important impact on the mechanical strength of geopolymer occurred during the process of vanadium tailings generating geopolymer.

Sep 1, 2012

By S. D. Michaelson

Open pits and quarries are the major sources of all "hard rock" tonnage mined today. Normally, ore is fractured from the pit face by blasting and then truck-hauled to a primary crusher where processing begins; over- burden (or waste) is generally truck-hauled from the pit to dump areas. Truck haulage of blasted ore and overburden accounts for some 25 to 50 percent of total mining costs in a typical open pit and commonly is the largest single cost factor. Obviously then, cost reduction efforts should properly focus on improving existing haulage systems and developing new breakthrough techniques for material transport. Continuous flow systems for large tonnages ordinarily will result in a lower cost than batch systems such as truck or rail haulage. Continuous flow with pipelines for liquids and slurries, or conveyors for medium to coarse dry materials (in the -8 in. range) are the accepted economic answers for bulk materials handling over reasonable distances.

Jan 1, 1968

By B. K. Cantrell

A miner working in an underground coal mine with diesel equipment is exposed to a wide array of pollutants from the diesel exhaust. These include CO, CO2, NO, NO2, SO2, diesel-exhaust aerosol, and a variety of hydrocarbon compounds. A quantitative definition of the health risk resulting from these exposures remains elusive, but during the past several years, progress has been made in defining the problem. Results from epidemiological studies by Garshick, et al. (1988); animal inhalation studies by Mauderly, et al. (1986); Iwai, et al. (1986); and Brightwell, et al. (1986); and in vitro studies by Lewtas, et al. (1986), have provided sufficient data for the National Institute of Occupational Safety and Health (NIOSH) to recommend that "whole diesel exhaust be regarded as a 'potential occupational carcinogen,' as defined in the Cancer Policy of the Occupational Safety and Health Administration," NIOSH (1988). NIOSH further stated that "though the excess risk of cancer in diesel-exhaust-exposed workers has not been quantitatively estimated, it is logical to assume that reduction in exposure to diesel exhaust in the workplace would reduce the excess risk."

Jan 1, 1990

By Ramanathan Ayothiraman, Anurag Singh

"An experimental program was undertaken to investigate the effects of randomly distributed basalt fibre on the index and engineering properties of Dhanori clay and to compare its performance with the properties of soil reinforced with polypropylene fibre. In the present investigation, 7 groups of soil samples were prepared at four different percentages of basalt fibre and polypropylene fibre content and tests were done for measuring their consistency limits, compaction characteristics, unconfined compression strength and consolidation properties. The test results indicate that the inclusion of basalt fibre in Dhanori clay resulted in significant improvement in properties. The improved properties are not comparable with polypropylene fibres, nevertheless, the improvement by basalt fibres is able to meet the typical design target values and the cost is very much less than synthetic fibres. More importantly, basalt fibres are environment friendly.INTRODUCTIONConstruction of buildings in low lands with engineered filling, flexible and rigid pavements for highways/airfields, and embankments for highways/railways are also part of major infrastructural development in addition to construction of tall buildings, bridges/fly overs, major dams and underground structures. The later projects require different improvement techniques than that is adopted in the former projects. Ground improvement techniques such as use of reinforcement inclusions within soil found as an effective and reliable technique. Especially such modification by fibre reinforcement, is primarily possible in engineered filling, pavements subgrade and embankments, where surface mixing is easier; and may not be feasible when stabilization/modification is required for deeper depths. In comparison with conventional reinforcement using geosynthetics (strips, geotextile, geogrid, etc.), there are some advantages in using randomly distributed fibre as reinforcement. In past few decades, the discrete fibres are simply added and mixed randomly with soil, in much the same way as cement, lime, or other additives.There are several studies (Ziegler et al. 1998; Puppala et al. 2000; Bei-xing et al. 2004; Cai et al. 2006; Tang et al. 2007, 2012, 2016; Abdi et al. 2008; Viswanadham et al. 2009; Le et al. 2015) that investigated the behaviour of polypropylene fibre-reinforced soil and reported that an increase in fibre content caused an increase in strength and shrinkage potential but brought on the reduction of swelling potential. The length of fibres had an insignificant effect on soil characteristics, whereas fibre contents proved more influential and effective. A study on rubber fibre conducted by Hambirao and Rakaraddi (2014) mentions that tensile cracking of clays can be improved with the inclusion of short rubber fibres, optimum fibre content was about 15 % of weight of soil. Several experimental studies (Babu et al. 2008; Chaple and Dhatrak 2013; Vibhakar and Nahta 2014; Soundara and Senthilkumar 2015; Goyal et al. 2015; Jayasree et al. 2014, 2015) were conducted on coir fibre-reinforced soil and concluded that it helped in reducing the swell potential and 1% fibre by weight of the soil almost doubled the CBR value. Martins et al. (2015) found that 4% of sisal fibre by weight of the soil reduced the visibility of cracks. Pillai and Ayothiraman (2012), Ayothiraman et al. (2014) and Sahu et al. (2016) have demonstrated that human hair fibres can be used to improve the properties of both fine grained and coarse grained soils."

Jan 1, 1900

By Bráulio Pinto Terra

Devido à sua vasta aplicação, o estudo das propriedades mecânicas das superligas de níquel é de grande importância. A superliga 718 possui papel fundamental no funcionamento de grades espaçadoras em reatores nucleares. As grades espaçadoras são oriundas de chapas laminadas, submetidas a tratamentos térmicos de solubilização e de envelhecimento. O objetivo do presente trabalho é analisar a anisotropia das propriedades mecânicas de amostras de 0,3mm de espessura, tratadas termicamente por solubilização e envelhecimento, e testadas por tração uniaxial. Além disso, obteve-se os expoentes de encruamento nas condições estudadas, bem como o índice de anisotropia. Foi possível observar maiores valores de limite de escoamento e de alongamento para as amostras transversais provenientes de ambos tratamentos térmicos, enquanto o limite de resistência apresentou comportamento contrário, sendo os maiores valores oriundos das amostras longitudinais.

Oct 30, 2017

By Q Zhuo, P C. Pistorius, M N. Al-Harbi

A likely increasingly important pathway for future low-carbon ironmaking and steelmaking is the combination of gas-based direct reduction with electric furnace steelmaking (DRI-EAF route), or with electric smelting (DRI-ESF route). In the DRI-EAF route, the gangue that is present in the iron ore is fluxed and removed as slag in the melting (steelmaking) step. This is in contrast with integrated steelmaking, in which the gangue is removed as part of blast furnace ironmaking. For DRI-EAF steelmaking, the amount and composition of slag depend on the iron ore composition, flux additions and iron yield. Slag volume and composition affect phosphorus removal, foaming behaviour and the process energy requirements. In this work, heat data from a year of DRI-EAF production was analysed to test whether the expected relationship between slag volume and electricity consumption for EAF steelmaking was observed. The data include slag analyses (one sample per shift), and heatlevel information on all inputs, final steel temperature and dissolved oxygen concentration, electricity consumption, tapped steel mass and tap-to-tap time. In analysing the data, the slag volume was estimated from the assayed slag CaO concentration and CaO inputs to the EAF. The expected effect of slag volume on steelmaking energy consumption was calculated with a mass and energy balance, considering the heat of mixing of the slag. The calculated energy requirement of slag formation is in line with previous estimates reported in the literature.

Aug 21, 2024

By Pertti Koukkari, Nagendra Tripathi, Karri Penttilä, Justin Salmine

ChemSheet is a thermodynamic multi‐phase multi‐component simulation software, which is used as an Add‐in in Microsoft Excel. In ChemSheet, the unique Constrained Gibbs free energy method can be used to include dynamic constraints and reaction rates of kinetically slow reactions, yet retaining full consistency of the multiphase thermodynamic model. With appropriate data, ChemSheet models can be used to simulate reactors and processes in all fields of thermochemistry. The presentation will cover off‐line modeling of Cu‐flash smelters and advanced thermochemical simulation coupled with on‐line process control of Cu‐Ni smelting. The presentation will describe an off‐line model of Cu‐smelter based on critically assessed properties of the Al-Ca-Cu-Fe-O-S-Si –system (slag, matte and liquid metal) by using the quasichemical model. A four‐stage reactor model (shaft, settler, uptake and bath) is used for optimizing process parameters and feed particle distribution. As a second example, an advanced thermochemical model of a Ni-Cu sulphide smelting plant will be given. The on‐line model covers the operation of treating Ni-Cu-S concentrate via roasters, electric furnace and converters, producing a high grade Bessemer matte product for further refining. The model integrates the thermochemistry of the roasters and electric furnace, and predicts important process parameters such as degree of sulphur elimination in the fluid‐bed roasters, matte grade, iron metallization, slag losses and the iron to silica ratio in the electric furnace slag. Both models can be used to assist process engineers and operators in calculating the addition rates of coke, flux and air for different feed scenarios.

Jan 1, 2014

By Thierno FALL

This paper describes the study of the work-roll during the hot rolling process thanks to a 3D model built with the Finite Element Method (FEM). In terms of computational cost, that method needs high resources compared to 1D model which are mostly used. However, the 3D model is built to have a better understanding of the work-roll thermal and mechanical behavior during the hot rolling process. The thermal model shows that the highest temperature reached during rolling are within the range of 500°C and 600°C. The thermal field input used to simulate the mechanical behavior of the work-roll shows a biaxial thermal stress state, in the circumferential and axial planes. However, a peak of radial stress is observed in the backup zone. It did not generate plastic strain but could influence the fatigue behavior of the work-roll.

Oct 1, 2019

By Katsutoshi Inoue, Shafiq Alam

Several novel types of chemically modified chitosan were prepared by immobilizing functional groups of EDTA and DTPA onto polymer matrices of chitosan in order to investigate their potential for mutual adsorptive separation among rare earths. Following the batch wise adsorption tests to elucidate their basic adsorption characteristics for rare earths, mutual separation was carried out using a column packed with the chemically modified chitosan. The separation between Sm(III) and Y(III) was tested using a column packed with EDTA-type chitosan while mutual separation among 4 light rare earths, La(III), Ce(III), Pr(III) and Nd(III) was tested using a column packed with DTPA-type chitosan. In both cases, satisfactory mutual separation was achieved by the chromatographic operation using these chemically modified chitosan.

Jan 1, 2014

PRESIDENT MOSES: Mr. Hall, can you tell us something that will help our cause? R. DAWSON HALL: I did not want to tell anything; I wanted rather to say something, if. I said anything at all, about my impressions regarding the safety of the mines in the West. We heard yesterday how terribly dangerous they were, and I think that is due to the natural conditions. It is interesting to note that many of the developments of safety, which you will find all through the country, had their origin here in the Rocky Mountain States. It has not been because the Rocky Mountain States have been negligent - though, of course, they could have been more active - but it is becaues the conditions have been such as to make accidents more numerous. Rock dusting by mechanical means was used here before any other country adopted it, let alone the United States. It is true that rock dusting was started in England; but it was by hand, as it remained with the Victor -American Fuel Company to be the first to distribute rock dust by machines, and that is to the credit of Mr. Murray, who was the man that did the original dusting in those mines. It was at Delagua, they put up shelving and put dust on it; they used the adobe, and Mr. Pryde, at Reliance, very early in the game, put dust in the Reliance Mines, and some of the dust, I believe, is there yet but they can hardly find it for the new dust. That is not all. I believe it was first in the Utah Fuel Company's mine that incombustible clay was used for stemming, and in the East, where we were in the habit of using slack entirely, that was a big advantage. Another thing that the West has originated has been the wetting of the chain in cutting. The people in Alabama took a great deal of credit for having used that very early, but not as early as Mr. Brennan did at the Hanna Mine, he having used water on the cutter bits in 1913. Another development was that the Phelps Dodge Corporation were the first people to use, I believe in the United States, storage battery locomotives for main haulage, and while they didn't go ahead with that, so far as putting in power trucks and mining machines, until just recently-I think the Consolidation Coal Company in the East managed to get ahead of them in that development,-notwith-standing, they were the earliest to use it for main haulage. When I came through this section of the country, in 1912, I think it was, I went through the mines of the Union Pacific Coal Company. I was surprised to see the extent to which fire-proofing had been carried out in that mine, with regard to non-combustible brattices and overcasts, which were of concrete; even the boxes were covered with sheet metal. They were very far ahad of us in that respect; far, far ahead of us in the East, because the East has its favorable conditions in the fact that most of the lump in the mines is more or less wet all the time. Another safety provision which has been taken by the Utah Fuel Company, was shooting from the surface. That has not spread very much in the, East, but it has been used in Oklahoma and the middle West. I think there is plenty of evidence that the Western people have been thinking for themselves, in going ahead and' establishing new standards in Safety. One of the most unusual things is this Safety Committee, permanent Safety Committee of the Rocky Mountain Coal Mining Institute, which has been endeavoring here to find out the conditions under which safety cant best be practiced. I think it is those who venture to. criticize the West that) have to show that in the East there is not the spirit which has led the Rocky Mountain region to endeavor to reduce its very terrible death rate that really exists. It has to be faced and it furnishes a cause, an incentive; for further work toward safety; but none can deny that the desire of the western mining man has been to find

Jan 1, 1926

By W. G. Davenport

Chapter 4 examined Inco (oxygen) flash smelting of pure chalcopyrite concentrate. It showed that the oxygen and flux requirements for auto thermal smelting are readily determined by a matrix calculation. This chapter extends this matrix approach by applying it to a multi-mineral concentrate.

Jan 1, 2001

By Nath S. Parate

With the extension of mining beneath residential and industrial areas, it is becoming increasingly necessary to extract coal and minerals in such a way that subsidence damage due to groundmovement is reduced to a minimum. Understanding clearly of the mechanism of subsidence development is a must in view of the environmental problems and the energy crisis today. This paper gives a simple analysis of various components resulting from subsidence and the influence of other factors on their development. An up-to-date review of the subsidence and strain profiles is presented, with particular references to the coal mining operations. The importance of this topic from mining damage to structures, buildings properties and environment in mining areas is undeniable. Field results are discussed.

Jan 1, 1982

By X. J. Wu

Effects of various factors such as diaphragm materials, composition of electrolytes and current density on copper electrowinning from cupric chloride solutions was investigated. It is found that the crux of this process is to prevent the dissolution of copper by cupric ion and the formation of suspended CuCl precipitate. A process with high difference of copper concentrations between the feed solution and the spent electrolyte was selected. With this process, in which the feed solution contains 90 g/dm3 [Cu"], 3M NaC1, and 10mg/dm3 bone glue, and the spent electrolytes contains 10 g/dm3 [Cul, a very smooth and dense copper cathode can be produced with current efficiency above 93% and energy requirement less than 1.7 kwh/kg Cu at 25°C with N2 sparging. If a slightly higher energy requirement is permitted, smooth and dense copper cathodes can be produced at the current density up to 800 A/m2 with the identical solutions.

Jan 1, 1991